Multiscale Analysis of Material Variability in Polycrystalline Materials.
Abstract not provided.
Baines, Andrew James↗
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Open-Source Software for Material Accountancy Analysis
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Shoman, Nathan↗
Development of an immersion fiber optic Raman probe for real-time analysis of molten materials
This study presents an advancement in high-temperature Raman spectroscopy, specifically for analyzing molten materials. It introduces an approach by integrating a fiber-optic Raman probe with a copper block protection system designed to endure extreme thermal conditions. The copper block features an open port designed to accommodate an external telescope with a 3 cm focal length, enabling Raman spectra collection in challenging high-temperature environments. A built-in gas channel ensures a continuous flow of argon gas to prevent flux intrusion. The robust copper block acts as a reliable shield, safeguarding the fiber-optic Raman probe within molten materials. This enhancement maintains the probe's integrity and significantly improves its resilience, making it ideal for rigorous investigations of molten substances. This advancement is particularly relevant in metallurgy, where flux materials impact production quality and efficiency. The ability to acquire Raman signals under elevated thermal conditions offers opportunities for studying molecular dynamics, compositional changes, and chemical interactions within molten substances. This introduced direct immersion probing technique has implications, benefiting both scientific and industrial fields. It holds promise for advancing research and exploration in various contexts, from fundamental scientific inquiries to practical applications in metallurgical processes, where flux materials are critical for optimizing production quality and efficiency. Furthermore, this approach enhances the capabilities of high-temperature Raman spectroscopy, making it a valuable tool for investigating molten materials and their properties in diverse settings.
Argon↗
Accelerator Vacuum Windows: A Review of Past Research and a Strategy for the Development of a New Design for Improved Safety and Longevity for Particle Accelerators
Vacuum window research continues at Fermilab and this paper will examine cost effective, consistent designs which can have a huge impact on accelerator laboratories in terms of safety and cost. Issues such as the design, materials, analysis, testing and fabrication are addressed, including beam scattering plots and materials cost-benefit analysis and examining different materials which can potentially be substitutes for beryllium. A previous research paper has examined current fabrication and design techniques and also failure modes at Fermi, and this paper examines previous research in addition to emerging technologies. Many different paths have been taken by HEP Laboratories throughout the world with varying success. The history of vacuum window development is extensive and not well defined, and a matrix of what research has already been done on materials and joint design for vacuum windows will be shown. This report finally includes a treatise for vacuum window technology and a view towards emerging designs and materials and discusses future advances of research such as fabrication techniques including additive manufacturing and ultrasonic welding. Further exploration into these would prove beneficial to developing vacuum windows that are safer and stronger while being more transparent to the beam.
43 PARTICLE ACCELERATORS↗
Evaluating the pressure dependence of PZT structures using a virtual reality environment
Pb–Zr–Ti–O (PZT) perovskites span a large solid-solution range and have found widespread use due to their piezoelectric and ferroelectric properties that also span a large range. Crystal structure analysis via Rietveld refinement facilitates materials analysis via the extraction of the structural parameters. These parameters, often obtained as a function of an additional dimension (e.g., pressure), can help to diagnose materials response within a use environment. Often referred to as “ in-situ ” studies, these experiments provide an abundance of data. Viewing structural changes due to applied pressure conditions can give much-needed insight into materials performance. However, challenges exist for viewing/presenting results when the details are inherently three-dimensional (3D) in nature. For PZT perovskites, the use of polyhedra (e.g., Zr/Ti–O 6 octahedra) to view bonding/connectivity is beneficial; however, the visualization of the octahedra behavior with pressure dependence is less easily demonstrated due to the complexity of the added pressure dimension. We present a more intuitive visualization by projecting structural data into virtual reality (VR). We employ previously published structural data for Pb 0.99 (Zr 0.95 Ti 0.05 ) 0.98 Nb 0.02 O 3 as an exemplar for VR visualization of the PZT R3c crystal structure between ambient and 0.62 GPa pressure. This is accomplished via our in-house CAD2VR™ software platform and the new CrystalVR plugin. The use of the VR environment enables a more intuitive viewing experience, while enabling on-the-fly evaluation of crystal data, to form a detailed and comprehensive understanding of in-situ datasets. Discussion of methodology and tools for viewing are given, along with how recording results in video form can enable the viewing experience.
