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At least 199 records · Page 11

Exfoliation of Cu-Containing Poly(triazine imide): From Three-Dimensional to Two-Dimensional Particle Morphology

Controlling the morphological parameters of extended covalent organic frameworks remains challenging and represents an important yet often elusive metric of consideration. Typically, carbon nitride materials possess local ordering but remain largely amorphous in terms of their long-range order and orientation. This study probes the synthesis of a crystalline carbon nitride, poly(triazine imide) lithium bromide which possesses an atomically-precise extended structure, and demonstrates its exfoliation into a two-dimensional hexagonal sheet-like morphology. Furthermore, a previously unreported carbon nitride material, poly(triazine imide) copper bromide, or PTI-CuBr, was developed through an additional flux-assisted cation-exchange process and is shown to retain its internal Cu cations during solvothermal exfoliation. Characterization by dynamic light scattering and high-angle annular dark-field scanning electron microscopy reveals the morphological changes and captures the high aspect ratio of the thin carbon nitride sheets with <10 nm thickness while maintaining hundreds of nm in width. Additional characterization by energy-dispersive spectroscopy and X-ray photoelectron spectroscopy confirms that the Cu:Br:N molar ratio was maintained within the extended layers throughout the exfoliation process. This top-down synthesis approach differs from typical methods that isolate thin sheets for subsequent metal−cation coordination and illustrates the importance of maintaining oxygen-free conditions to minimize copper clustering. Thus, this new approach is demonstrated to provide a consistent and more homogeneous occupancy of the PTI pore spaces throughout the carbon nitride framework.

Exfoliation↗

3D quantum ghost imaging microscope

Quantum ghost imaging uses quantum-entangled photons to generate a two-dimensional image with only a bucket detector at the sample. Here we expand on this approach to generate a three-dimensional image without scanning. A quantum-entangled light source directly links information between a pair of 2D sensors, one of which captures a standard image from one perspective and a second sensor which captures a ghost image from a perpendicular perspective. By correlating the spatial information from the two detectors for each photon pair, we obtain three dimensions of spatial information (x, y, and z) for each scattered photon. We demonstrate that this system can study microscopic environments by imaging scattering from metallic nanoparticle clusters. This approach has the potential to greatly reduce the flux of light required to obtain a 3D image of a biological sample and thereby extend the number of images that can be obtained before photodamaging the sample.

Eshun, Audrey [Lawrence Livermore National Laborat↗

Scattering in discrete random media with implications to propagation through rain

The multiple scattering effects on wave propagation through a volume of discrete scatterers were investigated. The mean field and intensity for a distribution of scatterers was developed using a discrete random media formulation, and second order series expansions for the mean field and total intensity derived for one-dimensional and three-dimensional configurations. The volume distribution results were shown to proceed directly from the one-dimensional results. The multiple scattering intensity expansion was compared to the classical single scattering intensity and the classical result was found to represent only the first three terms in the total intensity expansion. The Foldy approximation to the mean field was applied to develop the coherent intensity, and was found to exactly represent all coherent terms of the total intensity.

Ippolito, L. J., Jr.↗

An experimental investigation of a three-dimensional wall jet

An experimental investigation of the effects of a curved and flat wall surface on the flow development of an axisymmetric jet exhausting into a moving airstream has been made. Of primary concern was the comparison of the one-point statistical properties of the unconfined jet to the quantities measured in the flows over a flat plate and a curved wall surface. Quantities measured in this investigation included mean velocities in all three directions, turbulent intensities, autocorrelations, power spectral densities, and intermittencies. The investigation was confined to the near field of the turbulent jet. The curved wall (flap) was found to have a very large effect on both the mean velocity and the turbulent velocity components of the flowfield. The potential core region of the jet was found to break up most rapidly for the flow over the flap. A laser-Doppler velocimeter, using a phase locked-loop processor, was used to make the desired velocity field measurements. To determine the intermittency profiles, a laser light scattering technique was employed.

Catalano, G. D.↗

Measurements of the sampling volume of an infrared laser doppler velocimeter for the study of feasibility of simultaneous three-dimensional velocity profile mapping

High resolution incoherent mapping of the sampling volume was performed to determine the three dimensional profile of the volume of the beam from which information can be obtained by scattering. The incoherent sampling volume of the infrared laser Doppler velocimeter was found to be heavily dependent upon the configuration of the outgoing laser beam. In general when only half the beam is allowed to focus at the focal plane, the x, y traverses indicate a broader beam with nominal side lobes. However, if the total beam is permitted to impinge on the focal plane there is substantial narrowing of the beam with increased maximum intensity and an increase in side lobes. The double maximum indicated by the coherent sampling volume appears to be an artifact of the scanning process not a fundamental entity of the sampling volume.

