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NASA NTRS1983

Isotopic inferences of ancient biochemistries - Carbon, sulfur, hydrogen, and nitrogen

In processes of biological incorporation and subsequent biochemical processing sizable isotope effects occur as a result of both thermodynamic and kinetic fractionations which take place during metabolic and biosynthetic reactions. In this chapter a review is provided of earlier work and recent studies on isotope fractionations in the biogeochemical cycles of carbon, sulfur, hydrogen, and nitrogen. Attention is given to the biochemistry of carbon isotope fractionation, carbon isotope fractionation in extant plants and microorganisms, isotope fractionation in the terrestrial carbon cycle, the effects of diagenesis and metamorphism on the isotopic composition of sedimentary carbon, the isotopic composition of sedimentary carbon through time, implications of the sedimentary carbon isotope record, the biochemistry of sulfur isotope fractionation, pathways of the biogeochemical cycle of nitrogen, and the D/H ratio in naturally occurring materials.

Schidlowski, M.↗
NASA NTRS1992

Linkages between terrestrial ecosystems and the atmosphere

The primary research issue in understanding the role of terrestrial ecosystems in global change is analyzing the coupling between processes with vastly differing rates of change, from photosynthesis to community change. Representing this coupling in models is the central challenge to modeling the terrestrial biosphere as part of the earth system. Terrestrial ecosystems participate in climate and in the biogeochemical cycles on several temporal scales. Some of the carbon fixed by photosynthesis is incorporated into plant tissue and is delayed from returning to the atmosphere until it is oxidized by decomposition or fire. This slower (i.e., days to months) carbon loop through the terrestrial component of the carbon cycle, which is matched by cycles of nutrients required by plants and decomposers, affects the increasing trend in atmospheric CO2 concentration and imposes a seasonal cycle on that trend. Moreover, this cycle includes key controls over biogenic trace gas production. The structure of terrestrial ecosystems, which responds on even longer time scales (annual to century), is the integrated response to the biogeochemical and environmental constraints that develop over the intermediate time scale. The loop is closed back to the climate system since it is the structure of ecosystems, including species composition, that sets the terrestrial boundary condition in the climate system through modification of surface roughness, albedo, and, to a great extent, latent heat exchange. These separate temporal scales contain explicit feedback loops which may modify ecosystem dynamics and linkages between ecosystems and the atmosphere. The long-term change in climate, resulting from increased atmospheric concentrations of greenhouse gases (e.g., CO2, CH4, and nitrous oxide (N2O)) will further modify the global environment and potentially induce further ecosystem change. Modeling these interactions requires coupling successional models to biogeochemical models to physiological models that describe the exchange of water, energy, and biogenic trace gases between the vegetation and the atmosphere at fine time scales. There does not appear to be any obvious way to allow direct reciprocal coupling of atmospheric general circulation models (GCM's), which inherently run with fine time steps, to ecosystem or successional models, which have coarse temporal resolution, without the interposition of physiological canopy models. This is equally true for biogeochemical models of the exchange of carbon dioxide and trace gases. This coupling across time scales is nontrivial and sets the focus for the modeling strategy.

Bretherton, Francis↗
NASA NTRS2004

Ocean Carbon Flux, Transport, and Burial Within the Western and Eastern US Coastal Zones

This project has been to develop and apply a regional. eddy-resolving circulation and biogeochemistry model of both the western and eastern U.S. coastal regions, capable of simulating the processes that control the carbon cycle. Validation has been by statistical comparison with analyses from various satellite measurements, including those from EOS sensors, as well as from in situ measurements. Sensitivity studies were carried out to investigate how the coastal ecosystem and biogeochemical cycles respond to changes in climate, large-scale eutrophication from indus- trial pollution, and other anthropogenic induced changes. The research has been conducted in collaboration with research groups at UCLA. NASA/GSFC (Wallops), Rutgers, and SIO. Overall. the project was focused on several key modeling issues, each of which tie back into completing the primary task of developing a coastal carbon model for both the eastern and western US. coasts. Individual groups within the entire program are still collaborating to address these specific tasks. These include: implementation of the coupled circulation/biogeochemical model within the U.S. West Coast. including high-resolution, embedded subdomains for the Southern California Bight and Monterey Bay region; development of a biogeochemical model with resolved carbon, nitrogen and oxygen cycles; development of data assimilation techniques for use of satellite data sets; reconfiguration of the model domain to U.S. East Coast; development of coastal forcing fields: development of methods to compare the model against remotely sensed data; and, the test of model sensitivity to environmental conditions. Below, we present a summary of the progress made toward achieving these soak. Because this has been a multi-institutional, collaborative effort, we note the groups involved with particular activities.

