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At least 199 records · Page 11
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NASA NTRS1981

Thermal iron ions in high speed solar wind streams. II - Temperatures and bulk velocities

Mitchel and Roelof (1980) reported the detection of iron in high speed solar wind flows using the small, but finite sensitivity of solid state detectors to Fe ions in the low energy (50-200 keV protons) L1 channel of the NOAA/JHU energetic particle experiment (EPE). In the current investigation, the EPE response is modeled to a convected Maxwellian to obtain the thermal velocity, flow angle, and bulk velocity of the iron distribution. It is assumed that the iron bulk flow velocity can be represented as a vector sum of the hydrogen bulk velocity and an interplanetary magnetic field (IMF) aligned velocity increment. It is found that the velocity increment is smaller than the local Alfven speed in magnitude, and that the iron thermal velocity is comparable with or greater than the proton thermal velocity, with the 'thermal' velocity defined as the square root of 2kT/m.

Mitchell, D. G.↗
NASA NTRS1981

Composition and origin of the unusual Oktibbeha County iron meteorite

Oktibbeha County, the most Ni-rich iron meteorite, has been analyzed for Ni, Co, Cu, Ga, Ge, As, Sb, Ir, and Au. Cu and Sb are higher than in any other iron, but other trace elements are within the ranges typically found in iron meteorites. Extrapolation of trace element trends in group IAB indicates that Oktibbeha County is a member of this group. This sheds light on the origin of groups IAB and IIICD, which are thought to be derived from impact melts on parent bodies of chondritic composition. Lafayette (iron), another sample reported in the literature to have a similarly high Ni content, is probably a pseudometeorite.

Kracher, A.↗
NASA NTRS1980

Silver isotopic anomalies in iron meteorites - Cosmic-ray production and other possible sources

Sources of excess Ag-107 observed in iron meteorites are investigated with emphasis on reactions of cosmic-ray particles with palladium. Cross sections for the production of the silver isotopes from palladium by energetic cosmic-ray particles are estimated to calculate spallogenic production rates relative to that of Mn-53 from iron. The upper limits for the production rates of Ag-107 and Ag-109 by energetic galactic cosmic-ray particles are 690 and 270 atoms/min/kg(Pd), respectively, and the maximum rate for making excess Ag-107 by spallation reactions is 400 atoms/min/kg(Pd). The excess Ag-107 cannot be produced by a long exposure to cosmic-ray particles, and because it is harder to make the amount of Pd-107 observed in the iron meteorites by an early intense proton irradiation than it is to make the Al-26 observed in other meteorites, it is concluded that the excess Ag-107 is due to the decay of nucleosynthetic Pd-107 in the iron meteorites.

Reedy, R. C.↗
NASA NTRS1983

The adsorption and thermal decomposition of tricresylphosphate (TCP) on iron and gold

Because tricresyl-phosphate (TCP) is a common antiwear additive in lubricants, there is great interest in its interactions with metal substrates. The TCP was allowed to adsorb on polycrystalline iron and gold at room temperature. X-ray photoelectron spectroscopy (XPS) was used to analyze the adsorbed species. The substrate was then heated in steps to 330 C, and the changes in the adsorbate were analyzed after each step. On both substrates saturation adsorption occurred at about one monolayer, but the sticking coefficient was less on gold than on iron. Comparison of the XPS spectra of TCP on each substrate with the spectrum from condensed TCP indicated nondissociative adsorption on gold, possibly by dipole-induced dipole interaction. On iron, there was apparently additional interaction between the substrate and the tolyl groups on the TCP molecule. TCP began to desorb molecularly from gold as soon as the gold was heated above room temperature. The desorption was complete by 200 C. However, when the iron substrate was heated, TCP did not desorb but decomposed between 150 and 250 C.

Wheeler, D. R.↗
NASA NTRS1982

Iron metal production in silicate melts through the direct reduction of Fe/II/ by Ti/III/, Cr/II/, and Eu/II/

The production of metallic iron in silicate melts by chemical reactions of Ti(3+), Cr(2+), and Eu(2+) with Fe(2+) is demonstrated under experimental conditions in a simplified basaltic liquid. These reactions form a basis for interpreting the role of isochemical valency exchange models in explanations for the reduced nature of lunar basalts. The redox couples are individually investigated in the silicate melt to ascertain reference redox ratios that are independent of mutual interactions. These studies also provide calibrations of spectral absorptions of the Fe(2+) and Ti(2+) species in these glasses. Subsequent spectrophotometric analyses of Fe(2+) and Ti(2+) in glasses doped with both iron and titanium and of Fe(2+) in glasses doped with either iron and chromium or iron and europium ascertain the degree of mutual interactions in these dual-doped glasses.

