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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Modular Stirling Radioisotope Generator

High efficiency radioisotope power generators will play an important role in future NASA space exploration missions. Stirling Radioisotope Generators (SRG) have been identified as a candidate generator technology capable of providing mission designers with an efficient, high specific power electrical generator. SRGs high conversion efficiency has the potential to extend the limited Pu-238 supply when compared with current Radioisotope Thermoelectric Generators (RTG). Due to budgetary constraints, the Advanced Stirling Radioisotope Generator (ASRG) was canceled in the fall of 2013. Over the past year a joint study by NASA and DOE called the Nuclear Power Assessment Study (NPAS) recommended that Stirling technologies continue to be explored. During the mission studies of the NPAS, spare SRGs were sometimes required to meet mission power system reliability requirements. This led to an additional mass penalty and increased isotope consumption levied on certain SRG-based missions. In an attempt to remove the spare power system, a new generator architecture is considered which could increase the reliability of a Stirling generator and provide a more fault-tolerant power system. This new generator called the Modular Stirling Radioisotope Generator (MSRG) employs multiple parallel Stirling convertor/controller strings, all of which share the heat from the General Purpose Heat Source (GPHS) modules. For this design, generators utilizing one to eight GPHS modules were analyzed, which provide about 50 to 450 watts DC to the spacecraft, respectively. Four Stirling convertors are arranged around each GPHS module resulting in from 4 to 32 Stirling/controller strings. The convertors are balanced either individually or in pairs, and are radiatively coupled to the GPHS modules. Heat is rejected through the housing/radiator which is similar in construction to the ASRG. Mass and power analysis for these systems indicate that specific power may be slightly lower than the ASRG and similar to the MMRTG. However, the reliability should be significantly increased compared to ASRG.

Stirling Cycle↗
NASA NTRS1972

United States Space Nuclear Electric Power Program.

The principal characteristics and design features of major systems and technological developments in U.S. space nuclear power activities are reviewed, covering radioisotope thermoelectric generators, reactor space electric power technology, and the advanced liquid metal cooled power reactor program. The topics also include heat source design and development, thermoelectric efficiency, high performance thermoelectric materials, and alloy developments. The U.S. Space Electric Power Program is described as one aimed at the development of a minimum number of standard components and power modules for both radioisotopes and reactor systems that will meet the widest possible range of future requirements. The need to reduce the high cost of the isotopic generators already used in space missions is stressed.

Newby, G. A.↗
NASA NTRS1985

Computerized data acquisition and analysis for measuring thermal diffusivity

JPL has been leading a concentrated effort to develop improved thermoelectric materials for space applications. Thermoelectric generators are an attractive source of electrical energy for space power because of lack of moving parts and slow degradation of performance. Thermoelectric material is characterized by: Seebeck coefficient, electrical resistivity and thermal conductivity. To measure the high temperature thermal conductivity is experimentally very difficult. However, it can be calculated from the specific heat and thermal diffusivity which are easier to measure at high temperatures, especially using the flash method. Data acquisition and analysis for this experiment were automated at JPL using inexpensive microcomputer equipment. This approach is superior to tedious and less accurate manual analysis of data. It is also preferred to previously developed systems utilizing expensive minicomputers or mainframes.

