Momentum transfer to solid surfaces by N2 molecules in the energy range 7-200 ev
Momentum transfer from neutral nitrogen molecules to solid surfaces measured for various incident beam molecule energies
Boring, J. W.↗
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Photochemistry and lifetimes of interstellar molecules
A quantitative discussion is presented of the lifetime against photodecomposition, or the probability of photodecomposition, of interstellar molecules. In addition to photodissociation, molecules can also be destroyed by interaction with high energy radiation and energetic particles. These processes are much less effective than destruction by ultraviolet radiation. However, when the ultraviolet is highly attenuated in clouds, the energetic radiation and particles will persist and will become relatively more important and the ultimate lifetimes in clouds may depend upon these processes.
Stief, L. J.↗
Multiphoton excitations in vibrational rotational states of diatomic molecules in intense electromagnetic field
A theory is presented and a calculational procedure is outlined for evaluating transition amplitudes of multiphoton excitations of vibrational-rotational levels in diatomic molecules. This theory can be utilized in studying behavior of molecules in intense electromagnetic fields.
Faisal, F. H. M.↗
Interstellar molecules and the origin of life.
Synopsis of the various views expressed at the conference held at NASA Ames Research Center in February 1971 on the relationship of interstellar molecules to the origin of life, intended to provide a basis for future discussion and work in this area. The topics covered include: a summary of molecules discovered, the interstellar environment, laboratory measurements, chemical evolution, and exobiology.
Buhl, D.↗
Spectroscopy of tetrabenzporphin molecules and possible astrophysical implications.
Quasi-line spectra of MgTBP (chi) and H2TBP are presented with a view toward laboratory simulation of the diffuse interstellar spectra. Experimental results are discussed which strongly suggest that molecule chi meets all the critical tests for spectral identification. The IR spectrum and visible data of molecule chi are discussed and analysed in terms of a simple vibronic self-consistent energy level diagram.
Johnson, F. M.↗
Molecule formation. I - In normal H I clouds. II - In interstellar shock waves.
The formation of simple molecules and their role in the chemistry and physics of the interstellar medium is considered. The requirements for recombination reactions to occur on interstellar grains with the subsequent buildup of a molecular mantle are discussed. Together with a discussion of depletion and heating of the evolving gas, this forms the basis for a treatment of the precollision history of dust and gas. All the chemical reactions included in the calculations are given, as well as the results of calculations for two values of the intercloud pressure and for a range of cloud masses. Shock waves in clouds whose precollision history has been calculated are treated, followed by discussion of the shock structure and the dynamics of the grains. The process of sputtering is treated, and expressions are given for the cooling rates, including cooling due to the molecules formed behind the shock front. All the chemical reactions included in the calculations are given, as well as the results of calculations for a range of shock velocities and initial molecular hydrogen abundances.
Aannestad, P. A.↗
New thermodynamic functions for the C3 molecule.
When graphite is used as ablation material in heat shields, very often a prominent carbon species vaporized into the stream is C3. The thermodynamic properties of the C3 molecule are, therefore, important in calculating transport phenomena in the ablation flow field. The nature of the C3 thermodynamic functions has been in doubt because of the uncertain contribution of the bending mode vibrations to the total internal energy of the molecule. An approach for overcoming these difficulties is considered. The results of the computations are presented in the form of graphs and approximating functions.
Pearson, W. E.↗
Spectroscopy and reactions of molecules important in chemical evolution
The research includes: (1) hot hydrogen atom reactions in terms of the nature of products produced, mechanism of the reactions and the implication and application of such reactions for molecules existing in interstellar clouds, in planetary atmospheres, and in chemical evolution; (2) photochemical reactions that can lead to molecules important in chemical evolution, interstellar clouds and as constituents in planetary atmospheres; and (3) spectroscopic and theoretical properties of biomolecules and their precursors and where possible, use these to understand their photochemical behavior.
Becker, R. S.↗
Birefringing arising from the reorientation of the polarizability anisotropy of molecules in collisionless gases
The refractive index change in a collisionless gas is evaluated from the Stark shifts of the rotational energy levels that arise from the polarizability anisotropy. For the limit of an extremely short-duration excitation, a multilevel coherent effect resulted in delayed refractive index bursts. Both stationary and transient responses of this birefringence to an optical field were considered for symmetric top molecules, with particular emphasis on the special case of linear molecules.
Lin, C. H.↗
Production of organic molecules by proton irradiation
Preliminary experiments were carried out to investigate the effectiveness of proton irradiation for producing organic chromophores. The source of the 2 MeV protons used in the experiments was a model Van de Graaff accelerator. The gas cells used were hollow aluminum cylinders. The test results show that energetic protons can be an effective energy source for the formation of complex molecules from simple ones. With the exception of sulfide compounds none of the molecules that were identified are colored. However, coloring agents could be contained in unresolvable fractions.