Rodriguez, Mark A. (ORCID:0000000269405044)↗
SOFIA: Spectrometer Optimized for Facility Integrated Applications
Los Alamos National Laboratory researchers developed the Spectrometer Optimized for Facility Integrated Applications (SOFIA) for new capabilities in non-destructive nuclear material analysis, nuclear data measurements, and actinide science. SOFIA is the first ultra-high resolution gamma spectrometer technology based on low-temperature microcalorimeter designs. By precisely measuring the gamma rays passively emitted from radioactive and nuclear materials, SOFIA provides rapid, completely nondestructive analysis to improve the economics and timeliness of nuclear material analysis by reducing reliance on costly sampling and destructive analysis. By developing the first compact instrument based on ultrahigh resolution microcalorimeter gamma spectroscopy, the researchers intended to bring this technology into practical use in nuclear facilities and analytical laboratories.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
FEAMAC/CARES Stochastic-Strength-Based Damage Simulation Tool for Ceramic Matrix Composites
Reported here is a coupling of two NASA developed codes: CARES (Ceramics Analysis and Reliability Evaluation of Structures) with the MAC/GMC (Micromechanics Analysis Code/ Generalized Method of Cells) composite material analysis code. The resulting code is called FEAMAC/CARES and is constructed as an Abaqus finite element analysis UMAT (user defined material). Here we describe the FEAMAC/CARES code and an example problem (taken from the open literature) of a laminated CMC in off-axis loading is shown. FEAMAC/CARES performs stochastic-strength-based damage simulation response of a CMC under multiaxial loading using elastic stiffness reduction of the failed elements.
composite structures↗
Stochastic-Strength-Based Damage Simulation Tool for Ceramic Matrix Composite
Reported here is a coupling of two NASA developed codes: CARES (Ceramics Analysis and Reliability Evaluation of Structures) with the MAC/GMC (Micromechanics Analysis Code/ Generalized Method of Cells) composite material analysis code. The resulting code is called FEAMAC/CARES and is constructed as an Abaqus finite element analysis UMAT (user defined material). Here we describe the FEAMAC/CARES code and an example problem (taken from the open literature) of a laminated CMC in off-axis loading is shown. FEAMAC/CARES performs stochastic-strength-based damage simulation response of a CMC under multiaxial loading using elastic stiffness reduction of the failed elements.
ceramic matrix composites↗
High-Activity Microscopic Nuclear-Sourced Particles to Investigate Nuclear Release Scenarios - 18026
Advances in microscopy and materials analysis have allowed for the study of materials at resolutions not previously attainable a decade ago. Such information extends to not only their existence, but also their composition, the likely source term and if applicable, their short or long-term environmental stability. This work describes the analysis undertaken on the larger 'ejecta' type of particulate collected following the INES Level 7 incident at the Fukushima Daiichi Nuclear Power Plant in March 2011. However, the methods and procedures employed during this work, on material with enormously contrasting characteristics, have far wider applications within nuclear forensics, safeguards, security and material compliance. Resulting from the analysis of micron-scale 'atmospheric' material in previous works have been able to derive information relating to the emission and subsequent transportation characteristics of the release event, as well as determining the local-scale impacts of this radioactive fallout. This analysis of the larger-scale (100's of micron) 'ejecta' material, collected from closer to the plant, has been able to reveal details pertaining to the specific in-reactor conditions at the time of the release as well as the nature of the explosion events. (authors)
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
Analysis of a used pair of arcjet electrodes
The anode and cathode of a 30-kW class arcjet engine have been sectioned and analyzed. This arcjet was operated for a total time of 573 hours at power levels between 25 and 30 kW with ammonia at flow rates of 0.25 and 0.27 gm/s. The accumulated run time was sufficient to clearly establish erosion patterns and their causes. The type of electron emission from various parts of the cathode surface was made clear by Scanning Electron Microscope analysis. A Scanning Electron Microscope was used to study recrystallization on the hot anode surface. These electrodes were made of 2 percent thoriated tungsten and the surface thorium content and gradient perpendicular to the surfaces was determined by quantitative microprobe analysis. The results of this material analysis on the electrodes and recommendations for improving electrode operational life time are presented.
Pivirotto, Thomas J.↗
Electrode erosion in steady-state electric propulsion engines
The anode and cathode of a 30 kW class arcjet engine were sectioned and analyzed. This arcjet was operated for a total time of 573 hr at power levels between 25 and 30 kW with ammonia at flow rates of 0.25 and 0.27 gm/s. The accumulated run time was sufficient to clearly establish erosion patterns and their causes. The type of electron emission from various parts of the cathode surface was made clear by scanning electron microscope analysis. A scanning electron microscope was used to study recrystallization on the hot anode surface. These electrodes were made of 2 percent thoriated tungsten and the surface thorium content and gradient perpendicular to the surfaces was determined by quantitative microprobe analysis. The results of this material analysis on the electrodes and recommendations for improving electrode operational life time are presented.
