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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Cost effective data system design approach for EOS AM-1

The question of how to design a cost-effective data system for a space-based application with a high aggregate data rate is addressed. The steps used by the EOS AM-1 design team are defined. A summary of the design as of January 1993 is outlined. The AM-1 Science Data system is comprised of one subsystem that ingests, formats, and routes data - the Science Formatting Equipment (SFE), and another that records the data. Key interfaces are the interfaces to the high rate science instruments, the real-time transmitters, and the internal interface between the SFR and the Solid State Recorder. A cost-effective design approach for the AM-1 data system must take into account impacts on ground systems, data processing facilities, availability of data for real-time users, and future spacecraft designs.

Westmeyer, Paul A.↗
DOE OSTI2016

Effect of intermetallic compounds on the thermal conductivity of Ti-Cu composites

Ti films were deposited by magnetron sputtering on polycrystalline Cu substrates. The samples were annealed at different temperatures and characterized by x-ray diffraction for phase identification, scanning electron microscopy, and energy dispersive spectrometry for microstructure and composition and transient thermoreflectance for thermal conductivity and interface thermal conductance. The results showed that the diffused layer of Ti in Cu contained intermetallic compounds and solid solution of Ti in Cu. The thermal conductivity of the diffused layer is reduced, and the thickness increased for higher annealing temperature. The interface thermal conductance also decreased for higher temperature of annealing. A stable Cu{sub 4}Ti phase was formed after annealing at 725 °C with thermal conductivity of 10 W m{sup −1} K{sup −1}. The interface thermal conductance between the intermetallic compound and the solid solution of Ti in Cu also was reduced to 30 MW m{sup −2} K{sup −1}. The effective thermal resistance of the diffused layer and the interface was found to increase for higher annealing temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Quantitative Sum-Frequency Generation Vibrational Spectroscopy of Molecular Surfaces and Interfaces: Lineshape, Polarization and Orientation

Sum-frequency generation vibrational spectroscopy (SFG) can provide detailed information and understanding of molecular vibrational spectroscopy, orientational and conformational structure, and interactions of molecular surfaces and interfaces, through quantitative measurement and analysis. In this review, we present the current status and discuss the main developments on the measurement of intrinsic SFG spectral lineshape, formulations for polarization measurement and orientation analysis of the SFG-VS spectra. The main focus is to present a coherent formulation and discuss the main concepts or issues that can help to make SFG-VS a quantitative analytical and research tool in revealing the chemistry and physics of complex molecular surface and interface.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2014

Intrinsic Chirality and Prochirality at Air/R-(+)- and S-(-)-Limonene Interfaces: Spectral Signatures with Interference Chiral Sum-Frequency Generation Vibrational Spectroscopy

We report in this work detailed measurements on the chiral and achiral sum-frequency vibrational spectra in the C-H stretching vibration region (2800-3050cm-1) of the air/liquid interfaces of R-limonene and S-limonene, using the recently developed high-resolution broadband sum-frequency generation vibrational spectroscopy (HR-BB-SFG-VS). The achiral SFG spectra of R-limonene and S-limonene, as well as the equal amount (50/50) racemic mixture show that the enantiomers are with the same interfacial orientations. The interference chiral SFG spectra of the limonene enantiomers exhibit spectral signature from chiral response of the Cα-H stretching mode, and spectral signature from prochiral response of the CH2 asymmetric stretching mode, respectively. The chiral spectral feature of the Cα-H stretching mode changes sign from R-limonene to S-limonene, and disappears for the 50/50 racemic mixture. While the prochiral spectral feature of the CH2 asymmetric stretching mode is the same for R-limonene and S-limonene, and also surprisingly remains the same for the 50/50 racemic mixture. These results provided detail information in understanding the structure and chirality of molecular interfaces, and demonstrated the sensitivity and potential of SFG-VS as unique spectroscopic tool for chirality characterization and chiral recognition at the molecular interface.

