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At least 199 records · Page 11

Consumer Guide to Home Water Efficiency

Learn how a water-efficient home helps you minimize your water use, harness water for reuse, conserve energy, and save money. This fact sheet from Energy Saver includes information on ENERGY STAR-qualified appliances, why to improve water efficiency, and how to save water and energy.

water efficiency, water heating, saving water, wat↗

Opportunities for Using the Industrial Assessment Center Database for Industrial Water Use Analysis

The manufacturing sector accounted for approximately 5–6% of total U.S. water use in 2015. Of that amount, 75–80% is self supplied withdrawal from surface-water and groundwater sources and the remainder is from public water supplies. Although manufacturing facilities commonly locate in water-scarce areas, water scarcity still poses a great risk to the manufacturing sector. Reliable water is necessary for any facility that relies on it for process and comfort cooling, cleaning, employee use, and steam generation. One of these barriers to water efficiency is the lack of reliable data on overall U.S. industrial water use—how it is used and the quantities required for each sector. If a facility cannot be easily compared with a facility of similar size and sector, knowing if it is effectively using water conservation best practices is difficult. One potential source of industrial water use data is the U.S. Department of Energy (DOE)–sponsored Industrial Assessment Centers (IACs). IACs are university-based organizations that provide free audits to small- and medium-sized manufacturing facilities to identify productivity improvement and waste and energy reduction opportunities. The IACs also maintain a database of all the audits conducted, which currently holds more than 19,267 assessments and 145,000 recommendations (as of July 24, 2020). This database also contains energy utility (electricity, natural gas, and other fuels) and water utility data, making it a potential data source for industrial water use. This report attempts to create regression models to predict a small- or medium-sized industrial facility’s annual water use or cost based on its industrial subsector and several possible relevant variables. Using data collected by IAC assessments, models for several industrial subsectors were generated via stepwise regression techniques to determine which variables (annual sales, number of employees, facility/plant area, annual production hours, and a water stress metric) are relevant.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Comparison of multi-stage air treatment process divided by the same temperature and enthalpy difference

The multi-stage air treatment system has been proposed recently, and lower grade chilled/hot water could be used and energy efficiency could be improved. However, it has not been studied which division method of air treatment processes has higher energy efficiency. In this study, the model to calculate the energy consumption of multi-stage air treatment process is introduced, and the effects of two division methods, i.e. multi-stage air treatment process divided by the same temperature difference (ST method) or same enthalpy difference (SE method) between inlet and outlet at each stage, under 9 different air inlet parameters in the 2-stage and 3-stage air treatment processes are analysed and compared. The results show that (1) the system energy consumption of the SE method is generally lower than that of the ST method; (2) there is generally a larger energy consumption reduction rate of SE method when the air relative humidity is 70% compared to relative humidity of 50% and 90%; (3) the difference between ST method and SE method is not great, so both methods can be used for the design of multi-stage treatment system although SE method is normally recommended.

Wang, Wentao↗

Annual Herbaceous Plants Exhibit Altered Morphological Traits in Response to Altered Precipitation and Drought Patterns in Semiarid Sandy Grassland, Northern China

The frequency and intensity of extreme precipitation events and severe drought are predicted to increase in semiarid areas due to global climate change. Plant morphological traits can reflect plant responses to a changing environment, such as altered precipitation or drought patterns. In this study, we examined the response of morphological traits of root, stem, leaf and reproduction meristems of annual herbaceous species to altered precipitation and drought patterns in a semiarid sandy grassland. The study involved a control treatment (100% of background precipitation) and the following six altered precipitation treatments: (1) P(+): precipitation increased by 30%, (2) P(++): precipitation increased by 60%, (3) P(-): precipitation decreased by 30%, (4) P(--): precipitation decreased by 60%, (5) drought 1 (D1): 46-day drought from May 1st to June 15th, and (6) drought 2 (D2): 46-day drought from July 1st to August 15th. P(++) significantly increased root length, flower length-to-width ratio, both P(+) and P(++) significantly increased stem length and flower number in the plant growing seasons, while all of them decreased under P(-) and P(--). The annual herbaceous plants marginally increased the number of second-level stem branches and stem diameter in order to better resist the severe drought stress under P(--). P(+) and P(++) increased the root, stem, leaf, and flower dry weight, with the flower dry weight accounting for a larger proportion than the other aboveground parts. Under D2, the plants used the limited water resources more efficiently by increasing the root-to-shoot ratio compared with P(-), P(--) and D1, which reflects biomass allocation to belowground increased. The linear mixed-effects models and redundancy analysis showed that the root-to-shoot ratio and the dry weight of various plant components were significantly affected by morphological traits and altered precipitation magnitude. Our results showed that the herbaceous species have evolved morphological trait responses that allow them to adapt to climate change. Such differences in morphological traits may ultimately affect the growing patterns of annual herbaceous species, enhancing their drought-tolerant capacity in semiarid sandy grassland during the ongoing climate change.

