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A preliminary analysis of the Mariner 10 color ratio map of Mercury

A preliminary geological analysis of the Mariner 10 orange/UV color ratio map of Mercury is given, assuming a basaltic crust. Certain errors in the map are pointed out. The relationship between color and terrain are distinctly non-lunar. Rays and ejecta are bluer than average on Mercury, whereas they are redder on the Moon. This fact, along with the lack of the ferrous band in Mercury's spectral reflectance and smaller albedo contrasts, implies that the crust is low in Fe and Ti. There is no correlation between color boundaries and the smooth plains on Mercury, in contrast with the strong correlation between color and maria-highlands contacts on the Moon. The smooth plains are not Mercurian analogs of lunar maria, and a lunar-type of second wave melting did not occur. Ambiguous correlations between color and topography indicate that older, redder materials underlie younger, bluer rocks in many places on the planet, implying that the last stages of volcanism involved low-Fe lavas covering higher-Fe rocks. There is some evidence of late Fe-rich pyroclastic activity.

Rava, Barry↗

Remote Sensing of Aerosol and Non-Aerosol Absorption

Remote sensing of aerosol from the new satellite instruments (e.g. MODIS from Terra) and ground based radiometers (e.g. the AERONET) provides the opportunity to measure the absorption characteristics of the ambient undisturbed aerosol in the entire atmospheric column. For example Landsat and AERONET data are used to measure spectral absorption of sunlight by dust from West Africa. Both Application of the Landsat and AERONET data demonstrate that Saharan dust absorption of solar radiation is several times smaller than the current international standards. This is due to difficulties of measuring dust absorption in situ, and due to the often contamination of dust properties by the presence of air pollution or smoke. We use the remotely sensed aerosol absorption properties described by the spectral sin le scattering albedo, together with statistics of the monthly optical thickness for the fine and coarse aerosol derived from the MODIS data. The result is an estimate of the flux of solar radiation absorbed by the aerosol layer in different regions around the globe where aerosol is prevalent. If this aerosol forcing through absorption is not included in global circulation models, it may be interpreted as anomalous absorption in these regions. In a preliminary exercise we also use the absorption measurements by AERONET, to derive the non-aerosol absorption of the atmosphere in cloud free conditions. The results are obtained for the atmospheric windows: 0.44 microns, 0.66 microns, 0.86 microns and 1.05 microns. In all the locations over the land and ocean that were tested no anomalous absorption in these wavelengths, was found within absorption optical thickness of +/- 0.005.

Kaufman, Y. J.↗

CIMEL Measurements of Zenith Radiances at the ARM Site

Starting from October 1, 2001, Cimel at the ARM Central Facility in Oklahoma has been switched to a new "cloud mode." This mode allows taking measurements of zenith radiance when the Sun in blocked by clouds. In this case, every 13 min. Cimel points straight up and takes 10 measurements with 9 sec. time interval. The new Cimel's mode has four filters at 440, 670, 870 and 1020 nm. For cloudy conditions, the spectral contrast in surface albedo dominates over Rayleigh and aerosol effects; this makes normalized zenith radiances at 440 and 670 as well as for 870 and 1020 almost indistinguishable. We compare Cimel measurements with other ARM cart site instruments: Multi-Filter Rotating Shadowband Radiometer (MFRSR), Narrow Field of View (NFOV) sensor, and MicroWave Radiometer(MWR). Based on Cimel and MFRSR 670 and 870 nm channels, we build a normalized difference cloud index (NDCI) for radiances and fluxes, respectively. Radiance NDCI from Cimel and flux NDCI from MFRSR are compared between themselves as well as with cloud Liquid Water Path (LWP) retrieved from MWR. Based on our theoretical calculations and preliminary data analysis,there is a good correlation between NDCIs and LWP for cloudy sky above green vegetation. Based on this correlation, an algorithm to retrieve cloud optical depth from NDCI is proposed.

Marshak, Alexander↗

How Can AERONET Help with Monitoring Clouds?

