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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Effect of structure and morphology on thermal and electrical properties of polycarbonate film capacitors

Research is reported to identify polycarbonate (PC) film characteristics and fabrication procedures which extend the reliable performance range of PC capacitors to 125 C without derating, and establish quality control techniques and transfer technology to US PC film manufacturers. The approach chosen to solve these problems was to develop techniques for fabricating biaxially oriented (BX) 2 microns or thinner PC film with a low dissipation factor up to 140 C; isotropic dimensional stability; high crystallinity; and high voltage breakdown strength. The PC film structure and morphology was then correlated to thermal and electrical capacitor behavior. Analytical techniques were developed to monitor film quality during capacitor fabrication, and as a result, excellent performance was demonstrated during initial capacitor testing.

Yen, S. P. S.↗

Ellipsometric characterization of In(0.52)Al(0.48)As and of modulation doped field effect transistor structures on InP substrates

The dielectric function of a thick layer of In(0.52)Al(0.48)As lattice matched to InP was measured by variable angle spectroscopic ellipsometry in the range 1.9-4.1 eV. The In(0.52)Al(0.48)As was protected from oxidation using a thin In(0.53)Ga(0.47)As cap that was mathematically removed for the dielectric function estimate. The In(0.52)Al(0.48)As dielectric function was then verified by ellipsometric measurements of other In(0.53)Ga(0.47)As/In(0.52)Al(0.48)As structures, including (MODFET), and is shown to provide accurate structure layer thicknesses.

Alterovitz, S. A.↗

Effective Gust Structure at Low Altitudes as Determined from the Reactions of an Airplane

Measurements of gust structure and gust intensity were made in the lower levels of the atmosphere (0 to 3,500 ft.). An Aeronca C-2 airplane was used as the measuring instrument, the gust structure being derived from the recorded motions of the airplane. Data were also obtained on wind velocities and temperatures as functions of altitude for use in attempting to correlate the gust-structure data with various meteorological quantities. The results indicated little or no correlation between the gust velocity and the gradient distance. The data, however, did indicate that an airplane the size of the Aeronca will respond most frequently to gusts having gradient distance of the order of 30 feet. The maximum true gust velocity measured during the investigation was 25 feet per second.

Donely, Philip↗

Nonaxisymmetric Disturbances in a Jet and Their Effect on Structural Loading

A model of sound generated in a high subsonic (Mach 0.9) circular jet is solved numerically in cylindrical coordinates for nonaxisymmetric disturbances. The jet is excited by transient mass injection by a finite duration pulse via a rotating ring source. The flow field, near field and far field pressure disturbances corresponding to these sources are described. In particular, the resulting pressure field, which would serve to excite nearby panels, is illustrated together with preliminary results on the excitation of thin slices of nearby panels. We consider both the short time behavior of the jet and the long time behavior, after the initial excitation pulse has exited the computational domain. The long time behavior of the jet is dominated by vorticity and pressure disturbances generated at the nozzle lip and growing as they convect downstream in the jet. These disturbances generate sound as they propagate. We find that rotating nonaxisymmetric disturbances persist for long times. Furthermore, depending on location, both in phase and out of phase behavior can be found upon reflection across the jet axis.

Bayliss, A.↗

Benchmark studies of the effectiveness of structural and internal materials as radiation shielding for the international space station

Accelerator-based measurements and model calculations have been used to study the heavy-ion radiation transport properties of materials in use on the International Space Station (ISS). Samples of the ISS aluminum outer hull were augmented with various configurations of internal wall material and polyethylene. The materials were bombarded with high-energy iron ions characteristic of a significant part of the galactic cosmic-ray (GCR) heavy-ion spectrum. Transmitted primary ions and charged fragments produced in nuclear collisions in the materials were measured near the beam axis, and a model was used to extrapolate from the data to lower beam energies and to a lighter ion. For the materials and ions studied, at incident particle energies from 1037 MeV/nucleon down to at least 600 MeV/nucleon, nuclear fragmentation reduces the average dose and dose equivalent per incident ion. At energies below 400 MeV/nucleon, the calculation predicts that as material is added, increased ionization energy loss produces increases in some dosimetric quantities. These limited results suggest that the addition of modest amounts of polyethylene or similar material to the interior of the ISS will reduce the dose to ISS crews from space radiation; however, the radiation transport properties of ISS materials should be evaluated with a realistic space radiation field. Copyright 2003 by Radiation Research Society.

