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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Thermal Energy Grid Storage (TEGS) Using Multi-Junction Photovoltaics (MPV) (Final Technical Report)

The project aimed to develop a thermal energy storage battery that converts electricity to heat and stores heat at ultra-high temperatures (>2000°C) in graphite blocks. The thermal battery discharge uses TPV cells that directly convert thermal energy to electrical energy without any moving parts. All components of this technology were successfully demonstrated at the laboratory scale in this project. Development of extremely low cost (< $20/kWh) grid level energy storage is a crucial necessity to reach high penetrations of renewables. The thermal battery technology developed in this project is expected to meet the cost targets that would enable full renewable penetration. The project focused on four key aspects of this technology: Converting electricity to ultra-high temperature heat: This was done through development of graphite Joule heaters. Major issues related to arcing, heater evaporation and deterioration due to long term oxidation were addressed to ensure lifetime exceeding the service lifetime of the battery. Converting ultra-high temperature heat back to electricity: This was done through development of beyond state-of-the-art TPV cells. We demonstrated energy conversion efficiency of >40% that is a world record and exceeds the average energy conversion efficiency of turbines in the USA. The findings are peer-reviewed and published in Nature, and received a wide media attention globally. Protecting the TPV cells to ensure lifetime: Deposition of volatilized material, such as sublimated material or particles, on the TPV cell could greatly reduce the efficiency and lifetime of the TPV cells by blocking their view to the heat source and causing cell overheating. In this project we developed and demonstrated an approach that reduces the deposition rate, ensuring long > 30 year life. Technoeconomic feasibility and commercialization: In collaboration with the project’s technical advisory board, we developed a technoeconomic model. The model shows that, at large scales (> 1GWh) the thermal battery technology is projected to reach a cost of energy stored below $10/kWh-e, with a cost per unit power < $0.5/W-e and a roundtrip efficiency of 50%. These results, along with the technical achievements in the project led to the creation of a startup company (i.e., Fourth Power) that is pursuing commercialization of the technology.

25 ENERGY STORAGE↗

Experimental study of a thermal energy storage-integrated heat pump system for load shifting in space cooling and heating

This study experimentally investigates an all-season thermal energy storage-integrated heat pump (TES-HP) system developed to enhance building energy efficiency and support grid-interactive operation through load shifting in both cooling and heating. A 4-ton commercial rooftop air-source heat pump was modified by integrating a hydronic thermal energy storage (TES) unit containing a phase change material (PCM) with a melting temperature of 22.0 °C. The system employs two reversing valves and three electronic expansion valves to enable six operating modes, including normal, TES charging, and TES discharging in both cooling and heating seasons. A subcooling-controlled electronic expansion valve was implemented to mitigate refrigerant maldistribution caused by unequal internal volumes among the heat exchangers. Compared with a baseline heat pump, the TES-HP reduced power consumption by 30–50% during cooling at an ambient temperature of 40.6 °C, and by up to 60% during heating at −15.0 °C, while maintaining high performance under cold-climate conditions. Additionaly to experimental evaluation, a simplified annualized on-peak analysis was conducted to compare the TES-HP with the baseline system, indicating an on-peak electricity reduction of approximately 876 kWhₑ per unit per year and associated on-peak cost savings under time-of-use pricing. These results demonstrate that the TES-HP effectively decouples HP operation from adverse ambient conditions, improving flexibility, resilience, and energy efficiency. This work advances prior research by experimentally proving the integration of PCM-based TES for a year-round, load-flexible HVAC operation.

42 ENGINEERING↗

DEMO-FTES: Development, Monitoring, and Control of Fracture Thermal Energy Storage in Crystalline Rock Formations (CRADA Final Report)

The DEMO-FTES project investigated the feasibility of Fracture Thermal Energy Storage (FTES) as a seasonal energy storage solution in crystalline rock formations. FTES leverages hydraulically induced fractures to exchange heat between circulating fluids and the surrounding rock mass, enabling long-term thermal energy retention due to the high specific heat and low thermal conductivity of rock. This approach has the potential to reduce heating and cooling energy demands and enhance building energy resilience. The project combined dimensional analysis, numerical modeling, laboratory experiments, and meso-scale field tests to evaluate FTES performance and advance its technology readiness level from 3 to 5. Scaling analysis identified key dimensionless parameters governing heat transfer and fluid flow, ensuring laboratory and field tests were representative of larger-scale systems. Numerical simulations using TOUGH and iTOUGH2 frameworks supported experiment design and interpretation, modeling fracture geometry, thermal-hydraulic behavior, and thermo-mechanical coupling. Laboratory tests at EPFL involved creating single and multiple fractures in 25 cm cubic samples of Gabbro and Granite under true triaxial stress.