When conditions are inappropriate to make AErosol RObotic NETwork (AERONET) measurements for aerosol studies, new measurements related to cloud physics can be made instead. As such, several AERONET CIMEL sunphotometers have been equipped with a new "cloud mode." This mode allows the CIMELs to make measurements of zenith radiance when the Sun in blocked by clouds. When in cloud mode, a CIMEL points straight up every 10-15 minutes and takes 10 measurements over a 9 second time interval at four wavelengths: 440,670,870, and 1020 nm. For cloudy conditions above green vegetation, the spectral contrast in surface albedo dominates over Rayleigh and aerosol effects. We have developed a new method for retrieving cloud optical depth, even for broken clouds, that uses data from the 670 (and/or 440) and 870 nm channels. In addition to cloud optical depth, the method also infers a "radiatively effective" cloud fraction. The results of the retrievals at the ARM Central Facility in Oklahoma are compared with the ones from Microwave Radiometer (MWR) and Multi-Filter Rotating Shadowband Radiometers (MFRSR).

Marshak, A.↗

Internally Consistent MODIS Estimate of Aerosol Clear-Sky Radiative Effect Over the Global Oceans

Modern satellite remote sensing, and in particular the MODerate resolution Imaging Spectroradiometer (MODIS), offers a measurement-based pathway to estimate global aerosol radiative effects and aerosol radiative forcing. Over the Oceans, MODIS retrieves the total aerosol optical thickness, but also reports which combination of the 9 different aerosol models was used to obtain the retrieval. Each of the 9 models is characterized by a size distribution and complex refractive index, which through Mie calculations correspond to a unique set of single scattering albedo, assymetry parameter and spectral extinction for each model. The combination of these sets of optical parameters weighted by the optical thickness attributed to each model in the retrieval produces the best fit to the observed radiances at the top of the atmosphere. Thus the MODIS Ocean aerosol retrieval provides us with (1) An observed distribution of global aerosol loading, and (2) An internally-consistent, observed, distribution of aerosol optical models that when used in combination will best represent the radiances at the top of the atmosphere. We use these two observed global distributions to initialize the column climate model by Chou and Suarez to calculate the aerosol radiative effect at top of the atmosphere and the radiative efficiency of the aerosols over the global oceans. We apply the analysis to 3 years of MODIS retrievals from the Terra satellite and produce global and regional, seasonally varying, estimates of aerosol radiative effect over the clear-sky oceans.

Remer, Lorraine A.↗

Biomass Burning Aerosol Absorption Measurements with MODIS Using the Critical Reflectance Method

This research uses the critical reflectance technique, a space-based remote sensing method, to measure the spatial distribution of aerosol absorption properties over land. Choosing two regions dominated by biomass burning aerosols, a series of sensitivity studies were undertaken to analyze the potential limitations of this method for the type of aerosol to be encountered in the selected study areas, and to show that the retrieved results are relatively insensitive to uncertainties in the assumptions used in the retrieval of smoke aerosol. The critical reflectance technique is then applied to Moderate Resolution Imaging Spectrometer (MODIS) data to retrieve the spectral aerosol single scattering albedo (SSA) in South African and South American 35 biomass burning events. The retrieved results were validated with collocated Aerosol Robotic Network (AERONET) retrievals. One standard deviation of mean MODIS retrievals match AERONET products to within 0.03, the magnitude of the AERONET uncertainty. The overlap of the two retrievals increases to 88%, allowing for measurement variance in the MODIS retrievals as well. The ensemble average of MODIS-derived SSA for the Amazon forest station is 0.92 at 670 nm, and 0.84-0.89 for the southern African savanna stations. The critical reflectance technique allows evaluation of the spatial variability of SSA, and shows that SSA in South America exhibits higher spatial variation than in South Africa. The accuracy of the retrieved aerosol SSA from MODIS data indicates that this product can help to better understand 44 how aerosols affect the regional and global climate.

Zhu, Li↗

Absorption Properties of Mediterranean Aerosols Obtained from Multi-year Ground-based and Satellite Remote Sensing Observations