Sun, Shan-Shan↗

A Year-Round Energy-Efficient Fresh Air Handling System with Two-Stage Heat Pumps and Lake Water Pre-Treatment

Supplying fresh air is important for indoor air quality, but the energy consumption to treat fresh air is significant. The main problems in existing fresh air system include: supplying single-temperature water to treat fresh air and not applying natural energy sufficiently restrict the efficiency improvement of cooling and heat sources; unused air handling devices under most operating conditions throughout the year increase the fan energy consumption. Thus, this study proposes an efficient fresh air system that uses lake water to pre-treat fresh air and two-stage heat pumps for further treatment, and the unused air handling devices in the system are bypassed. A fresh air system in northern China is selected as a case to show the annual energy performance of the proposed system, and a comparative analysis is conducted between the proposed system and a traditional system. The results show that the annual energy-savings of the proposed system compared to the traditional system come from fans, and compressors, which are 56.5%, and 31.1%, respectively, with an entire system energy saving of 32.2%. The proposed system can achieve an annual system coefficient of performance (COP) of 5.5. This study provides potential for further improving the energy efficiency in fresh air treatment.

Liang, Chenjiyu↗

A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water

Iodine is widely used as an antimicrobial reagent for water disinfection in the wilderness and outer space, but residual iodine and iodide need to be removed for health reasons. Currently, it is challenging to remove low concentrations of iodine and iodide in water (~5 ppm). Furthermore, the remediation of iodine and iodide across a broad temperature range (up to 90 °C) has not previously been investigated. In this work, we report a nitrate dimer-directed synthesis of a single-crystalline ionic hydrogen-bonded crosslinked organic framework (HCOF-7). HCOF-7 removes iodine and iodide species in water efficiently through halogen bonding and anion exchange, reducing the total iodine concentration to 0.22 ppm at room temperature. Packed HCOF-7 columns were employed for iodine/iodide breakthrough experiments between 23 and 90 °C, and large breakthrough volumes were recorded (≥18.3 L/g). Finally, the high iodine/iodide removal benchmarks recorded under practical conditions make HCOF-7 a promising adsorbent for water treatment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Lattice-Nitrogen-Mediated Chemistry Suppresses Hydrogen Evolution for Record Faradaic Efficiency in Ammonia Synthesis

Ammonia (NH 3 ) production using air, water, and electricity offers a transformative route to carbon-free chemical synthesis, addressing global sustainability challenges. However, the hydrogen evolution reaction (HER) in aqueous systems significantly hinders NH 3 selectivity, limiting Faradaic efficiency (FE) to below ~15%. Here, we report an FE of approximately 48%, the highest recorded for aqueous NH 3 synthesis, using two-dimensional (2D) nitride catalysts. These catalysts enable lattice nitrogen protonation through the Mars-van Krevelen (MvK) mechanism, effectively suppressing HER. Using operando spectroelectrochemistry, we identified active sites and tracked nitrogen vacancy cycles, providing unprecedented insights into the reaction pathways. Our findings, supported by advanced computational techniques and complementary spectroscopic analyses, highlight the stability and efficiency of the MvK cycle, setting a new benchmark for sustainable NH 3 production.