Chirality↗
NASA NTRS1990

Multi-terabyte image storage and distribution for NASA's Hubble Space Telescope

The modular architecture, functionality, and key components of the Hubble Space Telescope Data Archive Distribution Service (DADS) are presented. DADS functions comprise archive management, catalog management, and user interface. The distributed modular architecture utilized is made up of four subsystems, including the archive, host, catalog, and the Science Operations ground System/DADS Interface Processor. All data generated by the HST are archived in DADS on 12-in. optical disks. DADS is a permanent archive with a data capacity of 30 terabytes that can be expanded to 68 terabytes. Supplementary information and stellar observations will be instantly accessible through DADS, which can collect and archive more than 3 gigabytes per day of image and support data over the lifetime of the HST. Electronic and physical media will be accessible through 140 network connections, with a catalogue to assist in data set selection.

Weller, H. W., Jr.↗
DOE OSTI2022

Formation of misfit dislocation arrays and helium nanochannels near copper surface assisted by high-temperature graphene deposition

Misfit dislocation arrays (MDAs) at semi-coherent heterogeneous interface have been demonstrated effectiveness to trap and then outgas helium (He) for alleviating void swelling in metals, but limited by atomic-level thin film deposition that is difficult to scale-up for industrial production. In this work, we proposed an innovative strategy that could generate semi-coherent homophase interfaces in a same grain by varying surface energy density assisted by high-temperature graphene (Gr) deposition. This strategy transforms strain energy and surface energy, two originally distinctive processes into successive processes, and demonstrates experimentally and theoretically by introducing {111} copper (Cu) in a {100} Cu grain. Subsequent He implantation and electrical resistivity measurement results suggest that high-density MDAs originated at this {111}/{100} interface could form stable He nanochannels near Cu surface with Gr assistance, manifesting by ultra-low increased ratio of the electrical resistivity (i.e. ~3800% of Cu vs. ~90% of Gr/Cu) after He implantation. Finally, the present findings may provide a new strategy for efficiently managing He and achieving surface protection of advanced metals, merely by depositing a super-rigid material on metal surface to greatly reduce surface energy density.

36 MATERIALS SCIENCE↗
DOE OSTI2023

The impact of feedstock size and composition on the hydrothermal growth of (U,Th)O 2

Bulk crystal growth of refractory oxides requires unique approaches, and the U x Th 1-x O 2 solid solution is no exception. Hydrothermal transport reactions of U 0.1 Th 0.9 O 2 onto ThO 2 seeds with feedstocks comprised of U 0.1 Th 0.9 O 2 or mixtures of UO 2 and ThO 2 with a nominal composition of U 0.1 Th 0.9 O 2 are investigated with µ-Raman spectroscopy and X-ray fluorescence. In each case, the trends in stoichiometry as a function of distance from the seed are analyzed and the deviations from the nominal stoichiometry discussed. When the feedstock is composed of mixed oxides, the particle surface area’s influence on the feedstock dissolution rate is the dominant factor and can produce U-rich stoichiometries as high as U 0.75 Th 0.25 O 2 . When composed solely of U 0.1 Th 0.9 O 2 , the total growth amount depends on the particle size, but the obtained stoichiometry is the product of differing solubilities. Although the U0.1Th0.9O 2 feedstock produces the most homogeneous growth, the ending growth of the smallest particle UO 2 /ThO 2 mixture yields the stoichiometry closest to U 0.1 Th 0.9 O 2 . How to obtain desired stoichiometries from mixtures by matching the particle size and solubilities is briefly discussed.

36 MATERIALS SCIENCE↗
NASA NTRS1992

An object-oriented approach for supporting both X and terminal interfaces

While the X Window System is clearly becoming the dominant user interface between display system, there is still a continuing need to support character cell terminal devices. For a user interface application which must support both, it is desirable to be able to use them to their fullest extent, as opposed to simply providing a character-based display within an X window. An object-oriented application framework is presented here which allows the full capabilities of each system to be used while minimizing and isolating the amount of device-dependent code. Every user interface application consists of two parts: the various components used to display information and accept user input, and the processing of the interaction between these components. Many user interfaces are built around a core set of components such as menus, text entry fields, and forms. For a given application, the interaction between these components is the same regardless of the display system in use. Our approach is to implement each component as an object, accessible via a single public interface. All of the code necesary to implement the component for the desired display system is completely encapsulated within the object. The application is then written as a collection of objects interacting in a device-independent manner with one another. If a display system provides additional capabilities, the application can be extended by adding objects (e.g. for image display in X). We are currently implementing StarView, the user interface to the HST science archive (STDADS) using this approach. StarView will be written in C++ and will use Vermont Views for the terminal interface and OSF/Motif for the X Window interface.