McWilliams, James C.↗
NASA NTRS2003

Biogeochemistry of hypersaline microbial mats illustrates the dynamics of modern microbial ecosystems and the early evolution of the biosphere

Photosynthetic microbial mats are remarkably complete self-sustaining ecosystems at the millimeter scale, yet they have substantially affected environmental processes on a planetary scale. These mats may be direct descendents of the most ancient biological communities in which even oxygenic photosynthesis might have developed. Photosynthetic mats are excellent natural laboratories to help us to learn how microbial populations associate to control dynamic biogeochemical gradients.

Ecosystem↗
NASA NTRS2023

Broader Impacts and Outreach Videos on Ocean Physics and Biogeochemistry

This is just a preliminary NF1676 in advance of filming for a project....A convergent team of experts in biology, chemistry, physics, engineering, mathematics, and computational modeling examine how dynamic and coupled phytoplankton-pathogen-particle-predator linkages coalesce to explain the observed high spatial variability in the efficiency of the export of particulate organic carbon (POC) to the deep ocean. They elucidate and quantify the linkages between viruses and ballast minerals to increase understanding of carbon cycling in the oceanic biological carbon pump and the impact of viruses within it. By providing knowledge than can be used to improve the parameterization of carbon export in Earth system models, the project will help reduce uncertainty in regional marine biogeochemical projections, potentially improving marine ecosystem and fisheries management on timescales from seasons to decades. The project includes activities that provide teaching resources and hands-on training to educators within a ‘Tools of Science’ program that provides a simple and succinct way to communicate the process of scientific research to students in a way that is useful to teachers. The project couples laboratory-based experiments on model host-virus-grazer systems with extensive field based observational and manipulative studies on natural populations of diatoms and coccolithophores, the two phytoplankton groups that account for most of the estimated particulate organic matter flux to the deep ocean. Experiments and measurements integrate diagnostic biological and chemical controls on infection and particle coagulation theory with microscale physics and grazing to quantify links to each hypothesized export mechanism under field-relevant turbulent conditions. Cutting-edge engineering and analytical tools are used to diagnose and track infection dynamics while characterizing and quantifying particle aggregation and disaggregation, mineral dissolution, sinking dynamics, grazing rates, and fecal pellet production at unprecedented resolution and under well-defined, microscale physical regimes. Field campaigns elucidate the relative efficiency of hypothesized mechanisms in stimulating POC export in natural blooms, while providing bulk and size-resolved estimates of POC flux.

Daniel B Whitt↗
NASA NTRS2001

Merging Ocean Color Data from Multiple Missions

Oceanic phytoplankton may play an important role in the cycling of carbon on the Earth, through the uptake of carbon dioxide in the process of photosynthesis. Although they are ubiquitous in the global oceans, their abundances and dynamics are difficult to estimate, primarily due to the vast spatial extent of the oceans and the short time scales over which their abundances can change. Consequently, the effects of oceanic phytoplankton on biogeochemical cycling, climate change, and fisheries are not well known. In response to the potential importance of phytoplankton in the global carbon cycle and the lack of comprehensive data, the National Aeronautics and Space Administration (NASA) and the international community have established high priority satellite missions designed to acquire and produce high quality ocean color data. Seven of the missions are routine global observational missions: the Ocean Color and Temperature Sensor (OCTS), the Polarization and Directionality of the Earth's Reflectances sensor (POLDER), Sea-viewing Wide Field-of-view Sensor (SeaWiFS), Moderate Resolution Imaging Spectrometer-AM (MODIS-AM), Medium Resolution Imaging Spectrometer (MERIS), Global Imager (GLI), and MODIS-PM. In addition, there are several other missions capable of providing ocean color data on smaller scales. Most of these missions contain the spectral band complement considered necessary to derive oceanic pigment concentrations (i.e., phytoplankton abundance) and other related parameters. Many contain additional bands that can provide important ancillary information about the optical and biological state of the oceans. Any individual ocean color mission is limited in ocean coverage due to sun glint and clouds. For example, one of the first proposed missions, the SeaWiFS, can provide about 45% coverage of the global ocean in four days and only about 15% in one day.