Chmielewski, A.↗
NASA NTRS2008

Thermal Expansion Studies of Selected High Temperature Thermoelectric Materials

Radioisotope thermoelectric generators (RTGs) generate electrical power by converting the heat released from the nuclear decay of radioactive isotopes (typically plutonium-238) into electricity using a thermoelectric converter. RTGs have been successfully used to power a number of space missions and have demonstrated their reliability over an extended period of time (tens of years) and are compact, rugged, radiation resistant, scalable, and produce no noise, vibration or torque during operation. System conversion efficiency for state-of-practice RTGs is about 6% and specific power less than or equal to 5.1 W/kg. Higher specific power would result in more on-board power for the same RTG mass, or less RTG mass for the same on-board power. The Jet Propulsion Laboratory has been leading, under the advanced thermoelectric converter (ATEC) project, the development of new high-temperature thermoelectric materials and components for integration into advanced, more efficient RTGs. Thermoelectric materials investigated to date include skutterudites, the Yb14MnSb11 compound, and SiGe alloys. The development of long-lived thermoelectric couples based on some of these materials has been initiated and is assisted by a thermo-mechanical stress analysis to ensure that all stresses under both fabrication and operation conditions will be within yield limits for those materials. Several physical parameters are needed as input to this analysis. Among those parameters, the coefficient of thermal expansion (CTE) is critically important. Thermal expansion coefficient measurements of several thermoelectric materials under consideration for ATEC are described in this paper. The stress response at the interfaces in material stacks subjected to changes in temperature is discussed, drawing on work from the literature and project-specific tools developed here. The degree of CTE mismatch and the associated effect on the formation of stress is highlighted.

silicon germanium↗
NASA NTRS2004

Disordered Zinc in Zn4Sb3 with Phonon-Glass and Electron-Crystal Thermoelectric Properties

By converting waste heat into electricity, thermoelectric generators could be an important part of the solution to today's energy challenges. The compound Zn4Sb3 is one of the most efficient thermoelectric materials known. Its high efficiency results from an extraordinarily low thermal conductivity in conjunction with the electronic structure of a heavily doped semiconductor. Previous structural studies have been unable to explain this unusual combination of properties. Here, we show through a comprehensive structural analysis using single-crystal X-ray and powder-synchrotron-radiation diffraction methods, that both the electronic and thermal properties of Zn4Sb3 can be understood in terms of unique structural features that have been previously overlooked. The identification of Sb3- ions and Sb-2(4-) dimers reveals that Zn4Sb3 is a valence semiconductor with the ideal stoichiometry Zn13Sb10. In addition, the structure contains significant disorder, with zinc atoms distributed over multiple positions. The discovery of glass-like interstitial sites uncovers a highly effective mechanism for reducing thermal conductivity. Thus Zn4Sb3 is in many ways an ideal 'phonon glass, electron crystal' thermoelectric material.

phases↗
NASA NTRS2017

Long-term Neutron Background Environment Measured by the Dynamic Albedo of Neutrons (DAN) Instrument onboard Mars Science Laboratory (MSL)

The Dynamic Albedo of Neutrons (DAN) instrument onboard Mars Science Laboratory (MSL) consists of a pulsed neutron generator (PNG) and the neutron detector/electronics (DE) module. There are two 3He-proportional counters used in the DE module. One counter is surrounded with a Cd shell enclosure and measures epi-thermal neutrons with >0.4 eV. The second detector does not have a Cd shell enclosure and measures both thermal and epi-thermal neutrons. The main scientific objectives of DAN are two-fold: (1) the primary objective is to measure the bulk hydrogen abundance (in forms of water or hydrated minerals) of the sub-surface and (2) the secondary objective is to measure the background neutron environment at the surface. DAN achieves the first objective by using a pulsed 14 MeV neutron source (ACTIVE mode). Emitted neutrons undergo a series of nuclear interactions with the regolith and lose energy. The DAN DE module then measures the time profile of the neutrons returned from the regolith. Even a small amount of hydrogen, as low as 0.1 weight % in the regolith, can effectively moderate the high energy neutrons [Mitrofanov, et al., ]. The less-moderated (or epi-thermal) neutrons arrive at the detector earlier than the more-moderated (or thermal) neutrons. The shape and magnitude of neutron time profile curves after pulses can be used to estimate the depth distribution of the hydrogen content. When no neutron pulse is used (PASSIVE mode) DAN measures the neutron background environment at the Mars surface. There are two sources of the background neutrons which DAN would measure: one is secondary neutrons generated by galactic cosmic ray (GCR) interactions with atmospheric and surface materials and the other is neutrons from the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) onboard MSL as a power source. The passive mode data for the first 1300 sols of the MSL mission are presented in this paper. A summary of the DAN surface operation is described by [Mitrofanov et al., 2012; Jun et al., 2013.

