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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

Theoretical studies of ionic and atomic impact phenomena

An absorbing sphere model based on the Landau-Zener method was developed for calculating the energy dependence of the total cross sections for the reaction A(+) + B(-) yields A star + B + Delta E, in which A or B may be atomic or molecular species. It was found that the cross sections were highly dependent on the electron detachment energy of B(-). The ionization total cross sections for Ne star (2p5 3s 3P) + Ar were calculated over a large energy range and compared with experiments.

Olson, R. E.↗
NASA NTRS1972

D autoionization states of He and ionic H

Positions of the lowest 1,3De autoionization states of He and H(-) below the n = 2 level of the He(+) and H were calculated variationally, using Feshbach's Q-operator formalism. The trial wave function is of the Hylleraas-type with appropriate angular momentum factors. The widths and the shifts of the states have also been calculated. The shifts are found to be positive for all the states calculated here. The results with 112 terms for most states are lower than any previously calculated. The calculated lowest autoionization states of the He and H(-) (relative to the ground states of He and H respectively) are 59.902 eV and 10.1185 eV, in good agreement with the observed values of 59.9 eV and 10.13 + or 0.015 eV.

Bhatia, A. K.↗
NASA NTRS1972

A theory of scattering from irregularities in a magneto-ionic medium.

Attempt to determine what effect the anisotropy of the background medium will have on the scattering of electromagnetic waves from ionospheric irregularities. A Green's function is used to solve the scattered power using a certain bistatic geometry. Since the medium is anisotropic, cross-mode scattering in addition to self-mode scattering is possible. Several examples are given.

Simonich, D. M.↗
NASA NTRS1973

Ultrafiltration by a compacted clay membrane. I - Oxygen and hydrogen isotopic fractionation. II - Sodium ion exclusion at various ionic strengths.

Laboratory experiments were carried out to determine the magnitude of the isotopic fractionation of distilled water and of 0.01N NaCl forced to flow at ambient temperature under a hydraulic pressure drop of 100 bars across a montmorillonite disk compacted to a porosity of 35% by a pressure of 330 bars. The ultrafiltrates in both experiments were depleted in D by 2.5% and in O-18 by 0.8% relative to the residual solution. No additional isotopic fractionation due to a salt-filtering mechanism was observed at NaCl concentrations up to 0.01N. Adsorption is most likely the principal mechanism which produces isotopic fractionation, but molecular diffusion may play a minor role. The results suggest that oxygen and hydrogen isotopic fractionation of ground water during passage through compacted clayey sediments should be a common occurrence, in accord with published interpretations of isotopic data from the Illinois and Alberta basins. It is shown how it is possible to proceed from the ion exchange capacity of clay minerals and, by means of the Donnan membrane equilibrium concept and the Teorell-Meyer-Siever theory, develop a theory to explain why and to what extent ultrafiltration occurs when solutions of known concentration are forced to flow through a clay membrane.

Coplen, T. B.↗
NASA NTRS1973

A study of selected radiation and propagation problems related to antennas and probes in magneto-ionic media

Research consisted of computations toward the solution of the problem of the current distribution on a cylindrical antenna in a magnetoplasma. The case of an antenna parallel to the applied magnetic field was investigated. A systematic method of asymptotic expansion was found which simplifies the solution in the general case by giving the field of a dipole even at relatively short range. Some useful properties of the dispersion surfaces in a lossy medium have also been found. A laboratory experiment was directed toward evaluating nonlinear effects, such as those due to power level, bias voltage and electron heating. The problem of reflection and transmission of waves in an electron heated plasma was treated theoretically. The profile inversion problem has been pursued. Some results are very encouraging, however, the general question of stability of the solution remains unsolved.

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NASA NTRS1974

Alkali oxide-tantalum oxide and alkali oxide-niobium oxide ionic conductors

A search was made for new cationic conducting phases in alkali-tantalate and niobate systems. The phase equilibrium diagrams were constructed for the six binary systems Nb2O5-LiNbO3, Nb2O5-NaNbO3, Nb2O5-KNbO3, Ta2O5-NaTaO3, Ta2O5-LiTaO3, and Ta2O5-KTaO3. Various other binary and ternary systems were also examined. Pellets of nineteen phases were evaluated (by the sponsoring agency) by dielectric loss measurements. Attempts were made to grow large crystals of eight different phases. The system Ta2O5-KTaO3 contains at least three phases which showed peaks in dielectric loss vs. temperature. All three contain structures related to the tungsten bronzes with alkali ions in non-stoichiometric crystallographic positions.

