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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Forecasting Global Fire Emissions on Subseasonal to Seasonal (S2S) Time Scales

Fire emissions of gases and aerosols alter atmospheric composition and have substantial impacts on climate, ecosystem function, and human health. Warming climate and human expansion in fire‐prone landscapes exacerbate fire impacts and call for more effective management tools. Here we developed a global fire forecasting system that predicts monthly emissions using past fire data and climate variables for lead times of 1 to 6 months. Using monthly fire emissions from the Global Fire Emissions Database (GFED) as the prediction target, we fit a statistical time series model, the Autoregressive Integrated Moving Average model with eXogenous variables (ARIMAX), in over 1,300 different fire regions. Optimized parameters were then used to forecast future emissions. The forecast system took into account information about region‐specific seasonality, long‐term trends, recent fire observations, and climate drivers representing both large‐scale climate variability and local fire weather. We cross‐validated the forecast skill of the system with different combinations of predictors and forecast lead times. The reference model, which combined endogenous and exogenous predictors with a 1 month forecast lead time, explained 52% of the variability in the global fire emissions anomaly, considerably exceeding the performance of a reference model that assumed persistent emissions during the forecast period. The system also successfully resolved detailed spatial patterns of fire emissions anomalies in regions with significant fire activity. This study bridges the gap between the efforts of near‐real‐time fire forecasts and seasonal fire outlooks and represents a step toward establishing an operational global fire, smoke, and carbon cycle forecasting system.

vapor pressure↗

Short-duration low-gravity experiments - Time scales, challenges and results

Short-duration low-gravity experiments can be conducted either in drop tubes and drop towers, or on sounding rockets and aircraft on ballistic trajectories. While these facilities offer more frequent flight opportunities and higher cost effectiveness than orbiting spacecraft, their relatively short low-gravity times are often perceived as limiting their utility to only a narrow range of applications and research areas. In this review it is shown, based on scaling laws for diffusive transport of momentum, species and heat, radiative heat transfer and capillarity-driven motion, that with proper consideration of the characteristic length scales, a host of phenomena can be meaningfully investigated during a few seconds. This usefulness of short-duration low-gravity facilities is illustrated with numerous results of recent studies of solidification, combustion, transport in multiphase systems, statics and dynamics of liquid surfaces, magnetic Benard convection, fluid management, transport properties and the graviperception in cells.

Rosenberger, F.↗

Time-Resolved Ultrafast Transient Polarization Spectroscopy to Investigate Nonlinear Processes and Dynamics in Electronically Excited Molecules on the Femtosecond Time Scale

Here, we report a novel experimental technique to investigate ultrafast dynamics in photoexcited molecules by probing the third-order nonlinear optical susceptibility. A non-colinear 3-pulse scheme is developed to probe the ultrafast dynamics of excited electronic states using the optical Kerr effect by time-resolved polarization spectroscopy. Optical heterodyne and optical homodyne detection are demonstrated to measure the third-order nonlinear optical response for the S 1 excited state of liquid nitrobenzene, which is populated by 2-photon absorption of a 780 nm 35 fs excitation pulse.

47 OTHER INSTRUMENTATION↗

Phase transitions in Zr at sub-nanosecond time scales

Here solid-solid phase transitions are investigated in Zr thin films using shock compression induced by a short laser pulse (<1 ns). Shock wave profiles are measured at free surfaces for films of different thicknesses (a few micrometers) using chirped-pulse line velocimetry with 10 ps time resolution. Experiments are performed at pressures up to ~50 GPa, which is sufficient to reach the ω and β phases under equilibrium conditions. The shock wave structures are analyzed using a general Lagrangian analysis method, which allows for the calculation of stress–strain paths and assessments of phase transition behavior. In agreement with recent short laser pulse experiments using ultra-fast x-ray diffraction, we do not find any clear evidence of the α–ω transition, though this would be expected from the phase diagram. Instead, we infer a direct transformation to a metastable β-phase at lower shock pressures (<20 GPa) and equilibrium β at higher pressures. Through the velocimetry analysis, we find α–β transformation onset times of less than ~100 ps and completion times of less than ~200 ps.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Empirical models of the eddy heat flux and vertical shear on short time scales

