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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

The Role of H I in Regulating the Size Growth of Local Galaxies

We study the role of atomic hydrogen (H I ) in regulating the size growth of local galaxies. The size of a galaxy, $D$ $r$,25 , is characterized by the diameter at which the r-band surface brightness reaches ${\mu }_{{\rm{r}}}=25.0\,\mathrm{mag}\,{\mathrm{arcsec}}^{-2}$. We find that the positions of galaxies in the size ($D$ $r$,25 )-stellar-mass ($M$*) plane strongly depend on their H I -to-stellar-mass ratio ($M$ H I /$M$*). In the H I -rich regime, galaxies that are richer in H I tend to have larger sizes. Such a trend is not seen in the H I –poor regime, suggesting that size growth is barely affected by the H I content when it has decreased to a sufficiently low level. An investigation of the relations between size, $M$ H I /$M$*, and star formation rate (SFR) suggests that size is more intrinsically linked with $M$ H I /$M$*, rather than SFR. We further examine the H i-to-stellar-disk size ratio ($D$ H I /$D$ $r$,25 ) of galaxies and find that at log($M$ H I /$M$*) > -0.7, $D$ H I /$D$ $r$,25 is weakly correlated with $M$*. These findings support a picture in which the H I -rich galaxies live in an inside-out disk-growing phase regulated by gas accretion and star formation. In conclusion, the angular momentum of the accreted materials is probably the key parameter in shaping the size of a H I -rich galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗

H2@Airports (Workshop Summary Report)

This report serves as the proceedings of the H2@Airports Workshop held virtually by the U.S. Department of Energy (DOE) in collaboration with the U.S. Department of Transportation (DOT) and Department of Defense (DOD), November 4-6, 2020. Presentations from the workshop can be found at H2@Airports Workshop: https://www.energy.gov/eere/fuelcells/h2airports-workshop. The workshop was held to assess the state of the art for electric aircraft and airport applications specifically using hydrogen fuel cells, to discuss operational requirements and lessons learned on early fuel cell aviation and airport projects, to understand current technology gaps, to identify collaborative research and development (R&D) opportunities, to highlight codes, standards, safety, and regulatory challenges, and to identify potential actions that address them. Experts and stakeholders from industry, government, and academia met to discuss the current state of the art of hydrogen and fuel cell technologies and the requirements for using these technologies in aviation applications and land-based applications at airports. This report summarizes the discussions and diverse opinions expressed at the workshop.

08 HYDROGEN↗

Persistent Hot-Spot Mix in Cryogenic Direct-Drive Fusion Experiments

We show that an x-ray emission signature associated with acceleration phase mass injection correlates with poor experimental hot-spot convergence and a reduced neutron production relative to expectations. It is shown that with increased target mass as well as with higher-design adiabats, this signature is reduced, whereas with increased debris on the target the signature is increased. Here, we estimate that the vapor region in typical best designs may have up to 2x the assumed hydrogen mass at the start of deceleration.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Damage of thermal control coating properties by energetic mercury ion bombardment.

The thermophysical properties (absorptance and emittance) of five commonly used spacecraft thermal control coatings have been measured in situ after exposure to 1.5 and 3 KeV mercury ions. Sample temperature was varied from 20 to 150 C. The results showed negligible change in emittance but significant degradation of the solar absorptance at fluences of 10 to the 17th power ions/sq cm. Plots of absorptance as a function of ion fluence are presented, along with pre- and post-exposure ex situ spectral absorptance measurements. The widely used Z93 white paint exhibited quantitative degradation from mercury ions similar to that reported by other experimenters for hydrogen and helium ions.

Kelley, L. R.↗

Absorption cross sections of stratospheric molecules

Two classes of molecular species must be considered in a calculation of photochemical rates in the stratosphere. The first class consists of molecular oxygen and ozone, while the second class contains the remainder of the minor constituents. If accurate values of the transmitted fluxes are required at large optical depths, the cross sections for molecular oxygen and ozone must be known to within a few per cent at least. On the other hand, the photochemical rates for the minor species are given simply by the relevant cross sections. A review of published cross sections is presented, giving attention to molecular oxygen, ozone, nitric oxide, nitrogen dioxide, nitrous oxide, nitric acid, ammonia, water vapor, hydrogen peroxide, carbon monoxide, carbon dioxide, and sulfur dioxide.