Pivirotto, Thomas J.↗
Analysis of bulk heterojunction material parameters using lateral device structures
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solar (photovoltaic), phonons, energy storage (inc↗
Strength of tantalum to 276 GPa determined by two x-ray diffraction techniques using diamond anvil cells
Tantalum (Ta) is a metal that has useful properties that make it useful in extreme environments. It is therefore important to understand how Ta performs in such extreme conditions by accurately measuring its properties. In this work, the yield strength of tantalum has been measured at pressures up to 276 GPa using axial and radial x-ray diffraction (XRD) methods in diamond anvil cells (DAC). We measured strength using XRD in a radial DAC to 50 GPa, in an axial DAC to 60 GPa using diamonds with standard flat culets, and in a final experiment to 276 GPa using toroidal diamond anvils. The radial XRD data were refined using the Material Analysis Using Diffraction (MAUD) Rietveld software package to extract lattice strain and the yield strength. The axial data were refined using the General Structure Analysis System (GSAS) II and a linewidth method was used to calculate the yield strength. The yield strength measured near ambient pressure was found to be 0.5 GPa and increased with pressure up to 50 GPa, where the yield strength plateaued at a value of 2.4 GPa. At pressures above 60 GPa, the strength increased again to a maximum value of 9 GPa at the highest pressure of 276 GPa. Here, the data from the three experiments show good agreement between the methods and previously reported experimental data. This agreement illustrates the value of axial diffraction data for material strength determination and allows for measurements at multihundreds of GPa using toroidal DACs.
36 MATERIALS SCIENCE↗
Structural analysis of bioceramic materials for denture application
Structural analysis has been performed on bioceramic materials for denture application by using X-ray diffraction (XRD), X-ray fluorescence (XRF), and Scanning Electron Microscopy (SEM). XRF is using for analysis chemical composition of raw materials. XRF shows the ratio 1 : 1 : 1 : 1 between feldspar, quartz, kaolin and eggshell, respectively, resulting composition CaO content of 56.78 %, which is similar with natural tooth. Sample preparation was carried out on temperature of 800 °C, 900 °C and 1000 °C. X-ray diffraction result showed that the structure is crystalline with trigonal crystal system for SiO{sub 2} (a=b=4.9134 Å and c=5.4051 Å) and CaH{sub 2}O{sub 2} (a=b=3.5925 Å and c=4.9082 Å). Based on the Scherrer’s equation showed the crystallite size of the highest peak (SiO{sub 2}) increase with increasing the temperature preparation. The highest hardness value (87 kg/mm{sup 2}) and match with the standards of dentin hardness. The surface structure was observed by using SEM also discussed.
36 MATERIALS SCIENCE↗
Application of the cubic polynomial strength criterion to the failure analysis of composite materials
A comparative failure analysis is presented based on the application of quadratic and cubic forms of the tensor polynomial lamina strength criterion to various composite structural configurations in a plane stress state. Failure loads have been predicted for off-angle laminates under simple loading conditions and for symmetric-balanced laminates subject to varying degrees of biaxial tension, including configurations subject to multimode failures. Some experimental data are also provided to support these calculations. From these results, the necessity of employing a cubic strength criterion to accurately predict the failure of composite laminae is demonstrated.
Tennyson, R. C.↗
Analytical Chemistry Laboratory
The Analytical Chemistry and Material Development Group maintains a capability in chemical analysis, materials R&D failure analysis and contamination control. The uniquely qualified staff and facility support the needs of flight projects, science instrument development and various technical tasks, as well as Cal Tech.
chemical analysis↗
Thermal Analysis and Testing of Candidate Materials for PAIDAE Inflatable Aeroshell
The Program to Advance Inflatable-Decelerators for Atmospheric Entry (PAIDAE) is a NASA project tasked with developing and evaluating viable inflatable-decelerator aeroshell geometries and materials. Thermal analysis of material layups supporting an inflatable aeroshell was completed in order to identify expected material response, failure times, and to establish an experimental test matrix to keep barrier layer materials from reaching critical temperature limits during thermal soak. Material layups were then tested in the 8- foot High Temperature Tunnel (8'HTT), where they were subjected to hypersonic aerothermal heating conditions, similar to those expected for a Mars entry. This paper presents a broad overview of the thermal analysis supporting multiple materials, and layup configurations tested in the 8'HTT at flight conditions similar to those that would be experienced during Mars entry trajectories. Direct comparison of TPS samples tested in the 8'HTT verify that the thermal model accurately predicted temperature profiles when there are up to four materials in the test layup. As the number of material layers in each test layup increase (greater than 4), the accuracy of the prediction decreases significantly. The inaccuracy of the model predictions for layups with more than four material layers is believed to be a result of the contact resistance values used throughout the model being inaccurate. In addition, the harsh environment of the 8'HTT, including hot gas penetrating through the material layers, could also be a contributing factor.
DelCorso, Joseph A.↗
FEAMAC-CARES Software Coupling Development Effort for CMC Stochastic-Strength-Based Damage Simulation
Reported here is a coupling of two NASA developed codes: CARES (Ceramics Analysis and Reliability Evaluation of Structures) with the MACGMC composite material analysis code. The resulting code is called FEAMACCARES and is constructed as an Abaqus finite element analysis UMAT (user defined material). Here we describe the FEAMACCARES code and an example problem (taken from the open literature) of a laminated CMC in off-axis loading is shown. FEAMACCARES performs stochastic-strength-based damage simulation response of a CMC under multiaxial loading using elastic stiffness reduction of the failed elements.
Reliability↗