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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Graphite Fluoride Fiber Composites For Heat Sinking

Graphite fluoride fiber/polymer composite materials consist of graphite fluoride fibers in epoxy, polytetrafluoroethylene, or polyimide resin. Combines high electrical resistivity with high thermal conductivity and solves heat-transfer problems of many electrical systems. Commercially available in powder form, for use as dry lubricant or cathode material in lithium batteries. Produced by direct fluorination of graphite powder at temperature of 400 to 650 degree C. Applications include printed-circuit boards for high-density power electronics, insulators for magnetic-field cores like those found in alternators and transformers, substrates for thin-film resistors, and electrical-protection layers in aircraft de-icers.

Hung, Ching-Cheh↗

Regional sources and sinks of dust on Mars: Viking observations of Cerberus, Solis Planum, and Syrtis Major

A study of seasonal variation of albedo features in the Cerberus, Solis Planum, and Syrtis Major regions was based on Viking Orbiter data obtained over more than one complete Martian year. Contour maps of Lambert albedo and single point thermal inertia were constructed from the Infrared Thermal Mapper experiment data, and Orbiter images were used to determine the pattern and variability of regional winds (inferred from wind streak orientations). Coupled with ground based radar data, these data allow the regional sediment transport direction, surface properties (texture, morphology, and roughness), and the implications of the observed seasonal and longer term dust redistribution to be investigated. Results are outlined.

Lee, Steven W.↗

Mineralogical sinks for biogenic elements on Mars

The efficacy of biochemical reactions on Mars should depend not only on concentrations of the biogenic elements H, C, N, O, and S but also on the forms (compounds and water-souble ions) that are available to those elements. It is possible that mineralogical reactions could act to lock biogenic elements into relatively inaccessible inorganic forms or, alternatively, to shelter sensitive organic compounds from chemically hostile environments. Recognition of these competing pathways is essential in planning sampling mission and in situ experiments directed toward assessing the biological potential of Mars.

Gooding, J. L.↗

Effects Of Heat Sinks On VPPA Welds

Report describes theoretical and experimental study of absorption of heat by metal blocks in contact with metal plate while plate subjected to variable-polarity plasma-arc (VPPA) welding. Purpose of study to contribute to development of comprehensive mathematical model of temperature in weld region. Also relevant to welding of thin sheets of metal to thick blocks of metal, heat treatment of metals, and hotspots in engines.

Nunes, Arthur C.↗

Source And Sink Of Iodine For Drinking Water

Proposed system for controlling concentration of iodine in potable water exploits temperature dependence of equilibrium partition of iodine between solution in water and residence in ion-exchange resin. Used to maintain concentration of iodine sufficient to kill harmful microbes, but not so great to make water unpalatable. Requires little attention, yet controls concentration of iodine more precisely than iodination and deiodination by manual techniques. Conceived for use aboard spacecraft, system has terrestrial applications in regions where water must be kept potable, resupply difficult, and system must operate largely unattended.

Sauer, Richard L.↗

An investigation of the atmospheric sources and sinks of Methyl Bromide

Methyl Bromide (CH3Br) is a ubiquitous component of the atmosphere and has been implicated as an important player in the depletion of stratospheric ozone. Atmospheric CH3Br abundances, interhemispheric gradients, oceanic concentrations, man-made emissions, and removal processes have been analyzed and interpreted with the help of a simple box model and a 2D global photochemical model. Its calculated atmospheric lifetime (T) of 1.7-1.9 years, based on reaction with OH radicals, is consistent with a global source of 90-110 Gg (10 exp 9 g)/year. Consequences of a much shorter lifetime of 1.2 years, due to possible deposition/hydrolysis losses, are also considered. Available data are used to estimate a CH3Br source that is 35 percent (20-50 percent) man-made and 65 percent (80-50 percent) natural. Oceans are substantially supersaturated and provide the most important natural source of about 60 (40-80) Gg/year.