catalysts↗

Review of liquid desiccant air dehumidification systems coupled with heat pump: System configurations, component design, and performance

Vapor Compression Systems (VCS) are the most common air conditioning technology. VCS cool the air to its dew point temperature (overcooling) to remove water vapor in the air through condensation and then reheats the air back to the comfort temperature for direct use. The VCS process is inefficient due to overcooling and reheating. Liquid Desiccant Dehumidification (LDD) is a potentially energy-efficient air conditioning. LDD removes water vapor in the process air using liquid desiccant’s high-water affinity. It hybrids with sensible cooling to control temperature and humidity separately. The LD in the LDD becomes weak after dehumidification. The LDD needs additional heating to regenerate the weak Liquid Desiccant (LD) to a high concentration for dehumidification. Earlier versions of the LDD systems use highly concentrated liquid desiccant (large water removal capability) to dehumidify the air by only dealing with latent load. It leads to highly elevated temperatures above 60 °C of heat sources (combustion or electric resistance-based heating) for regeneration. The energy needed for the elevated temperature heat resource significantly reduces or demolishes the benefit of LDD systems. In the recent two decades, researchers have investigated a new configured LDD system that couples an LDD with a heat pump at both dehumidification and regeneration sides for better efficiency. The heat pump provides cooling (from the evaporator) for both dehumidification and sensible cooling and simultaneous heating from the condenser for regeneration. The highly integrated system (HP-LDD) with improved efficiency enables the LDD to operate at lower concentrations and temperatures in dehumidification and regeneration. This paper depicts the working principle behind HP-LDD and its heating and cooling requirements. It reviews the comparison between the HP-LDD systems and the conventional LDD systems regarding system configurations, component design, energy efficiency, and dehumidification performance characteristics. The main findings from the review include the preferred use of packed bed over membrane-based dehumidifiers, the use of internally cooled dehumidifiers enabled by the HP cooling capacity, the high dispersion of HP operation conditions, and the dependence of dehumidification performance on various dehumidifiers. Finally, an outlook for future research on HP-LDD strategies is presented based on the reviewed works and their limitations.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Mitigation of hydrogen crossover in liquid alkaline water electrolysers using gas recombination catalysts

The rising demand for hydrogen calls for improvements in the efficiency of liquid alkaline water electrolysers (LAWEs), which can be fulfilled by advanced electrodes or separators. Nevertheless, they also intensify hydrogen crossover and safety concerns, thus mandating efficient mitigation strategies. Here we studied the correlation between cathodes and hydrogen crossover behaviours and mitigated safety risks by designing a gas recombination catalyst (GRC). We attribute the elevated hydrogen crossover associated with platinum-based cathodes to their preferential utilization for the hydrogen evolution reaction that creates elevated hydrogen supersaturation, as evidenced by direct measurements of dissolved hydrogen concentration. Varying the placement of platinum layers relative to the cathode–separator interface also supports this conclusion. The implementation of a GRC reduces hydrogen crossover by 95% without affecting LAWE performance and functions for over 1,000 h at 1 A cm−2. This study provides insights into hydrogen supersaturation and the crossover mechanism, as well as offering a promising pathway to enhance the efficiency and reliability of alkaline water electrolysis.

Liu, Haotian↗

Perovskite/Perovskite Tandem Photoelectrodes for Low-Cost Unassisted Photoelectrochemical Water Splitting