Roth, R. S.↗
NASA NTRS1978

The nuclear and ionic charge distribution particle experiments on the ISEE-1 and ISEE-C spacecraft

The ISEE-1 and ISEE-C instruments are designed to measure the elemental abundances, charge state composition, energy spectra, and angular distributions of energetic ions in the energy range 2 keV/charge to 80 MeV/nucleon and electrons between 75 and 1300 keV. The instrument consists of three sensor systems: (1) ULECA which is an electrostatic deflection system with rectangular solid-state detectors for the 3-560 keV/charge range; (2) ULEWATT which is a double dE/dX vs E thin-window flowthrough proportional counter/solid-state detector telescope for the 0.2-80 MeV/nucleon (Fe) range; and (3) ULEZEQ which is a combination of an electrostatic deflection analyzer and a thin-window dE/dX vs E system with thin-window proportional counter and position-sensitive solid-state detector. The applications of the instruments to solar and interplanetary phenomena and to magnetospheric acceleration and trapped particles are discussed.

Hovestadt, D.↗
NASA NTRS1979

Spectroscopy of the extreme ultraviolet dayglow at 6.5A resolution - Atomic and ionic emissions between 530 and 1240A

EUV spectra (530-1500A) of the day airglow in up, down and horizontal aspect orientations have been obtained with 6.5A resolution and a limiting sensitivity of 5R from a rocket experiment. Below 834A the spectrum is rich in previously unobserved OII transitions connecting with 4S(0), 2D(0), and 2P(0) states. Recent broad-band photometric observations of geocoronal HeI 584A emission in terms of the newly observed OII emissions are shown. The OI 989A and OI 1304A emissions exhibit similar dependence on altitude and viewing geometry with the OI 989A brightness 1/15 that of OI 1340. Emission at 1026A is identified as geocoronal HI Lyman beta rather than OI multiplet emission and observed intensities agree well with model estimates. An unexpectedly high NI 1200/NI 1134A brightness ratio is evidence of a significant contribution from photodissociative excitation of N2 to the NI 1200A source function.

Gentieu, E. P.↗
NASA NTRS1979

The solubility of olivine in basaltic liquids - An ionic model

A model is presented which enables the temperature at which olivine is in equilibrium with any alkali-depleted basaltic compound to be calculated to within + or - 30 C. It is noted that the error increases substantially when applied to terrestrial basalts which contain several weight percent alkalis. In addition the model predicts and quantifies the reduced activity of SiO4(4-) monomers due to increasing SiO2 concentrations in the melt. It is shown that the coordination of alumina in melts which precipitate olivine only appears to be dominantly octahedral, while titanium acts as a polmerizing agent by interconnecting previously isolated SiO4(4-) monomers. It is concluded that the model is sufficiently sensitive to show that there are small repulsive forces between Mg(2+) and calcium ions which are in association with normative diopside in the melt.

Herzberg, C. T.↗
NASA NTRS1979

In situ identification of various ionic species in Jupiter's magnetosphere

Continuing analysis of the Voyager 1 in situ measurements of the plasma (10-5,950 V) near Jupiter has revealed the existence of further atomic and molecular ions as minor constituents of the plasma. Ions with mass per charge values of 1, 8, 10-2/3, 16, 23, 32, 64, about 104, and about 160 were identified within 20 Jovian radii of Jupiter in the dayside magnetosphere. Wherever both protons and heavy ions were detected, the mass density was dominated by the heavy ions by a factor of about 100. The plasma ions moved with a common component of velocity which is not always the value expected geometrically from co-rotation. The ions with mass per charge values equal to or larger than 64 were probably molecular ions.

Sullivan, J. D.↗
NASA NTRS1979

Characterization and growth of epitaxial layers of Gs exhibiting high resistivity for ionic implantation

Either classical or low temperature epitaxial growth techniques can be used to control the deposition of buffer layers of GaAs on semiconducting substrates and to obtain the resistivity and purity desired. Techniques developed to study, as a function of thickness, the evolution of mobilities by photoHall, and the spectroscopy of shallow and deep centers by cathodoluminescence and current transients reveal one very pure layer of medium resistivity and high mobility, and another "dead layer" of elevated resistivity far from the surface. The highly resistive layer remains pure over several microns, which appears interesting for implantation.

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