Singh, Hanwant B.↗

Atmospheric sulfur hexafluoride - Sources, sinks and greenhouse warming

An estimate is obtained of worldwide production of SF6, from which a global emission rate is derived and extrapolated for the next 20 years. The atmospheric lifetime of SF6 is then estimated based on a known mechanism (e.g., photolysis and atmospheric oxidation) and/or on the mass balance method. Finally, the radiative forcing of SF6 is calculated based on recent laboratory IR absorption data, and the expected warming over the time period 1950-2010 is computed for several emission scenarios. Calculations showed that SF6 is 3 times more effective as a greenhouse gas compared to CFC 11 on a per-molecule basis. However, based on projected emission scenarios, the expected warming from SF6 through 2010 is small (0.004 C), compared to the warming from CO2 and other trace gases (0.8 C).

Ko, Malcolm K. W.↗

Atmospheric Sulfur Hexafluoride: Sources, Sinks and Greenhouse Warming

Model calculations using estimated reaction rates of sulfur hexafluoride (SF6) with OH and 0('D) indicate that the atmospheric lifetime due to these processes may be very long (25,000 years). An upper limit for the UV cross section would suggest a photolysis lifetime much longer than 1000 years. The possibility of other removal mechanisms are discussed. The estimated lifetimes are consistent with other estimated values based on recent laboratory measurements. There appears to be no known natural source of SF6. An estimate of the current production rate of SF6 is about 5 kt/yr. Based on historical emission rates, we calculated a present-day atmospheric concentrations for SF6 of about 2.5 parts per trillion by volume (pptv) and compared the results with available atmospheric measurements. It is difficult to estimate the atmospheric lifetime of SF6 based on mass balance of the emission rate and observed abundance. There are large uncertainties concerning what portion of the SF6 is released to the atmosphere. Even if the emission rate were precisely known, it would be difficult to distinguish among lifetimes longer than 100 years since the current abundance of SF6 is due to emission in the past three decades. More information on the measured trends over the past decade and observed vertical and latitudinal distributions of SF6 in the lower stratosphere will help to narrow the uncertainty in the lifetime. Based on laboratory-measured IR absorption cross section for SF6, we showed that SF6 is about 3 times more effective as a greenhouse gas compared to CFC 11 on a per molecule basis. However, its effect on atmospheric warming will be minimal because of its very small concentration. We estimated the future concentration of SF6 at 2010 to be 8 and 10 pptv based on two projected emission scenarios. The corresponding equilibrium warming of 0.0035 C and 0.0043 C is to be compared with the estimated warming due to CO2 increase of about 0.8 C in the same period.

Sze, Nien Dak↗

An Analysis and Procedure for Determining Space Environmental Sink Temperatures With Selected Computational Results

The purpose of this report was to analyze the heat-transfer problem posed by the determination of spacecraft temperatures and to incorporate the theoretically derived relationships in the computational code TSCALC. The basis for the code was a theoretical analysis of the thermal radiative equilibrium in space, particularly in the Solar System. Beginning with the solar luminosity, the code takes into account these key variables: (1) the spacecraft-to-Sun distance expressed in astronomical units (AU), where 1 AU represents the average Sun-to-Earth distance of 149.6 million km; (2) the angle (arc degrees) at which solar radiation is incident upon a spacecraft surface (ILUMANG); (3) the spacecraft surface temperature (a radiator or photovoltaic array) in kelvin, the surface absorptivity-to-emissivity ratio alpha/epsilon with respect to the solar radiation and (alpha/epsilon)(sub 2) with respect to planetary radiation; and (4) the surface view factor to space F. Outputs from the code have been used to determine environmental temperatures in various Earth orbits. The code was also utilized as a subprogram in the design of power system radiators for deep-space probes.

