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DOE OSTI2025

Photo-Swing CO2 Capture Using a Branched Polyethylenimine As Sorbents and TiN Light Absorber

Using branched polyethylenimine as the sorbent material for dilute CO2 capture, a photo-swing method is demonstrated in an industrially relevant support architecture using titanium nitride (TiN) nanosized light absorbers coupled with low-power LEDs with irradiances up to 420 mW cm-2. The photo-swing desorption process is applied to dry and humid streams of 400 ppm CO2 diluted in N2. Consistent with known sorption mechanisms for aminopolymers, humid CO2 streams increased the CO2 uptake, in our case by ~30%. The photo-swing CO2 capture desorbed ~83% and ~100% CO2 compared to thermally-driven desorption over the same period for a dry and humid CO2 stream, respectively. The photo-swing CO2 capture exhibits robust performance over >90 cycles without significant signs of photo(thermal) induced sorbent degradation. This work lays the groundwork for photo-swing DAC technology as a scalable, energy-efficient solution for CO2 capture, well-suited for modular systems in remote locations utilizing intermittent renewable energy sources.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Energy Storage Technologies and U.S. Department of War Requirements

This report offers an overarching primer the energy storage market and assessment of each technology’s suitability for U.S. Department of War applications. We find that battery energy storage is the most promising technology for energy storage applications in terms of energy density and cost. While commercial and advanced Li-ion can satisfy certain electric mobility (e.g., cars, midsized vehicles) and electric flight application (e.g. drones) needs of DoW, next generation technologies like Li metal solid-state batteries, and conversion chemistries (Li-air, Li-CFx) are needed for heavy duty applications like armored vehicles, tanks, airplanes, jets. Batteries should also be supplemented with technologies such as supercapacitors and next-generation flywheels to provide short bursts of high energy for high power needs. Thermal energy storage solutions (sensible and latent heat) and fuel cells (PEMFC and SOFC) are good alternatives for supporting energy storage applications in terms of energy density and cost. Gravity-based energy storage promises the least energy density with high cost and should only be used for niche DoW applications. Of the different gravity energy storage technologies reviewed, pumped-hydro, flywheel, and compressed air energy storage are promising, while solid gravity energy storage appears the least attractive. Military facilities requiring 14 days of energy storage can benefit from flow batteries, especially commercial VFRBs and next generation iron-air systems. While VFRBs are expensive, iron-air batteries have the coupled benefits of low cost and good energy density promising 100+ hours of storage.

25 ENERGY STORAGE↗

NASA NTRS1975

Chemical equilibrium of ablation materials including condensed species

Equilibrium is determined by finding chemical composition with minimum free energy. Method of steepest descent is applied to quadratic representation of free-energy surface. Solution is initiated by selecting arbitrary set of mole fractions, from which point on free-energy surface is computed.

Stroud, C. W.↗

DOE OSTI2024

Energy Efficiency Assistance for Galena Alaska

The City of Galena sits along the north bank of the Yukon River with no road access. Temperatures regularly reach negative 20°F in the winter and sunlight extends for up to 21 hours a day in the summer. Galena’s 400 residents, including members of the Koyukuk Athabascan culture, primarily use fuel oil and locally forested wood for heating and electricity generation. Because these resources are costly to obtain, local households have a high energy burden, spending 7% of their annual income on energy (averaging $4,000 per year). To reduce this burden, the City of Galena joined the U.S. Department of Energy’s (DOE) Remote Alaska Community Energy Efficiency (RACEE) Competition, where they received financial and technical assistance to implement energy savings solutions across their community, including building envelope improvements, solar panels, and LED lighting. Additionally, Galena installed new energy monitoring equipment to continue measuring the impacts of this work beyond the RACEE project.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2026

Energy–Performance Trade-offs in Privacy-Preserving Federated Learning on SmartNIC-Enabled HPC Systems

