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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Design study for Thermal Infrared Multispectral Scanner (TIMS)

The feasibility of dividing the 8-12 micrometer thermal infrared wavelength region into six spectral bands by an airborne line scanner system was investigated. By combining an existing scanner design with a 6 band spectrometer, a system for the remote sensing of Earth resources was developed. The elements in the spectrometer include an off axis reflective collimator, a reflective diffraction grating, a triplet germanium imaging lens, a photoconductive mercury cadmium telluride sensor array, and the mechanical assembly to hold these parts and maintain their optical alignment across a broad temperature range. The existing scanner design was modified to accept the new spectrometer and two field filling thermal reference sources.

Stanich, C. G.↗
NASA NTRS1981

Defect chemistry and characterization of Hg(1-x)Cd(x)Te

Undoped mercury cadmium telluride crystals were subjected to high temperature equilibration at temperatures ranging from 400 C to 655 C in various Hg atmospheres. Hall effect and mobility measurements were carried out on the crystals quenched to room temperature subsequent to the high temperature equilibration. The variation of the hole concentration in the cooled crystals at 77 K as a function of the partial pressure of Hg at the equlibration temperatures, together with a comparison of the hole mobility in the undoped samples with that in the copper and phosphorous doped samples yielded a defect model for the undoped crystals, according to which, the undoped crystals are essentially intrinsic at the equilibration temperatures and the native acceptor defects are doubly ionized. Native donor defects appear to be negligible in concentration, implying that the p to n conversion in these alloys is mainly due to residual foreign donor impurities. The thermodynamic constants for the intrinsic excitation process as well as for the incorporation of the doubly ionized native acceptor defects in the undoped crystals were obtained.

Vydyanath, H. R.↗
NASA NTRS1981

Defect chemistry and characterization Hg(1-x)Cd(x)Te

Iodine doped single crystal samples of mercury cadmium telluride were annealed at temperatures varying from 450 C to 600 C in Hg vapor and quenched to room temperature. Hall effect measurements at 77 K on the crystals cooled to room temperature indicate the samples to be n-type after anneals at high Hg pressures whereas they turn p-type after anneals at low Hg pressures; the electron concentration increases with increase in Hg pressure. The results are explained on the basis that the crystals are saturated with (Hg,Cd)I2, with a fraction of the iodine being present as donor occupying tellurium lattice sites and a fraction being present as acceptors resulting from the iodine on tellurium lattice sites pairing with the doubly ionized native acceptor defects. The solubility of the donor species increases with increase in Hg pressure, whereas that of the acceptor species increases with decrease in Hg pressure. Equilibrium constants for the incorporation of the iodine species as well as the pairing reaction were established.

Vydyanath, H. R.↗
NASA NTRS1981

The Limb Infrared Monitor of the Stratosphere /LIMS/ experiment - Temperature and nitrogen dioxide results

The Limb Infrared Monitor of the Stratosphere (LIMS) is a satellite-borne radiometer which scans across the earth's limb, measuring infrared radiation emitted by specific atmospheric gases in a number of broad channels. Instrumentation includes a folded telescope, which focuses the radiation from the limb onto an array of six mercury-cadmium-telluride detectors. A scan mirror within the telescope sweeps the fields of view across the horizon, with each up or down scan lasting 12 seconds. The measurements are inverted to yield distributions of temperature and nitrogen dioxide. The temperature is determined from two channels covering the intervals 595-739 per cm and 645-673 per cm of the 15 micron bands of CO2, with maximum signal to noise ratio of 500-1000. Nitrogen dioxide is determined from measurements in a channel from 1580-1613 per cm, with an S/N of approximately 100. Results show that the LIMS temperature and nitrogen dioxide data are characterized by high precision.

Gille, J. C.↗
NASA NTRS1981

Advanced methods for preparation and characterization of infrared detector materials

Differential thermal analysis data were obtained on mercury cadmium telluride alloys in order to establish the liquidus temperatures for the various alloy compositions. Preliminary theoretical analyses was performed to establish the ternary phase equilibrium parameters for the metal rich region of the phase diagram. Liquid-solid equilibrium parameters were determined for the pseudobinary alloy system. Phase equilibrium was calculated and Hg(l-x) Cd(x) Te alloys were directionally solidified from pseudobinary melts. Electrical resistivity and Hall coefficient measurements were obtained.

