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At least 199 records · Page 11

Relative toxicity testing of spacecraft materials. 1: Spacecraft materials

In chamber thermodegradation procedures were used to access the lethality to rats of the pyrolysis/combustion products of three foams, an adhesive backed metallic tape and RTV silicone rubber adhesive sealant used in spacecraft construction. The role of carbon monoxide in the overall pyrolysate toxicity was also investigated. Post exposure observation of the rats, histological evaluation of selected organs, carbon monoxide concentration in the chamber atmosphere during exposure and the percent carboxyhemoglobin in the animals expiring in the chamber are discussed. Thermogravimetric analysis and dosage response results are given. The lethal effect of the RTV silicon appears to be due to physical obstruction of the respiratory system by particulate matter from pyrolysis.

Lawrence, W. H.↗

NASA Tech Briefs, December 2007

Topics include: Ka-Band TWT High-Efficiency Power Combiner for High-Rate Data Transmission; Reusable, Extensible High-Level Data-Distribution Concept; Processing Satellite Imagery To Detect Waste Tire Piles; Monitoring by Use of Clusters of Sensor-Data Vectors; Circuit and Method for Communication Over DC Power Line; Switched Band-Pass Filters for Adaptive Transceivers; Noncoherent DTTLs for Symbol Synchronization; High-Voltage Power Supply With Fast Rise and Fall Times; Waveguide Calibrator for Multi-Element Probe Calibration; Four-Way Ka-Band Power Combiner; Loss-of-Control-Inhibitor Systems for Aircraft; Improved Underwater Excitation-Emission Matrix Fluorometer; Metrology Camera System Using Two-Color Interferometry; Design and Fabrication of High-Efficiency CMOS/CCD Imagers; Foam Core Shielding for Spacecraft CHEM-Based Self-Deploying Planetary Storage Tanks Sequestration of Single-Walled Carbon Nanotubes in a Polymer PPC750 Performance Monitor Application-Program-Installer Builder Using Visual Odometry to Estimate Position and Attitude Design and Data Management System Simple, Script-Based Science Processing Archive Automated Rocket Propulsion Test Management Online Remote Sensing Interface Fusing Image Data for Calculating Position of an Object Implementation of a Point Algorithm for Real-Time Convex Optimization Handling Input and Output for COAMPS Modeling and Grid Generation of Iced Airfoils Automated Identification of Nucleotide Sequences Balloon Design Software Rocket Science 101 Interactive Educational Program Creep Forming of Carbon-Reinforced Ceramic-Matrix Composites Dog-Bone Horns for Piezoelectric Ultrasonic/Sonic Actuators Benchtop Detection of Proteins Recombinant Collagenlike Proteins Remote Sensing of Parasitic Nematodes in Plants Direct Coupling From WGM Resonator Disks to Photodetectors Using Digital Radiography To Image Liquid Nitrogen in Voids Multiple-Parameter, Low-False-Alarm Fire-Detection Systems Mosaic-Detector-Based Fluorescence Spectral Imager Plasmoid Thruster for High Specific-Impulse Propulsion Analysis Method for Quantifying Vehicle Design Goals Improved Tracking of Targets by Cameras on a Mars Rover Sample Caching Subsystem Multistage Passive Cooler for Spaceborne Instruments GVIPS Models and Software Stowable Energy-Absorbing Rocker-Bogie Suspensions

Source record↗

Materials and Processes Engineering's Role in the Reconstruction and Failure Analysis of The Space Shuttle Columbia

Conclusions: The hot gases, having flooded the wing interior, quickly heated the upper and lower wing surfaces allowing the aluminum honeycomb facesheets and the wing tiles to debond. The thin-wall aluminum truss tubes would soon collapse and the aerodynamic and structural integrity of the left wing would be effectively destroyed. The forensic evidence is consistent with the observed External Tank foam impact 81 seconds into launch. This is the most probable cause of the damage to the Reinforced Carbon-Carbon. (RCC) leading edge.