Aerosol absorption properties are of high importance to assess aerosol impact on regional climate. This study presents an analysis of aerosol absorption products obtained over the Mediterranean Basin or land stations in the region from multi-year ground-based AERONET and satellite observations with a focus on the Absorbing Aerosol Optical Depth (AAOD), Single Scattering Albedo (SSA) and their spectral dependence. The AAOD and Absorption Angstrom Exponent (AAE) data set is composed of daily averaged AERONET level 2 data from a total of 22 Mediterranean stations having long time series, mainly under the influence of urban-industrial aerosols and/or soil dust. This data set covers the 17 yr period 1996-2012 with most data being from 2003-2011 (approximately 89 percent of level-2 AAOD data). Since AERONET level-2 absorption products require a high aerosol load (AOD at 440 nm greater than 0.4), which is most often related to the presence of desert dust, we also consider level-1.5 SSA data, despite their higher uncertainty, and filter out data with an Angstrom exponent less than 1.0 in order to study absorption by carbonaceous aerosols. The SSA data set includes both AERONET level-2 and satellite level-3 products. Satellite-derived SSA data considered are monthly level 3 products mapped at the regional scale for the spring and summer seasons that exhibit the largest aerosol loads. The satellite SSA dataset includes the following products: (i) Multi-angle Imaging SpectroRadiometer (MISR) over 2000-2011, (ii) Ozone Monitoring Instrument (OMI) near-UV algorithm over 2004-2010, and (iii) MODerate resolution Imaging Spectroradiometer (MODIS) Deep-Blue algorithm over 2005-2011, derived only over land in dusty conditions. Sun-photometer observations show that values of AAOD at 440 nm vary between 0.024 +/- 0.01 (resp. 0.040 +/- 0.01) and 0.050 +/- 0.01 (0.055 +/- 0.01) for urban (dusty) sites. Analysis shows that the Mediterranean urban-industrial aerosols appear "moderately" absorbing with values of SSA close to approximately 0.94-0.95 +/- 0.04 (at 440 nm) in most cases except over the large cities of Rome and Athens, where aerosol appears more absorbing (SSA approximately 0.89-0.90 +/- 0.04). The aerosol Absorption Angstrom Exponent (AAE, estimated using 440 and 870 nm) is found to be larger than 1 for most sites over the Mediterranean, a manifestation of mineral dust (iron) and/or brown carbon producing the observed absorption. AERONET level-2 sun-photometer data indicate the existence of a moderate East-West gradient, with higher values over the eastern basin (AAEEast. = 1.39/AAEWest. = 1.33) due to the influence of desert dust. The North-South AAE gradient is more pronounced, especially over the western basin. Our additional analysis of AERONET level-1.5 data also shows that organic absorbing aerosols significantly affect some Mediterranean sites. These results indicate that current climate models treating organics as nonabsorbing over the Mediterranean certainly underestimate the warming effect due to carbonaceous aerosols. A~comparative analysis of the regional SSA variability has been attempted using satellite data. OMI and MODIS data show an absorbing zone (SSA approximately 0.90 at 470-500 nm) over Northeastern Africa that does not appear in the MISR retrievals. In contrast, MISR seems able to observe the East-West SSA gradient during summer, as also detected by AERONET. Also, the analysis of SSA provided by satellites indicates that the aerosol over the Mediterranean Sea appears less absorbing during spring (MAM) than summer (JJA).

satellite remote sensing observations↗

Aerosol Seasonal Variations over Urban-Industrial Regions in Ukraine According to AERONET and POLDER Measurements

The paper presents an investigation of aerosol seasonal variations in several urban-industrial regions in Ukraine. Our analysis of seasonal variations of optical and physical aerosol parameters is based on the sun-photometer 2008-2013 data from two urban ground-based AERONET (AErosol RObotic NETwork) sites in Ukraine (Kyiv, Lugansk) as well as on satellite POLDER instrument data for urban-industrial areas in Ukraine. We also analyzed the data from one AERONET site in Belarus (Minsk) in order to compare with the Ukrainian sites. Aerosol amount and optical depth (AOD) values in the atmosphere columns over the large urbanized areas like Kyiv and Minsk have maximum values in the spring (April-May) and late summer (August), whereas minimum values are observed in late autumn. The results show that fine-mode particles are most frequently detected during the spring and late summer seasons. The analysis of the seasonal AOD variations over the urban-industrial areas in the eastern and central parts of Ukraine according to both ground-based and POLDER data exhibits the similar traits. The seasonal variation similarity in the regions denotes the resemblance in basic aerosol sources that are closely related to properties of aerosol particles. The behavior of basic aerosol parameters in the western part of Ukraine is different from eastern and central regions and shows an earlier appearance of the spring and summer AOD maxima. Spectral single-scattering albedo, complex refractive index and size distribution of aerosol particles in the atmosphere column over Kyiv have different behavior for warm (April-October) and cold seasons. The seasonal features of fine and coarse aerosol particle behavior over the Kyiv site were analyzed. A prevailing influence of the fine-mode particles on the optical properties of the aerosol layer over the region has been established. The back-trajectory and cluster analysis techniques were applied to study the seasonal back trajectories and prevailing directions of the arrived air mass for the Kyiv and Minsk sites.