Federated learning (FL) is increasingly deployed on accelerator-rich high-performance computing (HPC) systems, yet the system-level energy cost of privacy-aware FL remains poorly understood, particularly across heterogeneous networking and server-placement options. We present a measurement-driven study of energy–performance trade-offs for FL on GH200-class nodes across three deployment configurations: CPU-Ethernet, CPU-InfiniBand (RDMA-capable), and a DPU-hosted FL server over InfiniBand using a BlueField-3 SmartNIC/DPU. Using NVIDIA FLARE (NVFLARE), we align node-level power telemetry with per-round timing extracted from NVFLARE logs to quantify time-to-solution (TTS), energy-to-solution (ETS), energy-delay product (EDP), and synchronization behavior for three transformer models (ALBERT, DistilBERT, BERT), trained with and without differential privacy (DP). We find that interconnect choice is the dominant driver of runtime and energy: host-managed InfiniBand consistently reduces communication overhead versus Ethernet, yielding lower TTS/ETS/EDP. In contrast, in our NVFLARE deployment, placing the FL server on the DPU does not consistently match CPU-InfiniBand performance and can be slower—especially for larger models—highlighting that server placement alone is not sufficient to guarantee end-to-end gains. Finally, under our fixed-round protocol, DP increases per-round cost and runtime variance; ETS increases largely in proportion to TTS because average node power remains relatively stable across configurations.

Kotevska, Olivera [ORNL] (ORCID:0000000316772243)↗

DOE OSTI2024

Optimizing Nonaqueous Sodium–Polysulfide Redox-Flow Batteries: The Role of Solvation Effects with Glyme Solvents

Nonaqueous redox-flow batteries (NARFBs) that use economical alkali metals and the corresponding metal polysulfides are highly attractive for grid-scale energy storage. Although sodium–sulfur systems have been recognized as promising candidates and have been the focus of many studies due to their high earth abundance and energy density, an understanding of the role of the solvation chemistry of commonly used glyme solvents is missing. Herein, we report a systematic investigation into the solvation effects of glyme-based Na-S electrolytes through comprehensive physiochemical experiments and Density Functional Theory (DFT) simulations. Our findings revealed, on one hand, that an optimal coordination strength between glymes and Na + could maintain a relatively smooth Na + diffusion. On the other hand, glyme solvents with extended chain lengths shift the reduction potential of S 8 2– negatively to elevate the formation barrier of undesirable short-chain polysulfides (S n 2– , n ≤ 4) that have high membrane permeability. This solvation phenomenon not only mitigates capacity fading but also extends the operational longevity of the Na-S NARFBs. In conclusion, the results underscore the critical roles of balanced solvent–cation interactions and controlled redox potentials in improving the stability and efficiency of Na-S NARFB systems, marking a significant advancement in the development of sustainable energy storage solutions.

25 ENERGY STORAGE↗

NASA NTRS1974

The abundances of nuclei in the cosmic radiation

The relative abundances are treated as a consequence of processes in cosmic ray transport occurring during passage of the radiation through interstellar material at high velocity. Some of the subjects mentioned are nuclear fragmentation and the production of secondary nuclei, nuclear reactions, energy loss and nuclear decay, ionization, the range-energy relation and propagation variables, capture and loss of electrons, the propagation of nuclei, the transport equation, equilibrium solutions, energy-dependent path length distribution, exponential path length distributions, discrete spectra, sources, supernovae, and the origin of the abundances. The connection between the space-time features of the sources, the material traversed, and the effects of magnetic fields is established by describing the particle-field interaction as a diffusive or random-walk process.

Reames, D. V.↗

NASA NTRS1991

Energy functions for regularization algorithms

Regularization techniques are widely used for inverse problem solving in computer vision such as surface reconstruction, edge detection, or optical flow estimation. Energy functions used for regularization algorithms measure how smooth a curve or surface is, and to render acceptable solutions these energies must verify certain properties such as invariance with Euclidean transformations or invariance with parameterization. The notion of smoothness energy is extended here to the notion of a differential stabilizer, and it is shown that to void the systematic underestimation of undercurvature for planar curve fitting, it is necessary that circles be the curves of maximum smoothness. A set of stabilizers is proposed that meet this condition as well as invariance with rotation and parameterization.

Delingette, H.↗

DOE OSTI2025

The effect of residential solar on energy insecurity among low- to moderate-income households

Each year, millions of Americans experience energy insecurity, or the inability to afford enough energy to meet their basic needs. Here, this study evaluates whether residential rooftop solar can serve as a preventative solution to energy insecurity among low- to moderate-income households. Using a national, matched sample of solar and non-solar households based on detailed and address-specific data, we find that solar leads to large, robust and salient reductions in five indicators of energy insecurity. Moreover, the benefits of solar ‘spill over’ to improve a household’s ability to pay other energy bills. The results suggest that rooftop solar may be an effective tool for policymakers who seek to reduce energy insecurity.

