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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Design of Quasi-Terminator Orbits near Primitive Bodies

Quasi-terminator orbits are a class of quasi-periodic orbits around a primitive body that exist in the vicinity of the well-known terminator orbits. The inherent stability of quasi-terminator trajectories and their wide variety of viewing geometries make them a very compelling option for primitive body mapping missions. In this paper, we discuss orbit design methodologies for selection of an appropriate quasi-terminator orbit that would meet the needs of a specific mission. Convergence of these orbits in an eccentric, higher-fidelity model is also discussed with an example case at Bennu, the target of the upcoming NASA's OSIRIS-REx mission.

mapping↗

En Route Detect and Avoid Well Clear in Terminal Area Landing Pattern

A fast time simulation was conducted to test the detect and avoid Well Clear definition designed for en route use when an unmanned aircraft (UA) is approaching the landing pattern of the terminal area. Measures focused on were loss of well clear and alerts intended to help the pilot avoid loss of well clear. Data indicated warning-level alerts will occur outside the typical Class D airspace which may prevent the UA from normal operations in the terminal airspace. Other aircraft on 45o entry could result in “nuisance” alerts which may also prevent the UA from normal operations in the terminal airspace. However, eliminating horizontal proximity (τmod) has the potential to increase “nuisance” alerts on the 45o entry and downwind legs. Overall, this suggests that a more stringent definition of Well Clear may be advisable in the landing pattern of the terminal area.

Trujillo, Anna C.↗

Demonstration of a Modular, Scalable, Laser Communication Terminal for Manned Spaceflight Missions

Free-space laser communication systems are increasingly implemented on state of the art satellites for their high-speed connectivity. This work outlines the design, analysis and test of the Modular, Agile, Scalable Optical Terminal (MAScOT) we have developed to support Low-Earth Orbit (LEO) to deep-space communication links. In LEO, the MAScOT will be implemented on the International Space Station to support the Integrated Laser Communications Relay Demonstration (LCRD) LEO User Modem and Amplifier Terminal (ILLUMA-T) program. ILLUMA-T’s overarching objective is to demonstrate high bandwidth data transfer between LEO and a ground station via a geosynchronous (GEO) relay satellite. Outside of GEO, MAScOT will also be implemented on the Artemis-II mission to demonstrate high data rate optical communications to and from the moon as part of the Orion EM-2 Optical Communications (O2O) program. Both missions leverage the same modular architecture despite varying structural, thermal, and optical requirements. To achieve sufficient performance, the optical terminal relies on a coarse/fine nested tracking loop to realize sub-arcsecond pointing across +/- 120 deg elevation and +/- 175 deg azimuth field of regard. An integrated analysis of the MAScOT in support of both missions will be outlined in addition to scalable versions of this terminal for future missions.

Steven R. Gillmer↗

Dendroarchaeological Analysis of the Terminal Warehouse in New York City Reveals A History of Long-Distance Timber Transport During the Gilded Age

The Gilded Age of the late 19th century marked a period of rapid development and urbanization in New York City, U.S. To accommodate the high demand in wood products during that time, the timbers used for development of the city were increasingly sourced from locations distant from the northeastern United States. The Terminal Warehouse in the Chelsea neighborhood of New York City was one of many large buildings erected during this period of city expansion, and is an important symbol of New York City commerce during the late 1800s. To determine the history and provenance of timbers used in the construction of the Terminal Warehouse, we used tree-ring analysis on longleaf pine (Pinus palustris Mill.) joists that were original to the building. The ring-width patterns on the joists cross dated well internally, suggesting a common origin of the sampled lumber. Further, our Terminal Warehouse tree-ring chronology (1512–1891 C.E.) correlated strongly with existing tree-ring chronologies from western/central Georgia and eastern Alabama, indicating that the timbers were extracted from this region of the southeastern United States. The provenancing and dating of the Terminal Warehouse timbers underscores the important role that southern pines played in the expansion and development of New York City during the Gilded Age.