In this project, we aim to address the challenges of achieving efficient and cost-effective unassisted photoelectrochemical water splitting using perovskite/perovskite tandem photoelectrodes. We utilized the following unique approaches to advance our innovation. (1) We developed stable and efficient low-E g (1.2 – 1.4 eV) perovskites as the bottom electrodes. We demonstrated approaches to improve the photovoltaic performance and photothermal stability of low-E g Sn-Pb iodide perovskite solar cells. (2) We developed a low-temperature synthesis route to fabricate wide-E g (>1.8 eV) perovskite top electrodes. By combining theoretical and experimental investigation, we found methods to reduce the formation of defects and dislocations in the wide-E g mixed halide perovskites and suppress halide segregation. (3) We developed a robust metal oxide-based interconnecting layer to integrate two perovskite layers into tandem photoelectrodes. Our monolithically integrated tandem devices feature a high V OC of more than 2 V and a high J SC of more than 15 mA/cm 2 . We showed the new design of the tandem photoelectrodes that is critical to the stable operation of tandem photoelectrodes for unassisted PV/PEC water splitting. (4) We demonstrated a water-impermeable barrier of carbon paste/epoxy/metal foil composite, which can prevent photocorrosion and water ingress of perovskite active layers. This surface protection enabled the operation of perovskite photoelectrodes in water and significantly enhanced the long-term stability of our tandem devices. (5) We conducted standardized PEC characterization in collaboration with NREL and reported accurate determination of solar-to-hydrogen conversion efficiencies of perovskite/perovskite tandem photoelectrodes. At the end of the project, we demonstrated perovskite/perovskite tandem photoelectrodes with STH efficiencies of up to 18% and less than 20% efficiency loss after continuous operation for more than 500 hours in water. Our results demonstrate the potential to develop a low-cost, durable, and efficient water-splitting system that meets the DOE 2026 and 2031 cost targets for hydrogen production.

08 HYDROGEN↗

Drought conditioning of rhizosphere microbiome influences maize water use traits

Background and Aims: Beneficial plant–microbe interactions can improve plant performance under drought; however, we know less about how drought-induced shifts in microbial communities affect plant traits. Methods: We cultivated Zea mays in fritted clay with soil microbiomes originating from contrasting environments (agriculture or forest) under two irrigation treatments (well-watered or water limited). Using this design, we investigated whether water conditioning was carried forward through the microbiome to affect a subsequent plant cohort that was subjected to either a well-watered or water limited treatment. Results: Regardless of the microbiome-origin, plants inoculated with a microbiome from a water limited legacy had traits that allowed them to avoid stress but conserve water. They produced longer roots to explore soil, generated greater soil dissolved organic carbon, potentially stimulating the microbiome, and slower soil water content loss during drought. A well-watered legacy resulted in plants that delayed permanent stomatal closure and higher photosynthetic nitrogen use efficiency. In plants with a forest-originated microbiome, a well-watered legacy and water treatment also resulted in higher rates of photosynthesis and stomatal conductance. Conclusion: These results demonstrate that soil microbiomes can be developed to influence plant drought performance, impacting crop resilience, using short-term microbial conditioning.

60 APPLIED LIFE SCIENCES↗

A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water

Abstract Iodine is widely used as an antimicrobial reagent for water disinfection in the wilderness and outer space, but residual iodine and iodide need to be removed for health reasons. Currently, it is challenging to remove low concentrations of iodine and iodide in water (≈5 ppm). Furthermore, the remediation of iodine and iodide across a broad temperature range (up to 90 °C) has not previously been investigated. In this work, we report a nitrate dimer‐directed synthesis of a single‐crystalline ionic hydrogen‐bonded crosslinked organic framework (H C OF‐7). H C OF‐7 removes iodine and iodide species in water efficiently through halogen bonding and anion exchange, reducing the total iodine concentration to 0.22 ppm at room temperature. Packed H C OF‐7 columns were employed for iodine/iodide breakthrough experiments between 23 and 90 °C, and large breakthrough volumes were recorded (≥18.3 L g −1 ). The high iodine/iodide removal benchmarks recorded under practical conditions make H C OF‐7 a promising adsorbent for water treatment.

