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At least 199 records · Page 11

Chloride-Based Volatility for Waste Reduction and/or Reuse of Metallic-, Oxide- and Salt-Based Reactor Fuels

The objective of the chloride based volatility project (CBV) was to demonstrate the ability to separate uranium from used fuel to enable process improvements resulting in 10x reduction of waste volume, while maintaining safeguards standards and global backend costs at $\$$1/MW-hr. Current industrial practices perform separations of used fuel using solvent media in the form of aqueous and molten salt processes, resulting in contaminated process waste. The CBV approach utilized solid state chemistry with no solvent media and was successful in chlorinating uranium and fission product oxides that sublimed into the gas phase and were collected in targeted condensation zones based on temperature gradients of chlorinated products. Recovery of better than 95% of initial uranium in the form of UCl4 was demonstrated when simulated used nuclear fuel was used. Laser induced breakdown spectroscopy, LIBS, and ultraviolet-visible spectroscopy, UV-Vis, were combined into a high temperature flow cell design and utilized as process monitoring techniques to observed chlorinated products leave the reaction vessel in real time.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

EUV spectroscopy of 3 RSCVn binaries

The extreme ultraviolet (EUV) spectroscopy of several binary stars containing cool components is used to define the high temperature plasma structure of these stars and their stellar atmospheres. Different line emission spectra are reported, along with a spectrum analysis of Capella, a nearby bright multiple star system, using data from the EUVE satellite.

Dupree, A. K.↗

Mariner 9 ultraviolet spectrometer experiment - Mars airglow spectroscopy and variations in Lyman alpha.

Mariner 9 ultraviolet spectrometer observations show the Mars airglow consists principally of emissions that arise from the interaction of solar ultraviolet radiation with carbon dioxide, the principal constituent of the Mars atmosphere. Two minor constituents, atomic hydrogen and atomic oxygen, also produce airglow emissions. The airglow measurements show that ionized carbon dioxide is only a minor constituent of the ionosphere. Using the airglow measurements of atomic oxygen, it is possible to infer that the major ion is ionized molecular oxygen. The escape rate of atomic hydrogen measured by Mariner 9 is approximately the same as that measured two years earlier by Mariner 6 and 7. If the current escape rate has been operating for 4.5 billion years and if water vapor is the ultimate source, an amount of oxygen has been generated that is far in excess of that observed at present. Mariner 9 observations of Mars Lyman alpha emission over a period of 120 days show variations of 20%.

Barth, C. A.↗

A compact, high resolution Michelson interferometer for atmospheric spectroscopy in the near ultraviolet

A new, compact Fourier Transform Michelson interferometer (FTUV) with an apodized resolving power greater than 300,000 at 300 nm, high throughput and wide spectral coverage has been developed. The objectives include atmospheric spectroscopy (direct solar absorption and solar scattering) and laboratory spectroscopy of transient species. In this paper, we will briefly describe the prototype FTUV instrument and the results of preliminary laboratory investigations of OH and ClO spectra in emission and absorption.

Sander, Stanley P.↗

Ultraviolet high-resolution spectroscopy from the Space Telescope

The High Resolution Spectrograph is one of five scientific instruments which will be part of the Space Telescope observatory. The spectrograph was designed to take advantage of the imaging and pointing capabilities of the telescope to obtain ultraviolet spectra with spectral resolution comparable to large, ground-based coudeinstruments. Some of the results of the ground-based testing program will be described, along with applications of these properties to future science programs.

Ebbets, D. C.↗

Highly charged ion approach to measure nuclear charge radii of Fr, Ra, and Rn isotopes for precision measurements

Conventional electron scattering and muonic atom spectroscopy techniques are challenging to apply to heavy ions unless the element has at least one stable or extremely long-lived isotope. To overcome this limitation, a recently introduced method for determining nuclear charge radii relies on extreme-ultraviolet (EUV) spectroscopy of the D 1 line in highly charged Na-like ions. In this work, we present an experimental approach to measure the nuclear charge radii of isotopes of radioactive elements such as Fr, Ra, and Rn using this method at TRIUMF’s Ion Trap for Atomic and Nuclear Science (TITAN) instrument, located at the ISAC radioactive beam facility. We also explore the potential of using Na-like D 2 lines in the soft x-ray region for future measurements.