Dendroprovenance↗

Insights and Observations From Operating A Laser Communication Terminal on the International Space Station (ISS)

The Integrated Laser Communication Relay Demonstration (LCRD) Low Earth Orbit User Modem and Amplifier Terminal (ILLUMA-T) is the first user platform for NASA’s first laser communication relay, LCRD. ILLUMA-T is hosted on the International Space Station (ISS) as an external payload of the Japanese Experiment Module – Exposed Facility (JEM-EF) situated in slot 3. The LCRD payload is hosted on the STPSat-6 spacecraft, which orbits Earth in a geostationary orbit at position 112 W. The ILLUMA-T-to-LCRD system provides a bidirectional, space-to-ground laser communication relay link transferring data up to 1.2 Gbps utilizing two optical ground stations (OGS), OGS-1 in California and OGS-2 in Hawai’i. This paper describes lessons learned from operating the ILLUMA-T system and examines topics such as the end-to-end system availability, predictive versus actual ephemeris, acquisition adjustments, modem timing and handshaking, the terminal’s physical placement and accommodations, and experiment development, execution, and analysis. The authors of this paper operate both the LCRD and ILLUMA-T laser terminals on a daily basis including pass planning, procedure execution, acquisition analysis, and real-time terminal commanding and telemetry monitoring. LCRD is a joint project involving NASA Goddard Space Flight Center (GSFC), the California Institute of Technology Jet Propulsion Laboratory (JPL), and Massachusetts Institute of Technology Lincoln Laboratory (MIT LL). The ILLUMA-T payload is managed by NASA GSFC in Greenbelt, Maryland whose partners include the ISS program office at NASA’s Johnson Space Center (JSC) in Houston, Texas; the Huntsville Operations Support Center (HOSC) at Marshall Space Flight Center (MSFC) in Huntsville, Alabama; the Glenn Research Center (GRC) in Cleveland, Ohio; and the MIT LL in Lexington, Massachusetts. ILLUMA-T is funded by the Space Communications and Navigation (SCaN) Program at NASA Headquarters in Washington, D.C.

Laser Communications↗

Evaluation of an Arrival Coordinator Position in a Terminal Metering Enviornment

NASA has developed an integrated arrival-management solution for terminal area precision scheduling (TAPSS). Ahuman-in-the-loop simulation investigated the performance of the components of the TAPSS system. The focus ofthis paper is set on the terminal radar approach control (TRACON) traffic management controller (TMC) and ArrivalRadar Coordinator (ARC) combined position, which played an integral part in coordinating, adjusting, and instantiatingthe arrival schedule computed by the TAPSS system. Analysis of the simulation data highlights the roleof the ARC within the described terminal metering environment, describes his planning strategies, the interactionswith his tools and coordination with controllers, and lends insights to the impact of the ARCs actions to the arrivalproblem. High levels of comfort and confidence were reported when working with the TAPSS system. Challengesposed the sequencing of unscheduled satellite arrival flights during periods of peak demand. To accommodate thoseflights into the arrival stream, the ARC had to identify sequence slots, while minimizing disruptions to the schedule.

terminal metering↗

Methods for Color Center Preserving Hydrogen‐Termination of Diamond

Abstract Chemical functionalization of diamond surfaces by hydrogen is an important method for controlling the charge state of near‐surface fluorescent color centers, an essential process in fabricating devices such as diamond field‐effect transistors and chemical sensors, and a required first step for realizing families of more complex terminations through subsequent chemical processing. In all these cases, termination is typically achieved using hydrogen plasma sources that can etch or damage the diamond, as well as deposited materials or embedded color centers. This work explores alternative methods for lower‐damage hydrogenation of diamond surfaces, specifically the annealing of diamond samples in high‐purity, non‐explosive mixtures of nitrogen and hydrogen gas, and the exposure of samples to microwave hydrogen plasmas in the absence of intentional stage heating. The effectiveness of these methods are characterized by x‐ray photoelectron spectroscopy (XPS), and comparison of the results to density‐functional modelling of the surface hydrogenation energetics implicates surface oxygen ligands as the primary factor limiting the termination quality of annealed samples. Finally, photoluminescence (PL) spectroscopy is used to verify that both the annealing and reduced sample temperature plasma methods are non‐destructive to near‐surface ensembles of nitrogen‐vacancy (NV) centers, in stark contrast to plasma treatments that use heated sample stages.