14 SOLAR ENERGY↗

NASA NTRS1975

Steady-state solutions of a diffusive energy-balance climate model and their stability

A diffusive energy-balance climate model, governed by a nonlinear parabolic partial differential equation, was studied. Three positive steady-state solutions of this equation are found; they correspond to three possible climates of our planet: an interglacial (nearly identical to the present climate), a glacial, and a completely ice-covered earth. Models similar to the main one are considered, and the number of their steady states was determined. All the models have albedo continuously varying with latitude and temperature, and entirely diffusive horizontal heat transfer. The stability under small perturbations of the main model's climates was investigated. A stability criterion is derived, and its application shows that the present climate and the deep freeze are stable, whereas the model's glacial is unstable. The dependence was examined of the number of steady states and of their stability on the average solar radiation.

Ghil, M.↗

NASA NTRS2004

Automating the Transition Between Sensorless Motor Control Methods for the NASA Glenn Research Center Flywheel Energy Storage System

The NASA Glenn Research Center (GRC) has been working to advance the technology necessary for a flywheel energy storage system for the past several years. Flywheels offer high efficiency, durability, and near-complete discharge capabilities not produced by typical chemical batteries. These characteristics show flywheels to be an attractive alternative to the more typical energy storage solutions. Flywheels also offer the possibility of combining what are now two separate systems in space applications into one: energy storage, which is currently provided by batteries, and attitude control, which is currently provided by control moment gyroscopes (CMGs) or reaction wheels. To date, NASA Glenn research effort has produced the control algorithms necessary to demonstrate flywheel operation up to a rated speed of 60,000 RPM and the combined operation of two flywheel machines to simultaneously provide energy storage and single axis attitude control. Two position-sensorless algorithms are used to control the motor/generator, one for low (0 to 1200 RPM) speeds and one for high speeds. The algorithm allows the transition from the low speed method to the high speed method, but the transition from the high to low speed method was not originally included. This leads to a limitation in the existing motor/generator control code that does not allow the flywheels to be commanded to zero speed (and back in the negative speed direction) after the initial startup. In a multi-flywheel system providing both energy storage and attitude control to a spacecraft, speed reversal may be necessary.

Fehrmann, Elizabeth A.↗

NASA NTRS1987

A numerical study of transient heat and mass transfer in crystal growth

A numerical analysis of transient heat and solute transport across a rectangular cavity is performed. Five nonlinear partial differential equations which govern the conservation of mass, momentum, energy and solute concentration related to crystal growth in solution, are simultaneously integrated by a numerical method based on the SIMPLE algorithm. Numerical results showed that the flow, temperature and solute fields are dependent on thermal and solutal Grashoff number, Prandtl number, Schmidt number and aspect ratio. The average Nusselt and Sherwood numbers evaluated at the center of the cavity decrease markedly when the solutal buoyancy force acts in the opposite direction to the thermal buoyancy force. When the solutal and thermal buoyancy forces act in the same direction, however, Sherwood number increases significantly and yet Nusselt number decreases. Overall effects of convection on the crystal growth are seen to be an enhancement of growth rate as expected but with highly nonuniform spatial growth variations.

Han, Samuel Bang-Moo↗

DOE OSTI2024

Bootstrap Principle for the Spectrum and Scattering of Strings

We show that the Veneziano amplitude of string theory is the unique solution to an analytically solvable bootstrap problem. Uniqueness follows from two assumptions: faster than power-law falloff in high-energy scattering and the existence of some infinite sequence in momentum transfer at which higher-spin exchanges cancel. The string amplitude—including the mass spectrum—is an output of this bootstrap. If the amplitude merely vanishes at high energies, the solution is a three-parameter family containing the Veneziano, Coon, and hypergeometric amplitudes, and more.

Field & string theory models & techniques↗

NASA NTRSDate not supplied

Overview of Nasa's Watts on the Moon Challenge Phase 1

As NASA works to extend human exploration of the solar system, unprecedented capacity for electrical and thermal energy will be needed to support sustained human presence and the beginning of industrial activity on the Moon. Solar energy is abundant on the lunar surface but extended night hours (up to 350 consecutive hours) and extreme temperature change from daylight to nighttime operation creates complexity for solar power use. Analogous issues arise on Earth, where demand for additional renewable energy generation, including solar, is rising, but better power management, distribution, and energy storage solutions are needed to address intermittency and resiliency, among other issues. To accelerate the development of technologies for power distribution and energy storage that can operate in extreme lunar conditions, NASA’s Centennial Challenges Program launched the Watts on the Moon Challenge in September 2020. Submissions for Phase 1 of the challenge were due in March 2021 and winners were announced in May 2021. This paper provides an overview of the challenge, key technical requirements, outcomes from Phase 1, and an update on Phase 2 of the challenge, which is currently ongoing.

