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At least 199 records · Page 11

On residual stress analysis and microstructural evolution for stainless steel type 304 spent nuclear fuel canisters weld joint: Numerical and experimental studies

Chloride-induced stress corrosion cracking (CISCC) in the weldments of austenitic stainless steel canisters is one of the primary safety concerns during the dry storage of used nuclear fuel at Independent Spent Fuel Storage Installations in coastal areas. In order to evaluate the CISCC behavior in the canister, a 3D sequentially coupled thermo-mechanical finite element model was built to simulate the residual stresses induced by two intersecting longitudinal and circumferential multi-pass welds in austenitic stainless steel mockup canister. Weld-induced residual stresses from simulation were in good agreement with the experimental measurement results by deep-hole drilling and contour methods. Through-wall high tensile axial and hoop stresses were observed in both the fusion zone and heat affected zone (HAZ) in the longitudinal and circumferential weld, respectively. On the other hand, the microstructure within the weldments of 304 stainless steel mockup was characterized using optical microscopy, scanning electron microscopy, electron back-scattered diffraction and energy dispersive X-ray spectroscopy methods. A few amount of MnS inclusions in both the base metal and HAZ, and a lot of (Mn,Si) x O y inclusions in the fusion zone were found. Meanwhile, there is some α'-martensite in the base metal, while the martensite was reversed in the HAZ. In the fusion zone, there is a lot of δ-ferrite. The martensite reversion phenomenon was also verified by the combination of Feritscope test and thermal simulation, which could predict a martensite reversion temperature as 400C°. The welding residual stresses and microstructure analysis results could offer the instructive information for the prediction of CISCC behavior of the spent nuclear fuel canisters.

36 MATERIALS SCIENCE↗

High-Pressure Synthesis of Bulk Cobalt Cementite, Co 3 C

Transition metal carbides find use in a wide range of advanced high-resilience applications including high-strength steels, heat shields, and deep-earth drills. However, carbides of the mid-to-late transition metals remain difficult to isolate and characterize on account of their metastability, which precludes the preparation of high-quality bulk single crystal samples using traditional solid-state methods. Herein, we report a combined computational and experimental survey of the cobalt-carbon binary system under high pressures and demonstrate that pressure offers a route toward the bulk synthesis of the metastable cementite-type cobalt carbide, Co 3 C, which under ambient conditions can only be prepared in low-dimensional thin film or nanoparticle forms. First-principles calculations reveal two competitive low-energy stoichiometric phases under ambient pressures - Pnnm-Co 2 C (Fe 2 C-type) and Pnma-Co 3 C (Fe 3 Ctype) - consistent with the known low-dimensional phases that have been studied for their promising magnetic properties. However, the calculated formation enthalpy of Pnma-Co 3 C decreases steadily with the applied pressure, while that of Pnnm-Co 2 C increases. Here, we pursue these results using high-pressure laser-heated synthesis methods coupled with in situ X-ray diffraction and observe the formation of Pnma-Co 3 C above 4.8 GPa. We determine the experimental bulk modulus of Co 3 C to be K o = 237 GPa (K p = 4.0). First-principles calculations of the phonon modes in Co 3 C reveal dynamical instabilities at ambient pressure that are absent under compression. These results offer a promising new route for the synthesis of rare-earth-free magnets.

36 MATERIALS SCIENCE↗

Geologic Characterization of the South Georgia Rift Basin for Source Proximal CO2 Storage