Zhang, Mingshi↗

Anion-Exchange-Membrane Electrolysis with Alkali-Free Water Feed

Hydrogen is a green and sustainable energy vector that can facilitate the large-scale integration of intermittent renewable energy, renewable fuels for heavy transport, and deep decarbonization of hard-to-abate industries. Anion-exchange-membrane water electrolyzers (AEM-WEs) have several achieved or expected competitive advantages over other electrolysis technologies, including the use of precious metal-free electrocatalysts at both electrodes, fluorine-free hydrocarbon-based ionomeric membranes and bipolar plates based on inexpensive materials. Contrasting the analogous proton-exchange-membrane system (PEM-WE), where pure water is circulated (no support electrolyte), the current generation of AEM-WEs necessitates the circulation of a dilute aqueous alkaline electrolyte for reaching high energy efficiency and durability. For several reasons, including but not limited to lower cost of balance-of-plant, lower operating cost and improved device's lifetime, achieving high cell efficiency and performance using an alkali-free water feed is highly desirable. In this review, we develop and build a foundational understanding of AEM-WEs operating with pure water, as well as discuss the effects of operating with natural water feeds like seawater. After a discussion of the possible advantages of pure-water-fed AEM-WEs, we cover the thermodynamic and kinetic processes involved in AEM-WE, followed by a detailed review of materials and components and their integration in the device. We highlight the influence of electrolyte composition and alkali/electrolyte-free feed on the membrane-electrode assembly, ionomers, electrocatalysts, porous transport layer, bipolar plates and operating configuration. We provide evidence for how the pure water feed engenders several issues related to the degradation of device components and propose mitigation strategies.

Electrodes↗

Integrated Radio Frequency and Ultrasonics with Conventional Processes for Efficient Water Removal in Pulp and Paper and Other Biomaterial Applications

Conventional drying processes used in the pulp and paper industry primarily involve lengthy, surface based, multi-cylinder conductive and convective drying with low thermal efficiencies and often use some fossil-based energy. Integration of cross cutting, electrically-powered, volumetric drying process intensification technologies based on Radio Frequency (RF) and acoustics (Ultrasonics) (US) will directly impart energy into the biomaterials resulting in improved energy efficiency and throughput. Integration of RFUS-based drying technology is expected to enable U.S. manufacturing industry to reduce capital and operating costs, energy consumption, and carbon emissions while increasing energy efficiency and throughput, improving product quality and sustainability, and helping preserve U.S. manufacturing jobs. The hybrid drying approach incorporates directed radio frequency (RF) and ultrasonic (US) energy with conventional conduction, diffusion and convective heat and mass transfer overcoming the limitations of the conventional drying processes and that meets/exceeds the minimum goals. We have shown the effective removal of free and bound water in the biomaterials by leveraging the synergies of RF and US technologies integrated with conventional manufacturing processes.

42 ENGINEERING↗

How Well Do U.S. Western Water Markets Convey Economic Information?

An efficient market implies that potential gains from trade are fully captured. Achieving this requires a well-functioning market where prices reflect all available information. In the case of water rights markets, this implies that the permanent water rights transfer price reflects the sum of discounted returns to this asset (i.e., the lease price), the market interest rate, and a risk premium that reflects potential future water scarcity. Here, the purpose of this study is to assess the efficiency of western U.S. water markets by using the asset pricing model to measure how well prices reflect long-run returns to permanent water rights.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Experimental measurements of fuel and water crossover in an active DMFC

This work measured polarization curves as well as the high-frequency resistance of active direct methanol fuel cell (DMFC) operates at around 80 °C with active controls of temperature, methanol concentration, airflow rate, and relative humidity. The relative humidity of the air did not have noticeable impacts on the fuel cell unless the operating temperature was near the evaporation temperature of water (100 °C). The hydrophobic water management layer (WML) between the membrane electrode assembly (MEA) and cathode air channel increases the mass transfer resistance and improves the water retention in MEA. Adding a WML increased the peak power density, decreased the ohmic resistance, and improved the fuel efficiency of the fuel cell, especially when it operated near 100 °C. This study also quantitatively measured methanol and water crossover as well as the fuel efficiency at different operating currents. The fuel efficiency increased significantly with the increase of the current density. Using a hydrophobic fuel management layer (FML) between the anode fuel channel and MEA reduced the fuel and water crossover rates and increased the ohmic resistance due to the decrease of the water content of the Nafion membrane. The FML improved fuel efficiency by reducing the methanol crossover. The combination of the FML and WML enabled the steady operation of DMFC using highly concentrated methanol solutions (up to 75 wt%).

