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At least 199 records · Page 11

Floating Node Method and Virtual Crack Closure Technique for Modeling Matrix Cracking-Delamination Migration

A novel approach is proposed for high-fidelity modeling of progressive damage and failure in composite materials that combines the Floating Node Method (FNM) and the Virtual Crack Closure Technique (VCCT) to represent multiple interacting failure mechanisms in a mesh-independent fashion. In this study, the approach is applied to the modeling of delamination migration in cross-ply tape laminates. Delamination, matrix cracking, and migration are all modeled using fracture mechanics based failure and migration criteria. The methodology proposed shows very good qualitative and quantitative agreement with experiments.

DeCarvalho, Nelson V.↗

Modeling Quasi-Static and Fatigue-Driven Delamination Migration

An approach was proposed and assessed for the high-fidelity modeling of progressive damage and failure in composite materials. It combines the Floating Node Method (FNM) and the Virtual Crack Closure Technique (VCCT) to represent multiple interacting failure mechanisms in a mesh-independent fashion. Delamination, matrix cracking, and migration were captured failure and migration criteria based on fracture mechanics. Quasi-static and fatigue loading were modeled within the same overall framework. The methodology proposed was illustrated by simulating the delamination migration test, showing good agreement with the available experimental data.

De Carvalho, N. V.↗

Hypervelocity Impact Study for Migration from Kevlar® KM2® 705 to KM2® Plus 775: Material Property Measurement and Evaluation as a Ballistic Enhancement in Whipple Shields

Dupont™, the manufacturer of Kevlar®, has begun migrating from KM2® to KM2® Plus for ballistic textiles. Kevlar® KM2® has become an essential element of numerous meteoroid and orbital debris (MMOD) shield systems primarily as a multi-layer insulation (MLI) enhancement, and as such, the migration has implications for numerous system level risk assessments for future vehicles that will need to use the newer KM2® Plus fiber system. While the chemical makeup of the two fabrics are identical, differences in processing have yielded higher tenacities and toughness for the KM2® Plus system. To address this migration, the Hypervelocity Impact Technology (HVIT) group in NASA Exploration Sciences at Johnson Space Center (JSC) has worked with the NASA Engineering and Safety Center (NESC), the Multi-Purpose Crew Vehicle (MPCV) and the MPCV European Service Module (MPCV-ESM) group of the European Space Agency (ESA) with its contractors Airbus and Thales Alenia Space-Italy (TAS-I) to study how KM2® Plus in the woven form of 850 denier 775 compares with KM2® in the woven form of 850 denier 705. The two forms of Kevlar® fabrics have been compared by direct-impact with a known mass and as the rear wall in Whipple shields using the two-stage, light-gas-gun at the Remote Hypervelocity Test Laboratory (RHTL) of NASA JSC White Sands Test Facility (WSTF). From these examinations, it has been found that KM2® Plus does in fact improve the ballistic performance as a ballistic enhancement of MLI with an estimated improvement of 9.5±6.1% between the two fabrics, and on a mass basis, the estimated mass of KM2® Plus 775 is 3.6±0.7% lighter than KM2 705, which means the mass performance improvement is even higher.

Joshua E Miller↗

Least Squares Reverse Time Migration (LSRTM) for Damage Imaging in Composite Laminates

A method for adapting least squares reverse time migration (LSRTM) for ultrasonic guided wave imaging of composite laminates is proposed in this paper. As composites become more widely used in fields such as the aerospace industry, the need for high-resolution imaging in structural health monitoring (SHM) and nondestructive evaluation (NDE) is also growing. For instance, delamination is a common problem in composite laminates, which has led to a certain degree of apprehension in the use of composite materials for load-bearing structures. Although the solver-based imaging techniques using conventional reverse time migration (RTM) methods illuminate damage with a wide range of damage-scattering effects, the resulting images do not fully define the damage regions due to the limited data acquisition aperture, sensor density, frequencies/wavelengths, and incompleteness of adjoint reconstruction. Previously, the LSRTM theory was derived by incorporating a least squares migration (LSM) algorithm into RTM, and benchmarked its high-resolution damage imaging performance for isotropic plates. To improve damage imaging in composite laminates, a process to create an ultrasonic guided wave-based LSRTM method for anisotropic materials is proposed in this paper. The derivation of the forward modeling operator and the adjoint operator is presented. Numerical case studies were conducted to show the improvement of LSRTM over RTM in mapping damage in composite plates. Multiple damage sites or damage with a complex shape were created in the numerical studies based on 1) Born approximation-based modeling or 2) reduction of the plate stiffness-based modeling. LSRTM begins by using a forward modeling process. The forward modeling accuracy for the flexural wave solver used in this study for LSRTM was also compared with the results from a three-dimensional rotated staggered grid (RSG) elastodynamic finite difference solver, previously open-sourced by NASA Langley Research Center. These benchmarking studies have shown that the LSRTM method is more effective in reducing artifacts, improving resolution, and enhancing damage model reconstruction compared to RTM in composite laminates.

