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At least 199 records · Page 11

Correction of Sampling Errors in Ocean Surface Cross-Sectional Estimates from Nadir-Looking Weather Radar

The return from the ocean surface has a number of uses for airborne meteorological radar. The normalized surface cross section has been used for radar system calibration, estimation of surface winds, and in algorithms for estimating the path-integrated attenuation in rain. However, meteorological radars are normally optimized for observation of distributed targets that fill the resolution volume, and so a point target such as the surface can be poorly sampled, particularly at near-nadir look angles. Sampling the nadir surface return at an insufficient rate results in a negative bias of the estimated cross section. This error is found to be as large as 4 dB using observations from a high-altitude airborne radar. An algorithm for mitigating the error is developed that is based upon the shape of the surface echo and uses the returned signal at the three range gates nearest the peak surface echo.

Caylor, I. Jeff↗

Surface Exposure Ages of Space-Weathered Grains from Asteroid 25143 Itokawa

Space weathering processes such as solar wind ion irradiation and micrometeorite impacts are widely known to alter the properties of regolith materials exposed on airless bodies. The rates of space weathering processes however, are poorly constrained for asteroid regoliths, with recent estimates ranging over many orders of magnitude. The return of surface samples by JAXA's Hayabusa mission to asteroid 25143 Itokawa, and their laboratory analysis provides "ground truth" to anchor the timescales for space weathering processes on airless bodies.

Keller, L. P.↗

Coordinated Analysis of an Experimentally Space Weathered Carbonaceous Chondrite

The surfaces of airless bodies experience solar wind irradiation and micrometeorite impacts, a process collectively known as space weathering. These mechanisms alter the chemical composition, microstructure, and optical properties of surface materials and considerable work has been done to understand this phenomenon in lunar and ordinary chondritic materials. However, ongoing sample return missions Hayabusa2 to asteroid Ryugu and OSIRIS-REx to asteroid Bennu have prompted the need to study the effects of space weathering on hydrated, organic-rich materials, especially in the context of early results. Understanding space weathering of these samples is critical for properly interpreting remote sensing data during asteroid encounters, for sample site selection, and for the eventual study of returned samples. We can better understand space weathering of carbonaceous materials by simulating these processes in the laboratory. Recent experiments have shown that the changes in spectral characteristics of carbonaceous chondrites are not consistent among experiments, suggesting additional work is needed before these results can inform our understanding of spectral variations on asteroidal surfaces. Similarly, substantial work remains to characterize the chemical and microstructural effects of these processes in order to correlate these features with spectral changes. Here, we build on our previous work, presenting new results of the pulsed laser irradiation of the Murchison (CM2) meteorite to simulate micrometeorite impacts and the progressive space weathering of carbonaceous surfaces.

Thompson, M. S.↗

Short-Term Retrospective Land Data Assimilation Schemes

Subsurface moisture and temperature and snow/ice stores exhibit persistence on various time scales that has important implications for the extended prediction of climatic and hydrologic extremes. Hence, to improve their specification of the land surface, many numerical weather prediction (NWP) centers have incorporated complex land surface schemes in their forecast models. However, because land storages are integrated states, errors in NWP forcing accumulates in these stores, which leads to incorrect surface water and energy partitioning. This has motivated the development of Land Data Assimilation Schemes (LDAS) that can be used to constrain NWP surface storages. An LDAS is an uncoupled land surface scheme that is forced primarily by observations, and is therefore less affected by NWP forcing biases. The implementation of an LDAS also provides the opportunity to correct the model's trajectory using remotely-sensed observations of soil temperature, soil moisture, and snow using data assimilation methods. The inclusion of data assimilation in LDAS will greatly increase its predictive capacity, as well as provide high-quality land surface assimilated data.

Houser, P. R.↗

Alteration of Lunar Rock Surfaces through Interaction with the Space Environment

Space weathering occurs on all ex-posed surfaces of lunar rocks, as well as on the surfaces of smaller grains in the lunar regolith. Space weather-ing alters these exposed surfaces primarily through the action of solar wind ions and micrometeorite impact processes. On lunar rocks specifically, the alteration products produced by space weathering form surface coatings known as patina. Patinas can have spectral reflectance properties different than the underlying rock. An understanding of patina composition and thickness is therefore important for interpreting re-motely sensed data from airless solar system bodies. The purpose of this study is to try to understand the physical and chemical properties of patina by expanding the number of patinas known and characterized in the lunar rock sample collection.