Bond, R. L.↗

Effects of boundary layer refraction and fuselage scattering on fuselage surface noise from advanced turboprop propellers

An acoustic disturbance's propagation through a boundary layer is discussed with a view to the analysis of the acoustic field generated by a propfan rotor incident to the fuselage of an aircraft. Applying the parallel flow assumption, the resulting partial differential equations are reduced to an ordinary acoustic pressure differential equation by means of the Fourier transform. The methods used for the solution of this equation include those of Frobenius and of analytic continuation; both yield exact solutions in series form. Two models of the aircraft fuselage-boundary layer system are considered, in the first of which the fuselage is replaced by a flat plate and the acoustic field is assumed to be two-dimensional, while in the second the fuselage is a cylinder in a fully three-dimensional acoustic field. It is shown that the boundary layer correction improves theory-data comparisons over simple application of a pressure-doubling rule at the fuselage.

Mcaninch, G. L.↗

Radar scene generation for tactical decision aids

The Mueller matrix and polarization covariance matrix for polarimetric radar systems was studied. The clutter was modeled by a layer of random permittivity, described by a three-dimensional correlation function, with variance, and horizontal and vertical correlation lengths. This model was applied, using the wave theory with Born approximations carried to the second order, to find the backscattering elements of the polarimetric matrices. Theoretical predictions are matched with experimental data for vegetation fields. The strong fluctuation theory was used to derive the backscattering cross sections. A two-layer anisotropic random medium model was developed for the active and passive microwave remote sensing of ice fields. A three-layer random medium model was adopted to study the volume scattering effects for the active and passive microwave remote sensing of snow-covered ice fields.

Kong, J. A.↗

Three-dimensional trajectory analyses of two drop sizing instruments: PMS OAP and PMS FSSP

Flow induced distortions of water drop fluxes and speeds seen by the instruments were predicted by use of three dimensional flow and trajectory calculation methods. Sensitivities were determined for the instruments, in isolation and mounted under the wing of an airplane, to: water drop diameter (2 to 1000 microns), angle of attack and free stream air speed. For the optical array probe in isolation and on the airplane at 0 deg angle of attack, flux distortions of practical consequence are not found. At 4 deg airplane angle of attack, partial flow stagnation under the uptilted wing causes significant decreases in both flux and speed for cloud size droplets. For the forward scattering spectrometer probe in isolation, only marginally significant sensitivities to free stream air speed are found, and no sensitivity is found to angle of attack. Both speed and flux of cloud size droplets are predicted to be undermeasured by from 12 to 24 percent depending on airplane angle of attack. For the wing-mounted instruments, effects of flow about the instruments themselves are found to be equal in importance to effects of flow about the airplane. Preferred orientation (canting) angles of distorted water drops are found to be functions of drop size, angle of attack and air speed.

Norment, Hillyer G.↗

Three-dimensional trajectory analyses of two drop sizing instruments - PMS OAP and PMS FSSP

Flow induced distortions of water drop fluxes and speeds seen by the instruments were predicted by use of three dimensional flow and trajectory calculation methods. Sensitivities were determined for the instruments, in isolation and mounted under the wing of an airplane, to: water drop diameter (2 to 1000 microns), angle of attack and free stream air speed. For the optical array probe in isolation and on the airplane at 0 deg angle of attack, flux distortions of practical consequence are not found. At 4 deg airplane angle of attack, partial flow stagnation under the uptilted wing causes significant decreases in both flux and speed for cloud size droplets. For the forward scattering spectrometer probe in isolation, only marginally significant sensitivities to free stream air speed are found, and no sensitivity is found to angle of attack. Both speed and flux of cloud size droplets are predicted to be undermeasured by from 12 to 24 percent depending on airplane angle of attack. For the wing-mounted instruments, effects of flow about the instruments themselves are found to be equal in importance to effects of flow about the airplane. Preferred orientation (canting) angles of distorted water drops are found to be functions of drop size, angle of attack and air speed.