Jiaze He↗

LAADS DAAC Migrates to the Cloud: Lessons Learned from Communicating About Earth Science Data on the Cloud

The Level-1 and Atmosphere Archive Distribution System (LAADS) Distributed Active Archive Center (DAAC) is migrating data to the cloud. As one of twelve DAACS supported by NASA’s Earth Science Data and Information System (ESDIS), LAADS is using moving away from on premise data storage facilities to migrating to Amazon Web Services, where the massive archive of data from the Moderate Imaging Spectroradiometer (MODIS) and the Visible Infrared Imaging Radiometer Suite (VIIRS) will be available for download and post-processing transformations online. The migration is happening in three phases and LAADS is concluding its beta testing period. This poster shows the lessons learned from communicating with a select group of users about how to effectively educate data users on using data in the cloud.

Tassia Owen↗

Determining the extent of potential fugitive fluid migration from geologic carbon storage in hydrocarbon-bearing reservoirs: Insights from one-dimensional numerical modeling

Numerical modeling of Geologic Carbon Sequestration in permeable reservoirs initially containing hydrocarbons is conducted using the multi-phase, multi-component thermohydrologic simulator TOGA (TOUGH Oil, Gas, Aqueous; TOUGH stands for Transport Of Unsaturated Groundwater and Heat), to determine how phase and composition of the original fluids influence the extent of the zone where upward fugitive fluid migration could potentially occur, denoted R f . The area within R f comprises regions of substantially elevated pressure and free-phase CO 2 saturation, where a breach in reservoir sealing capacity would lead to upward fugitive fluid migration. The model examines the conditions within the storage reservoir that could lead to fugitive flow, but does not model the fugitive flow itself. A one-dimensional radial model of the storage reservoir is used, and three initial phase conditions are considered: single-phase aqueous, two-phase gas-aqueous, and three-phase oil-gas-aqueous. Components that may be present are H 2 O, CO 2 , CH 4 , C 4 H 10 , and C 10 H 22 . The most important factors controlling Rf are (1) the initial gas-phase saturation within the reservoir, and (2) the lateral extent of multi-phase initial conditions, particularly CO 2 . The composition of liquid and gas phases has a secondary effect. The impact of reservoir depth, thickness, injection rate, and hydrologic properties are also briefly examined, with thickness (or equivalently injection rate) having the biggest effect. These results can help to understand important trends in potential response of CO 2 -EOR fields being considered for dedicated CO 2 storage.

CO₂ plume migration↗

Azobenzene-based sinusoidal surface topography drives focal adhesion confinement and guides collective migration of epithelial cells

Surface topography is a key parameter in regulating the morphology and behavior of single cells. At multicellular level, coordinated cell displacements drive many biological events such as embryonic morphogenesis. However, the effect of surface topography on collective migration of epithelium has not been studied in detail. Mastering the connection between surface features and collective cellular behaviour is highly important for novel approaches in tissue engineering and repair. Herein, we used photopatterned microtopographies on azobenzene-containing materials and showed that smooth topographical cues with proper period and orientation can efficiently orchestrate cell alignment in growing epithelium. Furthermore, the experimental system allowed us to investigate how the orientation of the topographical features can alter the speed of wound closure in vitro. Our findings indicate that the extracellular microenvironment topography coordinates their focal adhesion distribution and alignment. These topographic cues are able to guide the collective migration of multicellular systems, even when cell–cell junctions are disrupted.

