Search NASA⌕ Search

SEARCH · Search NASA

Results for “SUBLIMATION HEAT”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11

Triton's global heat budget

Internal heat flow from radioactive decay in Triton's interior along with absorbed thermal energy from Neptune total 5 to 20 percent of the isolation absorbed by Triton, thus comprising a significant fraction of Triton's surface energy balance. These additional energy inputs can raise Triton's surface temperature between about 0.5 and 1.5 K above that possible with absorbed sunlight alone, resulting in an increase of about a factor of about 1.5 to 2.5 in Triton's basal atmospheric pressure. If Triton's internal heat flow is concentrated in some areas, as is likely, local effects such as enhanced sublimation with subsequent modification of albedo could be quite large. Furthermore, indications of recent global albedo change on Triton suggest that Triton's surface temperature and pressure may not now be in steady state, further suggesting that atmospheric pressure on Triton was as much as ten times higher in the recent past.

Brown, R. H.↗

Thermal modeling of cometary nuclei

A model of the sublimation of volatile ices from a cometary nucleus is presented which includes the effects of (1) diurnal heating and cooling, (2) rotation period and pole orientation, (3) the thermal properties of the ice and subsurface layers, and (4) the contributions from coma opacity, scattering and thermal emission where the properties of the coma are derived from the integrated rate of volatile production by the nucleus. In applying the model to the case of the 1986 apparition of Halley's comet, it is found that the generation of a cometary dust coma increases the total energy reaching the Halley nucleus due to the greater geometrical cross-section of the coma as compared with the bare nucleus. The calculated coma opacity of Halley is about 0.2 at 1 AU from the sun and 1.2 at perihelion. Possible consequences of the results obtained for the generation of nongravitational forces, volatile production rates for comets and cometary lifetimes against sublimation are discussed.

Weissman, P. R.↗

Local heat/mass transfer and pressure drop in a two-pass rib-roughened channel for turbine airfoil cooling

The heat transfer characteristics of turbulent air flow in a multipass channel were studied via the naphthalene sublimation technique. The naphthalene-coated test section, consisting of two straight, square channels joined by a 180 deg turn, resembled the internal cooling passages of gas turbine airfoils. The top and bottom surfaces of the test channel were roughened by rib turbulators. The rib height-to-hydraulic diameter ratio (e/D) were 0.063 and 0.094, and the rib pitch-to-height ratio (P/e) were 10 and 20. The local heat/mass transfer coefficients on the roughened top wall and on the smooth divider and side walls of the test channel were determined for three Reynolds numbers of 15, 30, and 60, thousand, and for three angles of attack (alpha) of 90, 60, and 45 deg. Results showed that the local Sherwood numbers on the ribbed walls were 1.5 to 6.5 times those for a fully developed flow in a smooth square duct. The average ribbed-wall Sherwood numbers were 2.5 to 3.5 times higher than the fully developed values, depending on the rib angle of attack and the Reynolds number. The results also indicated that, before the turn, the heat/mass transfer coefficients in the cases of alpha = 60 and 45 deg were higher than those in the case of alpha=90 deg. However, after the turn, the heat/mass transfer coefficients in the oblique-rib cases were lower than those in the transverse rib case. Correlations for the average Sherwood number ratios for individual channel surfaces and for the overall Sherwood number ratios are reported. Correlations for the fully developed friction factors and for the loss coefficients are also provided.

Han, J. C.↗

MSL MMRTG Power Modeling for Lifetime Performance Predictions

The Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) has been providing power to the Mars Science Laboratory (MSL) rover, Curiosity, for surface operations since 2012. The Jet Propulsion Laboratory (JPL) has employed the Life Performance Prediction Model (LPPM) to generate predictions and outputs based upon flight data from the rover and experimental data from the thermoelectric (TE) couples. In order to make these predictions, LPPM requires various spacecraft inputs relevant to RTG performance such as fin root temperature, load voltage, general purpose heat source (GPHS) inventory, etc., combined with couple data such as thermoelectric properties, interface degradation, and sublimation properties. With tens of thousands of hours of flight data to date, LPPM can not only track performance to date, but also make predictions on the power output of the MMRTG through the 17-year end-of-design-life (EODL). These predictions are useful for mission planners and surface operators who rely on the MMRTG for power in order to perform the critical science necessary during the mission. This paper will showcase the power data extracted from the flight electronics, comparing it to the predictions and outputs generated from LPPM.

