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At least 199 records · Page 11

Concentrations of ethane (C2H6) in the lower stratosphere and upper troposphere and acetylene (C2H2) in the upper troposphere deduced from Atmospheric Trace Molecule Spectroscopy/Spacelab 3 spectra

This paper reports the results of the spectroscopic analysis of C2H6 and C2H2 absorption spectra obtained by the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument flown on the Shuttle as part of the Spacelab 3 mission. The spectra were recorded during sunset occultations occurring between 25 deg N and 31 deg N latitudes, yielding volume-mixing ratio profiles of C2H6 in the lower stratosphere and the upper troposphere, and an upper tropospheric profile of C2H2. These results compare well with previous in situ and remote sounding data obtained at similar latitudes and with model calculations. The results demonstrate the feasibility of the ATMOS instrument to sound the lower atmosphere from space.

Rinsland, C. P.↗

Isoprene over the Amazon Basin

Data obtained during the 1985 ABLE expedition to the Amazon are used to describe the diurnal and vertical variations of isoprene. Isoprene is a natural hydrocarbon emitted by many species of trees, particularly those in tropical forests. The concentrations of isoprene at lower levels in the atmosphere undergo large diurnal variations, with the highest concentrations during midday and the lowest during the night. At ground level, outside the forest, peak concentrations of about 3-parts per billion by volume (ppbv) of isoprene were observed around midday. Concentrations were nearly zero before sunrise, increased to their maximum values during the day, and declined after sunset. Concentrations of 1-2 ppbv of isoprene were observed up to 300 m. Near the canopy level, up to 8 ppbv of isoprene were observed. In the forest, concentrations are generally quite low below the canopy and are highest at the level of the canopy. Since the reaction of isoprene with OH radicals is extremely fast, its concentrations fall off rapidly with altitude, so that practically none of it was seen above the boundary layer. During nighttime, however, concentrations comparable to daytime values were observed at altitudes of 300 m and above.

Rasmussen, R. A.↗

Nighttime and daytime variation of atmospheric NO2 from ground-based infrared measurements

During the period of Feb. 28 to Mar. 2, 1986, 19 high resolution atmospheric spectra have been recorded during the night using the moon or during the day using the sun as a source with the Fourier transform spectrometer at the McMath Solar telescope on Kitt Peak. The NO2 absorption peak located at 2914.65/cm has been used to derive from the spectra the total vertical column densities of atmospheric NO2. A rather rapid decrease of the NO2 amount during the night has been observed, and its daytime increase from sunrise to sunset has been confirmed. A comparison with the predictions of a photochemical model is given.

Flaud, J.-M.↗

Effect of ephemeris errors on the accuracy of the computation of the tangent point altitude of a solar scanning ray as measured by the SAGE 1 and 2 instruments

An analysis was made of the error in the minimum altitude of a geometric ray from an orbiting spacecraft to the Sun. The sunrise and sunset errors are highly correlated and are opposite in sign. With the ephemeris generated for the SAGE 1 instrument data reduction, these errors can be as large as 200 to 350 meters (1 sigma) after 7 days of orbit propagation. The bulk of this error results from errors in the position of the orbiting spacecraft rather than errors in computing the position of the Sun. These errors, in turn, result from the discontinuities in the ephemeris tapes resulting from the orbital determination process. Data taken from the end of the definitive ephemeris tape are used to generate the predict data for the time interval covered by the next arc of the orbit determination process. The predicted data are then updated by using the tracking data. The growth of these errors is very nearly linear, with a slight nonlinearity caused by the beta angle. An approximate analytic method is given, which predicts the magnitude of the errors and their growth in time with reasonable fidelity.