59 BASIC BIOLOGICAL SCIENCES↗

Vector elastic deconvolution migration with dual wavefield decomposition

Here, we report elastic-wave imaging using multicomponent data can provide more useful subsurface information than acoustic-wave imaging, but it is usually algorithmically challenging. We have developed a vector elastic deconvolution migration method for high-resolution imaging of subsurface structures in isotropic and anisotropic elastic media. Our new method uses a vector deconvolution imaging condition based on dual wavefield decomposition, including an explicit directional wavefield separation using the Hilbert transform and a P/S vector wavefield decomposition using the low-rank decomposition method. Using three elastic models, we numerically determine that our new method produces notably higher resolution and more amplitude-balanced elastic images compared with a crosscorrelation-based vector elastic reverse time migration method.

58 GEOSCIENCES↗

Irradiation induced void spheroidization, shrinkage and migration in Cu at elevated temperatures: An in situ study

We show understanding the void evolution in irradiation environment is of great interest and significance, as irradiation-induced voids typically lead to pronounced volumetric swelling and degradation of mechanical properties. In situ studies on the irradiation response of nanovoids at elevated temperature remain limited. In this work, we performed systematic in situ 1 MeV Kr ++ irradiations on Cu with nanovoids in a transmission electron microscope up to 350 °C. The in situ studies revealed intriguing void spheroidization, shrinkage and migration. Furthermore, the morphology evolution and migration of nanovoids showed a strong dependence on irradiation temperature and initial void size. Post-irradiation analyses identified defect clusters in the form of stacking fault tetrahedrons, and the remaining large faceted nanovoids. The underlying mechanisms of irradiation-induced void spheroidization and shrinkage were discussed based on phase-field modeling.

36 MATERIALS SCIENCE↗

Analysis of position-dependent cavity parameters in irradiated metals to obtain insight on fundamental defect migration phenomena

Motion of point defects is a fundamental process that governs microstructure and properties of materials. Here, we examine the near-surface and grain boundary cavity swelling depth profiles in neutron- and ion-irradiated simple metals (Cu, Ni, and Fe-Cr) and investigate diffusional broadening of implanted Ni ions in Fe-Cr alloys. Vacancy migration energies and radiation-enhanced diffusion were experimentally estimated. Cavity denuded zone widths near planar sinks are shown to be dependent on temperature, damage rate, balance of point defects and sinks, and vacancy migration energies. An enhanced cavity swelling zone adjacent to the void-denuded zone was observed in specimens with low to moderate sink strength and interpreted as evidence of 1D gliding interstitial clusters. Radiation-enhanced diffusional broadening of implanted Ni ions (at 400–550 °C) in Fe and Fe-Cr was up to 250 nm toward the surface, which leads to a much broader near-peak-damage region where cavity swelling is suppressed. Diffusional broadening of implanted ions is calculated to be similarly pronounced for self-ion irradiations, particularly near the peak and higher swelling temperature regimes. Adequately high ion energies (~8–15 MeV) are recommended for ion-irradiation studies to provide a sufficiently broad midrange safe analysis region with minimized surface and injected ion effects.

36 MATERIALS SCIENCE↗

An isotopic test of the seasonal migration hypothesis for large grazing ungulates inhabiting the Palaeo-Agulhas Plain

The Greater Cape Floristic Region of South Africa was critical to the evolution of early modern humans ( Homo sapiens ) during the Pleistocene. The now submerged continental shelf formed its own ecosystem, the Palaeo-Agulhas Plain (PAP), where early humans lived and foraged. Grazing animals living on the plain might have migrated east and west tracking seasonally varying rains—a hypothesis tested here by examining δ 13 C and δ 18 O of serially-drilled teeth from seven ungulate genera: Alcelaphus , Connochaetes , Antidorcus , Redunca , Damaliscus , and Hippotragus . Modern observations and paleoecological reconstructions indicate that summer rainfall areas to the east have more C 4 grasses while the winter rainfall areas to the west have more C 3 grasses, and that summer and winter rains differ in δ 18 O. Thus, we analyze δ 13 C and δ 18 O preserved in herbivore teeth from the site of PP30 (a hyena den dating to ~151 ka) to infer diet and water source throughout tooth formation. On a generic level, we report none of the samples exhibit δ 13 C or δ 18 O values that differ significantly from a taxon that likely foraged locally through the year (Southern reedbuck, Redunca arundium ). Overall, results indicate that the PAP could support herbivore populations year-round without substantial migration, providing an ecosystem ideal for human inhabitants.