Norment, Hillyer G.↗

Backscattering by nonspherical particles - A review of methods and suggested new approaches

Scattering of electromagnetic radiation near the backward direction is more sensitive to particle shape than scattering near the forward direction. Mie theory is therefore of dubious applicability to predicting backscattering by atmospheric particles known to be irregular or to inverting measurements on such particles. An irregular particle is one with an uncertain shape. In the face of uncertainty one must adopt a statistical approach in which scattering properties of ensembles are determined. To obtain ensemble averages, a basis is needed for averaging over a set of electromagnetic microstates. Ensemble averages based on the Rayleigh theory for small ellipsoids and on the T matrix method for spheroids agree better with measurements than Mie theory does. The coupled-dipole method also provides a basis for ensemble averaging. This method also leads to a simple physical interpretation of why backscattering is so sensitive to particle shape and can be used to calculate scattering by one- and two-dimensional analogs to three-dimensional irregular particles.

Bohren, Craig F.↗

Scalar mixing in the supersonic shear layer

Experiments were conducted in a two-stream planar mixing layer facility at convective Mach numbers of 0.28 and 0.62. Mie scattering from condensed alcohol droplets and planar laser-induced fluorescence (PLIF) of nitric oxide were used for flow visualization in both the side and plan views. The PLIF signals were approximately proportional to mixture fraction and were used to generate statistical quantities. Visualizations using both the Mie scattering and PLIF indicate the structure is essentially two-dimensional at Mc = 0.28 and three-dimensional at Mc = 0.62. Perspective renderings of side view images show the structures are streamwise ramped at Mc = 0.28 and cross-stream ramped at Mc = 0.62. This difference appears to be associated with decreasing streamwise structure spacings at the higher Mc condition. The statistical analysis suggests that with increasing compressibility, the scalar fluctuations are smaller, and the fraction of mixed fluid is higher.

Clemens, N. T.↗

Direct time integration of Maxwell's equations in two-dimensional dielectric waveguides for propagation and scattering of femtosecond electromagnetic solitons

We present what are to our knowledge first-time calculations from vector nonlinear Maxwell's equations of femtosecond soliton propagation and scattering, including carrier waves, in two-dimensional dielectric waveguides. The time integration efficiently implements linear and nonlinear convolutions for the electric polarization, and the nonlinear convolution accounts for two quantum effects, the Kerr and Raman interactions. By retaining the optical carrier, the new method solves for fundamental quantities - optical electric and magnetic fields in space and time - rather than a nonphysical envelope function. It has the potential to provide an unprecedented two- and three-dimensional modeling capability for millimeter-scale integrated-optical circuits with submicrometer engineered inhomogeneities.

Joseph, Rose M.↗

A finite element: Boundary integral method for electromagnetic scattering

A method that combines the finite element and boundary integral techniques for the numerical solution of electromagnetic scattering problems is presented. The finite element method is well known for requiring a low order storage and for its capability to model inhomogeneous structures. Of particular emphasis in this work is the reduction of the storage requirement by terminating the finite element mesh on a boundary in a fashion which renders the boundary integrals in convolutional form. The fast Fourier transform is then used to evaluate these integrals in a conjugate gradient solver, without a need to generate the actual matrix. This method has a marked advantage over traditional integral equation approaches with respect to the storage requirement of highly inhomogeneous structures. Rectangular, circular, and ogival mesh termination boundaries are examined for two-dimensional scattering. In the case of axially symmetric structures, the boundary integral matrix storage is reduced by exploiting matrix symmetries and solving the resulting system via the conjugate gradient method. In each case several results are presented for various scatterers aimed at validating the method and providing an assessment of its capabilities. Important in methods incorporating boundary integral equations is the issue of internal resonance. A method is implemented for their removal, and is shown to be effective in the two-dimensional and three-dimensional applications.

Collins, J. D.↗

Plasma dust crystallization

In a ground-based definition study, a concept for a new type of microgravity experiment is developed. We formed a new state of matter: a crystalline lattice structure of charged micron-size spheres, suspended in a charge-neutral plasma. The plasma is formed by a low-pressure radio-frequency argon discharge. Solid microspheres are introduced, and they gain a negative electric charge. They are cooled by molecular drag on the ambient neutral gas. They are detected by laser light scattering and video photography. Laboratory experiments have demonstrated that a two-dimensional nonquantum lattice forms through the Coulomb interaction of these spheres. Microgravity is thought to be required to observe a three-dimensional structure.