Pinkowski, Stanley↗

Coating Thermoelectric Devices To Suppress Sublimation

A technique for suppressing sublimation of key elements from skutterudite compounds in advanced thermoelectric devices has been demonstrated. The essence of the technique is to cover what would otherwise be the exposed skutterudite surface of such a device with a thin, continuous film of a chemically and physically compatible metal. Although similar to other sublimation-suppression techniques, this technique has been specifically tailored for application to skutterudite antimonides. The primary cause of deterioration of most thermoelectric materials is thermal decomposition or sublimation - one or more elements sublime from the hot side of a thermoelectric couple, changing the stoichiometry of the device. Examples of elements that sublime from their respective thermoelectric materials are Ge from SiGe, Te from Pb/Te, and now Sb from skutterudite antimonides. The skutterudite antimonides of primary interest are CoSb3 [electron-donor (n) type] and CeFe(3-x)Co(x)Sb12 [electron-acceptor (p) type]. When these compounds are subjected to typical operating conditions [temperature of 700 C and pressure <10(exp -5) torr (0.0013 Pa)], Sb sublimes from their surfaces, with the result that Sb depletion layers form and advance toward their interiors. As the depletion layer advances in a given device, the change in stoichiometry diminishes the thermal-to-electric conversion efficiency of the device. The problem, then, is to prevent sublimation, or at least reduce it to an acceptably low level. In preparation for an experiment on suppression of sublimation, a specimen of CoSb3 was tightly wrapped in a foil of niobium, which was selected for its chemical stability. In the experiment, the wrapped specimen was heated to a temperature of 700 C in a vacuum of residual pressure <10(exp -5) torr (0.0013 Pa), then cooled and sectioned. Examination of the sectioned specimen revealed that no depletion layer had formed, indicating the niobium foil prevented sublimation of antimony at 700 C. This was a considerable improvement, considering that uncoated CoSb3 had been found to decompose to form the lowest antimonide at the surface at only 600 C. Evidently, because the mean free path of Sb at the given temperature and pressure was of the order of tens of centimeters, any barrier closer than tens of centimeters (as was the niobium foil) would have suppressed transport of Sb vapor, thereby suppressing sublimation of Sb

Sakamoto, Jeffrey↗

Modeling of Heat and Mass Transfer in a TEC-Driven Lyophilizer

Dewatering of wet waste during space exploration missions is important for crew safety as it stabilizes the waste. It may also be used to recover water and serve as a preconditioning step for waste compaction. A thermoelectric cooler (TEC)-driven lyophilizer is under development at NASA Ames Research Center for this purpose. It has three major components: (i) an evaporator section where water vapor sublimes from the frozen waste, (ii) a condenser section where this water vapor deposits as ice, and (iii) a TEC section which serves as a heat pump to transfer heat from the condenser to the evaporator. This paper analyses the heat and mass transfer processes in the lyophilizer in an effort to understand the ice formation behavior in the condenser. The analysis is supported by experimental observations of ice formation patterns in two different condenser units.

Yuan, Zeng-Guang↗

Analysis of surface ablation of noncharring materials

Computer program solves combined problem of heat transfer and material response for the stagnation region of blunt bodies experiencing melting and vaporizing or subliming ablation. Program contains formulas for the transitional regime to bridge between the free-molecule and continuum regimes.