An intimate relation exists between the vertical shear and the horizontal eddy heat flux within the atmosphere. In the present investigation empirical means are employed to provide clues concerning the relationship between the shear and eddy heat flux. In particular, linear regression models are applied to individual and joint time series of the shear and eddy heat flux. These discrete models are used as a basis to infer continuous models. A description is provided of the observed relationship between the flux and the shear, taking into account means, standard deviations, and lag correction functions.

Ghan, S. J.↗

The Vitrification and Determination of the Crystallization Time Scales of a Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 Bulk Metallic Glass Forming Liquid

Zr58.5Nb2.8Cul5.6Nil2.8All0.3 is the first bulk glass forming liquid that does not contain beryllium to be vitrified by purely radiative cooling in the containerless electrostatic levitation process. The measured critical cooling rate is 1.75 K/s. The sluggish crystallization kinetics enable the determination of the time-temperature-transformation (TTT) diagram between the liquidus and the glass transition temperatures. At the nose of the TTT diagram, the shortest time to reach crystallization in an isothermal experiment is 32 seconds. In contrast to other bulk metallic glasses the scatter in the crystallization onset times are small at both high and low temperatures.

Hays, C. C.↗

The modulation of the low-latitude radiation budget by cloud and surface forcing on interannual time scales

Regionally confined interannual perturbations in the tropical radiation budget associated with east-west circulations are examined along with the forcing mechanisms of these perturbations in relation to surface and cloudiness variability. A zonal harmonic analysis of emitted longwave radiation emphasizes that these variations are largely controlled at the planetary wave scale. The overall effect leads to an approximately 50 deg/yr propagation phase speed that is considerably slower than the oceanic Kelvin wave capable of driving east-west longwave (LW) anomalies through SST feedback. Examination of the time-dependent radiative energetics over the tropics reveals that the aforementioned anomaly LW propagation is mainly due to cloud forcing associated with east-west circulation changes. Diabatic heating associated with coupled ocean-atmosphere feedback appears to be larger responsible for the LW anomaly propagation.

Sohn, Byung-Ju↗

The cooling time scales of growing sunspots

The evolution of brightness and magnetic fields of growing sunspots is studied. Growing sunspots are found to be brighter (or less dark) than stable sunspots with the same magnetic field strength. From comparison of brightness and magnetic fields of a growing sunspot with those of stable sunspots, a dynamical parameter, the cooling time, of the growing sunspot is obtained. Ten growing sunspots are studied, and cooling times of 0.5 to 9 hr are found. Two models, the inhibition model and the Alfven wave model, give cooling times of about 0.05 hr, based on linear theory. The discrepancy between theory and observation may be due to the fact that the observed sunspots are in the nonlinear regime.

Chou, Dean-Yi↗

Evolutionary time scales for circumstellar disks associated with intermediate- and solar-type stars

The frequency with which massive, optically thick disks form around solar-type and intermediate mass stars is determined. Criteria are developed for diagnosing massive, optically thick disks, and the fraction of young, optically visible stars surrounded by such disks is determined. The range of survival times for massive, optically thick disks is determined by determining the fraction of stars surrounded by such disks as a function of stellar age. The existence of the probable descendents of massive, optically thick disks - optically thin dust disks, perhaps analogous to the structures surrounding Vega and Beta Pictoris - is established. The existence of structures in transition between those which are optically thick from the stellar surface outward, and those which are optically thin throughout is established.