Buglia, James J.↗

Studies of extended planetary atmospheres

Spectroscopic observations of gases and plasmas in the Jupiter system, and related phenomena such as the recently-discovered sodium atmospheres of Mercury and the Moon were made. Cunningham's work on Jupiter spectroscopy is complete. The optical thickness of the ammonia cloud increases from about 3 in the morning to 6 at sunset. This effect seems to be due to the combination of internal heat flow and a convective region heated at the top, giving strong convection at night and none during the day. Near-simultaneous methane data are of poor quality, but are consistent with this picture. Schneider's work on the sodium environment of Io is also complete. The eclipse data extend to nearly 10 Io radii and nicely match the densities in the outer regions (to 100 Io radii) obtained from the intensity scattered in the D lines. Other data show very fast jets of sodium (up to 100 km/sec), frequently tilted out of the orbital plane. Researchers seem to be seeing neutralized ions, not from the torus itself but from atmospheric sodium ionized and then quickly neutralized. The data set on Mercurian sodium has been augmented, and supplemented by IR reflectance spectra.

Hunten, Donald M.↗

Zonal Winds Between 25 and 120 Km Retrieved from Solar Occultation Spectra

Atmospheric winds at heights between 25 and 120 km have been retrieved with precisions of 5/ms from the Doppler shifts of atmospheric absorption lines measured from a satellite-borne instrument. Lines of the upsilon 3 CO2 and upsilon 2 H2O rotation-vibration bands caused by gases in the instrument allowed the instrumental frequency scale to be absolutely calibrated so that accurate relative speeds could be obtained. By comparing the positions of both sets of instrumental lines the calibration of the frequency scale was determined to be stable to a precision of less than 2 x 10(-5) cm during the course of each occultation. It was found that the instrumental resolution of 0.015 cm after apodization, the signal to noise ratio of about 100 and stable calibration allowed relative speeds to be determined to a precision of 5 ms or better by using small numbers of absorption lines between 1600 and 3200 cm. Absolute absorption line positions were simultaneously recovered to precisions of 5 x 10(-5) cm or better. The wind speed profiles determined from four sunset occultations and one sunrise occultation show remarkable similarities in the magnitudes and directions of the zonal wind velocities as functions of height. These wind profiles appear to be manifestations of atmospheric tides.

Vancleef, Garrett Warren↗

Comparative studies of aerosol extinction measurements made by the SAM II and SAGE II satellite experiments

Results from the Stratospheric Aerosol Measurement (SAM) II and Stratospheric Aerosol and Gas Experiment (SAGE) II are compared for measurement locations which are coincident in time and space. At 1.0 micron, the SAM II and SAGE II aerosol extinction profiles are similar within their measurement errors. In addition, sunrise and sunset aerosol extinction data at four different wavelengths are compared for occasions when the SAGE II and SAM II measurements are nearly coincident in space and about 12 hours apart.

Yue, Glenn K.↗

The mixing ratio of the stratospheric hydroxyl radical from far infrared emission measurements

Far infrared emission spectra of the stratosphere, measured with a 0.0033/cm resolution Fourier transform spectrometer using a limb scanning method, are analyzed in order to retrieve the vertical distribution of the hydroxyl radical (OH). The observations cover a time interval between 1300 and 2300 hours, showing a pronounced time decrease of the OH signals. Vertical profiles are obtained for the afternoon and sunset periods. An upper limit is derived from the small signals present in the night measurements. Three different methods of analysis have been applied to the same data set, and the results provided the basis for a critical discussion of the error sources. The results are compared with theoretical predictions and with the results of other experiments.

Carli, Bruno↗

Measurement of stratospheric HOCl - Concentration profiles, including diurnal variation

Determinations have been made of concentration profiles of HOCl in the earth's stratosphere, including the diurnal variation. Measurements of the rotational Q2 branch at 99.5/cm and of five RR(J3) transitions between 143 and 159/cm were made using far-infrared thermal emission spectroscopy. The spectra were obtained during a balloon flight of the FIRS 2 far-infrared Fourier-transform spectrometer and telescope from Palestine, Texas on May 12-13, 1988. From these measurements, altitude profiles of HOCl from 23 to 42 km are obtained. Daytime and nighttime average profiles of HOCl, as well as measurements on a 30-min time scale through the sunset transition at a single (35 km) altitude are presented. The measured profiles are lower than the current predictions from several modeling groups by a factor of approximately 0.6.

