The chemical classification of iron meteorites. I.
Ge and Ga concentration in selected Fe meteorites used to determine quantization in terms of multiple parent body hypothesis and planetary fractionation processes
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Ge and Ga concentration in selected Fe meteorites used to determine quantization in terms of multiple parent body hypothesis and planetary fractionation processes
New neutron activation data on 10 elements in 12 IIE and IIE-related irons lead to a reclassification of several irons. Seymchan and Lonaconing are removed from IIE, and Leshan added. Four IIE members are designated IIE-An to call attention to some anomalous properties. The eight normal IIE members define element-Ni trends generally similar to those in the nonmagmatic group IAB; the small negative slopes on W-Ni and Ir-Ni diagrams are strongly indicative of a nonmagmatic origin of the IIE irons. It is proposed that IIE irons like IAB irons originated as individual pools of impact-produced melt in the near-surface region of a chondritic parent body. The positive As-Ni and Au-Ni trends are the only evidence suggesting fractional crystallization, but their slopes are lower than those in magmatic group IIIAB, and only slightly higher than those of Cu and Sb in IAB. It is suggested that the S and C contents of the IIE precursor materials were much lower than those of the IAB precursors, thus higher temperatures were required to generate enough metallic melt to segregate into pools. These higher temperatures are also reflected in the nonchondritic compositions of the silicate inclusions.
The Nedagolla meteorite was recognized by Axon to be a rare example of an iron which has been preterrestrially reheated to the point of melting. The dendrite secondary arms are spaced 200 microns apart, implying that Nedagolla solidified and cooled at about 0.02 C/sec. The presence of (Fe, Cr)(1-x)S inclusions precipitated during cooling in the interdendritic regions, and evidence of solute redistribution of Ni, Cr, Co, Si, and P are consistent with this cooling rate. Such a rate indicates that Nedagolla cooled very near the surface of its parent 'body'. Secondary microstructural features including the presence of isothermal taenite and minute phosphide precipitates, which have formed from the dissolution of primary phosphide material, indicate a later reheating to about 750 C for a period of several hours.
Using negative thermal ionization mass spectrometry, Re and Os abundances were determined by isotope dilution and Os-187/Os-186 measured in 11 ordinary chondrites, and also in 1 IIB and 3 IIIB irons. In addition, Os-186/Os-188 and Os-189/Os-188 ratios were precisely determined for 3 unspiked ordinary chondrites as a means of constraining the intensity of any neutron irradiation these meteorites may have experienced.
The diameter-frequency distribution of large asteroids is analyzed, based on polarimetric and radiometric albedo data. The population of carbonaceous objects shows a high degree of fragmentation. But a class of apparently stony-iron asteroids shows a relative excess frequency between diameters of 100 to 200 km. It is proposed that the latter objects are predominantly metallic cores of a group of chemically differentiated planetesimals all of which (except Vesta) have suffered catastrophic collisions. Collision frequencies in the asteroid belt may have been much greater than previously supposed.
Quantitative evidence is adduced by cooling rate calculations for the impact melting, on the surface of a parent body, of troilite and metallic Fe, Ni inclusions found on 12 ordinary chondrites rather than their formation at depth from an internally derived melt. In the case of the Shaw and Rose City breccias of unmelted and melted material, their melted metal need not have cooled through 1000 C within a few meters of the surface. Shock-melted, fine-grained, irregular intergrowths of metal and troilite form in situ in many irons and some chondrites by rapid solidification at cooling rates greater than 100,000 C/sec, so that their kamacite and taenite compositions may result from annealing of metallic glass or very fine quench products at about 250 C.
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X-ray diffraction investigation of cohenite from Canyon Diablo meteorites and Odessa shock standards to determine shock-induced alterations in crystal character
Microscopic and X-ray diffraction study of octahedrite shock history
Electron microprobe analysis of potassium feldspar in Weekeroo Station meteorite
Findings of a chondrule in an inclusion from the octahedrite Netschaevo reported by Bunch et al. (1970) are confirmed and the presence of additional chondrules in the meteorite is reported. The bulk chemical composition, mineralogy, and mineral chemistry indicate that the chondritic material has properties intermediate between those of the H-group chondrites and those of the enstatite chondrites.
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