The project Geologic Characterization of the South Georgia Rift Basin for Source Proximal CO2 Storage is one of 9 site characterization projects that were implemented as part of ARRA (American Recovery and Reinvestment Act). Data from this project was used to improve resolution of data in NATCARB in the area of study. Data related to this study has already been incorporated in NATCARB Atlas. The South Carolina Research Foundation and partners evaluated the feasibility of CCS in the Jurassic/ Triassic (J / TR) saline formations of the buried Mesozoic South Georgia Rift (SGR) Basin that extends from South Carolina into Georgia. The J / TR sequence, based on preliminary assessment of limited geologic and geophysical data, appears to have both the appropriate areal extent and multiple horizons to permanently and safely store CO2 The presence of several igneous rock layers within the sequence may potentially provide adequate seals to prevent upward CO2 migration into the Coastal Plain aquifer systems. Approximately 81 kilometers of 2-D seismic reflection data were collected by Bay Geophysical, Inc. to explore a portion of the SGR located in southern Georgia. The 81 kilometers were divided into two lines approximately 40.5 kilometers each, with Line 1 intersecting Georgia well GGS 3457. Line 2 intersects Line 1 at the southern portion of Line 1 to maximize the extent of coverage away from GGS-3457 (a deep well drilled in the 1980s for oil and gas exploration). This well had a set of usable logs, including gamma and neutron logs that provided promising results related to CO2 storage. Results showed sandstone with porosity values greater than 10 percent and a thickness of 120 meters. The design of the seismic shot was to extrapolate information away from the well and to better define the extent of the SGR and the necessary reservoir and caprock for a successful CO2 injection. A numerical simulation model of CO2 Injection and migration was developed based on the geology log for the GGS-3457 well. The simulation model was used to investigate the feasibility of injecting 30 million metric tons of CO2 into SGR J / TA sediments and integrity of the diabase layers as seals to prevent CO2 migration.

2-D seismic↗

Applying 3D Geologic Modeling Workflows to the Argillite Reference Case (Rev. 1)

The objective of this short report is to document the application of our 3D geologic modeling workflow to an argillite (shale) host rock. Over the past four years, our team at Los Alamos National Laboratory has developed a geologic modeling workflow that can be applied to generic alluvial basins such as those found in the western United States. In “frontier” or “exploratory” basins where data are sparse, the first steps are to collect, evaluate and integrate available subsurface data into conceptual geologic models. Those models form the basis for constructing the geologic framework model, a 3D geocellular model ideally constrained by seismic and borehole data. To date we have constructed our models using “synthetic” well data derived from conceptual models, without the prospect of validating our workflow using “real” subsurface data. We were tasked to investigate whether our workflow designed for alluvial basin sediments could be applied to other potential repository host rocks. This task also provided the opportunity to work with high-quality subsurface data collected specifically for siting and evaluating a nuclear waste repository. Nagra, the Swiss governmental agency responsible for the disposal of the nation’s radioactive waste, generously provided us with data from two deep boreholes drilled through their argillaceous target formation. The aim of our proof-of-concept demonstration is to evaluate whether geostatistical methods offer a viable approach to property modeling in argillaceous rocks. Nagra provided us with the well data on the condition that we maintain confidentiality with all transferred information and results. Fortunately, Nagra posts numerous technical reports on its public website that describe the subsurface geology in great detail. All of the information and illustrations in this report related to the Swiss repository enterprise are taken from the Nagra public website.

58 GEOSCIENCES↗

Micro- and nano-porosity of the active Alpine Fault zone, New Zealand

Porosity reduction in rocks from a fault core can cause elevated pore fluid pressures and consequently influence the recurrence time of earthquakes. We investigated the porosity distribution in the New Zealand's Alpine Fault core in samples recovered during the first phase of the Deep Fault Drilling Project (DFDP-1B) by using two-dimensional nanoscale and three-dimensional microscale imaging. Synchrotron X-ray microtomography-derived analyses of open pore spaces show total microscale porosities in the range of 0.1 %–0.24 %. These pores have mainly non-spherical, elongated, flat shapes and show subtle bipolar orientation. Scanning and transmission electron microscopy reveal the samples' microstructural organization, where nanoscale pores ornament grain boundaries of the gouge material, especially clay minerals. Our data imply that (i) the porosity of the fault core is very small and not connected; (ii) the distribution of clay minerals controls the shape and orientation of the associated pores; (iii) porosity was reduced due to pressure solution processes; and (iv) mineral precipitation in fluid-filled pores can affect the mechanical behavior of the Alpine Fault by decreasing the already critically low total porosity of the fault core, causing elevated pore fluid pressures and/or introducing weak mineral phases, and thus lowering the overall fault frictional strength. We conclude that the current state of very low porosity in the Alpine Fault core is likely to play a key role in the initiation of the next fault rupture.

58 GEOSCIENCES↗

Preliminary organic analyses of the DSDP /JOIDES/ cores - Legs V-IX.

Descriptions of the methods used and results obtained in analyses of deep sea drilling cores. The analyses were performed in two phases (differing in degree of particularization) depending on the amount of core sample available. The results are presented in relation to the ages and to the fossil fauna and flora of the sediments.