25 ENERGY STORAGE↗

Insights into Methodologies and Stochastic Optimization of Thermal Energy Storage-Coupled Advanced Reactor Systems: A Comparison of Methods for Accessing Long-Term Sub-System Sizing Adequacy

This paper investigates the potential of coupling Thermal Energy Storage (TES) with Advanced Reactors (ARs) to address uncertainties posed by climate change in deep decarbonized power systems. The TES Use-case Team at Idaho National Laboratory (INL) has examined the potential of storing thermal energy from ARs during low demand periods and optimizing discharge during peak-priced hours, in both steady-state and transient conditions. Building on this groundwork, this study bridges the gaps in optimal sizing of the sub-system of TES-coupled AR systems using Risk Analysis Virtual Environment (RAVEN) and Holistic Energy Resource Optimization Network (HERON), INL?s framework for grid optimization. By applying this framework, we present statistically-robust optimal charge, discharge including balance of plant (BOP), and storage sizing for the High-Temperature Gas-Cooled Reactor (HTGR) with 203 MWth output. To this end, we generated synthetic price samples for 30 years using 2018 ? 2021 real-time market data from ERCOT, PJM and MISO. Our results reveals that the TES-coupled HTGR system is highly effective in maximizing revenue from electricity sales. We observed a substantial increase of 40 % in ERCOT and a noteworthy 15 % increase in PJM and MISO when compared to the conventional BOP without TES. This improvement is achieved through regionally-tailored sub-system sizing, which ranges from 398 to 416 MWth for the discharge system and 610 to 1029 MWth for the TES. We find that the average electricity price directly impacts the overall economics, while price volatility influences storage size. Additional sensitivity analyses were performed to access the impact of key assumptions on system economics and sizing, differentiating the optimization window (i.e., 24 ? 219 hours of chronological observations) and by imposing storage continuity condition in tracking TES cycles. We observed that at the 120-hour of the optimization window, a reasonable balance between computation time and accuracy was achieved. Our analysis also highlights the significance of conducting multi-day cycle analysis (> 120-hour) for TES to capture interaction between electricity prices and storage dynamics, providing a comprehensive understanding of TES behavior that AR developers should integrate into their plant designs.

25 ENERGY STORAGE↗

Experimental characterization of a triply periodic minimal surface PCM-to-air thermal energy storage device

Here, the expansion of energy production has intensified research into thermal energy storage (TES) to manage variability and improve system efficiency. Heat exchanger design is critical to achieving high power densities in TES systems. This study presents a high-surface-area phase change material (PCM)-to-air heat exchanger fabricated via resin-based stereolithography with a novel gyroid-based geometry tailored for enhanced performance. Material properties of the commercial PCM and resin were characterized using analytical techniques. A controlled air loop was used to evaluate heat transfer and pressure drop at various flow rates and inlet temperatures. Results show a strong dependence on the inlet temperature difference (ΔT) relative to the PCM melting point. During charging at the highest flow rate, increasing the inlet air temperature from ΔT = 5 °C to 20 °C above the melting point increased the average heat transfer rate by 187%. During discharging, decreasing the inlet temperature by the same ΔT below the melting point led to a 232% increase. Notably, the high-surface-area design enabled nearly symmetric charging and discharging behavior, a novel result for PCM-based TES systems which are often restricted by natural convection and other effects. The overall heat transfer coefficient was calculated and compared to values from standard design correlations. The maximum thermal effectiveness reached 95% at ΔT = 20 °C and a moderate flow rate of 34 m 3 /h. Peak coefficients of performance (COP) of 7 during charging and 6.4 during discharging were observed at ΔT = 20 °C and a low flow rate of 20 m 3 /h. These results demonstrate the viability of additively manufactured geometries for advanced TES applications.