Gregg, Watson W.↗
NASA NTRS2003

Merging Ocean Color Data From Multiple Missions

Oceanic phytoplankton may play an important role in the cycling of carbon on the Earth, through the uptake of carbon dioxide in the process of photosynthesis. Although they are ubiquitous in the global oceans, their abundances and dynamics are difficult to estimate, primarily due to the vast spatial extent of the oceans and the short time scales over which their abundances can change. Consequently, the effects of oceanic phytoplankton on biogeochemical cycling, climate change, and fisheries are not well known. In response to the potential importance of phytoplankton in the global carbon cycle and the lack of comprehensive data, NASA and the international community have established high priority satellite missions designed to acquire and produce high quality ocean color data (Table 6.1). Ten of the missions are routine global observational missions: the Ocean Color and Temperature Sensor (OCTS), the Polarization and Directionality of the Earth's Reflectances sensor (POLDER), Sea-viewing Wide Field-of-view Sensor (SeaWiFS), Moderate Resolution Imaging Spectrometer-AM (MODIS-AM), Medium Resolution Imaging Spectrometer (MERIS), Global Imager (GLI), MODIS-PM, Super-GLI (S-GLI), and the Visible/Infrared Imager and Radiometer Suite (VIIRS) on the NPOESS Preparatory Project (NPP) and the National Polar-orbiting Operational Environmental Satellite System (NPOESS). In addition, there are several other missions capable of providing ocean color data on smaller scales. Most of these missions contain the spectral band complement considered necessary to derive oceanic chlorophyll concentrations and other related parameters. Many contain additional bands that can provide important ancillary information about the optical and biological state of the oceans.

Gregg, Watson W.↗
NASA NTRS1991

Terrestrial biogeochemical cycles - Global interactions with the atmosphere and hydrology

A review is presented of developments in ecosystem theory, remote sensing, and geographic information systems that support new endeavors in spatial modeling. A paradigm has emerged to predict ecosystem behavior based on understanding responses to multiple resources. Ecosystem models couple primary production to decomposition and nutrient availability utilizing this paradigm. It is indicated that coupling of transport and ecosystem processes alters the behavior of earth system components (terrestrial ecosystems, hydrology, and the atmosphere) from that of an uncoupled model.

Schimel, David S.↗
NASA NTRS1997

Satellite Analysis of Ocean Biogeochemistry and Mesoscale Variability in the Sargasso Sea

The objective of this study was to analyze the impact of spatial variability on the time-series of biogeochemical measurements made at the U.S. JGOFS Bermuda Atlantic Time-series Study (BATS) site. Originally the study was planned to use SeaWiFS as well as AVHRR high-resolution data. Despite the SeaWiFS delays we were able to make progress on the following fronts: (1) Operational acquisition, processing, and archive of HRPT data from a ground station located in Bermuda; (2) Validation of AVHRR SST data using BATS time-series and spatial validation cruise CTD data; (3) Use of AVHRR sea surface temperature imagery and ancillary data to assess the impact of mesoscale spatial variability on P(CO2) and carbon flux in the Sargasso Sea; (4) Spatial and temporal extent of tropical cyclone induced surface modifications; and (5) Assessment of eddy variability using TOPEX/Poseidon data.

Siegel, D. A.↗
NASA NTRS2002

Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment(BASE-ASIA)

Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially in Africa, South America, and South East Asia. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass-burning processes, which influence the Earth-atmosphere energetics and hence impact both global climate and tropospheric chemistry. Some gases and aerosols can serve as active cloud condensation nuclei, which play important role in determining the net radiation budget, precipitation rate, and cloud lifetime. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); the reflectivity and emissivity of the land; and the stability of ecosystems and ecosystem biodiversity. Compared to Africa and South America, the climatology in South East Asia reveals quite different characteristics, showing distinct large-scale smoke and cloud sources and interaction regimes. The fresh water distribution in this region is highly dependent on monsoon rainfall; in fact, the predictability of the tropical climate system is much reduced during the boreal spring, which is associated with the peak season of biomass burning activities. Estimating the burning fuel (e.g., bark, branches, and wood), an important part of studying regional carbon cycle, may rely on utilizing a wide range of distinctive spectral features in the shortwave and longwave regions. Therefore, to accurately assess the impact of smoke aerosols in this region requires continuous observations from satellites, aircraft, networks of ground-based instruments and dedicated field experiments. A new initiative will be proposed and discussed.