Simoneit, B. R.↗

Residual glasses and melt inclusions in basalts from DSDP Legs 45 and 46 - Evidence for magma mixing

Microprobe analyses of natural glasses in basalts recovered by Legs 45 and 46 of the Deep Sea Drilling Project are reported and interpreted in the context of other geochemical, petrographic and experimental data on the same rocks (Rhodes et al., 1978). Residual glass compositions in the moderately evolved aphyritic and abundantly phyric basalts within each site indicate that none of the units is related to any other or to a common parent by simple fractional crystallization. The compositional trends, extensive disequilibrium textures in the plagioclase phenocrysts and the presence in evolved lavas of refractory plagioclase and olivine phenocrysts bearing primitive melt inclusions provide evidence that magma mixing had a major role in the genesis of the Leg 45 and 46 basalts. The magma parental to these basalts was most likely characterized by high Mg/(Mg + Fe/+2/), CaO/Al2O3, CaO/Na2O and low lithophile concentrations. A mixing model involving incremental enrichment of magmaphile elements by repeated episodes of mixing of relatively primitive and moderately evolved magmas, followed by a small amount of fractionation is consistent with the characteristics of the basalts studied.

Dungan, M. A.↗

Laser Micromachining In A Reactive Atmosphere

Drilling of deep holes in silicon by laser beam aided by conducting operation in reactive atmosphere. Atmosphere reacts with material ejected from hole and converts material to gas flowing away from work area. Hole cleaner and more sharply defined, and debris do not spatter surface of work.

Shlichta, Paul J.↗

Possible world-wide middle miocene iridium anomaly and its relationship to periodicity of impacts and extinctions

In a study of one million years of Middle Miocene sediment deposition in ODP Hole 689B in the Weddell Sea near Antarctica, a single iridium (Ir) anomaly of 44 (+ or - 10) x 10 to the 12th gram Ir per gram rock (ppt) was observed in core 6H, section 3, 50 to 60 cm, after background contributions associated with manganese precipitates and clay are subtracted. The ODP Hole 689B is 10,000 km away from another site, DSDP Hole 588B in the Tasman Sea north of New Zealand, where a single Ir anomaly of 144 + or - 7 ppt over a background of 11 ppt was found in an earlier study of 3 million years of deposition. From chemical measurements the latter deposition was thought to be impact-related. Ir measurements were made, following neutron activation, with the Iridium Coincidence Spectrometer. The age vs depth calibration curves given in the DSDP and ODP preliminary reports indicate the ages of the Iranomalies are identical, 11.7 million years, but the absolute and relative uncertainties in the curves are not known. Based on the newest age data the age estimate is 10 million years. As the Ir was deposited at the two sites at about the same time and they are one quarter of the way around the world from each other it seems likely that the deposition was world-wide. The impact of a large asteroid or comet could produce the wide distribution, and this data is supportive of the impact relationship deduced for Deep Sea Drilling Project (DSDP) 588B from the chemical evidence. If the surface densities of Ir at the two sites are representative of the world-wide average, the diameter of a Cl type asteroid containing the necessary Ir would be 3 + or - 1 km, which is large enough to cause world-wide darkness and hence extinctions although the latter point is disputed.

Asaro, F.↗

Magnetic microspherules associated with the K/T and upper Eocene extinction events

Magnetic microspherules were identified in over 20 K/T boundary sites, and in numerous Deep Sea Drilling Project (DSDP) cores from the Caribbean and Pacific, synchronous with the extinction of several radiolarian species near the end of the Eocene. The K/T magnetic spherules are of particular interest as carriers of Ir and other siderophiles generally found in abundance in K/T boundary clay. Furthermore the textures and unusual chemistry of their component magnetic phases indicate an origin at high temperature, possibly related to (an) unusual event(s) marking the end of the Cretaceous and Eocene periods. Their origin, along with the non-magnetic (sanidine) spheules, is generally ascribed directly to megaimpact events hypothesized to have periodically disrupted life on Earth. A survey of microspherical forms associated with known meteorite and impact derived materials reveals fundamental differences from the extinction related spherules. Low temperature magnetic experiments on the K/T and Upper Eocene spheroids indicate that, unlike tektites, extremely small superparamagnetic carriers are not present in abundance. The extensive subaerial exposure of Cretaceous combustible black shale during sea level regression in the latest Cretaceous represents a potential source for the magnetic spheroids found in certain K/T boundary clays. The recent discovery of high Ir abundances distributed above and below the K/T boundary within shallow water sediments in Israel, which also contain the most extensive known zones of combustion metamorphism, the so called Mottled Zone, adds a further dramatic footnote to the proposed association between the magnetic spheroids and combustion of organic shales. Interestingly, the Mottled Zone also contains the rare mineral magnesioferrite, which was identified both within the K/T magnetic spheroids and as discrete crystals in boundary clay from marine and continental sites.

