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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Laminar diffusion flames under micro-gravity conditions

Laminar methane and propane gas-jet diffusion flames have been theoretically and experimentally studied at NASA-Lewis under microgravity conditions. It is noted that laminar diffusion flames are strongly affected by the combined effects of kinetics, radiation, and such transient phenomena as flame ignition, stabilization, and extinction. Observations on the distinctive nature of the flame color and luminosity parameters in microgravity are presented, and flame behavior under transient, high-deceleration rates is discussed. Test hardware and instrumentation design are described.

Edelman, Raymond B.↗

Theoretical petrology

In the present paper, some areas of growing interest in the American efforts in petrology during the 1975-1978 quadrennium are reviewed. In igneous petrology, studies of structures and thermodynamic properties of silicate melts and of kinetics of igneous processes are in a period of rapid growth. Plate tectonic concepts have had (and will no doubt continue to have) an important influence by focusing interest on specific problems and by providing a framework for the understanding of petrogenesis. An understanding of mantle processes and evolution through the integration of petrological, geophysical, and geochemical constraints has been developed over the past 20 years, and will undoubtedly provide direction for future petrological studies.

Stolper, E.↗

A semiempirical atmosphere for alpha Tauri from neutral iron lines

A semiempirical model photosphere is constructed for the K5 III star Alpha Tau. The technique employed is based on measurements of the central fluxes in a series of lines in multiplets. Observations of four multiplets having a range in excitation potential yield the excitation temperature as a function of the optical depth in a reference line. If the temperature structure of an assumed starting model is changed to force agreement between the observed and predicted line source functions under the assumption that excitation and electron kinetic temperatures are equal, the final semiempirical model is cooler by 150 K in the outer layers and warmer by 150 K in deeper layers than the theoretical model with the parameters adopted for Alpha Tau.

Ramsey, L. W.↗

Nova-driven winds in globular clusters

Recent sensitive searches for H-alpha emission from ionized intracluster gas in globular clusters have set upper limits that conflict with theoretical predictions. It is suggested that nova outbursts heat the gas, producing winds that resolve this discrepancy. The incidence of novae in globular clusters, the conversion of kinetic energy of the nova shell to thermal energy of the intracluster gas, and the characteristics of the resultant winds are discussed. Calculated emission from the nova-driven models does not conflict with any observations to date. Some suggestions are made concerning the most promising approaches for future detection of intracluster gas on the basis of these models. The possible relationship of nova-driven winds to globular cluster X-ray sources is also considered.

Scott, E. H.↗

Collisional excitation of interstellar methyl cyanide

Theoretical calculations are used to determine the collisional excitation rates of methyl cyanide under interstellar molecular cloud conditions. The required Q(L,M) as a function of kinetic temperature were determined by averaging fixed energy IOS (infinite order sudden) results over appropriate Boltzmann distributions of collision energies. At a kinetic temperature of 40 K, rates within a K ladder were found to be accurate to generally better than about 30 percent.

Green, Sheldon↗

The Stratosphere 1981: Theory and measurements

Measurements of trace species are compared with theoretical estimates and the similarities and the differences between the two sets of data are discussed. The theoretical predictions are compared with long term trends in both column content and altitude profile of ozone as observed from ground-based and satellite instruments. The chemical kinetics and photochemistry of the stratosphere were reviewed.

Source record↗

Chemical kinetic reaction mechanism for the combustion of propane

A detailed chemical kinetic reaction mechanism for the combustion of propane is presented and discussed. The mechanism consists of 27 chemical species and 83 elementary chemical reactions. Ignition and combustion data as determined in shock tube studies were used to evaluate the mechanism. Numerical simulation of the shock tube experiments showed that the kinetic behavior predicted by the mechanism for stoichiometric mixtures is in good agrement with the experimental results over the entire temperature range examined (1150-2600K). Sensitivity and theoretical studies carried out using the mechanism revealed that hydrocarbon reactions which are involved in the formation of the HO2 radical and the H2O2 molecule are very important in the mechanism and that the observed nonlinear behavior of ignition delay time with decreasing temperature can be interpreted in terms of the increased importance of the HO2 and H2O2 reactions at the lower temperatures.

Jachimowski, C. J.↗

A theoretical study of photovoltaic converters

The final phase of research was performed in the model simulation for the solar simulator pumped atomic iodine laser. The geometry for the steady state laser operation with axial lasant flow is illustrated. The chemical kinetics for this laser are described.

Heinbockel, John H.↗

Design of A CVD Reactor for the Deposition of Diamond in A Microgravity Environment

There is a growing body of theoretical and experimental evidence suggesting that the uniformity, rate, adhesion, quality, and other key properties of Chemical Vapor Deposition (CVD) diamond coatings are influenced by the gas mixing kinetics in the thermal plasma environment of the reaction chamber. The implementation of, for example, Microwave Plasma Enhanced Chemical Vapor Deposition (MPECVD) process in microgravity has, thus, been suggested. Such a diamond deposition system, which overcomes the limitations of present systems and which is distiguishable from them by the use of high pressure MPECVD and recirculation of the would be effluent hydrogen and carbon, is described. Given the key fact that there is nothing in the effluent of the MPECVD process that is truly a byproduct or 'waste', the system can, at least in principle, lend itself to being closed loop yet dynamic. The exhaust contains hydrogen and carbon species which can be recirculated to the plasma reactor, that is, since there are no unusable reaction byproducts, the effluent can be fed back to the reaction chamber with no detriment, thus allowing deployment in a microgravity environment.