NASA Discipline Radiation Health↗

Intercalation And High-Pressure Effects On Structural Phase Transitions In Layered As x P 1-x Alloys

This project was aimed at understanding the role of composition, intercalation, and high pressure on the structural evolution of black phosphorous (BP) and layered arsenic phosphorous alloys, As y P 1-y . Under normal conditions, BP is the most stable phase of phosphorous, known as the α-phase, characterized by an orthorhombic honeycomb puckered crystal structure with the Cmca space group. On the other hand, the most stable phase of arsenic is its β-phase, known as gray arsenic (g-As), which has a rhombohedral buckled layered crystal structure with the R3m space group. In a wide range of compositions (y < 0.83), the arsenic phosphorous alloys form the α-phase, known as black arsenic phosphorous (b-As y P 1-y ) with a similar structure to BP. The project was aimed at the synthesis of BP and b-As y P 1-y with different compositions and at studying the structural evolution of these materials during intercalation with alkali metal (especially Li), and under high-pressure conditions. The main goals were to gain a better understanding of these processes and structural changes taking place under these conditions. In particular, the project was aimed at addressing whether such conditions could induce a structural transition between the α- and β-phases. For this, a series of systematic in-situ studies were conducted, including electrochemical lithium intercalation in an in-situ electrochemical cell, and high-pressure experiments in a diamond anvil cell (DAC). Overall, both types of experiments have shown that above a certain composition-dependent threshold level of intercalation or high pressure, the system undergoes phase segregation rather than phase transition. Specifically, the segregation of the excess arsenic was observed, and a single-phase system of b-As y P 1-y transformed into a two-phase system consisting of b-As y P 1-y and g-As, through the following process: 1∗(b-As y P 1-y ) → 1∗(b As y-δ P 1-y ) + δ∗(g-As). Also, the study showed that intercalation and high-pressure are two competing rather than synergistic processes causing at least a partial cancelation of these two factors

36 MATERIALS SCIENCE↗

Space-Based Solar Power Conversion and Delivery Systems Study. Volume 3: Microwave Power Transmission Studies

The Microwave Fower Beam Ionosphere effects and critical interfaces between th Microwave Power Transmission System (MPTS) and the Satellite were studied as part of the NASA/MSFC continuing research on the feasibility of power transmission from geosynchronous orbit. Theoretical predications of ionospheric modifications produced by the direct interaction of the MPTS on the earth's upper atmosphere are used to determine their impact on the performance of the Microwave Power Beam and Pilot Beam System as well as on other RF systems effected by the ionosphere. A technology program to quantitatively define these interactions is developed. Critical interface areas between the MPTS and the satellite which could have a major impact on cost and performance of the power system are idenfified and analyzed. The areas selected include: use of either a 20 kV versus 40 kV Amplitron, thermal blockage effects of Amplitron heat radiation by the satellite structure, effect of dielectric carry-through structure on power beam, and effect of material sublimation on performance of the Amplitron in Geosynchronous Orbit.

Source record↗

Radiation Effects in Photonic Modulator Structures

%T Radiation Effects in Photonic Modulator Structures%A Charles Barnes%A Roger Greenwell%J SPIE, Photonics for Space Environments%C Orlando, Florida, U.S.A.%D April 18-20, 1995%K Radiation%K Photonic Modulator Structures%U http://techreports.jpl.nasa.gov/1995/95-1057.pdfA review is given of the effects of radiation on various photonic modulator materials and devices including polymer-based structures, insulator-based devices, semiconductor-based devices and spatial light modulators. We conclude by providing recommendations for further work in the area of radiation effects in photonic modulators.!

Photonic↗

Axion structure formation – II. The wrath of collapse

ABSTRACT The first paper in this series showed that quantum chromodynamic axion dark matter, as a highly correlated Bose fluid, contains extra-classical physics on cosmological scales. The source of the derived extra-classical physics is exchange–correlation interactions induced by the constraints of symmetric particle exchange and interaxion correlations from self-gravitation. The paper also showed that the impact of extra-classical physics on early structure formation is marginal, as the exchange–correlation interaction is inherently non-linear. This paper continues the study of axion structure formation into the non-linear regime, considering the case of full collapse and virialization. The N-body method is chosen to study the collapse, and its algorithms are derived for a condensed Bose fluid. Simulations of isolated gravitational collapse are performed for both Bose and cold dark matter fluids using a prototype N-body code. Unique Bose structures are found to survive even the most violent collapses. Bose post-collapse features include dynamical changes to global structures, creation of new broad sub-structures, violations of classical binding energy conditions, and new fine structures. Effective models of the novel structures are constructed and possibilities for their observation are discussed.