Russell, Richard↗

The Evaluation of Composite Energy Absorbers for Use in UAM EVTOL Vehicle Impact Attenuation

The demand for new personal air-taxi services is leading to the development of lightweight Vertical Take-off and Landing (eVTOL) vehicles with electric propulsion for the Urban Air Mobility (UAM) industry. Manufacturers (OEMs) are considering many different designs to develop a vehicle that is able to take-off, cruise, and land autonomously with seating arrangements ranging between 2 and 15 passengers. It is unclear at present how the eventual market will mature; however, one of the common design characteristics noted by many of the OEMs is the use of advanced materials such as composites. A test and analysis program was initiated at NASA Langley Research Center (LaRC) in 2018 to evaluate the impact attenuation capabilities of various composite material systems with the goal of eventual implementation into an eVTOL vehicle. A series of 3-inch diameter by 6-inch length tubular specimens were fabricated from different material systems which included both traditional carbon and hybrid woven layers of fibers. Additionally, a subset of specimens were filled with closed-cell polyisocyanurate foam to help both with stabilization and crush response. The ultimate goal of the test program was to design a specimen capable of limiting the sustained crush acceleration to 20 g through a stable crush progression. After a series of material tests, these specimens were evaluated under both static and dynamic conditions for impact energy attenuation characteristics and crush stability. Additionally, a series of simulation models were developed in parallel to the test efforts. It is anticipated that the models developed using the component level test efforts can be used to help guide the development of a design for use in full-scale eVTOL vehicle applications.

Littell, Justin↗

Synthesis and Characterization of Soy Hull Biochar-Based Flexible Polyurethane Foam Composites

Flexible polyurethane foams are a diverse class of materials encompassing furniture, packaging, automotive, and many other industrial and domestic applications. Polyurethane foams are synthesized by the addition of polyols and isocyanates; however, the petroleum origin and toxic nature of isocyanates have driven many to look for more sustainable routes to production. Renewable fillers have emerged as a biobased resource to decrease the carbon footprint of this widely used polymeric material. In this study, soy hulls, as mass-produced, industrial by-products of soybean production, were used to create a biochar beneficial in the synthesis of flexible polyurethane foam composites. The addition of soy hull biochar was found to maintain the compression properties of foams at a decreasing isocyanate index, reducing the amount of isocyanates needed for production. In addition, the addition of biochar decreased the flammability of foams, important for many applications where consumer safety is important. The results point to the ability to create safer, more sustainable, and even more cost-effective polyurethane foams through the reduction in isocyanate use while maintaining the properties of this important class of polymers.

Chemistry↗

Characterization of Space Shuttle External Tank Thermal Protection System (TPS) Materials in Support of the Columbia Accident Investigation

NASA suffered the loss of the seven-member crew of the Space Shuttle Columbia on February 1, 2003 when the vehicle broke apart upon re-entry to the Earth's atmosphere. The final report of the Columbia Accident Investigation Board (CAIB) determined that the accident was caused by a launch ascent incident-a suitcase-sized chunk of insulating foam on the Shuttle's External Tank (ET) broke off, and moving at almost 500 mph, struck an area of the leading edge of the Shuttle s left wing. As a result, one or more of the protective Reinforced Carbon-Carbon (RCC) panels on the wing leading edge were damaged. Upon re-entry, superheated air approaching 3,000 F breached the wing damage and caused the vehicle breakup and loss of crew. The large chunk of insulating foam that broke off during the Columbia launch was determined to come from the so-called bipod ramp area where the Shuttle s orbiter (containing crew) is attached to the ET. Underneath the foam in the bipod ramp area is a layer of TPS that is a cork-filled silicone rubber composite. In March 2003, the NASA Marshall Space Flight Center (MSFC) in Huntsville, Alabama received cured samples of the foam and composite for testing from the Michoud Assembly Facility (MAF) in New Orleans, Louisiana. The MAF is where the Shuttle's ET is manufactured. The foam and composite TPS materials for the ET have been well characterized for mechanical property data at the super-cold temperatures of the liquid oxygen and hydrogen fuels used in the ET. However, modulus data on these materials is not as well characterized. The TA Instruments 2980 Dynamic Mechanical Analyzer (DMA) was used to determine the modulus of the two TPS materials over a range of -145 to 95 C in the dual cantilever bending mode. Multi-strain, fixed frequency DMA tests were followed by multi-frequency, fixed strain tests to determine the approximate bounds of linear viscoelastic behavior for the two materials. Additional information is included in the original extended abstract.