Schreiber, H. D.↗
NASA NTRS1982

Spectral characteristics of the iron oxides with application to the Martian bright region mineralogy

Reflectance spectra of eight polymorphs of FeOOH and Fe2O3 are determined in order to clarify the nature and significance of the iron oxide mineralogy on Mars. The effect of other components that might interfere with iron oxide absorption features is qualitatively constrained through the use of the Kebulka-Munk theory. It is found that the effect of temperature complicates the identification of a given Fe(3+) phase based on the position of the 6A1-4T1 absorption feature. While the Fe(3+) crystal field transitions are spin forbidden, most of the iron oxide polymorphs exhibit anomalously intense crystal field absorption features due to magnetic coupling between adjacent FeO6 octahedra. It is suggested that the resulting deviations from observed remotely sensed reflectance spectra of Mars may provide a basis for the exclusion of many iron oxide phases as significant components of the Martian Fe(3+) mineralogy. A comparison of these results with the visible region spectra of Martian bright regions indicates that the predominant Fe(3+)-bearing phase may be a magnetically disordered material, such as amorphous gels, some ferric sulphates, and other minerals in which Fe(3+) ions in the crystal structure are not magnetically coupled.

Sherman, D. M.↗
NASA NTRS1983

Experimental study of segregation in plane front solidification and its relevance to iron meteorite solidification

A directional solidification technique was developed and applied to the problem of fractional crystallization of an iron meteorite parent body. Samples of Fe-Ni alloys close to meteorite compositions and containing S, P, and C were made. The solidified structures contain secondary phases such as sulphides within the proeutectic single crystal austenite (taenite). As a result of these experiments, we propose that the secondary phases observed in iron meteorites were formed during primary solidification of austenite (taenite). The measured composition profiles of Ni, P and C in the alloys were used to explain the elemental distribution within a chemical group of iron meteorites. An analytical procedure was applied to determine the equilibrium distribution coefficients as a function of fraction solidified for Ni and P from the composition profiles. The distribution coefficients of Ni and P agree with previous values. These distribution coefficients are of particular interest in the determination of the elemental distributions in iron meteorites.

Sellamuthu, R.↗
NASA NTRS1984

The problem of iron partition between Earth and Moon during simultaneous formation as a double planet system

A planetary model is described which requires fractional vapor/liquid condensation, planet accumulation during condensation, a late start for accumulation of the Moon, and volatile accretion to the surfaces of each planet only near the end of the accumulation process. In the model, initial accumulation of small objects is helped if the agglomerating particles are somewhat sticky. Assuming that growth proceeds through this range, agglomeration continues. If the reservoir of vapor is being preferentially depleted in iron by fractional condensation, an iron-rich planetary core forms. As the temperature decreases, condensing material becomes progressively richer in silicates and poorer in iron, forming the silicate-rich mantle of an already differentiated Earth. A second center of agglomeration successfully forms near the growing Earth after most of the iron in the reservoir has been used up. The bulk composition of the Moon then is similar to the outer mantle of the accumulating Earth.

Cassidy, W. A.↗
NASA NTRS1984

Mossbauer spectroscopy and X-ray diffraction of samples from the Santa Catharina iron meteorite

Conversion electron Mossbauer spectroscopy (CEMS) of samples from the Santa Catharina iron meteorite shows the presence of the ordered iron-nickel phase with 50% Ni, tetrataenite, and of the paramagnetic iron-nickel phase with 25% Ni. The FeNi phase with 50% Ni amounts to 70% of the iron-nickel alloys. Futhermore, the CEM spectra show the presence of small peaks from one or more spinel compounds. These small peaks are more pronounced when regions near the rim of the samples are analyzed. The X-ray diffraction of different areas of the samples, both optically dark and optically light areas, shows the presence of a diffraction pattern from a single f.c.c. lattice with a lattice parameter of a=3.58A This means that the two different Fe-Ni phases seen in the CEMS analysis occupy the same lattice. The X-ray photographs also show the presence of super-structure reflections from the ordered FeNi phase, and that the orientation of the f.c.c. lattice is the same within the whole sample.