Matting, F. W.↗

Comparison of Ablation Predictions for Carbonaceous Materials Using CEA and JANAF-Based Species Thermodynamics

In most previous work at NASA Ames Research Center, ablation predictions for carbonaceous materials were obtained using a species thermodynamics database developed by Aerotherm Corporation. This database is derived mostly from the JANAF thermochemical tables. However, the CEA thermodynamics database, also used by NASA, is considered more up to date. In this work, the FIAT code was modified to use CEA-based curve fits for species thermodynamics, then analyses using both the JANAF and CEA thermodynamics were performed for carbon and carbon phenolic materials over a range of test conditions. The ablation predictions are comparable at lower heat fluxes where the dominant mechanism is carbon oxidation. However, the predictions begin to diverge in the sublimation regime, with the CEA model predicting lower recession. The disagreement is more significant for carbon phenolic than for carbon, and this difference is attributed to hydrocarbon species that may contribute to the ablation rate.

Milos, Frank S.↗

Propulsion System Development for the Iodine Satellite (iSAT) Demonstration Mission

The development and testing of a 200-W iodine-fed Hall thruster propulsion system that will be flown on a 12-U CubeSat is described. The switch in propellant from more traditional xenon gas to solid iodine yields the advantage of high density, low pressure propellant storage but introduces new requirements that must be addressed in the design and operation of the propulsion system. The thruster materials have been modified from a previously-flown xenon Hall thruster to make it compatible with iodine vapor. The cathode incorporated into this design additionally requires little or no heating to initiate the discharge, reducing the power needed to start the thruster. The feed system produces iodine vapor in the propellant reservoir through sublimation and then controls the flow to the anode and cathode of the thruster using a pair of proportional flow control valves. The propellant feeding process is controlled by the power processing unit, with feedback control on the anode flow rate provided through a measure of the thruster discharge current. Thermal modeling indicates that it may be difficult to sufficiently heat the iodine if it loses contact with the propellant reservoir walls, serving to motivate future testing of that scenario to verify the modeling result and develop potential mitigation strategies. Preliminary, short-duration materials testing has thus-far indicated that several materials may be acceptable for prolonged contact with iodine vapor, motivating longer-duration testing. A propellant loading procedure is presented that aims to minimize the contaminants in the feed system and propellant reservoir. Finally, an 80-hour duration test being performed to gain experience operating the thruster over long durations and multiple restarts is discussed.

Polzin, Kurt A.↗

Controls on the CO2 seasonal cycle

Surface pressure measurement performed by the Viking landers show substantial variations in pressure on seasonal timescales that are characterized by two local minima and two local maxima. These variations have widely been attributed to the seasonal condensation and sublimation of CO2 in the two polar regions. It has been somewhat of a surprise that the amplitude of the minimum and maximum that is dominated by the CO2 cycle in the north was much weaker than the corresponding amplitude of the south-dominated extrema. Another surprise was that the seasonal pressure cycle during years 2 and 3 of the Viking mission was so similar to that for year 1, despite the occurrence of two global dust storms during year 1 and none during years 2 and 3. An energy balance model that incorporates dynamical factors from general circulation model (GCM) runs in which the atmospheric dust opacity and seasonal date were systematically varied was used to model the observed seasonal pressure variations. The energy balance takes account of the following processes in determining the rates of CO2 condensation and sublimation at each longitudinal and latitudinal grid point: solar radiation, infrared radiation from the atmosphere and surface, subsurface heat conduction, and atmospheric heat advection. Condensation rates are calculated both at the surface and in the atmosphere. In addition, the energy balance model also incorporates information from the GCM runs on seasonal redistribution of surface pressure across the globe. Estimates of surface temperature of the seasonal CO2 caps were used to define the infrared radiative losses from the seasonal polar caps. The seasonal pressure variations measured at the Viking lander sites were closely reproduced.