Wingard, Charles D.↗

Research on oxygen solubility in aqueous amine solvents with common additives used for CO 2 chemical absorption

Oxidative degradation in amine based post-combustion carbon capture (PCCC) leads to solvent losses and decreased solvent performance. Oxygen (O 2 ) in the flue gas is dissolved into the aqueous solvent and can reactively degrade the amine component. Advanced aqueous amine solvents are designed to contain additional surfactant and anti-foam additives as well as two types of corrosion inhibitors. These additives contribute to improve the solvent performance while reducing foaming and corrosion of expensive equipment. This work examines the impact of these additives on oxygen solubility (or dissolved oxygen - DO) in various aqueous amines used in PCCC including ethanolamine (MEA), 1-amino-2-propanol (A2P), 2-amino-1-propanol (2A1P), 2-(methylamino)-ethanol (NMEA), 2-(ethylamine)-ethanol (2EAE), diethanolamine (DEA), methyl-diethanolamine (MDEA), dimethylethanolamine (DMEA), piperazine (PZ), 1,2-ethyldiamine (EDA), and 1,6 hexadiamine (HDA). Further, the impact of carbon loading on oxygen solubility with and without these additives was also examined. The surfactant and anti-foam additives had minimal impact on DO for all the solvents investigated. The two anticorrosion additives had opposite effects in the measured DO, 2- mercaptobenzothiazole (MBT) decreased the DO concentration, and sodium metavanadate showed an increase. These results indicate that several of these common additives can be expected to minimally affect DO related oxidative degradation in these advance amine solvents.

60 APPLIED LIFE SCIENCES↗

A Review of CCUS in the Context of Foams, Regulatory Frameworks and Monitoring

Greenhouse gas emission into the atmosphere is considered the main reason for the rise in Earth’s mean surface temperature. According to the Paris Agreement, to prevent the rise of the global average surface temperature beyond two degrees Celsius, global CO2 emissions must be cut substantially. While a transition to a net-zero emission scenario is envisioned by mid-century, carbon capture, utilization, and storage (CCUS) will play a crucial role in mitigating ongoing greenhouse gas emissions. Injection of CO2 into geological formations is a major pathway to enable large-scale storage. Despite significant recent technological advancements, mass deployment of these technologies still faces several technical and non-technical difficulties. This paper provides an overview of technical milestones reached thus far in CO2 capture, utilization, geological storage, monitoring technologies, and non-technical aspects such as regulatory frameworks and related policies in the US and the rest of the world. This paper describes different injection methods to store CO2 in various subsurface formations, the use of foams and the resulting potential gains in CO2 storage capacity, the role of nanoparticles for foam stabilization, and ensuring long-term storage safety. This work also addresses several safety-related aspects of geological storage and subsurface monitoring technologies that may mitigate risks associated with long-term storage.

42 ENGINEERING↗

Test-Analysis Correlation for Space Shuttle External Tank Foam Impacting RCC Wing Leading Edge Component Panels

The Space Shuttle Columbia Accident Investigation Board recommended that NASA develop, validate, and maintain a modeling tool capable of predicting the damage threshold for debris impacts on the Space Shuttle Reinforced Carbon-Carbon (RCC) wing leading edge and nosecap assembly. The results presented in this paper are one part of a multi-level approach that supported the development of the predictive tool used to recertify the shuttle for flight following the Columbia Accident. The assessment of predictive capability was largely based on test analysis comparisons for simpler component structures. This paper provides comparisons of finite element simulations with test data for external tank foam debris impacts onto 6-in. square RCC flat panels. Both quantitative displacement and qualitative damage assessment correlations are provided. The comparisons show good agreement and provided the Space Shuttle Program with confidence in the predictive tool.