Tsay, Si-Chee↗
NASA NTRS2003

The East and Southeast Asia Initiatives: Aerosol Column Measurements

Airborne dusts from northern China contribute a significant part of the air quality problem and, to some extent, regional climatic impact in Asia during spring- time. However, with the economical growth in China, increases in the emission of air pollutants generated from industrial and vehicular sources will not only impact the radiation balance, but adverse health effects to humans all year round. In addition, both of these dust and air pollution clouds can transport swiftly across the Pacific reaching North America within a few days, possessing an even larger scale effect. The Asian dust and air pollution aerosols can be detected by its colored appearance on current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and its evolution monitored by satellites and surface network. Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3,Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth- atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Two new initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented and discussed their contribution to better understand the impacts of aerosols on regional-to- global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, Si-Chee↗
NASA NTRS2000

Significant Findings: Tracking the SeaWiFS Record with a Coupled Physical/Biogeochemical/Radiative Model of the Global Oceans

The Sea-Viewing Wide Field-of-view Sensor (SeaWiFS) has observed 2.5 years of routine global chlorophyll observations from space. The mission was launched into a record El Nino event, which eventually gave way to one of the most intensive and longest-lasting La Nina events ever recorded. The SeaWiFS chlorophyll record captured the response of ocean phytoplankton to these significant events in the tropical Indo-Pacific basins, but also indicated significant interannual variability unrelated to the El Nino/La Nina events. This included large variability in the North Atlantic and Pacific basins, in the North Central and equatorial Atlantic, and milder patterns in the North Central Pacific. This SeaWiFS record was tracked with a coupled physical/biogeochemical/radiative model of the global oceans using near-real-time forcing data such as wind stresses, sea surface temperatures, and sea ice. This provided an opportunity to offer physically and biogeochemically meaningful explanations of the variability observed in the SeaWiFS data set, since the causal mechanisms and interrelationships of the model are completely understood. The coupled model was able to represent the seasonal distributions of chlorophyll during the SeaWiFS era, and was capable of differentiating among the widely different processes and dynamics occurring in the global oceans. The model was also reasonably successful in representing the interannual signal, especially when it was large, such as, the El Nino and La Nina events in the tropical Pacific and Indian Oceans. The model provided different phytoplankton group responses for the different events in these regions: diatoms were predominant in the tropical Pacific during the La Nina but other groups were predominant during El Nino. The opposite condition occurred in the tropical Indian Ocean. Both situations were due to the different responses of the basins to El Nino. The interannual variability in the North Atlantic, which was exhibited in SeaWiFS data as a decline in the spring/summer bloom in 1999 relative to 1998, resulted in the model from a more slowly shoaling mixed layer, allowing herbivore populations to keep pace with increasing phytoplankton populations. However, several aspects of the interannual cycle were not well-represented by the model. Explanations ranged from inherent model deficiencies, to monthly averaging of forcing fields, to biases in SeaWiFS atmospheric correction procedures.

Watson, Gregg W.↗
NASA NTRS2003

Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment (BASE-ASIA)

Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth-atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Analyses from satellite measurements reveal that smoke is frequently present solar (emitted thermal) radiation from clouds due to smoke aerosols can be reduced (enhanced) by as much as 100 (20) W/sq m over the month of March 2000. In addition, the reduction in cloud spectral reflectance at 670 run is large enough to lead to significant errors in retrieving cloud properties (e.g., optical thickness and effective radius) from satellite measurements. The fresh water distribution in this region is highly dependent on monsoon rainfall; in fact, the predictability of the tropical climate system is much reduced during the boreal spring. Estimating the burning fuel (e.g., bark, branches, and wood), an important part of studying regional carbon cycle, may rely on utilizing a wide range of distinctive spectral features in the shortwave and longwave regions. Therefore, to accurately assess the impact of smoke aerosols in this region requires continuous observations from satellites, aircraft, networks of ground-based instruments and dedicated field experiments. A new initiative will be proposed and discussed.

Tsay, Si-Chee↗
NASA NTRS2004

Dust, Pollution, and Biomass Burning Aerosols in Asian Pacific: A Column Satellite-Surface Perspective

Airborne dusts from northern China contribute a significant part of the air quality problem and, to some extent, regional climatic impact in Asia during spring-time. However, with the economical growth in China, increases in the emission of air pollutants generated from industrial and vehicular sources will not only impact the radiation balance, but adverse health effects to humans all year round. In addition, both of these dust and air pollution clouds can transport swiftly across the Pacific reaching North America within a few days, possessing an even larger scale effect. The Asian dust and air pollution aerosols can be detected by its colored appearance on current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and its evolution monitored by satellites and surface network. Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth-atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Two new initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented and discussed their contribution to better understand the impacts of aerosols on regional-to-global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, Si-Chee↗
NASA NTRS1984

Biological Oceanography

Within the framework of global biogeochemical cycles and ocean productivity, there are two areas that will be of particular interest to biological oceanography in the 1990s. The first is the mapping in space time of the biomass and productivity of phytoplankton in the world ocean. The second area is the coupling of biological and physical processes as it affects the distribution and growth rate of phytoplankton biomass. Certainly other areas will be of interest to biological oceanographers, but these two areas are amenable to observations from satellites. Temporal and spatial variability is a regular feature of marine ecosystems. The temporal and spatial variability of phytoplankton biomass and productivity which is ubiquitous at all time and space scales in the ocean must be characterized. Remote sensing from satellites addresses these problems with global observations of mesocale (2 to 20 days, 10 to 200 km) features over a long period of time.