Cisowski, Stanley M.↗

Impact wave deposits provide new constraints on the location of the K/T boundary impact

All available evidence is consistent with an impact into oceanic crust terminating the Cretaceous Period. Although much of this evidence is incompatible with an endogenic origin, some investigators still feel that a volcanic origin is possible for the Cretaceous/Tertiary (K/T) boundary clay layers. The commonly cited evidence for a large impact stems from delicate clay layers and their components and the impact site has not yet been found. Impact sites have been suggested all over the globe. The impact is felt to have occurred near North America by: the occurrence of a 2 cm thick ejecta layer only at North American locales, the global variation of shocked quartz grain sizes peaking in North America, the global variation of spinel compositions with most refractory compositions occurring in samples from the Pacific region and possibly uniquely severe plant extinctions in the North American region. The K/T boundary interval was investigated as preserved on the banks of the Brazos River, Texas. The K/T fireball and ejecta layers with associated geochemical anomalies were found interbedded with this sequence which apparently allows a temporal resolution 4 orders of magnitude greater than typical K/T boundary sections. A literature search reveals that such coarse deposits are widely preserved at the K/T boundary. Impact wave deposits have not been found elsewhere on the globe, suggesting the impact occurred between North and South America. The coarse deposits preserved in Deep Sea Drilling Project (DSDP) holes 151-3 suggest the impact occurred nearby. Subsequent tectonism has complicated the picture.

Hildebrand, A. R.↗

Seawater strontium isotopes at the Cretaceous-Tertiary boundary

Anomalously high values of Seawater Sr-87/Sr-86 near the Cretaceous-Tertiary (K-T) boundary have been reported. However, few of the data from the literature are from a single continuous section, and perhaps the most complete study of the boundary region, from a shallow marine limestone sequence in Alabama, showed elevated Sr-87/Sr-86 but no pronounced spike. Thus, in order to investigate the cause of the change in strontium isotopic composition, it is important to determine the exact nature and magnitude of the increase by studying in detail continuous sections through the boundary. If there is indeed a Sr isotope spike at the K-T boundary, it requires the addition of a large amount of radiogenic Sr to the oceans over a short time period, a phenomenon that may be linked to other large-scale environmental disturbances which occurred at that time. In order to address this question, a high-resolution strontium isotope study of foraminifera from three Deep Sea Drilling Project (DSDP) cores which recovered the K-T boundary section: Site 356 in the South Atlantic, Site 384 in the North Atlantic and Site 577 from the Shatsky Rise in the Pacific was initiated. The isotope measurements are being made on either single or small numbers of forams carefully picked and identified and in most cases examined by SEM before analysis. Because this work is not yet complete, conclusions drawn here must be viewed as tentative. They are briefly discussed.

Macdougall, J. D.↗

Step-wise extinctions at the Cretaceous-Tertiary boundary and their climatic implications

A comparative study of planktonic foraminifera and radiolarian assemblages from the Cretaceous-Tertiary (K-T) boundary section of the Beloc Formation in the southern Peninsula of Haiti, and the lowermost Danian sequence of the Micara Formation in southern Cuba reveals a remarkable pattern of step-wise extinctions. This pattern is consistent in both places despite the widely different lithologies of the two formations. Because of a step-wise extinction and the delayed disappearance of taxa known to be more representative of cooler water realms, it is inferred that a cooling trend which characterized the close of the Maastrichtian and the onset of the Tertiary had the major adverse effect on the existing biota. Although repetitive lithologic and faunal fluctuations throughout the Maastrichtian sediments found at Deep Sea Drilling Project (DSDP) site 146/149 in the Caribbean Sea indicate variations reminiscent of known climatically induced cycles in the Cenozoic, rapid biotic succession appears to have taken place during a crisis period of a duration greater than 2 mission years. Widespread and abundant volcanic activities recorded in the Caribbean area during the crisis period gives further credence to earlier contention that intense volcanism may have played a major role in exhacerbating pre-existing climatic conditions during that time.