Chance, K. V.↗

Observation of atmospheric fronts using Raman lidar moisture measurements

This paper presents the results of a field program using a ground-based Raman lidar system to observe changes in moisture profiles as a cold and a warm front passed over the NASA/Goddard Space Flight Center in Greenbelt, Maryland. The lidar operating only during darkness is capable of providing continuous high vertical resolution profiles of water vapor mixing ratio and aerosol scattering ratio from near the surface to about 7 km altitude. The lidar data acquired on three consecutive nights from shortly after sunset to shortly before sunrise, along with upper air data from specially launched rawinsondes, have provided a unique visualization of the detailed structure of the two fronts.

Melfi, S. H.↗

Energetic (above 60 eV) atmospheric photoelectrons

Data from low altitude plasma instrument (LAPI) on Dynamics Explorer 2 document a population of high-energy (up to 800 eV) atmospheric photoelectrons that has not been reported in the published literature. The source of these photoelectrons is postulated to be the soft X-ray portion of the whole sun spectrum. This conclusion is supported by sunrise-sunset characteristics that track those of the classical (below 60 eV) EUV-produced photoelectrons, and theoretical results from two models that incorporate the soft X-ray portion of the solar spectrum. The models include K-shell ionization effects and predict peaks in the photoelectron spectrum due to Auger electrons emitted from oxygen and nitrogen. The peak for nitrogen is observed as predicted, but the peak for oxygen is barely observable. Excellent quantitative agreement is achieved between theory and experiment by using reasonable adjustments to the few published soft X-ray spectra based on solar activity. The upflowing energetic photoelectrons provide a heretofore unknown source of electrons to the magnetosphere. They occur whenever and wherever the sun is up, that is, at all invariant latitudes. Their density is low, but they are steady and ubiquitous. If scattering and trapping occur on closed field lines, then photoelectrons could contribute as a significant particle source and thus represent a new facet of magnetosphere-ionosphere coupling.

Winningham, J. D.↗

Improved reference models for middle atmosphere ozone

This paper describes the improvements introduced into the original version of ozone reference model of Keating and Young (1985, 1987) which is to be incorporated in the next COSPAR International Reference Atmosphere (CIRA). The ozone reference model will provide information on the global ozone distribution (including the ozone vertical structure as a function of month and latitude from 25 to 90 km) combining data from five recent satellite experiments: the Nimbus 7 LIMS, Nimbus 7 SBUV, AE-2 Stratospheric Aerosol Gas Experiment (SAGE), Solar Mesosphere Explorer (SME) UV Spectrometer, and SME 1.27 Micron Airglow. The improved version of the reference model uses reprocessed AE-2 SAGE data (sunset) and extends the use of SAGE data from 1981 to the 1981-1983 time period. Comparisons are presented between the results of this ozone model and various nonsatellite measurements at different levels in the middle atmosphere.

Keating, G. M.↗

Variations of mesospheric equatorial ozone as observed by the Solar Maximum Mission

Tropical lower mesospheric ozone concentrations determined from UV sunset occultations demonstrate latitude dependent variations from 1985 through 1988. The annual and semiannual ozone behavior is caused primarily by equatorial temperature waves. Secular changes are the result of variations in mesospheric temperature, solar flux, and trace constituents which are involved in the ozone chemistry. The variation with latitude of the observed ozone trends between 1985 and 1989 is different from predictions of some models which simulate stratospheric and lower mesospheric ozone behavior over a sunspot cycle. This is the result of differences between the actual temperature structure of the atmosphere and that adopted in the models.

Aikin, Arthur C.↗

Refraction near the horizon

Variations in astronomical refraction near the horizon are examined. Sunset timings, a sextant mounted on a tripod, and a temperature profile are utilized to derive the variations in refraction data, collected from 7 locations. It is determined that the refraction ranges from 0.234 to 1.678 deg with an rms deviation of 0.16, and it is observed that the variation is larger than previously supposed. Some applications for the variation of refraction value are discussed.

