Development of battery separator material process Quarterly report
Polyacrylic acid effect on grafted polyethylene film in electrical resistance and ion migration
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Polyacrylic acid effect on grafted polyethylene film in electrical resistance and ion migration
Significant accomplishments include development of a procedure to correct for the substantial differences of transistor delay time as measured with different instruments or with the same instrument at different frequencies; association of infrared response spectra of poor quality germanium gamma ray detectors with spectra of detectors fabricated from portions of a good crystal that had been degraded in known ways; and confirmation of the excellent quality and cosmetic appearance of ultrasonic bonds made with aluminum ribbon wire. Work is continuing on measurement of resistivity of semiconductor crystals; study of gold-doped silicon, development of the infrared response technique; evaluation of wire bonds and die attachment; and measurement of thermal properties of semiconductor devices, delay time and related carrier transport properties in junction devices, and noise properties of microwave diodes.
Ground based studies of two proposed experiments which were to be conducted aboard the Skylab Laboratory are reported; metals melting experiment, and sphere forming experiment. These studies were conducted with the objectives of clarifying the effects of gravity and optimizing the experiments within the constraints of existing hardware. All process phenomena were considered, with particular attention given to adhesion-cohesion studies with emphasis on the fluid dynamics of the molten metal. Detailed thermal histories were generated for three-dimensional specimen geometry including radiation, conduction and vaporization losses with allowances for variable properties. In addition quantitative techniques were used to establish the gravitational level (magnitude and direction) for KC-135 aircraft flights and the actual Skylab mission for both experiments.
A study program was conducted to clarify the role of gravity in the fluid mechanics of certain molten metal processes of potential significance to manufacturing in space. In particular, analyses were conducted of the M551 Metals Melting Experiment and the M553 Sphere Forming Experiment to be conducted in the M512 Facility onboard Skylab. The M551 experiment consisted of a study of electron beam welding of various metals, and the M553 experiment studied the formation of molten metal spheres by free-floating in a near zero-gravity environment. The analyses of these experiments and a comparison with ground-based and KC135 experimental results are presented.
Specimens of the aluminum-33 wt% copper eutectic partially melted and resolidified in the low effective gravity of the orbiting Skylab were examined and characterized with respect to microstructural defects and thermal conductivity values. The results obtained were compared with similar evaluations of ground-based simulation melt-resolidification experiments and as-prepared unidirectionally solidified specimens. Thermal conductivity data and electrical resistivity data at temperatures from 25 C to 400 C did not show significant differences between ground and space processed specimens. A methology of evaluating the defects in the Al-Al2Cu structure was implemented. A specimen from Skylab 3 showed signs of instability in growth and several grains were found in the ingot. The specimen from Skylab 4 did not show such marked instability in growth and was found to contain fewer defects than the ground-processed specimens. This agrees with data from Georgia Institute of Technology which showed that there were fewer defects in both their Skylab 3 and 4 specimens than in ground processed specimens.
A research program was conducted to study the solidification of metals in the form of small spheres both in the one gravity environment of the earth laboratory and the low gravity environment of KC-135 trajectory flights and the Skylab 1/2 mission. The program had three phases. The details of the results of this program are contained in interim reports prepared at the conclusion of each of the three phases. This final report is intended to summarize the efforts and results described in detail in each of these interim reports, with particular emphasis on the differences observed between the ground-based and Skylab flight specimens.
The metallographic characterization, analysis, and property measurement of ground samples for comparison with those processed on Skylab are described. Experiments on metals melting and exothermic brazing are summarized, and results are presented.
A study program was conducted to clarify the role of gravity in the fluid mechanics of certain molten metal processes of potential significance to manufacturing in space. In particular, analyses were conducted of the M551 Metals Melting Experiment and the M553 Sphere Forming Experiment to be conducted in the M512 Facility onboard Skylab. The M551 experiment consisted of a study of electron beam welding of various metals, and the M553 experiment studied the formation of molten metal spheres by free-floating in a near zero-gravity environment. The analyses of these experiments and a comparison with ground-based and KC135 experimental results are presented.
