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At least 199 records · Page 11

Study of the dissociation of molecular hydrogen

Dissociators used to obtain an RF plasma discharge for hydrogen masers and the test system used for operation and evaluation of the dissociators are described. A compact sorption cartridge using a graphite matrix is tested as part of a hydrogen scavenging system. Testing of a vacuum enclosed hydrogen dissociator suitable for long term operation in space is described.

Vessot, R. F. C.↗

Molecular hydrogen emission from W51

The detection of emission from the v = 1 approaches 0 S(1) quadrupole transition of H2 toward the cluster of intense infrared and H2O maser sources in W51 (north) is reported. The apparent luminosity of this line in W51 (north) is only about 4% of the luminosity of the same line toward the Kleinmann-Low infrared cluster in Orion; however, additional line-of-sight extinction and spatial extent of the source may account for the lower apparent power in W51. Similarity in the infrared and H2O properties of these clusters is addressed. The implications of the H2 emission for mass loss in the W51 region is discussed and some proposed models of radiation-driven mass outflow from pre-main sequence stars are briefly considered.

Beckwith, S.↗

Molecular hydrogen ion /H2+/ absorption in planetary nebulae

Several IUE spectra of planetary nebulae show an absorption feature shortward of 1500 A which is believed to be due to H2(+). The nebulae are excited by stars of spectral type O3-O7 or continuum, and all but one have double-shell structure.

Feibelman, W. A.↗

Transition probabilities of the B-prime 1Sigma(u)(+) to X 1Sigma(g)(+) system of molecular hydrogen

From published potential energy curves and transition dipole moments, there are obtained by numerical integration of the equations of nuclear motion the vibrational eigenfunctions of the X 1Sigma(g)(+) and B-prime 1Sigma(u)(+) states of H2. The probabilities of radiative transitions from the discrete vibrational levels of the excited B-prime 1Sigma(u)(+) electronic state of H2 to the discrete and continuum vibrational levels of the ground X 1Sigma(g)(+) electronic state are calculated. The Franck-Condon factors are also presented.

Kwok, T. L.↗

Vibrationally excited molecular hydrogen in the upper atmosphere of Jupiter

A comprehensive theoretical model for vibrationally excited H2 in the upper atmosphere of Jupiter is presented. Theoretical calculations demonstrate the probable existence of significantly enhanced populations of vibrationally excited H2 in the Jovian upper atmosphere, especially in the auroral regions. It is also shown that this H2 is an important chemical sink of H(+) ions in the Jovian ionosphere and thus has a significant effect on the calculated ionospheric electron densities.

Cravens, T. E.↗

Imaging of molecular hydrogen and oxygen by single and two-photon fluorescence using laser and flashlamp sources

Two flow visualization techniques, i.e., simultaneous two-dimensional fluorescence imaging of H2 and O2 in a diffusion flame, and quasi-linear fluorescence imaging of O2, are presented. The first uses an injection-locked argon-fluoride excimer laser and a partial overlap of a two-photon ground state absorption in H2 with a single photon absorption from a vibrational level in O2. The second uses a simple, high-intensity ultraviolet flashlamp which provides a flux of photons in the 180-195 nm range, sufficient to produce a quasi-one-dimensional fluorescence image of hot/room temperature oxygen. Both techniques do not require that a seed material be introduced into the flow, they can image major flow constituents, and provide an instantaneous snapshot of the flow.

Diskin, Glenn S.↗

Dipole moments and transition probabilities of the i 3Pi sub g-b 3Sigma(+) sub u, c 3Pi sub u-a 3Sigma(+) sub g, and i 3Pi sub g-c 3Pi sub u systems of molecular hydrogen

Bonn-Oppenheimer-based ab initio calculations of dipole moments from the i 3Pi sub g-b 3Sigma(+) sub u, c 3Pi sub u-a 3Sigma(+) sub g, and i 3Pi sub g-c 3Pi sub u transitions of H2 have been conducted, to yield a tabulation of the dipole transition probabilities and Franck-Condon factors. These factors are given for transitions originating in the lowest vibrational level of the ground X 1Sigma(+) sub g state.