Abbott, M. R.↗
NASA NTRS1991

Biomass burning studies and the International Global Atmospheric Chemistry (IGAC) project

IGAC is an ambitious, decade-long and global research initiative concerned with major research challenges in the field of atmospheric chemistry; its chemists and ecosystem biologists are addressing the problems associated with global biomass burning (BMB). Among IGAC's goals is the achievement of a fundamental understanding of the natural and anthropogenic processes determining changes in atmospheric composition and chemistry, in order to allow century-long predictions. IGAC's studies have been organized into 'foci', encompassing the marine, tropical, polar, boreal, and midlatitude areas, as well as their global composite interactions. Attention is to be given to the effects of BMB on biogeochemical cycles.

Prinn, Ronald G.↗
NASA NTRS1983

Global Change: A Biogeochemical Perspective

A research program that is designed to enhance our understanding of the Earth as the support system for life is described. The program change, both natural and anthropogenic, that might affect the habitability of the planet on a time scale roughly equal to that of a human life is studied. On this time scale the atmosphere, biosphere, and upper ocean are treated as a single coupled system. The need for understanding the processes affecting the distribution of essential nutrients--carbon, nitrogen, phosphorous, sulfur, and water--within this coupled system is examined. The importance of subtle interactions among chemical, biological, and physical effects is emphasized. The specific objectives are to define the present state of the planetary life-support system; to ellucidate the underlying physical, chemical, and biological controls; and to provide the body of knowledge required to assess changes that might impact the future habitability of the Earth.

Mcelroy, M.↗
NASA NTRS2021

ACIX-Aqua: A Global Assessment of Atmospheric Correction Methods for Landsat-8 and Sentinel-2 Over Lakes, Rivers, and Coastal Waters

Atmospheric correction over inland and coastal waters is one of the major remaining challenges in aquatic remote sensing, often hindering the quantitative retrieval of biogeochemical variables and analysis of their spatial and temporal variability within aquatic environments. The Atmospheric Correction Intercomparison Exercise (ACIX-Aqua), a joint NASA – ESA activity, was initiated to enable a thorough evaluation of eight state-of-the-art atmospheric correction (AC) processors available for Landsat-8 and Sentinel-2 data processing. Over 1000 radiometric matchups from both freshwaters (rivers, lakes, reservoirs) and coastal waters were utilized to examine the quality of derived aquatic reflectances (ρ̂w). This dataset originated from two sources: Data gathered from the international scientific community (henceforth called Community Validation Database, CVD), which captured predominantly inland water observations, and the Ocean Color component of AERONET measurements (AERONET-OC), representing primarily coastal ocean environments. This volume of data permitted the evaluation of the AC processors individually (using all the matchups) and comparatively (across seven different Optical Water Types, OWTs) using common matchups. We found that the performance of the AC processors differed for CVD and AERONET-OC matchups, likely reflecting inherent variability in aquatic and atmospheric properties between the two datasets. For the former, the median errors in ρ̂w560 and ρ̂w664 were found to range from 20 to 30% for best-performing processors. Using the AERONET-OC matchups, our performance assessments showed that median errors within the 15–30% range in these spectral bands may be achieved. The largest uncertainties were associated with the blue bands (25 to 60%) for best-performing processors considering both CVD and AERONET-OC assessments. We further assessed uncertainty propagation to the downstream products such as near-surface concentration of chlorophyll-a (Chla) and Total Suspended Solids (TSS). Using satellite matchups from the CVD along with in situ Chla and TSS, we found that 20–30% uncertainties in ρ̂w490≤λ≤743nm yielded 25–70% uncertainties in derived Chla and TSS products for top-performing AC processors. We summarize our results using performance matrices guiding the satellite user community through the OWT-specific relative performance of AC processors. Our analysis stresses the need for better representation of aerosols, particularly absorbing ones, and improvements in corrections for sky- (or sun-) glint and adjacency effects, in order to achieve higher quality downstream products in freshwater and coastal ecosystems.

Nima Pahlevan↗