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At least 199 records · Page 11

Positive holes in magnesium oxide - Correlation between magnetic, electric, and dielectric anomalies

The present magnetic susceptibility investigation of high purity MgO single crystals notes an anomally at 800 K which is associated with increasing electrical conductivity, a rise in static dielectric constant from 9 to 150, and the appearance of a pronounced positive surface charge. These phenomena can be accounted for in terms of peroxy defects which represent self-trapped, spin-paired positive holes at Mg(2+) vacancy sites. The holes begin to decouple their spins above 600 K.

Batllo, F.↗

Controlled method of reducing electrophoretic mobility of macromolecules, particles, or cells

A method of reducing electrophoretic mobility of macromolecules, particles, cells, and other substances is provided which comprises interacting in a conventional electrophoretic separating procedure, the substances with a polymer-linked affinity compound comprised of a hydrophilic neutral polymer such as polyethylene glycol bound to a second component such as a hydrophobic compound, an immunocompound such as an antibody or antibody active fragment, or a ligand such as a hormone, drug, antigen, or a hapten. The reduction of electrophoretic mobility achieved is directly proportional to the concentration of the polymer-linked affinity compound employed, and such reduction can comprise up to 100 percent for particular particles and cells. The present invention is advantageous in that electrophoretic separation can now be achieved for substances whose native surface charge structure had prevented them from being separated by normal electrophoretic means. Depending on the affinity component utilized, separation can be achieved on the basis of the specific/irreversible, specific/reversible, semi-specific/reversible, relatively nonspecific/reversible, or relatively nonspecific/irreversible ligand-substance interactions.

Vanalstine, James M.↗

Current collection in an anisotropic collisionless plasma

A general method is given to derive the current-potential relations in anisotropic plasmas. Orbit limit current is assumed. The collector is a conductive sphere or an infinite cylinder. Any distribution which is an arbitrary function of the velocity vector can be considered as a superposition of many mono-energetic beams whose current-potential relations are known. The results for two typical pitch angle distributions are derived and discussed in detail. The general properties of the current potential relations are very similar to that of a Maxwellian plasma except for an effective temperature which varies with the angle between the magnetic field and the charging surface. The conclusions are meaningful to generalized geometries.

Li, Wei-Wei↗

Hypervelocity impact effects on solar cells

One of the space hazards of concern is the problem of natural matter and space debris impacting spacecraft. In addition to mechanical damage, impact velocities greater than 5 km/sec can produce shock induced ionization effects with resultant surface charging and complex chemical interactions. The upper limit of the velocity distribution for these particles is on the order of 70 km/sec. The second source of particulate matter is due to the presence of man and the machinery needed to place satellites in orbit. This 'man made' component of the space debris consists of waste, rocket exhaust, and debris caused by satellite break-up. Most of the particles are small. However as the size increases, debris purposefully thrown overboard such as garbage and human waste, combined with paint chips, plastic, wire fragments, bolts, etc., become formidable hazards which completely dominate the distribution function for some orbits. These larger fragments can produce penetration and spalling of the thick metallic structures associated with spacecraft. The particles most often encountered are aluminum oxide, associated with fuel residue, and paint chips. These debris types can have a wide range of particle sizes. It has been stated that the design of spacecraft will have to take the debris evolution into account and provide additional suitable armor for key components in the near future. The purpose of this work was to subject samples from solar power arrays, one of the key components of any spacecraft, to a debris flux typical of what might be found in space, and measure the degradation of the power panels after impact.

Rose, M. Frank↗

Hypervelocity impact effects on solar cells

One of the space hazards of concern is the problem of natural matter and space debris impacting spacecraft. This phenomena has been studied since the early sixties and a methodology has been established to determine the relative abundance of meteoroids as a function of mass. As the mass decreases, the probability of suffering collisions increases, resulting in a constant bombardment from particles in the sub-micron range. The composition of this 'cosmic dust' is primarily Fe, Ni, Al, Mg, Na, Ca, Cr, H, O, and Mn. In addition to mechanical damage, impact velocities greater than 5 k m/sec can produce shock induced ionization effects with resultant surface charging and complex chemical interactions. The upper limit of the velocity distribution for these particles is on the order of 70 km/sec. The purpose of this work was to subject samples from solar power arrays to debris flux typical of what would be encountered in space, and measure the degradation of the panels after impact.

Rose, M. Frank↗

Downward-deployed tethered satellite systems, measurement techniques, and instrumentation - A review

This paper describes a number of scheduled and proposed Shuttle-based downward-deployed tethered satellite systems (TSSs) the purpose of which is to determine the structure of the lower thermosphere and to measure the atmospheric and aerodynamic effects in the vicinity of the satellite, the aerothermodynamic effects on the satellite's surface, and the dynamics of the tether and its endmass, the satellite. The instruments for the downward-deployed tethered missions will include mass spectrometers and other density sensors, plasma instrumentation, optical spectrophotometers, magnetometers, and instrumentation to measure the effects on satellite surface (such as the surface temperature, heat transfer, and pressure; gas adsorption on surfaces, chemistry with other gas molecules and surface material, and desorption from the surface; and surface charging).