36 MATERIALS SCIENCE↗

Kinetic Isotope Effect in the Radical Step-Growth Termination of On-Surface Synthesized Graphene Nanoribbons

Bottom-up on-surface synthesis has emerged as a versatile tool to access and finely tune the electronic structure of nanographenes. The controlled generation of reactive intermediates catalyzed and stabilized by a supporting substrate has enabled the design, assembly, and characterization of a wide range of exotic tailor-made quantum materials. Even under these tightly controlled conditions, the growth of extended structures remains limited by termination processes and undesired side reactions. Here, we identify an H atom transfer as one principal contributor to the radical step growth termination that limits the on-surface growth of N = 7 armchair graphene nanoribbons (7-AGNRs) on Au(111) surfaces. Analysis of 7-AGNR lengths grown from protiated and deuterated molecular precursors reveals a primary kinetic isotope effect of KIE ∼ 1.4. First-principles density functional theory calculations suggest that a concerted H atom transfer mechanism that involves the breaking of a C–H/D bond in the transition state is associated with radical chain termination.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

The surface termination of a Fe (III) spin crossover molecular salt

From a comparison of the known molecular stoichiometry and x-ray photoemission spectroscopy, it is evident that the Fe(III) spin crossover salt [Fe(qsal) 2 Ni(dmit) 2 ] has a preferential surface termination with the Ni(dmit) 2 moiety, where qsal = N(8quinolyl)salicylaldimine, and dmit 2- = 1,3-dithiol-2-thione-4,5-dithiolato. This preferential surface termination leads to a significant surface to bulk core level shift for the Ni 2p x-ray photoemission core level, not seen in the corresponding Fe 2p core level spectra. A similar surface to bulk core level shift is seen in Pd 3d in the related [Fe(qsal) 2 ] 2 Pd(dmit) 2 . Inverse photoemission spectroscopy, compared with the x-ray absorption spectra at the Ni-L3,2 edge provides some indication of the density of states resulting from the dmit 2- = 1,3-dithiol-2-thione-4,5-dithiolato ligand unoccupied molecular orbitals and thus supports the evidence regarding surface termination in the Ni(dmit) 2 moiety.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Study of an Automatic System for Control of the Terminal Phase of Satellite Rendezvous

An analytical and simulation study has been conducted of an automatic system for control of the terminal phase of rendezvous between two space vehicles. The basic system employs switching and thrust orientation criteria based upon relative-motion parameters first to establish a collision course and then to reduce the range and range rate to zero, simultaneously. In addition, a technique has been devised by which the system effects control based upon the total amount of fuel available for this phase of the space mission. The onboard equipment assumed for the intercepting vehicle includes a special-purpose computer, an attitude-control system, a single main rocket engine with, multi-start capabilities, and sensors capable of measuring range, line-of sight angles, and the time derivatives of these quantities. Techniques are developed. for employing control with either modulated thrust or on-off thrust at a constant level. The results of an analog simulation study of the automatic control system in which a six-degree-of freedom vehicle is assumed are presented for various initial conditions at the beginning of the terminal phase. The results of the study indicate that the automatic system can effectively control the terminal phase of rendezvous over a wide range of initial conditions and control-system requirements and, in addition, can utilize the available fuel in a very efficient manner.

RENDEZVOUS↗

Age-dependent loss of the C-terminal amino acid from alpha crystallin

Antiserum made against the C-terminal region of alpha-A crystallin was used to monitor the purification of a tryptic peptide containing the C-terminus of the molecule from fetal versus adult bovine lenses. Mass spectral analysis of the peptide preparations obtained from these lenses demonstrated the presence of a peptide (T20) containing an intact C-terminus from fetal lenses and the presence of an additional peptide (T20') from older lenses that contained a cleaved C-terminal serine. These results demonstrate an age-dependent processing of alpha-A crystallin in the bovine lens, resulting in removal of the C-terminal amino acid residue.