Tate, C.↗
NASA NTRS2021

Thermal Systems Modeling of Chemical Integrated Power Source (CHIPS) to Survive Lunar Night Environments

This paper presents the results of the systems level thermal modeling for a conceptual Chemical Heat Integrated Power Source (CHIPS). This proposed system offers a combined thermal and electrical power source to support survival of spacecraft operating in extreme low temperature lunar environments, without the use of radioisotope-based sources. A conceptual design study has been completed for this system, that uses heat generated by an exothermic chemical reaction in place of radioisotope or electrical heat sources. The goal of the study was to evaluate the feasibility of such as system through thermodynamic and chemical analysis and thermal modeling, and to identify technology gaps to inform a technology development and maturation plan. The specific technical objectives focused on delivery of 90-100 Wth thermal power and 30-40 We electrical power for 336 hours to a representative Commercial Lunar Payload Services (CLPS) lander, to support lunar surface survival and limited operations through a lunar night. The total system mass was targeted at ≤50 kg. A highly exothermic chemical reaction system is used to generate on-board electrical power for spacecraft systems, and thermal power to maintain critical spacecraft/lander systems within their allowable flight temperature (AFTs). Based on the very high energy content of the chemical reaction system, a much higher amount of heat per unit mass can be delivered to the spacecraft, relative to a rechargeable lithium-ion battery and electrical heater(s). Since radioisotope heaters or generators are not used, the system will be orders of magnitude lower in cost than a radioisotope heating/power unit, without the attendant regulatory complexities. As part of the CHIPS concept, a fraction of the thermal power generated is converted to electrical power via an appropriate thermal-to-electric converter technology (such as a free piston Stirling converter or a thermoelectric generator module), to provide power to critical loads. This approach is ideally suited to support operation of commercial landers (e.g., via the CLPS program). In most cases, these landers are only designed to operate during a portion of the lunar day, with no provision for survival through the lunar night. By supporting lunar night survival, a mission can be extended through the lunar night and at least into another lunar day, thus turning a nominal eight-day mission into a 36-day mission. Therefore, the current system demonstration will focus on scalability to support at least 336 hours (one lunar night) of continuous thermal and electrical power generation. Although initially targeted to support lunar equatorial landings, the technology is extensible to missions at the lunar poles, other extreme environments in the Solar System or even air-independent applications on Earth (e.g., ocean exploration).

West, William↗
NASA NTRS2021

Thermal Systems Modeling of Chemical Heat Integrated Power Source (CHIPS) to Survive Lunar Night Environments

This paper presents the results of the systems level thermal modeling for a conceptual Chemical Heat Integrated Power Source (CHIPS). This proposed system offers a combined thermal and electrical power source to support survival of spacecraft operating in extreme low temperature lunar environments, without the use of radioisotope-based sources. A conceptual design study has been completed for this system, that uses heat generated by an exothermic chemical reaction in place of radioisotope or electrical heat sources. The goal of the study was to evaluate the feasibility of such a system through thermodynamic and chemical analysis and thermal modeling, and to identify technology gaps to inform a technology development and maturation plan. The specific technical objectives focused on delivery of 90 to 100 Wth thermal power and 30 to 40 We electrical power for 336 hours to a representative Commercial Lunar Payload Services (CLPS) lander, to support lunar surface survival and limited operations through a lunar night. The total system mass was targeted at ≤50 kg. A highly exothermic chemical reaction system is used to generate on-board electrical power for spacecraft systems, and thermal power to maintain critical spacecraft/lander systems within their allowable flight temperature (AFTs). Based on the very high energy content of the chemical reaction system, a much higher amount of heat per unit mass can be delivered to the spacecraft, relative to a rechargeable lithium-ion battery and electrical heater(s). Since radioisotope heaters or generators are not used, the system will be orders of magnitude lower in cost than a radioisotope heating/power unit, without the attendant regulatory complexities. As part of the CHIPS concept, a fraction of the thermal power generated is converted to electrical power via an appropriate thermal-to-electric converter technology (such as a free piston Stirling converter or a thermoelectric generator module), to provide power to critical loads. This approach is ideally suited to support operation of commercial landers (e.g., via the CLPS program). In most cases, these landers are only designed to operate during a portion of the lunar day, with no provision for survival through the lunar night. By supporting lunar night survival, a mission can be extended through the lunar night and at least into another lunar day, thus turning a nominal eight-day mission into a 36-day mission. Therefore, the current system demonstration will focus on scalability to support at least 336 hours (one lunar night) of continuous thermal and electrical power generation. Although initially targeted to support lunar equatorial landings, the technology is extensible to missions at the lunar poles, other extreme environments in the Solar System or even air-independent applications on Earth (e.g., ocean exploration).