Guberman, Steven L.↗

Electronic energy gap of molecular hydrogen from electrical conductivity measurements at high shock pressures

Electrical conductivities were measured for liquid D2 and H2 shock compressed to pressures of 10-20 GPa (100-200 kbar), molar volumes near 8 cu cm/mol, and calculated temperatures of 2900-4600 K. The semiconducting energy gap derived from the conductivities is 12 eV, in good agreement with recent quasi-particle calculations and with oscillator frequencies measured in diamond-anvil cells.

Nellis, W. J.↗

The unusual morphology of molecular hydrogen emission in the planetary nebula J900

We report new high-resolution near-infrared imaging observations of the planetary nebula J900, in broadband J, H, and K, and narrowband 2.122 micrometers (for H2 1-0 S(1)), Brackett-gamma, and continuum filters. The H2 images reveal a remarkable set of outward-extending features not detected in any previous observations of theis object. In the northwest lobe of the inner bipolar region, the H2 emission, Brackett-gamma emission, and underlying continuum are spatially resolved. The relative positions of the peaks of the line emission suggest an ionization front seen edge-on. The continuum emission, apparently located nearer to the central star, is likely due to transiently heated small dust grains. The extended H2 emission features are probably excited either by oblique shocks caused by material ejected from the nebula, or by radiation leaking from holes in the opacity surrounding the ionized shell.

Shupe, D. L.↗

Molecular Hydrogen in the Quiescent Disk of SW UMA

The FUSE observation has been reduced and a paper is in progress. The analysis has been slow because of the very noisy quality of the data. We anticipate submitting a paper in 2 or 3 months. The primary result is that there is no H_2 fluorescent emission. However, there seems to be no accretion disk. The upper limit to the continuum level is well below that observed by IUE, and while O VI lines are present, they are extremely faint and much narrower that the published and archival H alpha profiles. It appears that the accretion has essentially shut off entirely, leaving only very faint O VI and C III emission from the white dwarf. We are considering a magnetic model analogous to that for AE Aqr.

Raymond, John C.↗

Contributions of Solar Wind and Micrometeoroids to Molecular Hydrogen in the Lunar Exosphere

We investigate the density and spatial distribution of the H2 exosphere of the Moon assuming various source mechanisms. Owing to its low mass, escape is non-negligible for H2. For high-energy source mechanisms, a high percentage of the released molecules escape lunar gravity. Thus, the H2 spatial distribution for high-energy release processes reflects the spatial distribution of the source. For low energy release mechanisms, the escape rate decreases and the H2 redistributes itself predominantly to reflect a thermally accommodated exosphere. However, a small dependence on the spatial distribution of the source is superimposed on the thermally accommodated distribution in model simulations, where density is locally enhanced near regions of higher source rate. For an exosphere accommodated to the local surface temperature, a source rate of 2.2 g s-1 is required to produce a steady state density at high latitude of 1200 cm-3. Greater source rates are required to produce the same density for more energetic release mechanisms. Physical sputtering by solar wind and direct delivery of H2 through micrometeoroid bombardment can be ruled out as mechanisms for producing and liberating H2 into the lunar exosphere. Chemical sputtering by the solar wind is the most plausible as a source mechanism and would require 10-50 of the solar wind H+ inventory to be converted to H2 to account for the observations.

Impact↗

Irradiation with molecular hydrogen as an accelerated total dose hardness assurance test method for bipolar linear circuits

High dose rate irradiation with hydrogen stress is proposed as an accelerated total dose test method for bipolar linear circuits. The method is validated across process and circuit technologies with five parts that are commonly used in space: a comparator (LM193 from National Semi-conductor), a voltage regulator (HSYE-117 RH from Intersil), a voltage reference (LT1019 from Linear Technology), a JFET input op amp (OP42 from Analog Devices) and a temperature transducer (AD590 from Analog Devices). The testing technique could rapidly establish an upper bound to the low dose rate response of parts in space and help with the part selection process in the design phase of a mission. The technology dependence and the viability of this technique are qualitatively explored using a physical model describing the dose rate response and the effect of hydrogen in bipolar technologies. The model uses four core processes: 1) space charge effects, 2) free electron/hole pair recombination, hole-hydrogen defect reactions in the oxides and 4) proton depassivation of dangling bonds at the Si/SiO2 interface. Radiation hardness assurance implications are discussed.

Pease, Ron↗