Epitaxial growth of gallium arsenide with ammonium halides as transporting agents
Epitaxial growth of gallium arsenide with ammonium halides as transporting agents
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Epitaxial growth of gallium arsenide with ammonium halides as transporting agents
G-factors of F centers in alkali halide crystals determined by electron spin resonance measurements
Mean oscillation amplitudes, thermodynamic functions and molecular polarizabilities of mixed phosphorus halides
Feasibility of producing dispersion strengthened chromium by ball milling in hydrogen halides
Boron 11 nuclear quadrupole coupling constants in solid boron halides, finding fine structure on nuclear magnetic resonance in boron fluoride
Electron spin memory in optical pumping cycle of potassium halides F centers, measuring relaxed excited state g factors and spin resonance line widths
Electrolytic conductivity of aqueous solutions of sodium halides
Temperature effects on photoemissions from silver halides
Hydrogen halide cleaning of nickel 20 chromium containing dispersed thoria
External optical phonon modes in ammonium and deuteroammonium halides phase transitions as function of temperature, using IR and Raman spectra
Examining photoemission from silver halides from room to liquid nitrogen temperatures to determine electron energy states
Anomalous temperature dependent silver halides photoemission related to lattice vibrationally dependent hybridization of valence states
A method of detecting radiation damage tracks due to heavy particles in large single crystals of the silver halides is described. The tracks, when made visible with a simple electrical apparatus, appear similar to tracks in emulsions. The properties of the crystals, the technique of printing out the tracks, and evidence concerning the threshold energy for registering particles indicates that this method may find application in heavy ion dosimetry. The method has been found to be sensitive to stopping He nuclei and relativistic M group cosmic rays. Some impurities strongly influence the printout of the tracks, and the effects of these impurities are discussed.
The gas phase transitions of the mercuric halides were observed in the UV region by operating at temperatures above 400 K and at vapor pressures on the order of 0.5 mm. Spectral features exhibited by the chloride, bromide, and iodide of mercury correlate energetically with bands previously designated as intermolecular charge transfer transitions. The solution spectra of mercuric iodide and deep color of the crystals (if not due to some solid state interactions) indicate that this molecule may also have longer wavelength transitions.
Raman scattering data on ammonium halides in 1 and 2 disordered phases are reported. The effects of disorder and that of short range ordering is discussed in terms of group theoretical arguments.
After measuring ultrasonic velocity and density, the molecular compressibility values from Wada's formula were calculated, for alkali metal halide solutions in methyl, ethyl, butyl, and glycol alcohol. The temperature and concentration dependence were studied, finding deviations due to the hydrogen bonds of the solvent.
An EPR study of electron bombarded LiF, NaCl, KCl, CaF2 and BaF2 polycrystalline surfaces has shown that small metal particles are formed on the surfaces of the crystals. Identification was made from CESR signals. The symmetric line-shape of the signals, even at 77 K, indicated that the particles were less than 0.5 micron in diameter. Signals due to F centers were observed in LiF but not in the other halides. Implications to metal deposition are considered.
The feasibility of using alkali metal-silicon halide diffusion flames to produce solar-grade silicon in large quantities and at low cost is demonstrated. Prior work shows that these flames are stable and that relatively high purity silicon can be produced using Na + SiCl4 flames. Silicon of similar purity is obtained from Na + SiF4 flames although yields are lower and product separation and collection are less thermochemically favored. Continuous separation of silicon from the byproduct alkali salt was demonstrated in a heated graphite reactor. The process was scaled up to reduce heat losses and to produce larger samples of silicon. Reagent delivery systems, scaled by a factor of 25, were built and operated at a production rate of 0.5 kg Si/h. Very rapid reactor heating rates are observed with wall temperatures reaching greater than 2000 K. Heat release parameters were measured using a cooled stainless steel reactor tube. A new reactor was designed.