Pollack, J. B.↗

Space Evaporator Absorber Radiator (SEAR) for Thermal Storage on Manned Spacecraft

Future manned exploration spacecraft will need to operate in challenging thermal environments. State-of-the-art technology for active thermal control relies on sublimating water ice and venting the vapor overboard in very hot environments, and or heavy phase change material heat exchangers for thermal storage. These approaches can lead to large loss of water and a significant mass penalties for the spacecraft. This paper describes an innovative thermal control system that uses a Space Evaporator Absorber Radiator (SEAR) to control spacecraft temperatures in highly variable environments without venting water. SEAR uses heat pumping and energy storage by LiCl/water absorption to enable effective cooling during hot periods and regeneration during cool periods. The LiCl absorber technology has the potential to absorb over 800 kJ per kg of system mass, compared to phase change heat sink systems that typically achieve approx. 50 kJ/kg. This paper describes analysis models to predict performance and optimize the size of the SEAR system, estimated size and mass of key components, and an assessment of potential mass savings compared with alternative thermal management approaches. We also describe a concept design for an ISS test package to demonstrate operation of a subscale system in zero gravity.

Izenson, Michael G.↗

Determination of surface shear stress with the naphthalene sublimation technique

Aeolian entrainment and transport are functions of surface shear stress and particle characteristics. Measuring surface shear stress is difficult, however, where logarithmic wind profiles are not found, such as regions around large roughness elements. An outline of a method whereby shear stress can be mapped on the surface around an object is presented. The technique involves the sublimation of naphthalene (C10H8) which is a function of surface shear stress and surface temperature. This technique is based on the assumption that the transfer of momentum, heat and mass are analogous (Reynolds analogy). If the Reynolds analogy can be shown to be correct for a given situation, then knowledge of the diffusion of one property allows the determination of the others. The analytical framework and data acquisition for the method are described. The technique was tested in the Planetary Geology Wind Tunnel. Results show that the naphthalene sublimation technique is a reasonably accurate method for determining shear stress, particularly around objects where numerous point values are needed.

Lee, J. A.↗

Atmospheric entry of Mars-return nuclear-powered vehicles due to accidental termination of operations

The entry of nuclear reactors into Earth's atmosphere resulting from an accidental or inadvertent abort of a space vehicle powered by nuclear-thermal rockets is investigated. The study is made for a typical piloted Mars mission vehicle incapacitated by an accident or malfunction during the Earth-arrival phase of the Mars-return journey due to simultaneous, multiple failures of its component systems. A single accident/abort scenario resulting in three entry possibilities is considered for a nominal hyperbolic in-bound approach velocity of 8 km/sec. The most severe case involving a direct entry is then analyzed over a broad range of approach velocities extending to 12 km/sec to include sprint-type missions. The results indicate that the severe surface heating, stagnation pressures, and g-loads are greater than 150 kW/sq cm, 300 atm, and 800-g, respectively. The wall heat transfer rate exceeds the value that can be accommodated by a carbon heatshield through radiation equilibrium prior to sublimation at 5500 K. These conditions are beyond our previous experience in crew safety, structural design, and thermal protection.

Menees, Gene P.↗

The role of nonuniform internal heating in Triton's energy budget

Triton's large heliocentric distance and high albedo, combined with its unusually large silicate mass fraction, make internal heating more important in its energy budget than in that of any other icy satellite. Brown et al. have recently estimated that the average radiogenic heat flux (which is probably between 3.3 and 6.6 mW/sq m depending on core size and composition) may equal 5 to 20 pct. of the average absorbed insolation. On a global scale, this additional energy input appreciably increases the thermal emissivity required to be consistent with the observed surface temperature. Brown et al. also speculated that spatial variations of the internal flux may change the local sublimation deposition balance enough to lead to observable modifications of the distribution of volatiles on Triton's surface. An attempt is made to estimate the magnitude of internal heat flux variations due to the insulating effect of the polar caps, to mantle convection, and to cryovolcanism; the importance is evaluated of these variations in modifying the volatile distribution.