59 BASIC BIOLOGICAL SCIENCES↗

The impact of chemistry on anion migration in bixbyite-structured lanthanide oxides

This manuscript describes atomistic calculations of oxygen vacancy and interstitial migration in bixbyite structured lanthanide oxides. We examine two types of compounds, one in which only one type of lanthanide cation is present and a second class in which two lanthanides are present in a 3:1 ratio as dictated by the symmetry of the bixbyite crystal structure. Using temperature accelerated dynamics and the nudged elastic band method, we quantify the role of chemistry on the energy barriers for the most important pathways for both vacancy and interstitial migration. We then analyze the impact of these variations on the overall diffusivity of each defect, quantifying the contribution of each pathway using the theory of kinosons. We find that vacancy mobility can vary by as much as three orders of magnitude through changes in chemistry at 500 K. Changes in interstitial mobility are more modest but can still vary by an order of magnitude. This points to the ability to tune the mass transport characteristics of these compounds through appropriate choices in chemistry. We have also included supplementary information containing the atomic structures of the relevant pathways.

36 MATERIALS SCIENCE↗

Light induced ion migration studies in perovskite solar cell using nonlinear impedance spectroscopy

Complex interactions between mobile ions and charge carriers in perovskite solar cells (PSCs) make it challenging to fully understand their dynamic interplay. Exposure to light further complicates these interactions, altering the system’s dynamics and inducing nonlinear effects that lead to changes in the J−V curve. Understanding these effects is crucial for improving the operational stability of PSCs. Impedance spectroscopy (IS) is a powerful technique for evaluating relaxation processes in the frequency domain; however, it is limited in capturing nonlinear contributions. Here, in this work, nonlinear impedance spectroscopy (NLIS) is employed to analyze the higher harmonic response to AC perturbation, both in the dark and after short-term light exposure. A shift in the low-frequency (LF) higher harmonic peak is observed after open-circuit light exposure, attributed to an altered electric field suggesting ion re-distribution, whereas closed-circuit exposure shows no LF shift, indicating minimal ion movement. Additionally, light exposure reduces higher-order admittance, more notably in open-circuit conditions, suggesting decreased recombination. Temperature-dependent analysis was conducted to characterize the activation energy of migrating species, identifying iodide as the dominant migrating ion.

14 SOLAR ENERGY↗

Temperature-Dependent Communication between Pt/Al 2 O 3 Catalysts and Anatase TiO 2 Dilutant: the Effects of Metal Migration and Carbon Transfer on the Reverse Water–Gas Shift Reaction

In heterogeneous catalysis, unexpected effects from the supposedly inert reactor dilutant are not rare, but related understanding is lacking and inconsistent. Here we report investigations of the impacts of the anatase TiO 2 dilutant on the reverse water-gas shift (rWGS) reaction over Pt/Al 2 O 3 catalysts. Combining detailed kinetic data with microscopic and spectroscopic results, we demonstrate that the catalyst-dilutant communication depends on temperature. At high temperature (400 °C), Pt migrate from Al 2 O 3 to TiO 2 , resulting in higher dispersion and activity, without changing reaction mechanisms. The Pt migration is general to catalysts of different Pt nuclearity and various oxide dilutants. In contrast, at low temperature (250 °C), carboxylic acids (in particular acetic acid) present in the ambient air and adsorbed on TiO 2 are transferred onto Al 2 O 3 in close contact, effectively blocking the formate rWGS pathway. As a result, the rWGS can only proceed through the carboxyl pathway, and hence is significantly slower. The acetate transfer affects catalysts of different Pt nuclearity and support, but is unique to anatase TiO 2 dilutant. As the acetate layer is slowly removed under H 2 or the rWGS stream, the activity recovers. This work elucidates the complicated communication between catalysts and dilutants, which has general implications in heterogeneous catalysis, and resolves inconsistency in related reports in the literature. Finally, the impacts that anatase TiO 2 dilution has on the rWGS also unveil mechanistic understanding that further confirms the two co-existing rWGS pathways.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Probing vibronic coherence in charge migration in molecules using strong-field sequential double ionization