Frushour, A. M.↗

Frost Monitoring and Forecasting Using MODIS Land Surface Temperature Data and a Numerical Weather Prediction Model Forecasts for Eastern Africa

Frost is a major challenge across Eastern Africa, severely impacting agricultural farms. Frost damages have wide ranging economic implications on tea and coffee farms, which represent a major economic sector. Early monitoring and forecasting will enable farmers to take preventive actions to minimize the losses. Although clearly important, timely information on when to protect crops from freezing is relatively limited. MODIS Land Surface Temperature (LST) data, derived from NASA's Terra and Aqua satellites, and 72‐hr weather forecasts from the Kenya Meteorological Service's operational Weather Research Forecast model are enabling the Regional Center for Mapping of Resources for Development (RCMRD) and the Tea Research Foundation of Kenya to provide timely information to farmers in the region. This presentation will highlight an ongoing collaboration among the Kenya Meteorological Service, RCMRD, and the Tea Research Foundation of Kenya to identify frost events and provide farmers with potential frost forecasts in Eastern Africa.

Kabuchanga, Eric↗

Modelling the Phanerozoic carbon cycle and climate: constraints from the 87Sr/86Sr isotopic ratio of seawater

A numerical model describing the coupled evolution of the biogeochemical cycles of carbon, sulfur, calcium, magnesium, phosphorus, and strontium has been developed to describe the long-term changes of atmospheric carbon dioxide and climate during the Phanerozoic. The emphasis is on the effects of coupling the cycles of carbon and strontium. Various interpretations of the observed Phanerozoic history of the seawater 87Sr/86Sr ratio are investigated with the model. More specifically, the abilities of continental weathering, volcanism, and surface lithology in generating that signal are tested and compared. It is suggested that the observed fluctuations are mostly due to a changing weatherability over time. It is shown that such a conclusion is very important for the modelling of the carbon cycle. Indeed, it implies that the conventional belief that the evolution of atmospheric carbon dioxide and climate on a long time scale is governed by the balance between the volcanic input of CO2 and the rate of silicate weathering is not true. Rather carbon exchanges between the mantle and the exogenic system are likely to have played a key role too. Further, the increase of the global weathering rates with increasing surface temperature and/or atmospheric CO2 pressure usually postulated in long-term carbon cycle and climate modelling is also inconsistent with the new model. Other factors appear to have modulated the weatherability of the continents through time, such as mountain building and the existence of glaciers and ice sheets. Based on these observations, a history of atmospheric carbon dioxide and climate during Phanerozoic time, consistent with the strontium isotopic data, is reconstructed with the model and is shown to be compatible with paleoclimatic indicators, such as the timing of glaciation and the estimates of Cretaceous paleotemperatures.

NASA Discipline Number 52-30↗

Energetic Particles Dynamics in Mercury's Magnetosphere

We investigate the drift paths of energetic particles in Mercury's magnetosphere by tracing their motion through a model magnetic field. Test particle simulations solving the full Lorentz force show a quasi-trapped energetic particle population that gradient and curvature drift around the planet via "Shabansky" orbits, passing though high latitudes in the compressed dayside by equatorial latitudes on the nightside. Due to their large gyroradii, energetic H+ and Na+ ions will typically collide with the planet or the magnetopause and will not be able to complete a full drift orbit. These simulations provide direct comparison for recent spacecraft measurements from MESSENGER. Mercury's offset dipole results in an asymmetric loss cone and therefore an asymmetry in particle precipitation with more particles precipitating in the southern hemisphere. Since the planet lacks an atmosphere, precipitating particles will collide directly with the surface of the planet. The incident charged particles can kick up neutrals from the surface and have implications for the formation of the exosphere and weathering of the surface

Energetic particles↗

Problems at the Leading Edge of Space Weathering as Revealed by TEM Combined with Surface Science Techniques

Both transmission electron micros-copy (TEM) and surface analysis techniques such as X-ray photoelectron spectroscopy (XPS) were instrumen-tal in making the first characterizations of material generated by space weathering in lunar samples [1,2]. Without them, the nature of nanophase metallic Fe (npFe0) correlated with the surface of lunar regolith grains would have taken much longer to become rec-ognized and understood. Our groups at JSC and UVa have been using both techniques in a cross-correlated way to investigate how the solar wind contributes to space weathering [e.g., 3]. These efforts have identified a number of ongoing problems and knowledge gaps. Key insights made by UVa group leader Raul Barag-iola during this work are gratefully remembered.