Johnson, J.↗
DOE OSTI2018

3D Self-Architectured Steam Electrode Enabled Efficient and Durable Hydrogen Production in a Proton-Conducting Solid Oxide Electrolysis Cell at Temperatures Lower Than 600 °C

Hydrogen production via water electrolysis using solid oxide electrolysis cells (SOECs) has attracted considerable attention because of its favorable thermodynamics and kinetics. It is considered as the most efficient and low-cost option for hydrogen production from renewable energies. By using proton-conducting electrolyte (H-SOECs), the operating temperature can be reduced from beyond 800 to 600 °C or even lower due to its higher conductivity and lower activation energy. Technical barriers associated with the conventional oxygen-ion conducting SOECs (O-SOECs), that is, hydrogen separation and electrode instability that is primarily due to the Ni oxidation at high steam concentration and delamination associated with oxygen evolution, can be remarkably mitigated. Here, a self-architectured ultraporous (SAUP) 3D steam electrode is developed for efficient H-SOECs below 600 °C. At 600 °C, the electrolysis current density reaches 2.02 A cm –2 at 1.6 V. Instead of fast degradation in most O-SOECs, performance enhancement is observed during electrolysis at an applied voltage of 1.6 V at 500 °C for over 75 h, attributed to the “bridging” effect originating from reorganization of the steam electrode. The H-SOEC with SAUP steam electrode demonstrates excellent performance, promising a new prospective for next-generation steam electrolysis at reduced temperatures.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Controlled Growth of Ceria Nanoarrays on Anatase Titania Powder: A Bottom-up Physical Picture

The leading edge of catalysis research motivates physical understanding of the growth of nanoscale oxide structures on different supporting oxide materials that are themselves also nanostructured. This research opens up for consideration a diverse range of facets on the support material, versus the single facet typically involved in wide-area growth of thin films. In this paper, we study the growth of ceria nanoarchitectures on practical anatase titania powders as a showcase inspired by recent experiments. Density functional theory (DFT)-based methods are employed to characterize and rationalize the broad array of low energy nanostructures that emerge. Using a bottom-up approach, we are able to identify and characterize the underlying mechanisms for the facet-dependent growth of various ceria motifs on anatase titania based on formation energy. These motifs include 0D clusters, 1D chains, 2D plates, and 3D nanoparticles. Finally, the ceria growth mode and morphology are determined by the interplay of several factors including the role of the common cation valence, the interface template effect for different facets of the anatase support, enhanced ionic binding for more compact ceria motifs, and the local structural flexibility of oxygen ions in bridging the interface between anatase and ceria structures.

36 MATERIALS SCIENCE↗
NASA NTRS2004

Virtual Mission Operation Framework (VMOF)

The Virtual Mission Operation Framework (VMOF) is one of the project lifecycle engineering process improvement efforts initiated by the institutional technology infrastructure program at JPL. The VMOF is composed of three frameworks: a model integration framework, a simulation framework, and a visualization framework. The model integration framework interfaces with spacecraft system design, mission design, and structure design. The simulation framework interfaces with the operation scenario design, environmental phenomena science, and science payload system design. The visualization framework interfaces with the flight system testbed, the ground system, and the science analysis. The three frameworks of the VMOF collaborate to create a comprehensive virtual mission operation that enables a "validation-in-the-loop" system design process and lifecycle-continuous science-return validation.This paper discusses the technical approaches for each framework implementation, challenges and approaches involved in streamlining mission information access, and on-going activities toward enabling Model-Based Engineering Design in a collaborative distributed environment.

virtual mission operations↗
DOE OSTI2011

Enhancement in Ethanol Electrooxidation by SnO(x) Nanoislands Grown on Pt(111): Effect of Oxide-Metal Interface Sites