Strom, Stephen E.↗

Thick-target bremsstrahlung interpretation of short time-scale solar hard X-ray features

Steady-state analyses of bremsstrahlung hard X-ray production in solar flares are appropriate only if the lifetime of the high energy electrons in the X-ray source is much shorter than the duration of the observed X-ray burst. For a thick-target nonthermal model, this implies that a full time-dependent analysis is required when the duration of the burst is comparable to the collisional lifetime of the injected electrons, in turn set by the lengths and densities of the flaring region. In this paper we present the results of such a time-dependent analysis, and we point out that the intrinsic temporal signature of the thick-target production mechanism, caused by the finite travel time of the electrons through the target, may indeed rule out such a mechanism for extremely short duration hard X-ray events.

Emslie, A. G.↗

Global, Multi-Satellite Precipitation Analysis at Fine Time Scales using TRMM Plus other Satellites

A TRMM-based 3-hr analyses that uses TRMM observations to calibrate polar-orbit microwave observations from SSM/I (and other satellites, including AMSR on AQUA and ADEOS II) and geosynchronous IR observations is described. The various calibrated observations are combined into a final, 3-hr resolution map. This TRMM standard product will be available for the entire TRMM period (January 1998-present) in 2003 as product 3B-42 of the TRMM Version 6. A real-time version of this merged product is being produced and is available on the U.S. TRMM web site (trmm.gsfc.nasa.gov) at 0.25 degrees latitude-longitude resolution over the latitude range from 50 degrees N-50 degrees S. Examples will be shown, including its use in monitoring flood conditions and in relating weather-scale patterns to climate-scale patterns. Incorporation of this approach into the Global Precipitation Climatology Project (GPCP) will also be discussed.

Adler, Robert↗

Nonlinear reversal of photoexcitation on the attosecond time scale improves ultrafast X-ray diffraction images

The complex refractive index of a material governs its light-matter interactions, with intense light fields enabling tailored nonlinear optical responses. In the X-ray regime, rapid photoionization limits the potential of nonlinear techniques by inducing irreversible electronic damage. Here we demonstrate that intense, sub-femtosecond X-ray pulses, shorter than typical Auger decay times, can partially reverse photoexcitation via stimulated emission near atomic resonances. By analyzing thousands of coherent diffraction patterns and ion spectra from neon nanoparticles exposed to sub-fs and 15-fs pulses, we observe enhanced X-ray diffraction alongside reduced energy absorption for sub-fs pulses. Theoretical modeling attributes this to dynamics akin to Rabi flopping that prolong the lifetime of resonant states and suppress electronic bleaching. These findings suggest that ultrashort, intense X-ray pulses enable active control of X-ray refractive index and damage pathways, opening avenues for improved high-resolution imaging and nonlinear spectroscopy in complex nanoscale systems.

Ulmer, Anatoli [Universität Hamburg (Germany)] (OR↗

The dynamics of the Venus ionosphere. II - The effects of the time scale of the solar wind dynamic pressure variations

The effects on the upper dayside Venus ionosphere of a slow increase in solar wind dynamic pressure are simulated numerically with a one-dimensional (spherically symmetric) Lagrangian hydrodynamical code. The simulation is started with an extended ionosphere in pressure equilibrium with the solar wind at the ionopause. The pressure at the ionopause is gradually increased to five times the initial pressure with rise times of 5, 15, and 30 min. It is found that, for rise times greater than about 10 min, the compression of the ionopause is nearly adiabatic, with the ionopause moving downward at velocities of approximately 1-2 km/sec until it reaches a maximally compressed state, at which time the motion reverses. For short rise times the compression produces a shock wave similar to that occurring in the case of a sudden increase in pressure. The global implications of these processes are discussed within the context of Pioneer Venus observations and future theoretical work on this problem is outlined.