West, William↗
NASA NTRS2016

Development of Filled-Skutterudite Based Thermopile for High Temperature Sensors for Space and Terrestrial Applications

The Thermal Energy Conversion Technologies Group at the Jet Propulsion Laboratory has been pursuing the development of thermopiles capable of higher temperature operation in support of terrestrial and space sensing applications in extreme environments. The next-generation sensor technology would rely on filled skutterudite (SKD) compounds, the same materials currently being considered for use in the enhanced Multi-Mission Radioisotope Thermoelectric Generator (eMMRTG). We report on the design, development and fabrication of SKD-based prototype thermopile devices. The beginning-of-life (BOL) experimental and predicted performance of the SKD-based prototype thermopile in terms of electrical resistance, output voltage, current, power output and efficiency in the 423 to 723 K operating temperature range is reported and discussed.

Smith, Kevin L.↗
NASA NTRS2010

Fabrication of Lanthanum Telluride 14-1-11 Zintl High-Temperature Thermoelectric Couple

The development of more efficient thermoelectric couple technology capable of operating with high-grade heat sources up to 1,275 K is key to improving the performance of radioisotope thermoelectric generators. Lanthanum telluride La3-xTe4 and 14-1-11 Zintls (Yb14MnSb11) have been identified as very promising materials. The fabrication of advanced high-temperature thermoelectric couples requires the joining of several dissimilar materials, typically including a number of diffusion bonding and brazing steps, to achieve a device capable of operating at elevated temperatures across a large temperature differential (up to 900 K). A thermoelectric couple typically comprises a heat collector/ exchanger, metallic interconnects on both hot and cold sides, n-type and ptype conductivity thermoelectric elements, and cold-side hardware to connect to the cold-side heat rejection and provide electrical connections. Differences in the physical, mechanical, and chemical properties of the materials that make up the thermoelectric couple, especially differences in the coefficients of thermal expansion (CTE), result in undesirable interfacial stresses that can lead to mechanical failure of the device. The problem is further complicated by the fact that the thermoelectric materials under consideration have large CTE values, are brittle, and cracks can propagate through them with minimal resistance. The inherent challenge of bonding brittle, high-thermal-expansion thermoelectric materials to a hot shoe material that is thick enough to carry the requisite electrical current was overcome. A critical advantage over prior art is that this device was constructed using all diffusion bonds and a minimum number of assembly steps. The fabrication process and the materials used are described in the following steps: (1) Applying a thin refractory metal foil to both sides of lanthanum telluride. To fabricate the n-type leg of the advanced thermoelectric couple, the pre-synthesized lanthanum telluride coupon was diffusion bonded to the metal foil using a thin adhesion layer. (2) Repeating a similar process for the 14-1-11 Zintl p-type leg of the advanced thermoelectric couple. (3) Bonding thick CTE-matched metal plates on the metallized lanthanum telluride and Yb14MnSb11 to form the hot and cold sides of the thermoelectric couple. The calculated conversion efficiency of such an advanced couple would be about 10.5 percent, about 35 percent better than heritage radioisotope thermoelectric technology that relies on Si-Ge alloys. In addition, unlike Si-Ge alloys, these materials can be combined with many other thermoelectric materials optimized for operation at lower temperatures to achieve conversion efficiency in excess of 15 percent (a factor of 2 increase over heritage technology).