Lehoczky, S. L.↗
NASA NTRS1981

Moderate temperature detector development

P-side backside reflecting constant, photodiode characterization, and photodiode diffusion and G-R currents were investigated in an effort to develop an 8 m to 12 m infrared quantum detector using mercury cadmium telluride. Anodization, phosphorus implantation, and the graded band gap concept were approaches considered for backside formation. Variable thickness diodes were fabricated with a back surface anodic oxide to investigate the effect of this surface preparation on the diffusion limited zero bias impedance. A modeling technique was refined to thoroughly model diode characteristics. Values for the surface recombination velocity in the depletion region were obtained. These values were improved by implementing better surface damage removal techniques.

Marciniec, J. W.↗
NASA NTRS1981

Electric power needs in space

The power requirements for specific float zone experiments in space are presented. Power figures for the Space Shuttle and projected available power for advanced vehicles are given. The following power related trends are derived: (1) float zone processing of up to 5 cm diameter silicon and 16.0 cm diameter cadmium telluride can be conducted on a Shuttle pallet mission; (2) float zone processing of up to 8.5 cm diameter silicon for 70% total heating efficiency can be conducted on the initial MEC/space platform; (3) projected available host vehicle power for float zone sample heating; (4) induction heating is found to be the most promising heating method; (5) process control and ease of equipment integration into the host vehicle influence heating method selection.

Waltz, D. M.↗
NASA NTRS1981

1.0 to 2.5 micrometer short wavelength infrared /SWIR/ linear array technology for low background applications

A design concept is presented for a hybrid linear focal plane array operating in the 1.0 to 2.5 micron band under low background conditions such as encountered in spaceborne missions. The concept is based on direct gate coupling of the input from a photovoltaic mercury-cadmium telluride detector into a CCD multiplexer. Theoretical analysis indicates a specific detectivity at peak wavelength on the order of 10 to the 12th cm sq rt Hz/W when the system is operating at 200 K. Values of the voltage responsivity, specific detectivity and the relative voltage noise levels of the coupled system obtained in experimental studies with direct-gate-coupled 4.0-micron detectors support the theoretical analysis performed for the case of system detectivity limited by the CCD 1/f noise.

Stobie, J.↗
NASA NTRS1981

Further developments of electrographic image detectors

This paper reports the current status of a program to develop far- and middle-ultraviolet-sensitive electrographic detectors. These include large-format, semitransparent-photocathode detectors and opaque-photocathode electrographic Schmidt cameras. Modifications of a previously-demonstrated far-UV large-format detector to make it suitable for possible Shuttle/Spacelab space astronomy investigations have been implemented and tested. Middle-ultraviolet-sensitive large-format and Schmidt electrographic detectors are now in the laboratory development stage. Cesium telluride photocathodes are used to provide sensitivity in the 1700-3100 A spectral range, and techniques for processing these photocathodes are discussed. The preparation and use of polyimide barrier membranes, for protecting the photocathodes from deterioration by film outgassing, are described. A new opaque-photocathode vacuum-ultraviolet-sensitive electrographic detector has been demonstrated, which is based on an oblique-focusing electron optical system similar to that used by Princeton with electron-bombarded CCD arrays. Test results and potential applications of this detector are described.

Carruthers, G. R.↗
NASA NTRS1982

Refractive field correctors for the Starlab ultraviolet telescope

Field correctors for a one-meter, f/15 cassegrainian telescope were designed as part of a NASA-funded study of an astronomical obervatory on board of the Space Shuttle. By means of a Gasgoigne corrector and a biconcave field flattener, astigmatism and field curvature are corrected in a 0.6 deg field. Applicable wavelength ranges are limited by chromatic aberrations. The upper wavelength is selected to match a photocathode response limit. The lower wavelength limit is defined by a filter. Examples of usable wavelength ranges are: 210 nm - 1100 nm (multialkali photocathode, fused-silica corrector elements), 177 nm - 320 nm (cesium telluride photocathode, calcium fluoride correctors); and possibly 134 nm - 190 nm (cesium iodide photocathode, lithium fluoride correctors). Residual rms lateral color is smaller than 0.02 arc sec, and axial color is smaller than 0.25 arc sec (blur diameter at the ends of the wavelength range). The correctors introduce a small amount of coma. This is compensated by adjustment of the conic constants of the telescope mirrors.

Bottema, M.↗
NASA NTRS1983

High-temperature, high-pressure optical cells

For measuring the thermal diffusivity of HgCdTe melts by the laser-pulse method, an infrared transparent cell with flat windows of sufficient strength to withstand the high-vapor pressure of mercury had to be developed. Since mercury telluride expands on freezing, certain difficulties arose in returning the cell to room temperature without cracking it. T08 commercial fused silica is used in the construction of the cell, and the cells are transparent for wavelengths from about 3.5 microns in the infrared to 260 nm in the ultraviolet. The construction procedure for the required cells has been laborious. However, the obtained cell has routinely withstood internal pressures in excess of 60 atm at 900 C. Attention is given to the design of the windows, aspects of cell construction, and questions of loading.