Roy-Poulsen, H.↗
NASA NTRS1985

Native iron in the continental lower crust - Petrological and geophysical implications

Lower crustal granulite xenoliths recovered from a kimberlite pipe in western Africa contain native iron (Fe) as a decomposition product of garnet and ilmenite. Magnetic measurements show that less than 0.1 percent (by volume) of iron metal is present. Data from geothermometry and oxygen geobarometry indicate that the oxide and metal phases equilibrated between iron-wuestite and magnetite-wuestite buffers, which may represent the oxidation state of the continental lower crust, and the depleted lithospheric upper mantle. Ferromagnetic native iron could be stable to a depth of about 95 kilometers and should be considered in the interpretation of long-wavelength static magnetic anomalies.

Haggerty, S. E.↗
NASA NTRS1986

Origin of life and iron-rich clays

The premise that life began with self-replicating iron-rich clays is explored. In association with these clays and UV light, polar organic molecules, such as oxalic acid, were synthesized. The carbonaceous chondrites have both iron-rich clays and organic molecules. It is convenient to classify meteoritic organic matter into 3 categories: insoluble polymer, hydrocarbons and polar organics (soluble in water). Recent work on the delta D, delta N-15 and delta C-13 has made it clear that these three fractions have been made by three different mechanisms. A significant fraction of the insoluble polymer has a delta-D which suggests that it was made in an interstellar medium. The hydrocarbons seem to have been made on a parent body by a Fischer-Tropsch mechanism. The polar organics were probably synthesized in a mixture of carbonate (NH4)2CO3, Fe(++) ion and liquid water by radiolysis. In a set of experiments the radiolysis of (NH4)2CO3 in the presence and absence of Fe(++) ion has been examined. The synthesis of glycine in the presence of Fe(++) ion is 3-4 times that in the absence of ferrous ion. The effects of the addition of hydrocarbons to this mixture are explored. Iron-rich clays at low temperature and pressure are synthesized. So far the results are not sufficiently crystalline to look for replication. It should be noted that organic chelating agents such as oxalic acid do increase the crystallinity of the clays but not sufficiently. The hydrothermal synthesis of iron-rich clays is being examined.

Hartman, H. H.↗
NASA NTRS1986

Antarctic iron meteorites: An unexpectedly high proportion of falls of unusual interest

The inhabited and explored areas of Earth have contributed 725 iron meteorites, accounting for 28% of the 2611 authenticated meteorites known of all types. Observed fall statistics give a much different view of relative abundance. The 42 historic iron meteorite falls spanning 230 years suggests a frequency of one fall per 5.6 years and represents only 4.9% of the total 853 known falls. Antarctic iron meteorite recoveries offer promise of providing a new perspective on the influx problem. At least 42 iron meteorite specimens were found during the last 25 years by various field teams working in Antarctica. Most of these specimens were not described in detail, but the available data indicates that 21 separate falls are represented, 50% of the number of recovered specimens. Twelve of the 21 falls were both structurally classified and placed into chemical groups. They are listed in order of increasing structural complexity and/or Ni content.

Clarke, R. S., Jr.↗
NASA NTRS1987

Seasonal cycling of sulfur and iron in porewaters of a Delaware salt marsh

An extensive pore water data set has been gathered in the Great Marsh, Delaware over various seasons, salinities, and tides. The data all point to a complimentary redox cycle for sulfur and iron which operates seasonally and tidally. Surface oxidizing conditions prevail in summer, with more reducing conditions at depth during the winter. During the spring tides which flood the marsh, pyrite oxidation occurs releasing excess dissolved iron (II) and sulfate to the porewaters, and precipitating authigenic solid iron phases. The redox conditions in the porewaters of the upper zone during the summer is poised between mildly oxidizing and mildly reducing conditions as shown by pE calculations. This redox environment and intermediate iron-sulfur redox species may be important for the stimulation of plant growth (photosynthesis) and sustenance of a viable microbial community (heterotrophy and chemoautropy).