We propose a scheme for probing vibronic coherence in charge migration in molecules utilizing strong-field sequential double ionization. To demonstrate the feasibility of this approach, we perform full simulations of a pump-probe scheme employing few-cycle intense infrared pulses for N 2 and O 2 . We predict that the vibronic coherence between the pumped states will be directly imprinted in experimental observables such as kinetic energy release spectra and branching ratios of the dissociative dications. Our simulations are based on the recently developed density matrix approach for sequential double ionization model, which is capable of efficiently accounting for molecular orientations and enabling direct comparison with experimental results. Lastly, our findings strongly encourage the use of this probing scheme in future charge migration experiments.

74 ATOMIC AND MOLECULAR PHYSICS↗

FIRE: A Failure-Adaptive RL Framework for Edge Computing Migrations

In edge computing, users' service profiles are migrated between edge servers due to user mobility. Reinforcement Learning (RL) frameworks have been proposed to do so, often trained on simulated data. However, existing RL frameworks overlook occasional server failures, which although rare, impact latency-sensitive applications like AR/VR and real- time obstacle detection. These rare failures, being not adequately represented in historical training data, pose a challenge for data-driven RL algorithms. We introduce FIRE, a framework that adapts to rare events by training a RL policy in an edge computing digital twin environment. We propose FIRE-ImRE, an importance sampling-based Q-learning algorithm, which samples rare events proportionally to their impact on the value function. FIRE considers delay, migration, failure, and backup placement costs across individual and shared service profiles. We prove FIRE-ImRE's boundedness and convergence to optimality. Next, we introduce novel deep Q-learning (FIRE-ImDQL) and actor critic (FIRE-ImACRE) versions of our algorithm to enhance scalability. Here, we extend our framework to accommodate users with varying risk tolerances of rare failure events. Through trace-driven experiments, we show that FIRE reduces edge computing costs compared to vanilla RL and the greedy baseline in the event of failures.

Edge computing↗

Attosecond probing and control of charge migration in carbon-chain molecule

In quantum mechanics, when an electron is quickly ripped off from a molecule, a superposition of new eigenstates of the cation creates an electron wave packet that governs the charge flow inside, which has been called charge migration (CM). Experimentally, extracting such dynamics at its natural (attosecond) timescale is quite difficult. We report the first such experiment in a linear carbon-chain molecule, butadiyne (C 4 H 2 ), via high-harmonic spectroscopy (HHS). By employing advanced theoretical and computational tools, we showed that the wave packet and the CM of a single molecule are reconstructed from the harmonic spectra for each fixed-in-space angle of the molecule. For this one-dimensional molecule, we calculate the center of charge $\langle$ x $\rangle$ ( t ) to obtain v cm , to quantify the migration speed and how it depends on the orientation angle. The findings also uncover how the electron dynamics at the first few tens to hundreds of attoseconds depends on molecular structure. The method can be extended to other molecules where the HHS technique can be employed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Quasielastic least-squares reverse time migration of PS reflections

Conventional analysis of amplitude variation with offset for elastic PS reflections is based on analytical reflection coefficients in a layered medium, and wave-equation-based PS migration is mainly used to produce a structural image. To overcome this problem, we have developed a least-squares reverse time migration (LSRTM) method for elastic PS reflections based on a quasielastic wave equation. Here, the quasielastic wave equation can accurately model PS reflections with elastic amplitudes under the first-order Born approximation. Our LSRTM method inverts for perturbations of the S-wave velocity and density by minimizing the L 2 norm of the difference between recorded and predicted PS reflections modeled using a quasielastic wave equation. We refer to our new method as quasielastic LSRTM of PS reflections. Numerical tests on synthetic and field data indicate that our method can properly handle the amplitudes of elastic PS reflections and provides an accurate estimate of the perturbations of S-wave velocity and density. Extending the method to the 3D case is not straightforward and might require incorporating certain PS data processing techniques into the inversion itself.

58 GEOSCIENCES↗