Kirk, R. L.↗

Space-Based Solar Power Conversion and Delivery Systems Study. Volume 3: Microwave Power Transmission Studies

The Microwave Fower Beam Ionosphere effects and critical interfaces between th Microwave Power Transmission System (MPTS) and the Satellite were studied as part of the NASA/MSFC continuing research on the feasibility of power transmission from geosynchronous orbit. Theoretical predications of ionospheric modifications produced by the direct interaction of the MPTS on the earth's upper atmosphere are used to determine their impact on the performance of the Microwave Power Beam and Pilot Beam System as well as on other RF systems effected by the ionosphere. A technology program to quantitatively define these interactions is developed. Critical interface areas between the MPTS and the satellite which could have a major impact on cost and performance of the power system are idenfified and analyzed. The areas selected include: use of either a 20 kV versus 40 kV Amplitron, thermal blockage effects of Amplitron heat radiation by the satellite structure, effect of dielectric carry-through structure on power beam, and effect of material sublimation on performance of the Amplitron in Geosynchronous Orbit.

Source record↗

A numerical simulation of climate changes during the obliquity cycle on Mars

A one-dimensional seasonal energy balance climate model of the Martian surface is developed. The model shows the importance of using short-period diurnal and seasonal variations of solar irradiance instead of yearly-averaged quantities. The roles of meridional heat transport and greenhouse warming are shown to be important. The possible existence of hysteresis cycles in the formation and sublimation of permanent deposits during the course of the obliquity cycle is demonstrated.

Francois, L. M.↗

Study of Aerothermodynamic Modeling Issues Relevant to High-Speed Sample Return Vehicles

This paper examines the application of state-of-the-art coupled ablation and radiation simulations to highspeed sample return vehicles, such as those returning from Mars or an asteroid. A defining characteristic of these entries is that the surface recession rates and temperatures are driven by nonequilibrium convective and radiative heating through a boundary layer with significant surface blowing and ablation products. Measurements relevant to validating the simulation of these phenomena are reviewed and the Stardust entry is identified as providing the best relevant measurements. A coupled ablation and radiation flowfield analysis is presented that implements a finite-rate surface chemistry model. Comparisons between this finite-rate model and a equilibrium ablation model show that, while good agreement is seen for diffusion-limited oxidation cases, the finite-rate model predicts up to 50% lower char rates than the equilibrium model at sublimation conditions. Both the equilibrium and finite rate models predict significant negative mass flux at the surface due to sublimation of atomic carbon. A sensitivity analysis to flowfield and surface chemistry rates show that, for a sample return capsule at 10, 12, and 14 km/s, the sublimation rates for C and C3 provide the largest changes to the convective flux, radiative flux, and char rate. A parametric uncertainty analysis of the radiative heating due to radiation modeling parameters indicates uncertainties ranging from 27% at 10 km/s to 36% at 14 km/s. Applying the developed coupled analysis to the Stardust entry results in temperatures within 10% of those inferred from observations, and final recession values within 20% of measurements, which improves upon the 60% over-prediction at the stagnation point obtained through an uncoupled analysis. Emission from CN Violet is shown to be over-predicted by nearly and order-of-magnitude, which is consistent with the results of previous independent analyses. Finally, the coupled analysis is applied to a 14 km/s Earth entry representative of a Mars sample return. Although the radiative heating provides a larger fraction of the total heating, the influence of ablation and radiation on the flowfield are shown to be similar to Stardust.

Johnston, Christopher O.↗

Numerical Model Studies of the Martian Mesoscale Circulations

Studies concerning mesoscale topographical effects on Martian flows examined low-level jets in the near equatorial latitudes and the dynamical intensification of flow by steep terrain. Continuation of work from previous years included evaluating the dissipation of cold air mass outbreaks due to enhanced sensible heat flux, further sensitivity and scaling evaluations for generalization of the characteristics of Martian mesoscale circulation caused by horizontal sensible heat-flux gradients, and evaluations of the significance that non-uniform surface would have on enhancing the polar CO2 ice sublimation during the spring. The sensitivity of maximum and minimum atmospheric temperatures to changes in wind speed, surface albedo, and deep soil temperature was investigated.

Segal, M.↗