Stein, R. F.↗

TRMM Science Highlights and Status of Precipitation Estimates on Monthly and Finder Time Scales

The Tropical Rainfall Measuring Mission (TRMM) has completed three years in orbit. A summary of research highlights will be presented focusing on application of TRMM data to topics ranging from climate analysis, through improving forecasts, to microphysical research. Monthly surface rainfall estimates over the ocean based on different instruments on TRMM currently differ by 20%. The difference is not surprising considering the different type of observations available for the first time from TRMM with both the passive and active microwave sensors. Resolving this difference will strengthen the validity and utility of ocean rainfall estimates and is the topic of ongoing research utilizing various facets of the TRMM validation and field experiment programs. The TRMM rainfall estimates are intercompared among themselves and with other estimates, including those of the standard, monthly Global Precipitation Climatology Project (GPCP) analysis. The GPCP analysis agrees roughly in magnitude with the passive microwave-based TRMM estimates which is not surprising considering GPCP over-ocean estimates are based on passive microwave observations. A three year TRMM rainfall climatology is presented based on the TRMM merged product, including anomaly fields related to the changing ENSO situation during the mission. Results of merging TRMM, other passive microwave observations, and geosynchronous infrared rainfall estimates into a global, tropical 3-hour time resolution analysis will also be described.

Adler, Robert↗

TRMM: Science Highlights and Status of Precipitation Estimates on Monthly and Finer Time Scales

The Tropical Rainfall Measuring Mission (TRMM) has completed three years in orbit. A summary of research highlights will be presented focusing on application of TRMM data to topics ranging from climate analysis, through improving forecasts, to microphysical research. Monthly surface rainfall estimates Over the ocean based on different instruments on TRMM currently differ by 20%. The difference is not surprising considering the different type of observations available for the first time from TRMM with both the passive and active microwave sensors. Resolving this difference will strengthen the validity and utility of ocean rainfall estimates and is the topic of ongoing research utilizing various facets of the TRMM validation and field experiment programs. The TRMM rainfall estimates are intercompared among themselves and with other estimates, including those of the standard, monthly Global Precipitation Climatology Project (GPCP) analysis. The GPCP analysis agrees roughly in magnitude with the passive microwave-based TRMM estimates which is not surprising considering GPCP over-ocean estimates are based on passive microwave observations. A three-year TRMM rainfall climatology is presented based on the TRMM merged product, including anomaly fields related to the changing ENSO situation during the mission. Results of merging TRMM, other passive microwave observations, and geosynchronous infrared rainfall estimates into a global, tropical 3-hour time resolution analysis will also be described.

Adler, Robert↗

Bridging the time scale in exascale computing of chemical systems (Final Technical Report)

This report summarizes the work carried out with support of the United States Department of Energy under Award DE-SC0019441. The theme of this project was to develop and apply methods that allowed for the acceleration of atomistic calculations, particularly in challenging areas such as multiphase systems, electrified interfaces, uncertainty estimation, and applications requiring chemical accuracy, which tend to be applications where simulation time is severely bottlenecked by the computational time requirements. Much of the focus was on the application of emerging machine-learning methodologies, although a wide range of methodologies were employed. This report has two major sections. The first focuses on the methodological advances themselves. Within this part, we report a number of major advances, a few examples of which are described here. We report the first machine-learning scheme for the acceleration of electronically grand-canonical calculations (that is, those applicable to electrochemistry). We report new methods of performing transfer learning, in which physics-based priors can be used to provide predictions, often with uncertainty estimates, of images well outside of training sets; we also offer ways to fine-tune these transfer-learning models. We provide a new systematic means to generate and apply minimal training data sets to very large (10,000’s of atoms) systems, with only small training sets appropriate for electronic structure. We developed new methodologies to integrate surface vibrations into surface adsorption calculations. We made advances to the applicability of diffusion Monte Carlo methods to allow (learned) force prediction, finite-size error correction, and force-free means of searching for transition states. We integrated machine-learned atomistic predictions into mechanism generation codes. Additionally, we released new software including AmpTorch, a modernized version of our original atomistic machine-learning code Amp. The second part of this report focuses on the scientific applications that accompanied, and were often enabled by, the methodological advances described earlier. A few examples follow, but full details are in the individual chapters of the report. For example, we developed a general theory of phonon-induced friction on molecular adsorbates. We showed fundamentally how solvent influences the adsorption and desorption process and how it differs from the processes typically involved at the solid–gas interface, making aqueous-phase and electrocatalysis different from traditional thermocatalysis. We examined how metal–insulator and magnetic transitions can be probed, and accelerated exciton dynamics via Frenkel Hamiltonian parameters. We showed that the nearsighted force-training approach, developed within this project, can predict both the stability and reactivity of large nanoparticles, and can also lead to insights on catalyst coverage on binding energies and entropies. These applied studies, which generally integrated with our method development, allowed us to push forward the theoretical understanding of several reaction classes.