NASA Discipline Cell Biology↗

Involvement of the N-terminal region in alpha-crystallin-lens membrane recognition

Previous studies have demonstrated that alpha-crystallin binds specifically, in a saturable manner, to lens membrane. To determine the region of the alpha-crystallin molecule that might be involved in this binding, native alpha-crystallin from the bovine lens has been treated by limited digestion with trypsin, to produce alpha-A molecules with an intact C-terminal region, and a nicked N-terminal region. Compared to intact alpha-crystallin, trypsin-treated alpha-crystallin binds less avidly to lens membrane, suggesting that the N-terminal region of the alpha-A molecule may play a key role in the recognition between lens membrane and crystallin.

Non-NASA Center↗

Unmanned Aircraft Systems (UAS) Integration in the National Airspace System (NAS) Project: Terminal Operations HITL 1: Primary Results

This presentation covers the primary results of the Unmanned Aircraft Systems (UAS) Integration in the National Airspace System (NAS) Project Terminal Operations Foundational Human-in-the-Loop (HITL) simulation. The study tasked 16 pilots (half with manned piloting experience, and the other half with unmanned piloting experience) with maintaining "well clear" from other traffic while performing three different types of approaches into the Santa Rosa airport. A detect and avoid (DAA) system was provided to pilots to assist their ability to manage separation. The DAA system used in this test conformed to the criteria defined by RTCA Special Committee 228 (SC-228) in their Phase 1 Minimum Operational Performance Standards (MOPS) for UAS intending to operate in the NAS. The Phase 1 system was not designed to account for terminal operations, focusing instead on en route operations. To account for this, three different alerting and guidance configurations were presently tested in order to determine their effect on pilots operating the system in the terminal area. Results indicated that pilots with the alerting and guidance condition that provided the least amount of assistance (fewer alert levels and guidance types) experienced slightly increased pilot response times and rates of losses of separation. Additional data is presented on the effects of approach type and descriptive data on pilot maneuver preferences and ATC interoperability.

terminal environmen↗

Autonomous Coordinated Airspace Services for Terminal and Enroute Operations with Wind Errors

As novel uses of the airspace continue to multiply, there is increasing demand for access to high-density terminal areas around major airports. Since the predicted demand for urban-air-mobility and urban-package-delivery is very high, and the interactions between these different types of aircraft and missions will be extremely complex, increasingly autonomous systems will be required to manage safety and efficiency. This paper presents the current status of an autonomous safety system designed to ensure safe and efficient trajectories for aircraft in terminal airspace, the Terminal Advanced Airspace Concept. Previous papers have demonstrated the efficacy of this algorithm for handling commercial arrivals into a complex metroplex when there is no uncertainty present. This study extends that work to demonstrate the performance of the algorithm under high levels of uncertainty.

terminal operations↗

Autonomous Coordinated Airspace Services for Terminal and Enroute Operations with Wind Errors

As novel uses of the airspace continue to multiply, there is increasing demand for access to high-density terminal areas around major airports. Since the predicted demand for urban-air-mobility and urban-package-delivery is very high, and the interactions between these different types of aircraft and missions will be extremely complex, increasingly autonomous systems will be required to manage safety and efficiency. This paper presents the current status of an autonomous safety system designed to ensure safe and efficient trajectories for aircraft in terminal airspace, the Terminal Advanced Airspace Concept. Previous papers have demonstrated the efficacy of this algorithm for handling commercial arrivals into a complex metroplex when there is no uncertainty present. This study extends that work to demonstrate the performance of the algorithm under high levels of uncertainty.

terminal operations↗

Terminal Area Size and Switching Technique Analysis for Unmanned Aircraft Systems Operations

Unmanned Aircraft Systems (UAS) need to be able to comply with the Code of Federal Regulations Part 91 ‘see and avoid’ requirement. Detect and avoid (DAA) is an essential enabler for integrating UAS into the National Airspace System. A DAA system is a suite of sensors, trackers, and alerting and guidance algorithms that assists a remote pilot in maintaining separation from airborne traffic. Previous works have focused on operations transiting to and from Class A or special use airspace. More recent efforts have defined DAA system requirements for operations in and around the airport terminal environment. In continuation of this effort, this paper defines the DAA Terminal Area (DTA) size and switching technique for the DAA Well Clear (DWC) volume while transitioning between en route and the terminal area.