An integrated surface science and electrochemistry approach has been used to prepare and characterize SnO{sub x}/Pt(111) model catalysts and evaluate their electrochemical activity for the ethanol oxidation reaction (EOR). Nanoislands of SnO{sub x} are deposited onto the Pt(111) by reactive layer assisted deposition in which Sn metal is vapor deposited onto a Pt(111) surface precovered by NO{sub 2}. X-ray photoelectron spectroscopy (XPS) shows that the SnO{sub x} islands are highly reduced with Sn{sup 2+} being the dominant chemical species. After exposing the SnO{sub x}/Pt(111) surface to H{sub 2}O or an electrolyte solution, XPS provides evidence for a significant amount of H{sub 2}O/OH adsorbed on the reduced SnO{sub x} surfaces. Electrochemical testing reveals that the catalytic performance of Pt(111) toward ethanol electrooxidation is significantly enhanced with SnO{sub x} islands added onto the surface. The enhanced EOR activity is tentatively attributed to the efficient removal of CO{sub ads}-like poisoning species at Pt sites by oxygen-containing species that are readily formed on the SnO{sub x} nanoislands. Moreover, the strong dependence of the EOR activity on SnO{sub x} coverage provides experimental evidence for the importance of SnO{sub x}-Pt interface sites in the EOR.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2016

The Role of Interfacial Electronic Properties on Phonon Transport in Two-Dimensional MoS 2 on Metal Substrates

In this paper, we investigate the role of interfacial electronic properties on the phonon transport in two-dimensional MoS 2 adsorbed on metal substrates (Au and Sc) using first-principles density functional theory and the atomistic Green’s function method. Our study reveals that the different degree of orbital hybridization and electronic charge distribution between MoS 2 and metal substrates play a significant role in determining the overall phonon–phonon coupling and phonon transmission. The charge transfer caused by the adsorption of MoS 2 on Sc substrate can significantly weaken the Mo–S bond strength and change the phonon properties of MoS 2 , which result in a significant change in thermal boundary conductance (TBC) from one lattice-stacking configuration to another for same metallic substrate. In a lattice-stacking configuration of MoS 2 /Sc, weakening of the Mo–S bond strength due to charge redistribution results in decrease in the force constant between Mo and S atoms and substantial redistribution of phonon density of states to low-frequency region which affects overall phonon transmission leading to 60% decrease in TBC compared to another configuration of MoS 2 /Sc. Strong chemical coupling between MoS 2 and the Sc substrate leads to a significantly (~19 times) higher TBC than that of the weakly bound MoS 2 /Au system. Our findings demonstrate the inherent connection among the interfacial electronic structure, the phonon distribution, and TBC, which helps us understand the mechanism of phonon transport at the MoS 2 /metal interfaces. Finally, the results provide insights for the future design of MoS 2 -based electronics and a way of enhancing heat dissipation at the interfaces of MoS 2 -based nanoelectronic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Interfacial Engineering Enabled Novel Bi-Based Layered Oxide Supercells with Modulated Microstructures and Tunable Physical Properties

Two-dimensional layered materials hold great significance to fundamental scientific research and future nanoscale device applications. Besides the well-studied graphene and dichalcogenides, oxide-based layered materials are another family attracting significant research interests, for example, the Bi-based Bi 3 Fe 2 Mn 2 O 10-δ layered supercell (called BFMO322 SC) structure. BFMO322 SC is an excellent room-temperature multiferroic material, but its growth mechanism is unclear. In this work, Bi 2 Fe 1–x Mn x O 6 thin films with different Fe/Mn molar ratios were deposited on CeO 2 buffer layers by pulsed laser deposition. By varying the Fe/Mn molar ratios, it has been determined that Mn can favor the growth of Bi-based layered structures, while Fe cannot facilitate the growth. A series of novel layered supercell structures can be obtained by manipulating the growth kinetics at the substrate/film interface, as achieved by precisely controlling the growth conditions. More interestingly, the magnetization and optical band gap of the Bi-based layered structures can be tuned by varying the Fe/Mn molar ratios. This original work has demonstrated the power of interfacial engineering in enabling new Bi-based layered structures and thus is of great significance for the design of new layered structures with multifunctionalities.

36 MATERIALS SCIENCE↗
NASA NTRS1965

Working at the interface

Information transfer between space science and aerospace technology laboratories and industry

SPACE SCIENCE↗