Ukraine↗

Retrieving Aerosol Characteristics From the PACE Mission, Part 2: Multi-Angle and Polarimetry

The Plankton, Aerosol, Clouds, ocean Ecosystem (PACE) mission presents new opportunities and new challenges in applying observations of two complementary multi-angle polarimeters for the space-based retrieval of global aerosol properties.Aerosol remote sensing from multi-angle radiometric-only observations enables aerosol characterization to a greater degree than single-view radiometers, as demonstrated by nearly two decades of heritage instruments. Adding polarimetry to the multi-angle observations allows for the retrieval of aerosol optical depth, Angstrom exponent,parameters of size distribution, measures of aerosol absorption, complex refractive index and degree of non-sphericity of the particles, as demonstrated by two independent retrieval algorithms applied to the heritage POLarization and Directionality of the Earth's Reflectance (POLDER) instrument. The reason why this detailed particle characterization is possible is because a multi-angle polarimeter measurement contains twice the number of Degrees of Freedom of Signal (DFS) compared to an observation from a single-view radiometer. The challenges of making use of this information content involve separating surface signal from atmospheric signal, especially when the surface is optically complex and especially in the ultraviolet portion of the spectrum where we show the necessity of polarization in making that separation. The path forward is likely to involve joint retrievalsthat will simultaneously retrieve aerosol and surface properties, although advances will berequired in radiative transfer modeling and in representing optically complex constituents in those models. Another challenge is in having the processing capability that can keep pace with the output of these instruments in an operational environment. Yet, preliminaryalgorithms applied to airborne multi-angle polarimeter observations offer encouraging results that demonstrate the advantages of these instruments to retrieve aerosol layer height, particle single scattering albedo, size distribution and spectral optical depth, and also show the necessity of polarization measurements, not just multi-angle radiometricmeasurements, to achieve these results.

Remer, Lorraine A.↗

Global geologic map of asteroid (101955) Bennu indicates heterogeneous resurfacing in the past 500,000 years

Global geologic maps are useful tools for efficient interpretation of a planetary body, and they provide global context for the diversity and evolution of the surface. We used data acquired by the OSIRIS-REx spacecraft to create the first global geologic map of the near-Earth asteroid (101955) Bennu. As this is the first geologic map of a small, non-spherical, rubble-pile asteroid, we discuss the distinctive mapping challenges and best practices that may be useful for future exploration of similar asteroids, such as those to be visited with the Hera and Janus missions. By mapping on two centimeter-scale global image mosaics (2D projected space) and a centimeter-scale global shape model (3D space), we generated three input maps respectively describing Bennu’s shape features, geologic features, and surface texture. Based on these input maps, we defined two geologic units: the Smooth Unit and the Rugged Unit. The units are differentiated primarily on the basis of surface texture, concentrations of boulders, and the distributions of lineaments, mass movement features, and craters. They are bounded by several scarps. The Rugged Unit contains abundant boulders and signs of recent mass movement. It also has fewer small(<20 m), putatively fresh craters than the Smooth Unit, suggesting that such craters have been erased in the former. Based on these geologic indicators, we infer that the Rugged Unit has the younger surface of the two. Differential crater size-frequency distributions and the distribution of the freshest craters suggest that both unit surfaces formed ~10–65 million years ago, when Bennu was located in the Main Asteroid Belt, and the Smooth Unit has not been significantly resurfaced in the past 2 million years. Meanwhile, the Rugged Unit has experienced resurfacing within the past ~500,000years during Bennu’s lifetime as a near-Earth asteroid. The geologic units are consistent with global diversity in slope, surface roughness, normal albedo, and thermal emission spectral characteristics. The site on Bennu where the OSIRIS-REx mission collected a regolith sample is located in the Smooth Unit, in a small crater nested within a larger one. So although the Smooth Unit is an older surface than the Rugged Unit, the impact-crater settingindicates that the material sampled was recently exposed. Several similarities are apparent between Bennu and asteroid (162173) Ryugu from a global geologic perspective, including two geologic units distinguishable by variations in the number density of boulders, as well as in other datasets such as brightness.