25 ENERGY STORAGE↗

Thermal energy storage composites with preformed expanded graphite matrix and paraffin wax for long-term cycling stability and tailored thermal properties

Harvesting solar energy, preventing hot spots in electronics, transport of temperature-sensitive materials, and capture and repurposing of thermal energy require a latent heat thermal energy storage (TES) system to store/discharge heat repeatedly. For the practical application of phase change material (PCM) composites within TES systems, reliable thermal performance throughout its operational lifetime is essential. Nevertheless, the reliability of thermal conductivity in multi-phase composites over relevant numbers (>10 3 ) of melt/freeze cycles has barely been studied, particularly for composites containing fillers for thermal conductivity enhancement. Here, we introduce a preform-type expanded graphite (EG)/paraffin wax composite possessing highly robust heat transfer and storage properties even after 10,000 melt/freeze cycles. To achieve such excellent reliability, comparative studies on the combined influence of fabrication process, particle size, EG vol%, binder amount, and compaction on both magnitude and robustness of thermal conductivity were undertaken. Our parametric study has yielded a trade-off between thermal conductivity and latent heat. Based on our modeling, 20 vol% EG approaches the case where all EG particles are well-connected thermally while 10 vol% EG is close to loosely connected fillers in the matrix. Thermal conductivity of our paraffin composites containing 20 vol% EG (25.1 W·m -1 ·K -1 ) is highest among other EG/paraffin composites without aligned EG in the literature. After 10,000 thermal cycling, negligible conductivity fading was observed for the 10 vol% EG composite, while reduction in latent heat remained within 10% for all 10, 14, 17 and 20 vol% EG samples. Here we anticipate this work provides insight on suitable recipe for desirable magnitude and robustness of thermal conductivity of EG/paraffin composites.

25 ENERGY STORAGE↗

Demonstrate and De-Risk an Internally Lined Tank Design for Molten-Salt Thermal Energy Storage Benefitting CSP and Nuclear-Energy Sectors

The LIMOSA project extends the Gen3 CSP "Liquid Pathway" project to evaluate 720 degrees C thermal energy storage based on molten chloride salts. While SETO selected the Particle Pathway for Gen3 demonstration, LIMOSA was created to resolve a major risk factor with molten chloride salts - the design of the salt storage tank. The project team designed and assembled a test system leveraging experience from Oak Ridge National Lab and the Liquid Pathway Phases 1 and 2. The key innovation in the project is development of a graphite-foil barrier to protect insulation from salt intrusion and wetting.

chloride salt↗

Transient Physical Modelling for the Coupling of a High Temperature Gas Reactor with Thermal Energy Storage

Improving the flexibility of nuclear reactors to meet fluctuating demand on grids with high renewable energy generation penetration is key to improving reactor economics. Economic optimization using the code HERON gives maximum profit of coupling high temperature gas reactors (HTGRs) to thermal energy storage (TES) systems in the configuration shown in Figure 1 when following the demand in Figure 3. We look to model the physics of operation for a HTGR-TES using the HYBRID library in the code Modelica.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Additive Manufacturing of Thermal Energy Storage Composites with Microencapsulated Phase Change Materials Supported in a Multi-Polymer Matrix

Advanced manufacturing techniques, such as additive manufacturing (AM), that can directly integrate phase change materials (PCMs) have garnered interest in recent years due to their potential for development of highly efficient thermal energy storage architectures. Complex, high surface area geometries embedded with PCMs that are only feasible with AM can improve thermal management with reduced material waste. Our work focuses on developing composite filaments with microencapsulated phase change materials (MEPCM) bound within a single or dual polymer matrix that can be processed through standard filament extruders and additively manufactured using off-the-shelf 3D printers. Polymer powders, rather than polymer pellets, were key to homogenously mixed filaments achieving high MEPCM loadings with no deterioration in thermal energy storage (TES) capability during extrusion. Composite filaments contain upwards of 60 wt% MEPCM and were printed without loss in feature resolution, print speed, or layer adhesion. Storage enthalpies of printed composites range from 100 - 130 kJ/kg, which were within 5% of the theoretical enthalpy based on weight fraction of MEPCM and maintained enthalpies within 1% over 500 thermal cycles. We can reliably manufacture low density, high surface area structures like 15% gyroid infill, along with dense, compact pucks at a 100% concentric infill. Prints were also scalable to a 900 cm3 honeycomb infill heat exchanger model that has an estimated energy storage capacity of 9 Wh.