Conclusions of the team of specialists can be generalized as: (1) Brazing and welding of metal structures in an orbital near zero gravity condition are quite feasible. (2) Design of joints for fabrication in zero gravity will place less emphasis on the tolerances and proximity of the adjacent structures than on the quantity of liquid metal available. (3) Brazing of metallic joints has many advantages over electron beam welding for practical reasons: simplicity, launch weight, development costs, joint design tolerances, remotization, etc. (4) No evidence of different physical or mechanical properties of liquid metals in zero gravity was observed. However, many differences in liquid behavior were observed. Many of these effects have been called adhesion-cohesion phenomena.
Adhesion of the melted metals to the adjacent solid metals, and cohesion of the liquid metal to itself appeared to be equally as strong in zero gravity as on earth. Similar cut edge bead periodicity in cut thin plate, and similar periodic chevron patterns in full penetration welds were seen. The most significant practical result is that the design of braze joints for near zero gravity can be very tolerant of dimensional gaps in the joint. This conclusion is based on a comparison of narrow, wide and variable gap widths. Brazing is very practical as a joining or repairing technique for metal structures at zero gravity. The operation of the hardware developed to locate successive small (0.6 cm) diameter cylinders in the focus of the battery powered EB unit, melt the various metal specimens and deploy some liquid metal drops to drift in space, was generally successful. However, the sphericity and surface roughness were far from those of ball bearings.
Manufacturing processes which are expected to show drastic changes in a space environment due to the absence of earth gravity are classified according to (1) buoyancy and thermal convection sensitive processes and (2) processes where molecular forces like cohesion and adhesion remain as the relatively strongest and hence controlling factors. Some specific process demonstration experiments carried out during the Apollo 14 mission and in the Skylab program are described. These include chemical separation by electrophoresis, the M551 metals melting experiment, the M552 exothermic brazing experiment, the M553 sphere forming experiment, the M554 composite casting experiment, and the M555 gallium arsenide crystal growth experiment.
Nickel-tin (12 wt percent tin) samples were processed in the sphere forming experiment on Skylab 2. The results were characterized for sphericity, density, microhardness, porosity, surface morphology, segregation, chemical composition, Curie point, and crystallography. These results are discussed along with conclusions and recommendations.
Heat flow in a disc due to moving heat generated by electron beam was studied analytically. Computer programs based on the finite-element method were developed for the analysis of two and three dimensional mathematical models. The limited experimental data were compared with the analytical results, and factors which had influence on heat flow in the disc were studied. The computer programs were modified to consider the effects of metal melting and solidification as well as radiation. Temperature dependency of thermophysical properties was also considered.
Analytical and experimental studies made of heat flow in the exothermic brazing unit in the M552 experiment are described. The emphasis of the studies was placed on heat flow in the tube and the sleeve during a period from ignition to the time when the brazing alloy solidifies. Experiments were made of three specimens tested in a ground-based laboratory. Heat flow was determined by thermocouples. The analytical study covered two phases: (1) the effect of reduced gravity on heat flow in the exothermic brazing unit; and (2) the development of analytical models. The major mode of heat transfer was conduction and the effect of gravity was minimal. Good agreements were obtained between experimental and analytical results indicating the soundness of the analytical models.
The cost benefits and the feasibility of processing turbine blades, electrophoresis, and crystals in space were studied.
Space processing concepts investigated included an unmanned space factory, and a permanently launched factory. Product lines chosen for analysis were: (1) turbine blades, (2) tungsten targets for X-ray machines, (3) 1 sub G subclass separation by electrophoresis, and (4) high-price exotic crystals. The turbine blade, and 1 sub G products are considered promising candidates.
An Integrated Waste Management-Water System (WM-WS) which uses radioisotopes for thermal energy is described and results of its trial in a 4-man, 180 day simulated space mission are presented. It collects urine, feces, trash, and wash water in zero gravity, processes the wastes to a common evaporator, distills and catalytically purifies the water, and separates and incinerates the solid residues using little oxygen and no chemical additives or expendable filters. Technical details on all subsystems are given along with performance specifications. Data on recovered water and heat loss obtained in test trials are presented. The closed loop incinerator and other projects underway to increase system efficiency and capacity are discussed.
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