Lyle, Karen H.↗

Properties and applications of a pitch carbon microsphere composite

Some properties and applications of a pitch carbon microsphere composite are described. The small hollow microspheres are made from the pitch which is usually a wasted by-product of petroleum refining. In contrast to high density composites or syntactic foams in which microspheres are inclusions within a continuous matrix, this composite is an aggregate of microspheres bonded together by a small amount of thermosetting polymer which does not form a continuous matrix. The result is a composite with low density and thermal expansion, modest strength and rigidity, and high porosity and carbon content. Mechanical, thermal, and sorption properties have been measured. Applications of the composite include honeycomb filler for high temperature or ionizing radiation fields and a wicking absorber for solar-powered stills.

Price, H. L.↗

A comparison of ceramic and carbon-based reductants for vitrification of low-activity waste

Sucrose is the current baseline additive at the Hanford Waste Treatment and Immobilization Plant in Washington, USA to control foaming during waste feed to glass transitions and the redox state of the glass melt. Alternative reductants are being investigated to alleviate strain on effluent treatment from toxic acetonitrile production from incomplete combustion of sucrose. This study evaluates ceramic additive options including B4C, B6Si, SiC and VB2 in simulated low-activity waste feed, as well as coke dust, probing the feed volume expansion during melting as well as the gas evolution. All alternative reductant options examined significantly reduced acetonitrile production, however there was variability in their effectiveness as foam-reducing agents. VB2 and coke at the appropriate ratios were similarly effective as sucrose in controlling both foam volume and glass redox state, but with considerably less acetonitrile production. B4C, B6Si and SiC showed more promising foam control and very little acetonitrile production, however all of the final glasses were over reduced, i.e., Fe2+/FeT = 0.5. These alternative reductant studies provide operational flexibility to the operation of the vitrification plant, as well as options for alternative raw materials in industrial glass melting.

Rigby, Jessica C. (ORCID:0000000235719977)↗

Gas Sensor Evaluations in Polymer Combustion Product Atmospheres

Toxic gases produced by the combustion or thermo-oxidative degradation of materials such as wire insulation, foam, plastics, or electronic circuit boards in space shuttle or space station crew cabins may pose a significant hazard to the flight crew. Toxic gas sensors are routinely evaluated in pure gas standard mixtures, but the possible interferences from polymer combustion products are not routinely evaluated. The NASA White Sands Test Facility (WSTF) has developed a test system that provides atmospheres containing predetermined quantities of target gases combined with the coincidental combustion products of common spacecraft materials. The target gases are quantitated in real time by infrared (IR) spectroscopy and verified by grab samples. The sensor responses are recorded in real time and are compared to the IR and validation analyses. Target gases such as carbon monoxide, hydrogen cyanide, hydrogen chloride, and hydrogen fluoride can be generated by the combustion of poly(vinyl chloride), polyimide-fluoropolymer wire insulation, polyurethane foam, or electronic circuit board materials. The kinetics and product identifications for the combustion of the various materials were determined by thermogravimetric-IR spectroscopic studies. These data were then scaled to provide the required levels of target gases in the sensor evaluation system. Multisensor toxic gas monitors from two manufacturers were evaluated using this system. In general, the sensor responses satisfactorily tracked the real-time concentrations of toxic gases in a dynamic mixture. Interferences from a number of organic combustion products including acetaldehyde and bisphenol-A were minimal. Hydrogen bromide in the products of circuit board combustion registered as hydrogen chloride. The use of actual polymer combustion atmospheres for the evaluation of sensors can provide additional confidence in the reliability of the sensor response.