Brown, Kenneth G.↗

Separation of rat pituitary secretory granules by continuous flow electrophoresis

The separation of growth hormone-containing cytoplasmic secretory granules from the rat pituitary gland by continuous flow electrophoresis is described. The results are consistent with the hypothesis that granule subpopulations can be separated due to differences in surface charge; these, in turn, may be related to the oligomeric state of the hormone.

Hayes, Daniel↗

Electrophoretic interactions and aggregation of colloidal biological particles

The separation of cells or particles from solution has traditionally been accomplished with centrifuges or by sedimentation; however, many particles have specific densities close to unity, making buoyancy-driven motion slow or negligible, but most cells and particles carry surface charges, making them ideal for electrophoretic separation. Both buoyancy-driven and electrophoretic separation may be influenced by hydrodynamic interactions and aggregation of neighboring particles. Aggregation by electrophoresis was analyzed for two non-Brownian particles with different zeta potentials and thin double layers migrating through a viscous fluid. The results indicate that the initial rate of electrophoretically-driven aggregation may exceed that of buoyancy-driven aggregation, even under conditions in which buoyancy-driven relative motion of noninteracting particles is dominant.

Davis, Robert H.↗

Inception of Snapover and Gas Induced Glow Discharges

Ground based experiments of the snapover phenomenon were conducted in the large vertical simulation chamber at the Glenn Research Center (GRC) Plasma Interaction Facility (PIF). Two Penning sources provided both argon and xenon plasmas for the experiments. The sources were used to simulate a variety of ionospheric densities pertaining to a spacecraft in a Low Earth Orbital (LEO) environment. Secondary electron emission is believed responsible for dielectric surface charging, and all subsequent snapover phenomena observed. Voltage sweeps of conductor potentials versus collected current were recorded in order to examine the specific charging history of each sample. The average time constant for sample charging was estimated between 25 and 50 seconds for all samples. It appears that current drops off by approximately a factor of 3 over the charging time of the sample. All samples charged in the forward and reverse bias directions, demonstrated hysteresis. Current jumps were only observed in the forward or positive swept voltage direction. There is large dispersion in tile critical snapover potential when repeating sweeps on any one sample. The current ratio for the first snapover region jumps between 2 and 4.6 times, with a standard deviation less than 1.6. Two of the samples showed even larger current ratios. It is believed the second large snapover region is due to sample outgassing. Under certain preset conditions, namely at the higher neutral gas background pressures, a perceptible blue-green glow was observed around the conductor. The glow is believed to be a result of secondary electrons undergoing collisions with an expelled tenuous cloud of gas, that is outgassed from the sample. Spectroscopic measurements of the glow discharge were made in an attempt to identify specific lines contributing to the observed glow.

Galofaro, J. T.↗

Microgravity Experiments to Evaluate Electrostatic Forces in Controlling Cohesion and Adhesion of Granular Materials

The bulk behavior of dispersed, fluidized, or undispersed stationary granular systems cannot be fully understood in terms of adhesive/cohesive properties without understanding the role of electrostatic forces acting at the level of the grains themselves. When grains adhere to a surface, or come in contact with one another in a stationary bulk mass, it is difficult to measure the forces acting on the grains, and the forces themselves that induced the cohesion and adhesion are changed. Even if a single grain were to be scrutinized in the laboratory, it might be difficult, perhaps impossible, to define the distribution and character of surface charging and the three-dimensional relationship that charges (electrons, holes) have to one another. The hypothesis that we propose to test in microgravity (for dielectric materials) is that adhesion and cohesion of granular matter are mediated primarily by dipole forces that do not require the presence of a net charge; in fact, nominally electrically neutral materials should express adhesive and cohesive behavior when the neutrality results from a balance of positive and negative charge carriers. Moreover, the use of net charge alone as a measure of the electrical nature of grain-to-grain relationships within a granular mass may be misleading. We believe that the dipole forces arise from the presence of randomly-distributed positive and negative fixed charge carriers on grains that give rise to a resultant dipole moment. These dipole forces have long-range attraction. Random charges are created whenever there is triboelectrical activity of a granular mass, that is, whenever the grains experience contact/separation sequences or friction.

Marshall, J.↗

The Axisymmetric Pulsar Magnetosphere

We present the structure of the axisymmetric force-free magnetosphere of an aligned rotating magnetic dipole, in the case in which there exists a sufficiently large charge density (whose origin we do not question) to satisfy the ideal MHD condition, E (raised dot) B = 0, everywhere. The unique distribution of electric current along the open magnetic field lines which is required for the solution to be continuous and smooth is obtained numerically. We expect that our solution will be useful as the starting point for detailed studies of pulsar magnetospheres under more general conditions, namely when either the force-free and/or the ideal MHD condition E (raised dot) B = 0 are not valid in the entire magnetosphere. Based on our solution, we consider that the most likely positions of such an occurrence are the polar cap, the crossings of the zero space charge surface by open field lines, and the return current boundary, but not the light cylinder.