E R Jawin↗

Reflectance and Thermal Infrared Spectroscopy of Mars: Relationship Between ISM and TES for Compositional Determinations

Reflectance spectroscopy has demonstrated that high albedo surfaces on Mars contain heavily altered materials with some component of hematite, poorly crystalline ferric oxides, and an undefined silicate matrix. The spectral properties of many low albedo regions indicate crystalline basalts containing both low and high calcium pyroxene, a mineralogy consistent with the basaltic SNC meteorites. The Thermal Emission Spectrometer (TES) experiment on the Mars Geochemical Surveyor has acquired critical new data relevant to surface composition and mineralogy, but in a wavelength region that is complementary to reflectance spectroscopy. The essence of the completed research was to analyze TES data in the context of reflectance data obtained by the French ISM imaging spectrometer experiment in 1989. This approach increased our understanding of the complementary nature of these wavelength regions for mineralogic determinations using actual observations of the martian surface. The research effort focused on three regions of scientific importance: Syrtis Major-Isidis Basin, Oxia Palus-Arabia, and Valles Marineris. In each region distinct spatial variations related to reflectance, and in derived mineralogic information and interpreted compositional units were analyzed. In addition, specific science questions related to the composition of volcanics and crustal evolution, soil compositions and pedogenic processes, and the relationship between pristine lithologies and weathering provided an overall science-driven framework for the work. The detailed work plan involved colocation of TES and ISM data, extraction of reflectance and emissivity spectra from areas of known reflectance variability, and quantitative analysis using factor analysis and statistical techniques to determine the degree of correspondence between these different wavelength regions. Identified coherent variations in TES spectroscopy were assessed against known atmospheric effects to validate that the variations are due to surface properties. With this new understanding of reflectance and emission spectroscopy, mineralogic interpretations were derived and applied to the science objectives of the three regions.

Boyce, Joseph↗

Atmospheric Correction at AERONET Locations: A New Science and Validation Data Set

This paper describes an AERONET-based Surface Reflectance Validation Network (ASRVN) and its dataset of spectral surface bidirectional reflectance and albedo based on MODIS TERRA and AQUA data. The ASRVN is an operational data collection and processing system. It receives 50x50 square kilometer subsets of MODIS L1B data from MODAPS and AERONET aerosol and water vapor information. Then it performs an accurate atmospheric correction for about 100 AERONET sites based on accurate radiative transfer theory with high quality control of the input data. The ASRVN processing software consists of L1B data gridding algorithm, a new cloud mask algorithm based on a time series analysis, and an atmospheric correction algorithm. The atmospheric correction is achieved by fitting the MODIS top of atmosphere measurements, accumulated for 16-day interval, with theoretical reflectance parameterized in terms of coefficients of the LSRT BRF model. The ASRVN takes several steps to ensure high quality of results: 1) cloud mask algorithm filters opaque clouds; 2) an aerosol filter has been developed to filter residual semi-transparent and sub-pixel clouds, as well as cases with high inhomogeneity of aerosols in the processing area; 3) imposing requirement of consistency of the new solution with previously retrieved BRF and albedo; 4) rapid adjustment of the 16-day retrieval to the surface changes using the last day of measurements; and 5) development of seasonal back-up spectral BRF database to increase data coverage. The ASRVN provides a gapless or near-gapless coverage for the processing area. The gaps, caused by clouds, are filled most naturally with the latest solution for a given pixels. The ASRVN products include three parameters of LSRT model (k(sup L), k(sup G), k(sup V)), surface albedo, NBRF (a normalized BRF computed for a standard viewing geometry, VZA=0 deg., SZA=45 deg.), and IBRF (instantaneous, or one angle, BRF value derived from the last day of MODIS measurement for specific viewing geometry) for MODIS 500m bands 1-7. The results are produced daily at resolution of 1 km in gridded format. We also provide cloud mask, quality flag and a browse bitmap image. The new dataset can be used for a wide range of applications including validation analysis and science research.

Wang, Yujie↗

Assessment of MSS spectral indexes for monitoring arid rangeland

The utility of MSS spectral indexes for monitoring arid rangeland vegetation was tested by determining correlations between spectral indexes and vegetation parameters and by examining retrospective MSS data to determine if vegetation change could be detected and measured using spectral indexes. MSS Band 5, albedo, and the Kauth-Thomas Brightness component appear to be useful for monitoring total vegetation cover. Multiseasonal green vegetation indexes could be used to estimate changes in the shrub/grass ratio. In retrospective monitoring, spectral index change appeared to be offset from true change, indicating that the methods used to standardize data sets for differences in solar elevation and sensor radiometric response were not completely successful.