3D printing↗

Techno-Economic Analysis of Recuperated Joule-Brayton Pumped Thermal Energy Storage

This article describes a techno-economic model for pumped thermal energy storage systems based on recuperated Joule-Brayton cycles and two-tank liquid storage. Models have been developed for each component, with particular emphasis on the heat exchangers. Economic metrics such as the power and energy capital costs (i.e., per-kW and per-kWh capacity) and levelized cost of storage are evaluated by gathering numerous cost correlations from the literature, thereby enabling estimates of uncertainty. It is found that the use of heat exchangers with effectivenesses up to 0.95 is economically worthwhile, but higher values lead to rapidly escalating component size and system cost. Several hot storage fluids are considered; those operating at the highest temperatures (chloride salts) improve the round-trip efficiency but the benefit is marginal and may not warrant the additional material costs and risk when compared to lower-temperature nitrate salts. Cost-efficiency trade-offs are explored using a multi-objective optimization algorithm, yielding optimal designs with round-trip efficiencies in the range 59-72% and corresponding levelized storage costs of 0.12 0.03 and 0.38 0.10 $/kWhe. Lifetime costs are competitive with lithium-ion batteries for discharging durations greater than 6 h under current scenarios.

Carnot battery↗

Potential of Utilizing Thermal Energy Storage Integrated Ground Source Heat Pump System to Reshape Electricity Demand in the United States

Each year, more than 20% of electricity generated in the United States is consumed for meeting the thermal demands (e.g., space cooling, space heating, and water heating) in residential and commercial buildings. Integrating thermal energy storage (TES) with building’s HVAC systems has the potential to reshape the electric load profile of the building and mitigate the mismatch between the renewable generation and the demand of buildings. A novel ground source heat pump (GSHP) system integrated with underground thermal energy storage (UTES) has been proposed to level the electric demand of buildings while still satisfying their thermal demands. This study assessed the potential impacts of the proposed system with a bottom-up approach. The impacts on the electricity demand in various electricity markets were quantified. The results show that, within the capacity of the existing electric grids, the maximum penetration rate of the proposed system in different wholesale markets could range from 51% to 100%. Altogether, about 46 million single-family detached houses can be retrofitted into the proposed system without increasing the annual peak demand of the corresponding markets. By implementing the proposed system at its maximum penetration rate, the grid-level summer peak demand can be reduced by 9.1% to 18.2%. Meanwhile, at the grid level, the annual electricity consumption would change by –12% to 2%. The nationwide total electricity consumption would be reduced by 9%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Predictive model using artificial neural network to design phase change material-based ocean thermal energy harvesting systems for powering uncrewed underwater vehicles

Uncrewed Underwater Vehicles (UUVs) are a major beneficiary of the phase change material (PCM)-based ocean thermal energy harvesting technology for their mission needs. However, this technology relies on different parameters and energy conversion steps that could be critical to the general energy generation efficiency. Sea trials showed that the design performed lower than their laboratory design specifications. This underperformance results from different factors, mainly the UUV’s trajectory, travel time, underwater ocean currents, temperature fluctuations, and biofouling on the heat exchanger due to long term underwater operations. Therefore, there exists a need to continuously monitor the ambient energy harvesting system and predict system performance, for mission planning purposes. Two major parameters influencing the energy harvesting system include the final pressure inside the hydraulic energy storage vessel or accumulator, and the electrical load value. Here, this work focuses on the hydraulic to electric energy conversion system. Therefore, a combination of numerical model and experimental testing is used to develop a predictive model using artificial neural network using MATLAB. After validation with experimental testing, 1000 data samples obtained from the numerical model are used to train the ANN. Compared to the experimental results, the developed ANN model can predict in less than a second the designed benchtop system’s total efficiency with less than 15 percent maximum error range. This predictive model development represents a cost-effective way for optimization and a computational energy efficient mode aboard UUVs for mission planning for deployed UUVs using PCM-based ocean thermal energy harvesting technology.