Contopoulos, J.↗

The Living With a Star Geospace Investigations

The Living With a Star Geospace Investigations is established to effectively address those phenomena the Geospace environment that directly affect life and society. The priority science questions focus on two broad areas: (1) ionospheric variability, especially at mid-latitudes, that affects navigation and communications and (2) the source, acceleration mechanisms, and sinks of the radiation belts that degrade satellite lifetimes, produce surface charging, and threaten manned space flight. Candidate missions to address these science foci will be presented as well as possible additional investigations and experiments that would enable an understanding of the Geospace at the system level.

Spann, Jim↗

Two-dimensional life?

A model [Wachtershauser, G. (1988) Microbiol. Rev. 52, 452-484], according to which life started in the form of a monomolecular layer of interacting anionic metabolites electrostatically bound to a positively charged surface, is examined critically. The model raises a number of thermodynamic and kinetic difficulties.

NASA Discipline Number 52-20↗

Biofilms and the survival of opportunistic pathogens in recycled water

Microorganisms are likely to develop an organic film on pipes, water reservoirs and filters used for waste water reclamation during extended missions in space. These biofilms can serve to protect and concentrate potentially pathogenic microorganisms. Our investigation has emphasized the survival strategy of opportunistic pathogenic bacteria in distilled water. Pseudomonas aeruginosa and Staphylococcus aureus were used as test organisms. Cultures were incubated at 10 degrees, 25 degrees, and 37 degrees C. No viable Staphylococcus cells were detected after the first week of incubation. P. aeruginosa, however, survived in distilled water up to 5 months at all three temperatures tested. The starved cells were able to form a biofilm layer on stainless steel. The cells exhibited a negative surface charge. The charge may be involved in the adhesion of this bacterium to metal substrata. We are currently investigating the importance of adhesion in the survival of this and other potential human pathogens found in water recycling systems.

NASA Discipline Life Support Systems↗

Design and Modelling of a Microfluidic Electro-Lysis Device with Controlling Plates

Many Lab-on-Chip applications require sample pre-treatment systems. Using electric fields to perform cell-lysis in bio-MEMS systems has provided a powerful tool which can be integrated into Lab-on-a-Chip platforms. The major design considerations for electro-lysis devices include optimal geometry and placement of micro-electrodes, cell concentration, flow rates, optimal electric field (e.g. pulsed DC vs. AC), etc. To avoid electrolysis of the flowing solution at the exposed electrode surfaces, magnitudes and the applied voltages and duration of the DC pulse, or the AC frequency of the AC, have to be optimized for a given configuration. Using simulation tools for calculation of electric fields has proved very useful, for exploring alternative configurations and operating conditions for achieving electro cell-lysis. To alleviate the problem associated with low electric fields within the microfluidics channel and the high voltage demand on the contact electrode strips, two "control plates" are added to the microfluidics configuration. The principle of placing the two controlling plate-electrodes is based on the electric fields generated by a combined insulator/dielectric (gladwater) media. Surface charges are established at the insulator/dielectric interface. This paper discusses the effects of this interface charge on the modification of the electric field of the flowing liquid/cell solution.

Jenkins, A.↗

Working Group Reports and Presentations: Cis-lunar

Space agencies are committed to the "safe, sustained, affordable human and robotic exploration of the Moon, Mars, and beyond." However, we recommend that they explicitly define our ultimate goal and motivation in order to portray a sense of purpose to the public. Our goal is sustainable human settlement of the Moon and Mars and our motivation is to preserve the human race. All secondary exploration and science objectives flow from this main goal and are still imperative to our success. As an economic guiding principle, governments should be limited to those areas where only government can perform the activity and should recognize and coordinate with the larger private and military sectors. Also, space agencies must continue to fund the interdisciplinary science necessary to characterize environmental hazards associated with dust, radiation, surface charging, topology, and meteorites in order to make our first attempts at extraterrestrial living viable.

Laubscher, Bryan↗

Microfluidic System Simulation Including the Electro-Viscous Effect

This paper describes a practical approach using a general purpose lumped-parameter computer program, GFSSP (Generalized Fluid System Simulation Program) for calculating flow distribution in a network of micro-channels including electro-viscous effects due to the existence of electrical double layer (EDL). In this study, an empirical formulation for calculating an effective viscosity of ionic solutions based on dimensional analysis is described to account for surface charge and bulk fluid conductivity, which give rise to electro-viscous effect in microfluidics network. Two dimensional slit micro flow data was used to determine the model coefficients. Geometry effect is then included through a Poiseuille number correlation in GFSSP. The bi-power model was used to calculate flow distribution of isotropically etched straight channel and T-junction microflows involving ionic solutions. Performance of the proposed model is assessed against experimental test data.

Rojas, Eileen↗