Delgado, Rafael H.↗

Predictive Modeling of Electrodeposition in a Single Pore Flow-Through Electrode: From Electronucleation to Coating Thickness Uniformity

The emergence of advanced manufacturing methods capable of producing porous three-dimensional structures has expanded the design space for next-generation functional components. The ability to fabricate ordered 3D foams for use in electrocatalysis reactors has increased the need for controlled deposition of catalytic metals onto porous support materials, such as carbon. However, there is a lack of clear design guidelines for electrodeposition onto 3D substrates, due to the geometric complexity and multi-scale nature of the problem. Furthermore, electro-nucleation phenomena are often overlooked in macro-scale models of current distribution during deposition. Here, a graphite flow-through electrode (FTE) is used as a model system for copper deposition within a single pore. Potential distributions and electro-nucleation phenomena are coupled in a continuum level model by incorporating nucleation size and density as a function of overpotential, determined experimentally using in situ atomic force microscopy (AFM). The model predictions are validated by measuring the coating uniformity in the pore using micro-computed X-ray tomography (μCT). A scaling analysis comprising dimensionless parameters such as the Wagner number is presented. The simplified scaling relationship framework can guide the electrodeposition process and electrode design to optimize plating of porous substrates under fluid flow conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Shape Effect Analysis of Aluminum Projectile Impact on Whipple Shields

The informed design with respect to hypervelocity collisions involving micrometeoroid and orbital debris (MMOD) is influential to the success of space missions. For an orbit comparable to that of the International Space Station, velocities for MMOD can range from 1 to 15 km/s, with an average velocity around 10 km/cu s. The high energy released during collisions at these speeds can result in damage to a spacecraft, or worst-case, loss of the spacecraft, thus outlining the importance of methods to predict the likelihood and extent of damage due to an impact. Through experimental testing and numerical simulations, substantial work has been conducted to better understand the effects of hypervelocity impacts (HVI) on spacecraft systems and shields; however, much of the work has been focused on spherical impacting particles. To improve environment models for the analysis of MMOD, a large-scale satellite break-up test was performed at the Arnold Engineering and Development Complex to better understand the varied impactor geometries that could be generated from a large impact. As a part of the post-experiment analysis, an undertaking to characterize the irregular fragments generated is currently being performed by the University of Florida under the management of NASA's Orbital Debris Program Office at Johnson Space Center (JSC). DebriSat was a representative, modern LEO satellite that was catastrophically broken up in a HVI test. The test chamber was lined with a soft-catch system of foam panels that captured the fragments after impact. Initial predictions put the number of fragments larger than 2mm generated from the HVI at roughly 85,000. The number of fragments thus far extracted from the foam panels has exceeded 100,000, with that number continuously increasing. The shapes of the fragments vary dependent upon the material. Carbon-fiber reinforced polymer pieces, for instance, are abundantly found as thin, flat slivers. The characterization of these fragments with respect to their mass, size, and material composition needs to be summarized in a form that can be used in MMOD analysis. The mechanism that brings these fragment traits into MMOD analysis is through ballistic limit equations (BLE) that have been developed largely for a few types of materials1. As a BLE provides the failure threshold for a shield or spacecraft component based on parameters such as the projectile impact velocity and size, and the target's materials, thickness, and configuration, it is used to design protective shields for spacecraft such as Whipple shields (WS) to an acceptable risk level. The majority of experiments and simulations to test shields and validate BLEs have, heretofore, largely used spheres as the impactor, not properly reflecting the irregular shapes of MMOD. This shortfall has motivated a numerical impact analysis study of HVI involving non-spherical geometries to identify key parameters that environment models should provide.

Carrasquilla, Maria J.↗

STS-114: Discovery Post MMT Briefing

Wayne Hale, Space Shuttle Deputy Program Manager and Steve Poulos, Manager Orbit Project Office at Johnson Space Center is seen during a post Mission Management Team (MMT) briefing. The purpose of this briefing is to talk about the status of the Space Shuttle Discovery Orbiter, the Thermal Protection System (TPS) and the External Tank. Hale presents pictures of the missing foam off of the Hydrogen Protuberance Air Load (PAL) ramp and trajectory debris particles. Poulos explains in detail diagrams of the reinforced carbon-carbon system, possible scuff on the wing panel, coating damage, protruding gap filler and damaged tile blanket. Poulos tells what concerns him the most in terms of tile damage to the Space Shuttle Discovery.