Schaefer, Bradley E.↗

A technique for optimal temperature estimation for modeling sunrise/sunset thermal snap disturbance torque

A predictive temperature estimation technique which can be used to drive a model of the Sunrise/Sunset thermal 'snap' disturbance torque experienced by low Earth orbiting spacecraft is described. The twice per orbit impulsive disturbance torque is attributed to vehicle passage in and out of the Earth's shadow cone (umbra), during which large flexible appendages undergo rapidly changing thermal conditions. Flexible members, in particular solar arrays, experience rapid cooling during umbra entrance (Sunset) and rapid heating during exit (Sunrise). The thermal 'snap' phenomena has been observed during normal on-orbit operations of both the LANDSAT-4 satellite and the Communications Technology Satellite (CTS). Thermal 'snap' has also been predicted to be a dominant source of error for the TOPEX satellite. The fundamental equations used to model the Sunrise/Sunset thermal 'snap' disturbance torque for a typical solar array like structure will be described. For this derivation the array is assumed to be a thin, cantilevered beam. The time varying thermal gradient is shown to be the driving force behind predicting the thermal 'snap' disturbance torque and therefore motivates the need for accurate estimates of temperature. The development of a technique to optimally estimate appendage surface temperature is highlighted. The objective analysis method used is structured on the Gauss-Markov Theorem and provides an optimal temperature estimate at a prescribed location given data from a distributed thermal sensor network. The optimally estimated surface temperatures could then be used to compute the thermal gradient across the body. The estimation technique is demonstrated using a typical satellite solar array.

Zimbelman, D. F.↗

Lighting constraints on lunar surface operations

An investigation into the levels of ambient lighting on the lunar surface indicates that for most nearside locations, illumination will be adequate throughout most of the lunar night to conduct EVAs with only minor artificial illumination. The maximum lighting available during the lunar night from Earthshine will be similar to the light level on a July evening at approximately 8:00 pm in the southern United States (approximately 15 minutes after sunset). Because of the captured rotation of the Moon about the Earth, the location of the Earth will remain approximately constant throughout the lunar night, with consequent constant shadow length and angle. Variations in the level of Earthside illumination will be solely a function of Earth phase angle. Experience during the Apollo Program suggests that EVA activities during the period around the lunar noon may be difficult due to lack of surface definition caused by elimination of shadows.

Eppler, Dean B.↗

Improved reference models for middle atmosphere ozone

Improvements are provided for the ozone reference model which is to be incorporated in the COSPAR International Reference Atmosphere (CIRA). The ozone reference model will provide considerable information on the global ozone distribution, including ozone vertical structure as a function of month and latitude from approximately 25 to 90 km, combining data from five recent satellite experiments (Nimbus 7 LIMS, Nimbus 7 SBUV, AE-2 SAGE, Solar Mesosphere Explorer (SME) UVS, and SME IR). The improved models are described and use reprocessed AE-2 SAGE data (sunset) and extend the use of SAGE data from 1981 to the period 1981-1983. Comparisons are shown between the ozone reference model and various nonsatellite measurements at different levels in the middle atmosphere.

Keating, G. M.↗

A new spherical model for computing the radiation field available for photolysis and heating at twilight

Accurate computation of atmospheric photodissociation and heating rates is needed in photochemical models. These quantities are proportional to the mean intensity of the solar radiation penetrating to various levels in the atmosphere. For large solar zenith angles a solution of the radiative transfer equation valid for a spherical atmosphere is required in order to obtain accurate values of the mean intensity. Such a solution based on a perturbation technique combined with the discrete ordinate method is presented. Mean intensity calculations are carried out for various solar zenith angles. These results are compared with calculations from a plane parallel radiative transfer model in order to assess the importance of using correct geometry around sunrise and sunset. This comparison shows, in agreement with previous investigations, that for solar zenith angles less than 90 deg adequate solutions are obtained for plane parallel geometry as long as spherical geometry is used to compute the direct beam attenuation; but for solar zenith angles greater than 90 deg this pseudospherical plane parallel approximation overstimates the mean intensity.

Dahlback, Arne↗