Christoffersen, R.↗

Weathering of iron sulfides under Mars surface ambient conditions

The study of iron sulfide surface alternation reactions under Mars' surface ambient conditions begun during 1980 was extended through improved irradiation design and experimental protocols. A wider range of humidities and more intense irradiation were incorporated in the study. X-ray photoelectron spectra of irradiated chips suggest formation of FeSO4, FeCO3, and an iron oxide on the iron sulfide substrates studied.

Blackburn, T. R.↗

Surface Exposure Ages of Space-Weathered Grains from Asteroid 25143 Itokawa

We use the observed effects of solar wind ion irradiation and the accumulation of solar flare particle tracks recorded in Itokawa grains to constrain the rates of space weathering and yield information about regolith dynamics. The track densities are consistent with exposure at mm depths for 104-105 years. The solar wind damaged rims form on a much faster timescale, <10(exp 3) years.

Keller, L. P.↗

Determining Surface Exposure Ages of Regolith Grains in Lunar Core Sample 73002 By Investigating Solar Particle Irradiation Damage

Space weathering causes the surface soils of airless bodies like the Moon to be micro-structurally and chemically altered by exposure to micrometeoroid bombardment and solar wind irradiation. These alterations accumulate in surface grains with continued residence in the uppermost millimeters of regolith. Low energy solar wind ions (largely H+ and He+) produce a layer of radiation damage as they become implanted in grain surfaces. Also present are solar energetic particle (SEP) tracks, which are nanoscale lineations within grain interiors formed by heavy, high-energy ions (mainly Fe group nuclei) penetrating up to millimeters below the surface. Recent work has determined that the width of solar wind-damaged rims on anorthite and olivine, and their respective SEP track densities are correlated with each other and with grain surface exposure age. Core sample 73002, recently released under the Apollo Next Generation Sample Analysis (ANGSA) Program, has provided an opportunity to study material collected from the light mantle formation in the Taurus-Littrow Valley during Apollo 17. The light mantle is thought to have been deposited vial and slide originating from the neighboring South Massif. Spectral analysis of bulk core soils found a plagioclase rich composition, confirming a highlands origin of the formation. Spectral profiles and ferromagnetic resonance (FMR) measurements of bulk soils sampled at cm-intervals from 73002 indicate that regolith up to~9.5 cm in depth have maturity indices consistent with longer durations of surface processing than samples deeper in the core. Thus, this upper ~9 cm layer likely represents the maximum extent of an in-situ reworking zone which may have persisted over 5 to 17million years. Here we present an analysis of grain exposure ages within the in-situ reworking zone of 73002derived from SEP track density measurements via transmission electron microscopy.

J A McFadden↗

Evaluating Surface Exposure Timescales Derived From Solar Energetic Particle Track Densities for Grains From Apollo 17 Core Sample 73002

Space weathering causes the surface soils of airless bodies like the Moon to be morphologically, microstructurally, and chemically altered due to micrometeoroid bombardment and solar wind exposure. These processes produce a multitude of microstructural and chemical changes that accumulate on individual soil grains that are continuously exposed on the surface. One characteristic is the formation of solar wind damaged rims on grains which develop from low energy solar wind particles penetrating <100 nm in depth. Also present are solar energetic particle (SEP) tracks, which are nanoscale streaks of irradiation damage in grain interiors formed by heavy, high energy ions (predominantly Fe group nuclei) originating from solar energetic particles (SEPs) that penetrate millimeters below the surface.