Musick, H. B.↗

Generating Vegetation Leaf Area Index Earth System Data Record from Multiple Sensors: Theory - Part 1

The generation of multi-decade long Earth System Data Records (ESDRs) of Leaf Area Index (LAI) and Fraction of Photosynthetically Active Radiation absorbed by vegetation (FPAR) from remote sensing measurements of multiple sensors is key to monitoring long-term changes in vegetation due to natural and anthropogenic influences. Challenges in developing such ESDRs include problems in remote sensing science (modeling of variability in global vegetation, scaling, atmospheric correction) and sensor hardware (differences in spatial resolution, spectral bands, calibration, and information content). In this paper, we develop a physically based approach for deriving LAI and FPAR products from the Advanced Very High Resolution Radiometer (AVHRR) data that are of comparable quality to the Moderate resolution Imaging Spectroradiometer (MODIS) LAI and FPAR products, thus realizing the objective of producing a long (multi-decadal) time series of these products. The approach is based on the radiative transfer theory of canopy spectral invariants which facilitates parameterization of the canopy spectral bidirectional reflectance factor (BRF). The methodology permits decoupling of the structural and radiometric components and obeys the energy conservation law. The approach is applicable to any optical sensor, however, it requires selection of sensor-specific values of configurable parameters, namely, the single scattering albedo and data uncertainty. According to the theory of spectral invariants, the single scattering albedo is a function of the spatial scale, and thus, accounts for the variation in BRF with sensor spatial resolution. Likewise, the single scattering albedo accounts for the variation in spectral BRF with sensor bandwidths. The second adjustable parameter is data uncertainty, which accounts for varying information content of the remote sensing measurements, i.e., Normalized Difference Vegetation Index (NDVI, low information content), vs. spectral BRF (higher information content). Implementation of this approach indicates good consistency in LAI values retrieved from NDVI (AVHRRmode) and spectral BRF (MODIS-mode). Specific details of the implementation and evaluation of the derived products are detailed in the second part of this two-paper series.

Ganguly, Sangram↗

Characteristics of In Situ Fine Fraction Aerosol Spectra from 300-700 nm Observed Around the Korean Peninsula During KORUS-OC

In situ aerosol extinction and absorption spectra covering the 300-700 nm range at ≤ 1 nm spectral resolution were measured aboard the R/V Onnuri during the Korea U.S. – Ocean Color (KORUS-OC) cruise around the Korean Peninsula from May 21 through June 3, 2016. Total absorption spectra were obtained from aerosols collected on glass fiber filters and subsequently placed in the center of an integrating sphere (Labsphere DRA-CA-30) attached to a dual beam spectrophotometer (Cary 100 Bio UV-Visible Spectrophotometer, 0.2 nm spectral resolution). Absorption spectra from methanol and deionized water extracts of aerosols collected on Teflon filters were measured in a liquid waveguide capillary cell (World Precision Instruments LWCC- 3100, ~0.4 nm spectral resolution). Extinction spectra were measured with a custom built instrument (SpEx, ~0.8 nm spectral resolution). The measurements were obtained at a height of ~10 m above the sea surface with an inlet that limited the measured aerosols to diameters ≤ 1.3 µm. All four sets of spectra exhibit curvature in log-log space with 2nd order polynomials providing a better fit to the measured spectra than power law fits. The deionized water extracts were also analyzed with an ion chromatograph (Dionex ICS-3000 Ion Chromatography System) and with an aerosol mass spectrometer (Aerodyne Research, Inc. HR-ToF High Resolution Aerosol Mass Spectrometer) to examine chemical composition. These data indicate the optical spectra are sensitive to differing chemical properties of the measured ambient aerosols and suggest differing sources and/or atmospheric processes influence the observed optical signatures. The measured suite of spectra are combined to examine the spectral characteristics of single scattering albedo, as well as to examine the contribution of soluble absorbing chromophores to the total absorption spectra. Additional measurements made during the affiliated Korea U.S. - Air Quality (KORUS-AQ) campaign will be used to provide further insight on the observed spectral characteristics.