Ravi, Vilupanur A.↗
NASA NTRS1989

On the development of the power sources for the Ulysses and Galileo missions

The technically challenging European Space Agency Ulysses mission to explore the polar regions of the Sun and the NASA Galileo mission to explore Jupiter have prompted the development of the most powerful radioisotope thermoelectric generator (RTG) yet built for space use. This RTG, which was designed to provide a minimum of 285 We at beginning of mission builds upon the successful thermoelectric technology developed for the RTGs now in operation on the Voyager 1 and 2 spacecraft. A total of four flight RTGs, one ground qualification RTG, and one Engineering Unit have been built and tested for the Galileo and Ulysses missions. The tests have included measurements of functional performance, vibration response, magnetic signature, mass properties, nuclear radiation, and vacuum performance. The RTGs are fully flight qualified for both missions and are ready for launch.

Gary L. Bennett↗
NASA NTRS1980

Advanced thermoelectric material development at JPL

A large number of planetary missions under consideration for the next two decades will be using radioisotope thermoelectric generators to provide the necessary spacecraft electrical power. Performance, reliability, lifetime and cost of these RTGs are expected to be more demanding and will require the development of advanced thermoelectric materials. An advanced thermoelectric materials development program is being conducted by JPL and is the subject of this paper. Under this program, alloys of rare earth chalcogenides have been synthesized and their thermoelectric properties evaluated. The selection of specific compounds on which the program is currently concentrating is influenced by criteria such as low thermal conductivity, reasonably high operating temperatures (not less than 1000 C) and stability of the compounds. The paper discusses the rationale, approach and current status of the program. In addition, the thermoelectric and thermophysical property measurement used to evaluate the materials are described. The preliminary results and analysis of these experimental data are also given.

Stapfer, G.↗
NASA NTRS1978

Selenide technology evaluation program at JPL

Results are presented for experimental and analytical investigations of the overall performance of a selenide radioisotope thermoelectric generator intended to provide the electrical power for interplanetary spaceprobes such as the Galileo mission to Jupiter. The discussion focuses on technology areas of concern, electrical properties of the selenide thermoelectric materials used, and thermal conductivity of these materials for superior performance. It is shown that the selenide thermoelectric materials offer the advantage of high conversion efficiency. The long-life requirement on the power system for the Galileo mission necessitates proper design, known fabrication techniques, and reproducible assembly techniques in order to ensure stability of the thermoelectric properties. However, the thermophysical properties - sublimation and creep - of the p-material remains an area of considerable concern.

Stapfer, G.↗
NASA NTRS1989

Summary of miscellaneous hazard environments for hypothetical Space Shuttle and Titan IV launch abort accidents

The various analyses described here were aimed at obtaining a more comprehensive understanding and definition of the environments in the vicinity of the Radioisotope Thermal Generator (RTG) during certain Space Transportation System (STS) and Titan IV launch abort accidents. Addressed here are a number of issues covering explosion environments and General Purpose Heat Source Radioisotope Thermoelectric Generator (GPHS-RTG) responses to those environments.

Eck, M.↗
NASA NTRS2012

In-Situ Growth of Yb2O3 Layer for Sublimation Suppression for Yb14MnSb11 Thermoelectric Material for Space Power Applications

The compound Yb14MnSb11 is a p-type thermoelectric material of interest to the National Aeronautics and Space Administration (NASA) as a candidate replacement for the state-of-the-art Si-Ge used in current radioisotope thermoelectric generators (RTGs). Ideally, the hot end of this leg would operate at 1000 C in the vacuum of space. Although Yb14MnSb11 shows the potential to double the value of the thermoelectric figure of merit (zT) over that of Si-Ge at 1000 C, it suffers from a high sublimation rate at elevated temperatures and would require a coating in order to survive the required RTG lifetime of 14 years. The purpose of the present work is to measure the sublimation rate of Yb14MnSb11 and to investigate sublimation suppression for this material. This paper reports on the sublimation rate of Yb14MnSb11 at 1000 C (approximately 3 x 10(exp -3) grams per square centimeter hour) and efforts to reduce the sublimation rate with an in situ grown Yb2O3 layer. Despite the success in forming thin, dense, continuous, and adherent oxide scales on Yb14MnSb11, the scales did not prove to be sublimation barriers.