J. A. McFadden↗

The rate of pyrite decomposition on the surface of Venus

We report the results of a detailed experiment study of the kinetics and mechanism of pyrite (FeS2) chemical weathering under Venus surface conditions. Pyrite is thermodynamically unstable on the surface of Venus and will spontaneously decompose to pyrrhotite (Fe7S8) because the observed S2 partial pressure in the lower atmosphere of Venus is lower than the S2 vapor pressure over coexisting pyrite and pyrrhotite. Pyrite decomposition kinetics were studied in pure CO2 and CO2 gas mixtures along five isotherms in the temperature range 390-531 C. In all gas mixtures studied, pyrite thermally decomposes to pyrrhotite (Fe7S8), which on continued heating loses sulfur to form more Fe-rich pyrrhotites. During this process the pyrrhotites are also being oxidized to form magnetite (Fe3O4), which converts to maghemite (gamma-Fe2O3), and then to hematite (alpha-Fe2O3). The reaction rates for pyrite thermal decomposition to pyrrhotite were determined by measuring the weight loss. The thickness of the unreacted pyrite in the samples provided a second independent reaction rate measurement. Finally, Mossbauer spectra done on 42 of the 115 experimental samples provided a third set of independent reaction rate data. Pyrite decomposition follows zero-order kinetics and is independent of the amount of pyrite present. The rate of pyrite decomposition is apparently independent of the gas compositions used and of the CO2 number density over a range of a factor of 40. The derived activation energy of approximately 150 kJ/mole is the same in pure CO2, two different CO-CO2 mixtures, and a ternary CO-SO2-CO2 mixture. Based on data for a CO-CO2-SO2 gas mixture with a CO number density approximately 10 times higher than at the surface of Venus and a SO2 number density approximately equal to that at the surface of Venus, the rate of pyrite destruction on the surface of Venus varies from about 1225 +/- 238 days/cm at the top of Maxwell Montes (approximately 660 K) to about 233 +/- 133 days/cm in the plains of Venus (approximately 740 K). These lifetimes are very short on a geological time scale and show that pyrite cannot exist on the surface of Venus for any appreciable length of time.

Fegley, B., Jr.↗

Using ISCCP Weather States to Decompose Cloud Radiative Effects

The presentation will examine the shortwave (SW) and longwave (LW) cloud radiative effect CRE (aka "cloud radiative forcing") at the top-of-the-atmosphere and surface of ISCCP weather states (aka "cloud regimes") in three distinct geographical zones, one tropical and two mid-latitude. Our goal is to understand and quantify the contribution of the different cloud regimes to the planetary radiation budget. In the tropics we find that the three most convectively active states are the ones with largest SW, LW and net TOA CRE contributions to the overall daytime tropical CRE budget. They account for 59%, 71% and 55% of the total CRE, respectively. The boundary layer-dominated weather states account for only 34% of the total SW CRE and 41% of the total net CRE, so to focus only on them in cloud feedback studies may be imprudent. We also find that in both the northern and southern midlatitude zones only two weather states, the first and third most convectively active with large amounts of nimbostratus-type clouds, contribute ",40% to both the SW and net TOA CRE budgets, highlighting the fact that cloud regimes associated with frontal systems are not only important for weather (precipitation) but also for climate (radiation budget). While all cloud regimes in all geographical zones have a slightly larger SFC than TOA SW CRE, implying cooling of the surface and slight warming of the atmosphere, their LW radiative effects are more subtle: in the tropics the weather states with plentiful high clouds warm the atmosphere while those with copious amounts of low clouds cool the atmosphere. In both midlatitude zones only the weather states with peak cloud fractions at levels above 440 mbar warm the atmosphere while all the rest cool it. These results make the connection of the contrasting CRE effects to the atmospheric dynamics more explicit - "storms" tend to warm the atmosphere whereas fair weather clouds cool it, suggesting a positive feedback of clouds on weather systems. The breakdown of CRE by cloud regime are however not entirely similar between the two midlatitude zones. Despite the existence of an additional state in the nort!lern midlatitudes, only four weather states have net daytime CREs with absolute values above 100 Watts per square meter compared to six in the south. This reminds us that the environment where clouds occur also has a crucial role in determining their radiative effects. All the above make evident that reproducing grand averages of current CRE by climate models in only part of the challenge. If existing cloud regimes and shifts in their distributions and frequency of occurrence in a changed climate are not properly simulated, the radiative role of clouds will not be adequately predicted.

Oreopoulos, L.↗