Hudson, R. D.↗

Development of a Microwave Regenerative Sorbent-Based Hydrogen Purifier

This paper describes the design and fabrication of a Microwave Regenerative Sorbent-based Hydrogen Purifier (MRSHP). This unique microwave powered technology was developed for the purification of a hydrogen stream produced by the Plasma Pyrolysis Assembly (PPA). The PPA is a hydrogen recovery (from methane) post processor for NASA's Sabatier-based carbon dioxide reduction process. Embodied in the Carbon dioxide Reduction Assembly (CRA), currently aboard the International Space Station (ISS), the Sabatier reaction employs hydrogen to catalytically recover oxygen, in the form of water, from respiratory carbon dioxide produced by the crew. This same approach is base-lined for future service in the Air Revitalization system on extended missions into deep space where resupply is not practical. Accordingly, manned exploration to Mars may only become feasible with further closure of the air loop as afforded by the greater hydrogen recovery permitted by the PPA with subsequent hydrogen purification. By utilizing the well-known high sorbate loading capacity of molecular sieve 13x, coupled with microwave dielectric heating phenomenon, MRSHP technology is employed as a regenerative filter for a contaminated hydrogen gas stream. By design, freshly regenerated molecular sieve 13x contained in the MRSHP will remove contaminants from the effluent of a 1-CM scale PPA for several hours prior to breakthrough. By reversing flow and pulling a relative vacuum the MRSHP prototype then uses 2.45 GHz microwave power, applied through a novel coaxial antenna array, to rapidly heat the sorbent bed and drive off the contaminants in a short duration vacuum/thermal contaminant desorption step. Finally, following rapid cooling via room temperature cold plates, the MRSHP is again ready to serve as a hydrogen filter.

Wheeler, Richard R., Jr.↗

Understanding Hydrogenation Chemistry at MgB 2 Reactive Edges from Ab Initio Molecular Dynamics

Solid-state hydrogen storage materials often operate via transient, multistep chemical reactions at complex interfaces that are difficult to capture. Here, we use direct ab initio molecular dynamics simulations at accelerated temperatures and hydrogen pressures to probe the hydrogenation chemistry of the candidate material MgB 2 without a priori assumption of reaction pathways. Focusing on highly reactive ($10\overline{1}0$) edge planes where initial hydrogen attack is likely to occur, we track mechanistic steps toward the formation of hydrogen-saturated BH 4 – units and key chemical intermediates, involving H 2 dissociation, generation of functionalities and molecular complexes containing BH 2 and BH 3 motifs, and B–B bond breaking. Further, the genesis of higher-order boron clustering is also observed. Different charge states and chemical environments at the B-rich and Mg-rich edge planes are found to produce different chemical pathways and preferred speciation, with implications for overall hydrogenation kinetics. The reaction processes rely on B–H bond polarization and fluctuations between ionic and covalent character, which are critically enabled by the presence of Mg 2+ cations in the nearby interphase region. Our results provide guidance for devising kinetic improvement strategies for MgB 2 -based hydrogen storage materials, while also providing a template for exploring chemical pathways in other solid-state energy storage reactions.

08 HYDROGEN↗

Energy Justice in Low-TRL Research

The Carbon-Negative Hydrogen Workshop, hosted by NREL in Golden, Colorado, focused on developing a shared understanding of the importance of and opportunities for generation and use of carbon-negative H2 in industrial decarbonization. Attendees helped define research needs, spot barriers to commercialization, and identify technical challenges, opportunities, and knowledge gaps for this emerging technology area. Workshop discussion themes included energy justice in early-stage research, R&D pathways for negative-emissions H2, biomass gasification to carbon-negative H2, and policy and carbon accounting considerations.

carbon-negative hydrogen↗