08 HYDROGEN↗

Scaling Up: Demonstrating Risk Reduction and Cost Compression for Commercial Heat Pump Water Heaters - CRADA 625 (Abstract)

Commercial heat pump water heater (CHPWH) systems significantly decarbonize the commercial and multifamily sectors by eliminating the reliance on gas-fired water heating. CHPWH systems are also well suited to include load shift controls that enable load-up and shed commands for supporting grid reliability and time-of-use pricing structure. However, they have not had wide adoption due to factors including price, complexity, and perceived risk. Although CHPWHs have been available in the US for decades, they have not made significant market gains in part because the systems have required significant and costly engineering design expertise and proved lackluster performance. Successful widespread market adoption requires a different approach; a shift from the current custom specialized expertise project design and installation to a repeatable approach that requires little specialized knowledge or expertise and can deliver persistent performance. Using this type of holistic systems approach requires effectively integrating four CHPWH system key components: primary air-to-water heat pumps; primary thermal storage tanks, a temperature maintenance system, and a control system which has capabilities to manage the primary heat pump cycles, any back-up, supplemental, or temperature maintenance heating, alarms, and grid connectivity allowing for demand response (DR), and/or load shifting. The project team has developed and will implement a suite of tools to support faster, less expensive, and more reliable field installations of CHPWH technology and with the resulting data used to further improve the tool set. These tools include: (1) A tool for optimizing system size and costs. (2) A tool that predicts annual energy use and overall system efficiency. (3) The Advanced Water Heater Specification (AWHS 8.0) defining the components of a full CHPWH system addressing performance requirements by climate zone. (4) The Qualified Products List: (QPL) of approved products that meet the specifications requirements. (5) Training materials including online on-demand modules, instructor-led training, and virtual interactive video tours of CHPWH installations in multifamily buildings. Demonstration site identification in low-income buildings in underserved communities is currently underway. Preliminarily, the team anticipates having three demonstrations in the Pacific Northwest and three in the Northeast for a total of six sites. After the demonstration sites are finalized, and M&V instrumentation installations are complete, the team will gather performance data and confirm whether the CHPWH systems perform as predicted and use the data to improve the existing tools.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Comparison of plug flow and multi-node stratified tank modeling approaches regarding computational efficiency and accuracy

Residential water heaters contain water stratified by temperature-driven density differences. This implies that a water tank can reach a state in which the top and bottom sections have different temperatures, unless mixing happens. A high degree of thermal stratification can improve the efficiency of some water heaters, by saving the amount of energy required for the heat-up process. Studies of stratification became popular in the 1970s and it remains an active research topic today. The research has led to the development of different models and techniques to better predict and define a stratified tanks behavior. By comparing these models and techniques used previously to describe thermal stratification, the phenomenon could be better understood, exploited, and used to increase efficiency and thermal energy capacity in modern water tanks. From the existing models, we found the one-dimensional standard plug-flow and a multi node model to be appropriate for analyzing the processes of the heat up and cool-down in a water tank. These two models are based on energy balances. This work involved comparing the accuracy and computational effort needed to implement these models. To assess accuracy, we compared both types of existing models to experimental data (also collected in this work) which included a heat up process using an external heat pump. This external process included a layering process that has an eddy diffusivity at five times the rate of thermal diffusion. For this project, we implemented the models in MATLAB, the multi-paradigm numerical computing environment. We quantified model accuracy using the root mean squared error between modeled data and experimental data for six measured tank temperatures. Comparing the accuracy and the computational time taken to run the simulation provides a method to contrast the performance of each model and a way to rate it. The multi node model was run using from 6 to 96 spatial nodes; the plug flow model was run using 1 to 0.001 º C temperature bin sizes. Additionally, timesteps were varied from 4 to 236 s. The results quantify the tradeoff between accuracy and computational time, providing guidance for simulations to intelligently select the best model type and simulation parameters. This research can be used to validate the pre-existing models and possibly improve the modern water tank.

Bulnes, Fernando Karg↗