79 ASTRONOMY AND ASTROPHYSICS↗

Isopropyl 3-deoxy-α- D - ribo -hexopyranoside (isopropyl 3-deoxy-α-D-glucopyranoside): evaluating trends in structural parameters

Isopropyl 3-de­oxy-α-D-ribo-hexo­pyran­oside (isopropyl 3-de­oxy-α-D-gluco­py­ran­oside), C 9 H 18 O 5 , (I), crystallizes from a methanol–ethyl acetate solvent mixture at room temperature in a 4C1 chair con­form­ation that is slightly dis­torted towards the C5 S C1 twist-boat form. A com­parison of the structural parameters in (I), methyl α-D-gluco­pyran­oside, (II), α-D-gluco­pyranosyl-(1→4)-D-glucitol (maltitol), (III), and 3-de­oxy-α-D-ribo-hexo­pyran­ose (3-de­oxy-α-D-gluco­pyran­ose), (IV), shows that most endocyclic and exocyclic bond lengths, valence bond angles and torsion angles in the aldohexo­pyranosyl rings are more affected by anomeric configuration, aglycone structure and/or the con­form­ation of exocyclic substituents, such as hy­droxy­methyl groups, than by mono­deoxy­genation at C3. The structural effects observed in the crystal structures of (I)–(IV) were confirmed though density functional theory (DFT) calculations in com­puted structures (I) c –(IV) c . Exocyclic hy­droxy­methyl groups adopt the gauche–gauche (gg) con­form­ation (H5 anti to O6) in (I) and (III), and the gauche–trans (gt) con­form­ation (C4 anti to O6) in (II) and (IV). The O-glycoside linkage con­form­ations in (I) and (III) resemble those observed in disaccharides containing β-(1→4) linkages.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Synthesis, Structure, Characterization, and Decomposition of Nickel Dithiocarbamates: Effect of Precursor Structure and Processing Conditions on Solid-State Products

Single-crystal X-ray structures of four nickel dithiocarbamate complexes, the homoleptic mixed-organic bis-dithiocarbamates Ni[S2CN(isopropyl)(benzyl)]2, Ni[S2CN(ethyl)(n-butyl)]2, and Ni[S2CN(phenyl)(benzyl)]2, as well as the heteroleptic mixed-ligand complex NiCl[P(phenyl)3][(S2CN(phenyl)(benzyl)], were determined. Synthetic, spectroscopic, structural, thermal, and sulfide materials studies are discussed in light of prior literature. The spectroscopic results are routine. A slightly distorted square-planar nickel coordination environment was observed for all four complexes. The organic residues adopt conformations to minimize steric interactions. Steric effects also may determine puckering, if any, about the nickel and nitrogen atoms, both of which are planar or nearly so. A trans-influence affects the Ni-S bond distances. Nitrogen atoms interact with the CS2 carbons with a bond order of about 1.5, and the other substituents on nitrogen display transoid conformations. There are no strong intermolecular interactions, consistent with prior observations of the volatility of nickel dithiocarbamate complexes. Thermogravimetric analysis of the homoleptic species under inert atmosphere is consistent with production of 1:1 nickel sulfide phases. Thermolysis of nickel dithiocarbamates under flowing nitrogen produced hexagonal or -NiS as the major phase; thermolysis under flowing forming gas produced millerite (-NiS) at 300 C, godlevskite (Ni9S8) at 325 and 350 C, and heazlewoodite (Ni3S2) at 400 and 450 C. Failure to exclude oxygen results in production of nickel oxide. Nickel sulfide phases produced seem to be primarily influenced by processing conditions, in agreement with prior literature. Nickel dithiocarbamate complexes demonstrate significant promise to serve as single-source precursors to nickel sulfides, a quite interesting family of materials with numerous potential applications.

microscopy↗