08 HYDROGEN↗

A Short-lived Three-Belt Structure for sub-MeV Electrons in the Van Allen Belts: Time Scale and Energy Dependence

In this study we focus on the radiation belt dynamics driven by the geomagnetic storms during September 2017. Besides the long-lasting three-belt structures of ultrarelativistic electrons (>2 MeV, existing for tens of days), which has been studied intensively during the Van Allen Probe era, it is found that magnetospheric electrons of hundreds of keVs can also have three-belt structures at similar L extent during storm time. Measurements of 500–800 keV electrons from MagEIS instrument onboard Van Allen Probes show double-peaked (L = 3.5 and 4.5, respectively) flux-versus-L-shell profile in the outer belt, which lasted for 2–3 days. During the time interval of such transient three-belt structure, the energy-versus-L spectrogram shows novel distributions differing from both “S-shaped” and “V-shaped” spectrograms reported previously. Such peculiar distribution also illustrates the energy-dependent occurrence of the three-belt profile. Furthermore, the gradual formation of “reversed energy spectrum” at L ~ 3.5 also indicates that hiss scattering inside the plasmapause contributed to the fast decay of sub-MeV remnant belt.

79 ASTRONOMY AND ASTROPHYSICS↗

Short Time Scale Stability Monitoring of GOES-16 Visible Channels by Utilizing Daily Inter-Calibration Events with both VIIRS and MODIS Sensors

The CERES project relies on MODIS, VIIRS and geostationary (GEO) imager retrieved cloud properties to compute surface fluxes and convert CERES and GEO radiances into TOA fluxes. The CERES TOA and surface fluxes need to be of climate quality and any anomaly or discontinuity in the calibration of the MODIS, VIIRS, GEO radiances need to be mitigated or avoided. Due to the nature of the CERES instrument calibration, there is a lag time of 3 months before the processing of the CERES product. This allows the CERES team to investigate any unforeseen problems in the input datasets or GEO calibration discontinuities or anomalies before processing. The CERES geostationary imager calibration team is developing a daily monitoring system of GEO, MODIS and VIIRS visible channel radiances in order to detect any day to day discontinuities as part of the CERES/GEO coincident ray-matching calibration efforts. a GEO discontinuity can be detected using two MODIS and 2 VIIRS sensors simultaneously, thus increasing the sampling greatly over a single GEO/LEO radiance pairs. This method is being automated and has already detected three erroneous radiometric calibration events, which were verified with the GOES-16 event log page. One advantage of daily monitoring is that the time period needed to verify calibration drifts is reduced and the confidence to detect even smaller magnitudes of the calibration drift is increased over monthly monitoring. By utilizing Terra and Aqua MODIS and NPP and NOAA20 VIIRS imagers to inter-calibrate GOES-16, the GOES-16 calibration can be referenced to anyone of these imagers. If the CERES project transitions between the Aqua-MODIS imager to the NOAA20 VIIRS imager, the NOAA-20 VIIRS imager can be radiometrically scale to Aqua-MODIS calibration, thus avoiding a GOES-16 calibration discontinuity.

David Robert Doelling↗