Luther, George W., III↗
NASA NTRS1988

Bidirectional reflectance properties of iron-nickel meteorites

The effects of viewing geometry and small-scale (less than 1 mm) surface roughness on the bidirectional reflectance of iron-nickel meteorites were investigated by measuring the reflectance properties of Gibeon and Canyon Diablo iron-nickel meteorites. Several cut surfaces of each of these meteorites were polished with abrasive grits to controlled surface roughness, and a series of bidirectional reflectance spectra were taken at a variety of viewing geometries using NASA's RELAB facility. The measurements show that, for optically smooth surfaces, only the specular component of reflectance exhibited red-sloped continuum characteristic of iron. Spectra of surfaces that were much rougher than the wavelength of incident light exhibited iron's characteristic red sloped continuum and could be modeled by linear combinations of facets that are oriented in specular and nonspecular geometries with respect to the observer. Spectra of this latter type exhibit good agreement with the published spectra of M-type asteroids.

Britt, D. T.↗
NASA NTRS1989

Detailed non-LTE calculations of the iron emission from NGC 1068

The X-ray iron line emission from NGC 1068 observed by the Ginga satellite is modeled using the new multiline, multilevel, non-LTE radiative transport code ALTAIR and a detailed atomic model for Ne-like through stripped iron. The parameter space of the obscured type 1 Seyfert nucleus model for this object is studied. The equivalent width is greater than previously predicted. It is found that detailed radiative transfer can have a significant effect on the observed line flux both for the K alpha line and for the L-shell emission. The ionization of the iron increases with temperature. Therefore the K alpha equivalent width and energy is a function not only of the ionization parameter, but also of the column depth and temperature. For a likely model of NGC 1068 it is found that the iron abundance is about twice solar, but that modifications of this model may permit a smaller abundance.

Band, David L.↗
NASA NTRS1990

Iron K-shell emission from NGC 1068

The X-ray iron line emission from NGC 1068 is modeled using the new multiline, multilevel, non-LTE radiative transport code Altair and a detailed atomic model for Ne-like through-stripped iron. The X-rays passing through the ionized gas induce iron K-alpha line emission. The atomic model was constructed to describe in detail the K-shell ionization and K-alpha line emission, as well as to calculate the ionization state properly. A greater equivalent width than previously predicted is found because the observed K-alpha line is produced not only by fluorescence but also by line scattering of the continuum into the line of sight. The K-alpha equivalent width and energy are functions not only of the ionization parameter, but also of the column depth and temperature. For a likely model of NGC 1068, it is found that the iron abundance is about twice solar, but that modifications of this model may permit a smaller abundance.

Band, David L.↗
NASA NTRS1991

Iron availability, nitrate uptake, and exportable new production in the subarctic Pacific

This paper presents a critique of experimental data and papers by Martin et al. (1989, 1990), who suggested that the phytoplankton growth is iron-limited and that, small additions of iron to large subarctic ocean areas might be a way of removing significant amounts of atmospheric CO2 by increasing phytoplancton growth. Data are presented to show that, in the summer of 1987, the phytoplankton assemblage as a whole was not iron limited, as measured by the bulk removal of nitrate or by the increase of chlorophyll. It is suggested that grazing normally prevents the phytoplankton from reaching concentrations that reduce the iron (and nitrate) to levels that depress division rates drastically.

Banse, Karl↗
NASA NTRS1992

Reduction of iron-bearing lunar minerals for the production of oxygen

The kinetics and mechanism of the reduction of simulants of the iron-bearing lunar minerals olivine ((Fe,Mg)2SiO4), pyroxene ((Fe,Mg,Ca)SiO3), and ilmenite (FeTiO3) are investigated, extending previous work with ilmenite. Fayalite is reduced by H2 at 1070 K to 1480 K. A layer of mixed silica glass and iron forms around an unreacted core. Reaction kinetics are influenced by permeation of hydrogen through this layer and a reaction step involving dissociated hydrogen. Reaction mechanisms are independent of Mg content. Augite, hypersthene, and hedenbergite are reduced in H2 at the same temperatures. The products are iron metal and lower iron silicates mixed throughout the mineral. Activation energy rises with calcium content. Ilmenite and fayalite are reduced with carbon deposited on partially reduced minerals via the CO disproportionation reaction. Reduction with carbon is rapid, showing the carbothermal reduction of lunar minerals is possible.

Massieon, Charles↗