Denise P. Morris↗

DOE OSTI2024

Pore-Filling Induced Solid Electrolyte Failure of Ti-Doped Na 3 Zr 2 Si 2 PO 12 Characterized by Operando Synchrotron X-Ray Tomography

Solid-state batteries (SSBs), particularly those utilizing sodium metal, are emerging as a promising technology due to their potential for enhanced safety, higher energy density, and longer cycle life. NASICON (Na superionic conductor) materials, known for their robust crystalline structure and high ionic conductivity, are pivotal in the development of efficient sodium all-solid-state batteries. These materials exhibit high room-temperature ionic conductivity and electrochemical stability, making them ideal for various applications. Research has focused on improving NASICON's ionic conductivity and stability through doping, interface regulation, and composite anode design. Recent advancements include Ti-doped Na 3 Zr 2 Si 2 PO 12 (Ti-NZSP), which demonstrates improved surface stability, higher ionic conductivity, and increased critical current density. However, challenges such as Na dendrite formation and mechanical integrity under operational conditions persist. Advanced imaging techniques like operando synchrotron X-ray tomography have provided insights into failure mechanisms, revealing that pore-filling and dendrite growth are significant issues. Understanding these processes is essential for enhancing the performance and safety of Na-based SSBs. Here, this study underscores the need for continued research to address these challenges and develop reliable, high-performance solid-state electrolytes for future energy storage solutions.

25 ENERGY STORAGE↗

DOE OSTI2024

Multinonmetal-Doped V 2 O 5 Nanocomposites for Lithium-Ion Battery Cathodes

Lithium-ion batteries (LIBs) are critical for portable electronics and electric vehicles, demanding higher energy density to meet increasing energy storage needs. Current commercial cathode materials, such as LiFePO 4 and LiCoO 2 , are limited by a single electron transfer, restricting their energy density. Vanadium pentoxide (V 2 O 5 ) emerges as a promising high-capacity cathode due to its high theoretical capacity of 443 mA h g –1 with three Li storage capacities, significantly surpassing conventional materials. However, the practical application of V 2 O 5 is hindered by a large structural evolution and rapid capacity fading during full lithium intercalation. Here, this study introduces a multinonmetal doping (MNM) strategy to enhance V 2 O 5 cathodes by incorporating all-nonmetal dopants (B, P, and Si) and graphene (G). MNM-V 2 O 5 -G exhibits increased surface oxygen defects, improving charge transfer kinetics and thus enhancing the rate performance and cycling stability. Our results provide valuable insights into the role of surface oxygen defects in stabilizing V 2 O 5 with element doping. This research highlights the potential of multinonmetal doping to improve LIB cathode materials, offering a promising pathway for design of high-energy-density V 2 O 5 cathodes and advancing the development of next-generation energy storage solutions.

25 ENERGY STORAGE↗

NASA NTRS1988

Overview of a flywheel stack energy storage system

The concept of storing electrical energy in rotating flywheels provides an attractive substitute to batteries. To realize these advantages the critical technologies of rotor design, composite materials, magnetic suspension, and high efficiency motor/generators are reviewed in this paper. The magnetically suspended flywheel energy storage system, currently under development at the University of Maryland, consisting of a family of interference assembled rings, is presented as an integrated solution for energy storage.

Kirk, James A.↗

DOE OSTI2026

DEMO-FTES: Development, Monitoring, and Control of Fracture Thermal Energy Storage in Crystalline Rock Formations (CRADA Final Report)

The DEMO-FTES project investigated the feasibility of Fracture Thermal Energy Storage (FTES) as a seasonal energy storage solution in crystalline rock formations. FTES leverages hydraulically induced fractures to exchange heat between circulating fluids and the surrounding rock mass, enabling long-term thermal energy retention due to the high specific heat and low thermal conductivity of rock. This approach has the potential to reduce heating and cooling energy demands and enhance building energy resilience. The project combined dimensional analysis, numerical modeling, laboratory experiments, and meso-scale field tests to evaluate FTES performance and advance its technology readiness level from 3 to 5. Scaling analysis identified key dimensionless parameters governing heat transfer and fluid flow, ensuring laboratory and field tests were representative of larger-scale systems. Numerical simulations using TOUGH and iTOUGH2 frameworks supported experiment design and interpretation, modeling fracture geometry, thermal-hydraulic behavior, and thermo-mechanical coupling. Laboratory tests at EPFL involved creating single and multiple fractures in 25 cm cubic samples of Gabbro and Granite under true triaxial stress.

25 ENERGY STORAGE↗