Maurrasse, Florentin J-M. R.↗

Silicon carbide, an emerging high temperature semiconductor

In recent years, the aerospace propulsion and space power communities have expressed a growing need for electronic devices that are capable of sustained high temperature operation. Applications for high temperature electronic devices include development instrumentation within engines, engine control, and condition monitoring systems, and power conditioning and control systems for space platforms and satellites. Other earth-based applications include deep-well drilling instrumentation, nuclear reactor instrumentation and control, and automotive sensors. To meet the needs of these applications, the High Temperature Electronics Program at the Lewis Research Center is developing silicon carbide (SiC) as a high temperature semiconductor material. Research is focussed on developing the crystal growth, characterization, and device fabrication technologies necessary to produce a family of silicon carbide electronic devices and integrated sensors. The progress made in developing silicon carbide is presented, and the challenges that lie ahead are discussed.

Matus, Lawrence G.↗

Chemical Vapor Deposition Of Silicon Carbide

Large single-crystal SiC boules from which wafers of large area cut now being produced commerically. Availability of wafers opens door for development of SiC semiconductor devices. Recently developed chemical vapor deposition (CVD) process produces thin single-crystal SiC films on SiC wafers. Essential step in sequence of steps used to fabricate semiconductor devices. Further development required for specific devices. Some potential high-temperature applications include sensors and control electronics for advanced turbine engines and automobile engines, power electronics for electromechanical actuators for advanced aircraft and for space power systems, and equipment used in drilling of deep wells. High-frequency applications include communication systems, high-speed computers, and microwave power transistors. High-radiation applications include sensors and controls for nuclear reactors.

Powell, J. Anthony↗

Plio-Pleistocene time evolution of the 100-kyr cycle in marine paleoclimate records

A new time-series analysis technique (called envelope inversion), which is based on multiple taper spectral analysis, is used to address the question of an abrupt versus a gradual onset of the 100-kyr ice-age periodicity in the middle Pleistocene. Three long (greater than 2.6 m.y.) time series from Deep Sea Drilling Project site 607 (midlatitude Atlantic) and Ocean Drilling Program site 677 (equatorial Pacific) were analyzed using delta(O-18) records. Results do not yield compelling evidence for an abrupt change in the 100-kyr delta(O-18) signal. Rather, the results suggest that the 100-kyr delta(O-18) cycle is phase-locked with the 124-kyr eccentricity cycle some 300-400 kyr prior to its late Pleistocene growth in amplitude and phase lock with the 95-kyr eccentricity cycle.

Park, Jeffrey↗

The biostratigraphy and paleogeography of Maastrichtian inoceramids

The global distribution of Maastrichtian inoceramids is now known in enough detail that the patterns of disappearance can be used to place first-order constraints on paleoceanographic changes that may have occurred during that age. The Inoceramidae is an excellent group to focus on in a study of Maastrichtian events for the following reasons: (1) they were globally distributed in the early Maastrichtian; (2) they did not survive the age (i.e., they undergo change during the interval); and (3) they have left a rich microfossil and macrofossil record. Some inoceramids grew to be very large; however, even the largest often passively disaggregated and are preserved as hundreds of millions of characteristic, columnar, polygonal prisms of calcite approximately 100 microns across. This taphonomic process has greatly increased the inoceramid fossil record and provides a means of objectively estimating changes in their standing population. In addition, because these prisms commonly occur in Deep Sea Drilling Project (DSDP) and Ocean Drilling Program (ODP) cores, it is relatively easy to generate a truly global database. The existing macrofossil record of inoceramids has less temporal and spacial resolution but greater taxonomic resolution than the microfossil record. In concert the microfossil and macrofossil records of inoceramids demonstrate that important changes occurred during the Maastrichtian. These changes are distinct from the KT boundary catastrophe but are part of the larger KT transition.

Macleod, K. G.↗