Source record↗

Analysis and Tests of Reinforced Carbon-Epoxy/Foam-Core Sandwich Panels with Cutouts

The results of a study of a low-cost structurally efficient minimum-gage shear-panel design that can be used in light helicopters are presented. The shear-panel design is based on an integrally stiffened syntactic-foam stabilized-skin with an all-bias-ply tape construction for stabilized-skin concept with an all-bias-ply tape construction for the skins. This sandwich concept is an economical way to increase the panel bending stiffness weight penalty. The panels considered in the study were designed to be buckling resistant up to 100 lbs/in. of shear load and to have an ultimate strength of 300 lbs/in. The panel concept uses unidirectional carbon-epoxy tape on a syntactic adhesive as a stiffener that is co-cured with the skin and is an effective concept for improving panel buckling strength. The panel concept also uses pultruded carbon-epoxy rods embedded in a syntactic adhesive and over-wrapped with a bias-ply carbon-epoxy tape to form a reinforcing beam which is an effective method for redistributing load around rectangular cutout. The buckling strength of the reinforced panels is 83 to 90 percent of the predicted buckling strength based on a linear buckling analysis. The maximum experimental deflection exceeds the maximum deflection predicted by a nonlinear analysis by approximately one panel thickness. The failure strength of the reinforced panels was two and a half to seven times of the buckling strength. This efficient shear-panel design concept exceeds the required ultimate strength requirement of 300 lbs/in by more than 100 percent.

Baker, Donald J.↗

High-temperature high-pressure microfluidic system for rapid screening of supercritical CO 2 foaming agents

CO 2 foam helps to increase the viscosity of CO 2 flood fluid and thus improve the process efficiency of the anthropogenic greenhouse gas’s subsurface utilization and sequestration. Successful CO 2 foam formation mandates the development of high-performance chemicals at close to reservoir conditions, which in turn requires extensive laboratory tests and evaluations. This work demonstrates the utilization of a microfluidic reservoir analogue for rapid evaluation and screening of commercial surfactants (i.e., Cocamidopropyl Hydroxysultaine, Lauramidopropyl Betaine, Tallow Amine Ethoxylate, N,N,N' Trimethyl-N'-Tallow-1,3-diaminopropane, and Sodium Alpha Olefin Sulfonate) based on their performance to produce supercritical CO 2 foam at high salinity, temperature, and pressure conditions. The microfluidic analogue was designed to represent the pore sizes of the geologic reservoir rock and to operate at 100 °C and 13.8 MPa. Values of the pressure drop across the microfluidic analogue during flow of the CO 2 foam through its pore network was used to evaluate the strength of the generated foam and utilized only milliliters of liquid. The transparent microfluidic pore network allows in-situ quantitative visualization of CO 2 foam to calculate its half-life under static conditions while observing if there is any damage to the pore network due to precipitation and blockage. The microfluidic mobility reduction results agree with those of foam loop rheometer measurements, however, the microfluidic approach provided more accurate foam stability data to differentiate the foaming agent as compared with conventional balk testing. The results obtained here supports the utility of microfluidic systems for rapid screening of chemicals for carbon sequestration or enhanced oil recovery operations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Transfer functions

The vulnerability of electronic equipment to carbon fibers is studied. The effectiveness of interfaces, such as filters, doors, window screens, and cabinets, which affect the concentration, exposure, or deposition of carbon fibers on both (internal and external) sides of the interface is examined. The transfer function of multilayer aluminum mesh, wet and dry, polyurethane foam, and window screen are determined as a function of air velocity. FIlters installed in typical traffic control boxes and air conditioners are also considered.

Taback, I.↗