Jordan, Carolyn E↗

Hubble Space Telescope UV spectral observations of Io passing into eclipse

Time-resolved spectra of Io have been obtained with the Faint Object Spectrograph on the Hubble Space Telescope in January 1992 at times centered on the passage of Io into Jupiter's shadow. Two different eclipse observations covered 1100-1600 A and 2250-3300 A. In the far ultraviolet(far-UV) range, emission lines of atomic sulfur and oxygen from Io's atmosphere (similar to those previously detected with the International Ultraviolet Explorer (IUE)) have been observed from Io in sunlight, and the spatial extent of the emitting region has been resolved for the first time: this is 0.5-1 Io radii (R(sub Io)) above the surface. The emission lines are typically 1kR in brightness while Io is in sunlight, and decrease to a few hundred Rayleighs within 20 min or less of Io's passing into shadow. If the emissions are produced in Io's ionosphere, the decrease in shadow appears consistent with the collisional slowing and recombination of photoelectrons in 100-1000 s, with recombination an important quenching process if the dominant ion is molecular (i.e., SO2(+)) condensation, with the residual emission in shadow due either to plasma impact of gas above the hot volcanic calderas or electron impact on S and O. In the near-UV range, we have not detected any airglow emissions from Io's atmosphere in shadow, with the main limitation being a high level of scattered light from Jupiter. We derive a 3 sigma upper limit to the 2560 A SO emission feature of 1 KR, which is close to what is expected from electron impact on SO2 based on the obs erved brightness of the FUV S and O lines in shadow. A high signal-to-noise spectrum of Io's albedo in sunlight reveals a spectral shape similar to laboratory spectra of SO2 frost reflectivity, and the relative albedo spectrum changed as Io passed into eclipse and part of the disk was in shadow. No specific SO2 gas absorption features appear in the albedo spectrum, although there could be substantial gas absorption near 2800 A if the individual lines are narrow and saturated. Finally, we present preliminary models for the near-UV spectrum of Io as functions of SO2 frost areal coverage and SO2 gas density.

Clarke, John T.↗

Mars south polar spring and summer temperatures - A residual CO2 frost

Viking infrared thermal mapper (IRTM) energy measurements over the Mars south polar cap throughout the Martian spring and summer revealed complex spatial, spectral, and temporal variations. High albedos did not directly correspond with low temperatures, and as the cap shrank to its residual position, it maintained large differences in brightness temperature between the four IRTM surface-sensing bands at 7, 9, 11, and 20 microns. The late summer infrared spectral pattern can be matched by a surface consisting of CO2 frost with 20 micron emissivity of 0.8 and about 6% dark, warm soil under a dusty atmosphere of moderate infrared opacity and spectral properties similar to those measured for the Martian global dust storms. Low temperature, the absence of appreciable water vapor in the south polar atmosphere, and the absence of surface warming expected if H2O were to become exposed, all imply that the residual south polar cap was covered by solid CO2.

Kieffer, H. H.↗

Wavelength Dependence of the Absorption of Black Carbon Particles: Predictions and Results from the TARFOX Experiment and Implications for the Aerosol Single Scattering Albedo

Measurements are presented of the wavelength dependence of the aerosol absorption coefficient taken during the Tropical Aerosol Radiative Forcing Observational Experiment (TARFOX) over the northern Atlantic. The data show an approximate lamda(exp -1) variation between 0.40 and 1.0 micrometers. The theoretical basis of the wavelength variation of the absorption of solar radiation by elemental carbon [or black carbon (BC)] is explored. For a wavelength independent refractive index the small particle absorption limit simplifies to a lambda(exp -1) variation in relatively good agreement with the data. This result implies that the refractive indices of BC were relatively constant in this wavelength region, in agreement with much of the data on refractive indices of BC. However, the result does not indicate the magnitude of the refractive indices. The implications of the wavelength dependence of BC absorption for the spectral behavior of the aerosol single scattering albedo are discussed. It is shown that the single scattering albedo for a mixture of BC and nonabsorbing material decreases with wavelength in the solar spectrum (i.e., the percentage amount of absorption increases). This decease in the single scattering albedo with wavelength for black carbon mixtures is different from the increase in single scattering allied for most mineral aerosols (dusts). This indicates that, if generally true, the spectral variation of the single- scattering albedo can be used to distinguish aerosol types. It also highlights the importance of measurements of the spectral variation of the aerosol absorption coefficient and single scattering albedo.

Bergstrom, Robert W.↗