M L Languell↗

Turbulent Radiation Effects in HSCT Combustor Rich Zone

A joint UTRC-University of Connecticut theoretical program was based on describing coupled soot formation and radiation in turbulent flows using stretched flamelet theory. This effort was involved with using the model jet fuel kinetics mechanism to predict soot growth in flamelets at elevated pressure, to incorporate an efficient model for turbulent thermal radiation into a discrete transfer radiation code, and to couple die soot growth, flowfield, and radiation algorithm. The soot calculations used a recently developed opposed jet code which couples the dynamical equations of size-class dependent particle growth with complex chemistry. Several of the tasks represent technical firsts; among these are the prediction of soot from a detailed jet fuel kinetics mechanism, the inclusion of pressure effects in the soot particle growth equations, and the inclusion of the efficient turbulent radiation algorithm in a combustor code.

Hall, Robert J.↗

Solutal Convection Around Growing Protein Crystal and Diffusional Purification in Space

This work theoretically addressed two subjects: 1) onset of convection, 2) distribution of impurities. Onset of convection was considered analytically and numerically. Crystal growth was characterized by slow surface incorporation kinetics, i.e. growth kinetic coefficient beta (cm/s) small as compared to the typical bulk diffusion rate, D(sub 1)/h, where D(sub 1) is diffusivity of major crystallizing protein and h is the crystal size. Scaling type analysis predicted two laws on how the convection rate, v, essentially the Peclet number, Pe exactly equal to vh/D(sub 1), depends on dimensionless kinetic coefficient a exactly equal to beta h/D(sub 1). Namely: Pe = C(sub 2/5)(aRa(sup 2/5)) and Pe = C(sub 1) aRa. Here, Reynolds number Ra = rho(sub 1)(sup 0)gh(sup 3)(rho(sub p) - rho(sub w))/rho(sup p)rho(sub 1)vD(sub 1), v being solution viscosity. The constants C(sub 2/5), exactly equal to 0.28 and C(sub 1) exactly equal to 10(exp -2) found from the full scale computer simulation for a cylindrical crystal inside big cylindrical vessel. The linear boundary conditions connecting protein and impurity concentration at the interface with the flux to/from the interface was applied. No-slip condition for Navier-Shocker equations was employed. With these conditions, flow and concentration distributions were calculated. Validity of the Pe(Ra) dependencies follows for wide range of parameters for which numerical calculations have been accomplished and presented by various points.

Chernov, A. A.↗

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamic maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of Region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicon carbide is the single stable solid phase in Region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4, and SiH. Analysis of the kinetics of reaction for Region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to Regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamics maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicone carbide is the single stable solid phase in region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4 and SiH. Analyses of the kinetics of reaction for region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗

Thermal relaxation of a two-dimensional plasma in a d.c. magnetic field. I - Theory. II - Numerical simulation

Theoretical considerations relevant to the rate of thermal relaxation of a two-dimensional plasma in a strong uniform dc magnetic field are developed. The Vahala-Montgomery (1971) kinetic description is completed by providing a cut-off time for the time of interaction of two particles contributing to the collision term. The kinetic equation is shown to predict that thermal relaxation varies as a function of defined dimensionless time.

Hsu, J.-Y.↗

Current loop coalescence model of solar flares

A computer simulation and theoretical study of the physical characteristics of the explosive coalescence of current-carrying loops is presented. Characteristics of the explosive coalescence include a large impulsive increase of the kinetic energies of electrons and ions, the simultaneous heating and acceleration of electrons and ions in high and low energy ranges, and a break in the energy spectra of electrons and ions. A characteristic double subpeak structure is found in the quasi-periodic oscillations found in the time profiles of the solar flares of June 7, 1980 and November 26, 1982 which can be explained in terms of the coalescence instability of two current loops.

Tajima, T.↗

Atomic oxygen effects on spacecraft materials: The state of the art of our knowledge

In the flight materials exposure data base extensive quantitative data is available from limited exposures in a narrow range of orbital environments. More data is needed in a wider range of environments as well as longer exposure times. Synergistic effects with other environmental factors; polar orbit and higher altitude environments; and real time materials degradation data is needed to understand degradation kinetics and mechanism. Almost no laboratory data exists from high fidelity simulations of the LEO environment. Simulation and test system are under development, and the data base is scanty. Theoretical understanding of hyperthermal atom surface reactions in the LEO environment is not good enough to support development of reliable accelerated test methods. The laser sustained discharge, atom beam sources are the most promising high fidelity simulation-test systems at this time.

Koontz, Steven L.↗

A predicted energetic ion signature of a neutral line in the geomagnetic tail

Under certain assumptions one can predict the formation of a magnetic neutral line on theoretical grounds, generally as a result of an unstable current sheet. Neutral points also seen to form spontaneously in a wide variety of plasma simulatioons, from MHD to fully kinetic. Hence, such magnetic null regions are central to some models of magnetotail energization and magnetic substorms. Yet the observational evidence for such regions remains controversial. This paper presents a new signature of a neutral line: the field-aligned ion beam characteristic of current sheet acceleration becomes dispersed into a 'ridge' in the velocity space distribution function as a neutral line is approached. The results were obtained using single-particle simulations in a fixed magnetic field model. The origin of the ridge is shown to be due to initially earthward going ions which pass through the neutral line region. These ions come from a smaller part of the initially antiearthward flowing distribution, generating the depletion of the distribution function below the ridge.

Martin, R. F., Jr.↗