Holland, L. R.↗
NASA NTRS1984

Lead salt diode lasers and development of tunable solid state lasers for remote sensing

Extensive studies of the output characteristics of single quantum well lead-telluride lasers developed at the General Motors Research Laboratories were carried out. Threshold currents, output powers and line structures were measured as a function of temperature. Very low-current lasing thresholds, record high operating temperatures and over 30% tuning ranges were achieved. Excellent reproducibilities, good far-field patterns and reasonable linewidths (approx. 500 kHz) were found.

Freed, C.↗
NASA NTRS1986

Measuring Thermal Diffusivity of Molten Semiconductors

Thermal diffusivity of molten and solid mercury cadmium telluride measured with aid of new apparatus. Knowledge gained from such measurements help efforts to grow high-quality single crystals of this semiconductor for use in infrared detectors: Without knowledge of thermal diffusivity, difficult to control growth rate of solid from molten material.

Crouch, R.↗
NASA NTRS1986

Determining the Temperature Profile in a Cylindrical Sample

Power-series solution extrapolates from axial temperature profile. Thermal profile in homogeneous axisymmetric body determined throughout body if axial temperature profile known at any radius. New theory developed as aid in research on growth of mercury cadmium telluride for infrared detectors. In particular, applicable to Bridgman-Stockbarger growth, in which round cylindrical ampoule of molten ternary semiconductor is solidified directionally, from one end to other.

Clayton, J. C.↗
NASA NTRS1984

Solidification and crystal growth of solid solution semiconducting alloys

Problems associated with the solidification and crytal growth of solid-solution semiconducting alloy crystals in a terrestrial environment are described. A detailed description is given of the results for the growth of mercury cadmium telluride (HgCdTe) alloy crystals by directional solidification, because of their considerable technological importance. A series of HgCdTe alloy crystals are grown from pseudobinary melts by a vertical Bridgman method using a wide range of growth rates and thermal conditions. Precision measurements are performed to establish compositional profiles for the crystals. The compositional variations are related to compositional variations in the melts that can result from two-dimensional diffusion or density gradient driven flow effects ahead of the growth interface. These effects are discussed in terms of the alloy phase equilibrium properties, the recent high temperature thermophysical data for the alloys and the highly unusual heat transfer characteristics of the alloy/ampule/furnace system that may readily lead to double diffusive convective flows in a gravitational environment.

Lehoczky, S. L.↗
NASA NTRS1984

Experimental investigation of the effects of gravity on thermosolutal convection and compositional homogeneity in Bridgman grown, compound semiconductors

Lead-tin-telluride has been grown in a thermally stable mode (solutally unstable) and in a solutally stable (thermally unstable) mode in a Bridgman configuration. Significant differences in the crystal morphology and the compositional homogeneity have been found between the two configurations. In addition, for the solutally stable configuration, evidence has been found that the flow characteristics in the melt change drastically during the course of the run.

Crouch, R. K.↗
NASA NTRS1983

An imaging spectrometer experiment for the Shuttle

An imaging spectrometer experiment concept for earth remote sensing, developed as part of NASA's Multispectral Linear Array program, will map a series of test sites at high spatial and spectral resolution from the vantage point of the Shuttle payload bay. The instrument covers the spectral range from 0.4 to 2.5 micrometers with a sampling interval of 10 nanometers in the visible and near infrared (to 1.0 micrometer) and 20 nanometers in the short wavelength infrared (1.0 to 2.5 micrometers). Resolution corresponding to a ground instantaneous field of view (pixel size) of 30 meters is provided over a swath width of 12 kilometers. On-board data editing is utilized to select a subset of the data stream for transmission to the ground. The instrument utilizes silicon and mercury cadmium telluride area array detectors. Pointing mirrors are included to permit specific test sites to be imaged from the Shuttle orbit.

Wellman, J. B.↗
NASA NTRS1984

Sealed silica pressure ampoules for crystal growth

The properties of vitreous silica and the mechanics of thick walled pressure vessels are reviewed with regard to the construction of sealed silica crucibles such as are used in the growth of mercury-cadmium telluride crystals. Data from destructive rupture tests are reported, failure modes discussed, and recommendations for design given. Ordinary commercial clear vitreous silica from flame fused quartz can withstand a surface stress of 20 MPa or more in this application.

Holland, L. R.↗