Goree, John↗

Simulation of wave propagation in three-dimensional random media

Quantitative error analysis for simulation of wave propagation in three dimensional random media assuming narrow angular scattering are presented for the plane wave and spherical wave geometry. This includes the errors resulting from finite grid size, finite simulation dimensions, and the separation of the two-dimensional screens along the propagation direction. Simple error scalings are determined for power-law spectra of the random refractive index of the media. The effects of a finite inner scale are also considered. The spatial spectra of the intensity errors are calculated and compared to the spatial spectra of intensity. The numerical requirements for a simulation of given accuracy are determined for realizations of the field. The numerical requirements for accurate estimation of higher moments of the field are less stringent.

Coles, William A.↗

A three-dimensional orthogonal laser velocimeter for the NASA Ames 7- by 10-foot wind tunnel

A three-component dual-beam laser-velocimeter system has been designed, fabricated, and implemented in the 7-by 10-Foot Wind Tunnel at NASA Ames Research Center. The instrument utilizes optical access from both sides and the top of the test section, and is configured for uncoupled orthogonal measurements of the three Cartesian coordinates of velocity. Bragg cell optics are used to provide fringe velocity bias. Modular system design provides great flexibility in the location of sending and receiving optics to adapt to specific experimental requirements. Near-focus Schmidt-Cassegrain optic modules may be positioned for collection of forward or backward scattered light over a large solid angle, and may be clustered to further increase collection solid angle. Multimode fiber optics transmit collected light to the photomultiplier tubes for processing. Counters are used to process the photomultiplier signals and transfer the processed data digitally via buffered interface controller to the host MS-DOS computer. Considerable data reduction and graphical display programming permit on-line control of data acquisition and evaluation of the incoming data. This paper describes this system in detail and presents sample data illustrating the system's capability.

Dunagan, Stephen E.↗

Three-dimensional reconstruction of coronal mass ejections

Computer assisted tomography (CAT) techniques are used to reconstruct the three dimensional shape of coronal mass ejections in the interplanetary medium. Both the Helios 2 spacecraft zodiacal-light photometers and the Solwind coronograph measure changes in Thomson scattering of sunlight from electrons. The technique from near-perpendicular Solwind and Helios views are applied to determine the density of a mass ejection which left the solar surface on 24 May 1979. The coronograph and the Helios perspective views are not simultaneous; the Solwind observations extend outward to sky plane distances of only 10 of the solar radius, whereas the Helios 16 photometer observes to as close as 17 of the solar radius from the sun. The solution is obtained by assuming outward radial expansion and that the coronal mass ejections (CME's) have the same speed everywhere at the same height. The analyses show that CME's are extensive three dimensional structures (the CME of 24 May appears approximately shell) like in three dimensions.

Jackson, Bernard V.↗

VHF radar and rocket observations of equatorial spread F on Kwajalein

VHF radar data from the Summer 1990 Equatorial Spread F campaign on Kwajalein are presented. The Cornell 50 MHz portable radar interferometer (CUPRI) operated concurrently with the Altair UHF incoherent scatter radar throughout July and August and supported two sounding rocket flights on July 30 and August 2. This experiment provided the first opportunity to simultaneously diagnose equatorial spread F using the three prime experimental techniques: VHF/UHF coherent scatter, incoherent scatter, and in situ probe measurements of electric field and density fluctuations. The intensity of the coherent echoes observed was consistent with typical Jicamarca spread F observations, but chains of periodic, large-scale plasma upwellings were observed more often and for much longer durations on Kwajalein than have been seen over Peru. CUPRI also measured Doppler frequencies in one upwelling corresponding to 1200-m/s plasma drift velocities. This measurement agrees with recent observations of supersonic drift rates at the magnetic equator by spacecraft. Near the most active localized plasma upwellings, interferometer data reveal that the zonal drift rate of plasma irregularities can vary sharply in space, as one would expect for two-dimensional incompressible flow. We introduce a semiempirical model of the three-dimensional spectrum of F region irregularities that is consistent with the one-dimensional spectra of density fluctuations observed by sounding rockets and with the axial ratio of irregularities determined recently. Normalized to data from one of the rocket flights on Kwajalein, the model predicts the 3-m scattering cross-section measured by CUPRI to within a few decibels.

Hysell, D. L.↗