Electron beam ion trap↗

Emission Spectra of Uranium Particulates at High Temperature

The emission spectrum of micron-scale uranium particulates at high temperatures in the ultraviolet, visible, and near-infrared spectral regions is investigated using a heterogeneous shock tube. Temperatures from 3000 to 9000 K are characterized in an inert argon environment and with incremental amounts of added oxygen. Atomic line spectra do not emerge above the continuum emission spectrum until between 4500 and 5000 K in pure argon, and 6100 and 6600 K in 1% oxygen. For 5% oxygen, however, the threshold for atomic emission drops below 3800 K. Uranium monoxide molecular emission in the strongest visible band at 595.4 nm is not observed at any condition. Uncertainties in particle temperature determination in high-temperature shock tube environments are discussed, and limitations to such measurements are presented, such as those from experimental factors such as the powder loading method and expected detection limits of uranium species in relevant conditions.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Spectroscopy of the extreme-ultraviolet source Feige 24 - The binary orbit and the mass of the white dwarf

Results are reported for coude spectroscopy of the extreme-ultraviolet white dwarf Feige 24. Radial velocities of the H-alpha, He I 5876-A, and He I 6678-A emission lines, and the underlying M-dwarf absorption features, were determined from spectrograms obtained with the Lick 3-m telescope. The velocities show a binary period of 4.239(+ or - 0.0015) days. The emission-line and absorption-line velocities agree in phase, which indicates that the emission lines originate in the atmosphere of the M-dwarf secondary as a result of reprocessing of the EUV radiation. This effect is modeled, and the observed amplitude of the emission-line variability is used to place a lower limit on the orbital inclination. From these and other data it is shown that the mass of the white dwarf lies between 0.46 and 1.24 solar masses. Some possible implications for the evolution of binary stars are briefly discussed.

Thorstensen, J. R.↗

High resolution stellar spectroscopy in the balloon ultraviolet

The JSC/SRL Balloon-borne Ultraviolet Stellar Spectrometer (BUSS) comprises a 40 cm telescope, an echelle spectrograph and a SEC Vidicon detector. Operating at an altitude of 40 km this instrument provides spectra of stars with 0.1 A resolution in the 2000-3400 A region. Observations made on 19 May 1976, are discussed.

De Jager, C.↗

Spectroscopy of the extreme ultraviolet dayglow at 6.5A resolution - Atomic and ionic emissions between 530 and 1240A

EUV spectra (530-1500A) of the day airglow in up, down and horizontal aspect orientations have been obtained with 6.5A resolution and a limiting sensitivity of 5R from a rocket experiment. Below 834A the spectrum is rich in previously unobserved OII transitions connecting with 4S(0), 2D(0), and 2P(0) states. Recent broad-band photometric observations of geocoronal HeI 584A emission in terms of the newly observed OII emissions are shown. The OI 989A and OI 1304A emissions exhibit similar dependence on altitude and viewing geometry with the OI 989A brightness 1/15 that of OI 1340. Emission at 1026A is identified as geocoronal HI Lyman beta rather than OI multiplet emission and observed intensities agree well with model estimates. An unexpectedly high NI 1200/NI 1134A brightness ratio is evidence of a significant contribution from photodissociative excitation of N2 to the NI 1200A source function.

Gentieu, E. P.↗

Long-slit spectroscopy in the rocket ultraviolet of the Orion Nebula

The study deals with the extensive nebulosity in the Trapezium region of Orion. An entrance slit was placed at the focal plane of rocketborne telescope, creating a long-slit spectrograph with a wavelength resolution of 22 A FWHM and a spatial resolution of 14 in. along the slit. Data reduction is outlined, the structure of the Orion Nebula is discussed, and radiative transfer considerations are presented.

Bohlin, R. C.↗

Spectroscopy of the extreme ultraviolet dayglow during active solar conditions

The spectral characteristics of the mid-latitude daytime airglow observed between 530 and 1500 A under conditions of high solar activity are compared with those obtained at the same location during markedly lower solar activity. The spectral observations were made by two scanning spectrometers and an N2 3371 A photometer carried aboard Astrobee-F rockets launched from White Sands Missile Range, NM, on January 9, 1978 and June 27, 1980. The more recent data allow the partial resolution of the emission spectrum between 800 and 1200 A into a large number of weak N I, O I and N2 transitions. Data taken at 220 km altitude suggest an increase in atomic nitrogen density of more than a factor of 3 between the two observations, along with a doubling of the solar EUV flux at wavelengths less than 688 A. No evidence of a corresponding increase in the 10 to 50 eV photoelectron flux is found, however, an ionospheric sounding data indicate the peak electron density to have decreased during this period. The mechanism for this electron flux decrease in the face of increased EUV flux and only a three-fold increase in N concentration remains unknown.

Gentieu, E. P.↗

Ultraviolet high-resolution spectroscopy of the X-ray binary Sk 160/SMC X-1

High-resolution IUE spectra of Sk 160, the optical counterpart of the X-ray source SMC X-1, show substantial variations with orbital phase of the resonance P Cygni profiles. These variations are ascribed to the changing ionization state in the stellar wind caused by the X-rays emitted by the companion, as suggested by Hatchett and McCray and first established for the galactic X-ray binary Vela X-1. Furthermore, the profile observed during X-ray eclipse differs significantly from profiles of similar stars in the absence of X-ray ionization.

Hammerschlag-Hensberge, G.↗