30 DIRECT ENERGY CONVERSION↗

Pumped Thermal Energy Storage: Thermodynamics and Economics

This presentation gives an overview of Pumped Thermal Energy Storage (PTES), and in particular concentrates on the performance and cost of a Joule-Brayton cycle with liquid storage. Results for systems with supercritical CO2 are also presented. PTES may be hybridized with solar heat, and some examples are provided as well as an overview of potential issues.

41 EE - Solar Energy Technologies Office (EE-4S)↗

System and Component Development of Particle-Based Pumped Thermal Energy Storage

Reliable power supply from variable renewable resources requires energy storage at various scales to overcome resource intermittency. Long-duration energy storage (LDES, 10-100 hours) can improve dispatchability and grid reliability with increasing levels of renewable power supply. Thermal energy storage (TES) has siting flexibility and the ability to store a large capacity of energy, and thus has the potential to meet the LDES need and provide charging and discharging durations beyond the economic capacity of conventional batteries. TES technology has evolved from concentrating solar thermal power (CSP) generation and is recognized as an economic large-scale energy storage method. A standalone electric-thermal energy storage system supporting renewable integration of wind and solar power without CSP solar field can firm renewable generation and boost overall grid resilience and security.

concentrating solar thermal power↗

Technoeconomic Analysis of Steel Production with Electric Thermal Energy Storage

The iron and steel industry is an important manufacturing sector and one of the largest energy consumers in the United States and globally. Hydrogen direct reduction of iron ore (H2DRI) is considered a promising process that could enhance domestic steel production. This process requires hydrogen inlet temperatures up to 950 degrees C to drive the endothermic reduction of the iron ore pellets. In this work we investigate the technoeconomic performance of an H2DRI plant using electric thermal energy storage (ETES) technologies for the hydrogen heating, compared to conventional natural gas fired heaters, hydrogen fired heaters, and electric hydrogen heaters. A technoeconomic analysis framework for the plant is developed and used in multiple case studies, covering different hydrogen prices, grid electricity profiles, and financing scenarios. The levelized cost of steel production is found out to be in the range of $775-950/mt, which is mostly inside the benchmarked steel price of $941/mt. ETES-based hydrogen heating is found to be in par with conventional natural gas fired heaters, and cheaper than hydrogen fired heaters and electric hydrogen heaters. The major cost drivers are the iron ore and hydrogen feedstock, followed by the hydrogen compression and heating capital. Several insights and suggested future directions are identified.

08 HYDROGEN↗

Development, Monitoring, and Control of Fracture Thermal Energy Storage (FTES) in Crystalline Rock Formations (DEMO-FTES) (CRADA Final Report)

The DEMO-FTES project sought to demonstrate the thermal efficiency of fracture thermal energy storage (FTES) through numerical simulations, laboratory and meso-scale field tests. A detailed dimensional and scaling analysis was performed to identify key parameters and how they can be most effectively scaled to the laboratory and decameter scale. Numerical models were developed and used for three purposes: 1. Before field experiments, numerical modelling can be used to estimate fracture properties based on previous data from the EGS Collab experiment and then predict thermal hydrological behaviors of the fracture system with hot water injection/withdrawal, therefore, help to design the experiments (e.g., to decide the duration of the cycles based on the flow rate the pump can provide, and the estimated fracture properties); 2. After the field experiment, to estimate the system properties during the experiment (as the size and shape of a fracture could change over time), and understand why system performance is different than what has been predicted, i.e., to help understand the meso-scale test; and, 3. To model the lab experiments and estimate fracture properties and storage efficiency. Ultimately, the experiment and numerical models could shed light on the processes and uncertainty happening during fracture activation and help understand the scaling between lab and field test, and finally, the design and optimization of potential fracture thermal energy storage systems.

25 ENERGY STORAGE↗