Unmanned Aircraft Systems↗

NASA's Progress Toward Commercial Space Communications — SATCOM Demonstrations and Wideband Multilingual Terminal Development

The National Aeronautics and Space Administration (NASA) Space Communications and Navigation (SCaN) Program is continuing to forge a path toward programmatic and operational transformation enabling commercialization of communications and navigation services to the greatest extent possible for near Earth users. U.S. National Space Policy is driving government agencies to incorporate commercial offerings and services to the maximum extent possible. As such, NASA has no plans to build or deploy additional Tracking and Data Relay Satellites (TDRS), but will seek to fill NASA mission space-relay capability needs using commercial satellite communications (SATCOM) providers and services. The goal is to support an approach that is both flexible to commercial service constructs and provides continuity of support with current assets as long as required. Progress toward commercial services is advancing in two key areas: (1) awards have been made for demonstrations of SATCOM services, and (2) development of wideband and multilingual user terminals has advanced to the flight demonstration phase. The Communications Services Project (CSP) at Glenn Research Center (GRC), has awarded Funded Space Act Agreements (FSAA) to six industry vendors. Inmarsat Government Inc., Kuiper Government Solutions (KGS) LLC, SES Government Solutions, Space Exploration Technologies, Telesat U.S. Services LLC, and Viasat Incorporated will receive a combined $278.5 million to complete technology development and in-space demonstrations over the next several years. The end-to-end service capabilities being targeted are based on existing NASA mission operational needs. Accordingly, each company has proposed a technical approach to lower costs, increase flexibility, and improve performance for a broad range of missions. In the current market, industry vendors operate at a range of different frequencies and use variable, sometimes proprietary, coding and modulations schemes. As NASA strives for a network comprised of services provided by multiple distinct suppliers, interoperability is a fitting solution to unify the network. Wideband and multi-lingual user terminals are being developed to bridge differences in industry services. Building on ground demonstrations completed in 2021, the Johns Hopkins Applied Physics Lab (APL) will be flight testing a multi-lingual wideband terminal (payload) and demonstrating connectivity to both government and commercial relay services. This paper provides a discussion of the progress toward NASA’s commercial space communications goals and consideration of key challenges and next steps.

commercialization↗

Manipulating Surface Termination of Perovskite Manganate for Oxygen Activation

For ABO 3 perovskite oxides, one of the key issues limiting their utilization in heterogeneous catalysis is the dominant presence of catalytically inactive A-site cations at the surface. The engineering of B-site terminated perovskites is considered as an effective method to address this issue, especially when dealing with Mn/Co-based perovskite catalysts. However, to date, such a strategy has not been fully successful and remains a major challenge in the field. Herein, a Mn-terminated La 0.45 Sr 0.45 MnO 3 (B-LSM) is successfully synthesized via a one-pot hydrothermal method, in which low-valence Mn ions partially occupy the A site to form the active Mn-excess phase. Additionally, experimental results and theoretical calculations reveal that the presence of the surface Mn termination in B-LSM optimizes the hybrid orbitals of Mn 3d-O 2p and promotes the activation of surface lattice oxygen, where the pristine inert lattice O 2- is evolved into active and stable lattice O 2-x . Such structural optimization significantly reduces the activation energy barriers on going from O 2 ⁻ species to important intermediate O - species during O 2 activation. Moreover, this results in good stability and Pt-like activity for the B-LSM during CO oxidation. This work offers a new chemical route for the design of advanced perovskite-type oxides possessing novel functions.

36 MATERIALS SCIENCE↗