Nesbitt, James A.↗
NASA NTRS2010

Implications of Wind-Assisted Aerial Navigation for Titan Mission Planning and Science Exploration

The recent Titan Saturn System Mission (TSSM) proposal incorporates a montgolfiere (hot air balloon) as part of its architecture. Standard montgolfiere balloons generate lift through heating of the atmospheric gases inside the envelope, and use a vent valve for altitude control. A Titan aerobot (robotic aerial vehicle) would have to use radioisotope thermoelectric generators (RTGs) for electric power, and the excess heat generated can be used to provide thermal lift for a montgolfiere. A hybrid montgolfiere design could have propellers mounted on the gondola to generate horizontal thrust; in spite of the unfavorable aerodynamic drag caused by the shape of the balloon, a limited amount of lateral controllability could be achieved. In planning an aerial mission at Titan, it is extremely important to assess how the moon-wide wind field can be used to extend the navigation capabilities of an aerobot and thereby enhance the scientific return of the mission. In this paper we explore what guidance, navigation and control capabilities can be achieved by a vehicle that uses the Titan wind field. The control planning approach is based on passive wind field riding. The aerobot would use vertical control to select wind layers that would lead it towards a predefined science target, adding horizontal propulsion if available. The work presented in this paper is based on aerodynamic models that characterize balloon performance at Titan, and on TitanWRF (Weather Research and Forecasting), a model that incorporates heat convection, circulation, radiation, Titan haze properties, Saturn's tidal forcing, and other planetary phenomena. Our results show that a simple unpropelled montgolfiere without horizontal actuation will be able to reach a broad array of science targets within the constraints of the wind field. The study also indicates that even a small amount of horizontal thrust allows the balloon to reach any area of interest on Titan, and to do so in a fraction of the time needed by the unpropelled balloon. The results show that using the Titan wind field allows an aerobot to significantly extend its scientific reach, and that a montgolfiere (unpropelled or propelled) is a highly desirable architecture that can very significantly enhance the scientific return of a future Titan mission.

aerobot↗
NASA NTRS2007

Development of Advanced Stirling Radioisotope Generator for Space Exploration

Under the joint sponsorship of the Department of Energy and NASA, a radioisotope power system utilizing Stirling power conversion technology is being developed for potential future space missions. The higher conversion efficiency of the Stirling cycle compared with that of Radioisotope Thermoelectric Generators (RTGs) used in previous missions (Viking, Pioneer, Voyager, Galileo, Ulysses, Cassini, and New Horizons) offers the advantage of a four-fold reduction in PuO2 fuel, thereby saving cost and reducing radiation exposure to support personnel. With the advancement of state-of-the-art Stirling technology development under the NASA Research Announcement (NRA) project, the Stirling Radioisotope Generator program has evolved to incorporate the advanced Stirling convertor (ASC), provided by Sunpower, into an engineering unit. Due to the reduced envelope and lighter mass of the ASC compared to the previous Stirling convertor, the specific power of the flight generator is projected to increase from 3.5 to 7 We/kg, along with a 25 percent reduction in generator length. Modifications are being made to the ASC design to incorporate features for thermal, mechanical, and electrical integration with the engineering unit. These include the heat collector for hot end interface, cold-side flange for waste heat removal and structural attachment, and piston position sensor for ASC control and power factor correction. A single-fault tolerant, active power factor correction controller is used to synchronize the Stirling convertors, condition the electrical power from AC to DC, and to control the ASCs to maintain operation within temperature and piston stroke limits. Development activities at Sunpower and NASA Glenn Research Center (GRC) are also being conducted on the ASC to demonstrate the capability for long life, high reliability, and flight qualification needed for use in future missions.

Chan, Jack↗