Juhasz, Albert J.↗

Sources, Sinks, and the Distribution of OH in the Lower Stratosphere

Extensive measurement campaigns by the NASA ER-2 research aircraft have obtained a nearly pole-to-pole database of the species that control HOx (OH + HO2) chemistry. The wide dynamic range of these in situ measurements provides an opportunity to demonstrate empirically the mechanisms that control the HOx system. Measurements in the lower stratosphere show a remarkably tight correlation of OH concentration with the solar zenith angle (SZA). This correlation is nearly invariant over latitudes ranging from 70 S to 90 N and all seasons. An analysis of the production and loss of HOx in terms of the rate determining steps of reaction sequences developed by Johnston and Podolske and Johnston and Kinnison is used to clarify the behavior of the system and to directly test our understanding of the system with observations. Calculations using in situ measurements show that the production rate of HOx is proportional to O3 and ultraviolet radiation flux. The loss rate is proportional to the concentration and the partitioning of NOy (reactive nitrogen) and the concentration of HO2. In the absence of heterogeneous reactions, the partitioning of NOy is controlled by O3 and NOx and the concentration of HO2 is controlled by NOy and O3, so that the removal rate of OH is buffered against changes in the correlation of O3 and NOy. The heterogeneous conversion of NO2 to HNO3 is not an important net source of HO, because production and removal sequences are nearly balanced. Changes in NOy partitioning resulting from heterogeneous chemistry have a large effect on the loss rates of HOx, but little or no impact on the measured abundance of OH. The enhanced loss rates at high NO2/HNO3 are offset in the data set examined here by enhanced production rates resulting from increased photolysis rates resulting from the decreased O3 column above the ER-2.

Hanisco, T. F.↗

Sink or Swim

The traditional view of career development in the government goes something like this: Start your career as a functional apprentice. Become a functional expert over time by exhibiting technical leadership (whatever that means). Over time, seek out positions of increasingly greater responsibility with corresponding job titles. Make a gradual transition from a specialty focus to a managerial focus. Along the way submit to some vaccinations such as getting a Masters or PhD degree, attending some prestige courses, accepting a Headquarters assignment, and working at two or more field locations. Show some significant persistence and heaps of personal sacrifice. Avoid the big mistake. Burn no bridges.

Little, Terry↗

Constraining Oceanic Sources and Sinks of CO2 by Inverse Modeling: A First Step Toward Assimilation of In Situ and Remote Data

The primary goal of this collaborative project, lead by Nicholas Gruber at UCLA, is to better quantify the air-sea fluxes of pre-industrial and anthropogenic carbon dioxide CO2 for the global ocean with a newly developed inverse method. The method involves using ocean general circulation models (OGCMs) to characterize the subsurface distribution of tracers injected for different regions of the ocean surface. By linearly combining a series of these basis (or Greens) functions, one should be able to recreate any arbitrary ocean tracer field. In our case, we are using the global database of ocean dissolved inorganic carbon (DIC) from the WOCE/JGOFS global CO2 survey from the 1990s. The observed DIC field has been partitioned into pre-industrial and anthropogenic components using the empirical C* technique. We then solve for an optimal combination of the regional basis functions that best match the two sets observations in a least-squares sense with singular value decomposition. This in turn provides solutions for the regional air-sea CO2 fluxes (pre-industrial and anthropogenic) that are independent of more traditional estimates derived from surface water disequilibria in the partial pressure of CO2 and wind speed gas exchange parameterizations. We are apply the method to a suite of nine different OGCMs to test the robustness of the derived surface fluxes fields to differences in ocean circulation. Together with a collegue Keith Lindsay at NCAR, S. Doney's role in this project was to create the appropriate steady-state and temporally evolving basis functions from the NCAR CSM-1 ocean circulation model. Because of a slow start across the project in defining a common set of experimental protocols, we requested and were given a one year, no cost extension. Both the steady-state and temporally evolving basis functions were delivered to the UCLA group for further analysis. Additional information is included in the original extended abstract.

Doney, Scott↗

The Martian Soil as a Geochemical Sink for Hydrothermally Altered Crustal Rocks and Mobile Elements: Implications of Early MER Results

Hydrothermal and aqueous alteration can explain some of the exciting results from the MER team s analyses of the martian soil, including the major elements, mobile elements, and the nickel enrichment. Published results from the five lander missions lead to the following conclusions: 1) The soil appears to be globally mixed and basaltic with only small local variations in chemistry. Relative to martian basaltic meteorites and Gusev rocks the soils are depleted in the fluid-mobile element calcium, but only slightly enriched to somewhat depleted in iron oxide. 2) The presence of olivine in the soils based on M ssbauer data argues that the soil is only partly weathered and is more akin to a lunar regolith than a terrestrial soil. 3) The presence of bromine along with sulfur and chlorine in the soils is consistent with addition of a mobile element component to the soil.

Newsom, H. E.↗