Scattergood, T.↗
Dust particles and molecules in the extended atmospheres of carbon stars
It is shown that the absorption due to a circumstellar shell containing solid silicon carbide particles can very nicely explain the observed strong violet opacity in stars in which the carbon to oxygen ratio is greater than 1. It has been shown by Friedemann and Gilman that solid SiC particles can form in the cooler outer layers of such stars. Thermal re-emission from SiC particles is predicted to be in the 10-13 micron region, and recent infrared observations by Hackwell show an emission band in this region, thereby strongly supporting the SiC suggestion. It is also shown that the opacity due to C3 pseudocontinuum is not adequate to explain the observed violet opacity. It is suggested that the vibrational bands of C3 and SiC2 molecules should be among the major opacity sources in the infrared spectra of the late N-type carbon stars and some of the observed bands may be, at least in part, due to these molecules.
Gilra, D. P.↗
Short-range interaction between hydrogen molecules
Recent calculations of the ground state energy of a system of four hydrogen atoms are reviewed with the aim of discerning the short-range repulsive part of the interaction potential between two hydrogen molecules. Extended-basis CI calculations which include a diffuse 2p orbital appear to be capable of determining the total interaction energy between to hydrogen molecules for any separation. Consistent results of such calculations suggest that the potential for intermolecular separations in the region from 1 to 2.5 A can now be specified to better than 10% with considerable confidence. Analytic fits to spherical averages of these results are presented.
Mcmahan, A. K.↗
Chlorine-bearing molecules in interstellar clouds
The reaction Cl(+) + H2 yielding HCl(+) + H is rapid, and it leads to the formation of the molecules HCl(+), H2Cl(+), and HCl. It may be possible to detect HCl(+) near 3600 A, and HCl may be observable at 1291 A. Also, photodissociation of HCl(+) may be a significant source of protons within clouds, and chemical heating resulting from the destruction of chlorine-bearing molecules may account for perhaps 1-10 per cent of the expected cooling from diffuse interstellar clouds.-
Jura, M.↗
Interstellar molecules - Formation in solar nebulae
Herbig's (1970) hypothesis that solar nebulae might be the principal source of interstellar grains and molecules is investigated. The investigation includes the determination of physical and chemical conditions in the early solar system. The production of organic compounds in the solar nebula is studied, and the compounds in meteorites are compared with those obtained in Miller-Urey and Fischer-Tropsch-type (FTT) reactions, taking into consideration aliphatic hydrocarbons, aromatic hydrocarbons, purines, pyrimidines, amino acids, porphyrins, and aspects of carbon-isotope fractionation. It is found that FTT reactions account reasonably well for all well-established features of organic matter in meteorites investigated. The distribution of compounds produced by FTT reactions is compared with the distribution of interstellar molecules. Biological implications of the results are considered.
Anders, E.↗
Interstellar molecules
The Princeton equipment on the Copernicus satellite provides the means to study interstellar molecules between the satellite and stars from 20 to 1000 pc distant. The study is limited to stars relatively unobscured by dust which strongly attenuates the ultraviolet continuum flux used as a source to probe the interstellar medium. Of the 14 molecules searched for only three have been detected including molecular hydrogen, molecular HD, and carbon monoxide.
Drake, J. F.↗
Semiclassical S-matrix theory of vibrationally inelastic collisions between two diatomic molecules
We derive a semiclassical S matrix for vibrationally inelastic collisions between two diatomic molecules, assuming a collinear geometry. Our theory incorporates a quantum mechanical superposition principle with classical dynamics and, as such, is an extension of the atom-diatomic molecule theory of Miller. The several approximations to the S matrix differ in the complexity with which the interference between various classical trajectories is treated. We report numerical calculations for H2-D2 and D2-D2 collisions based on two different interaction potentials. The cruder approximations yield transition probabilities which agree with exact quantum mechanical results to within a factor of 2. More sophisticated approximations to the S matrix yield excellent quantitative agreement with the quantum calculations.
Cohen, S. C.↗
Inelastic scattering in atom-diatomic molecule collisions. I - Rotational transitions in the sudden approximation
The impact parameter method and the sudden approximation are applied to determine the total probability of inelastic rotational transitions arising from a collision of an atom and a homonuclear diatomic molecule at large impact parameters. An analytical approximation to this probability is found for conditions where the electron exchange or overlap forces dominate the scattering. An approximate upper bound to the range of impact parameters for which rotational scattering can be important is determined. In addition, an estimate of the total inelastic cross section is found at conditions for which a statistical model describes the scattering well. The results of this analysis are applied to Ar-O2 collisions and may be readily applied to other combinations of atoms and molecules.
Stallcop, J. R.↗
Monte Carlo calculations of diatomic molecule gas flows including rotational mode excitation
The direct simulation Monte Carlo method was used to solve the Boltzmann equation for flows of an internally excited nonequilibrium gas, namely, of rotationally excited homonuclear diatomic nitrogen. The semi-classical transition probability model of Itikawa was investigated for its ability to simulate flow fields far from equilibrium. The behavior of diatomic nitrogen was examined for several different nonequilibrium initial states that are subjected to uniform mean flow without boundary interactions. A sample of 1000 model molecules was observed as the gas relaxed to a steady state starting from three specified initial states. The initial states considered are: (1) complete equilibrium, (2) nonequilibrium, equipartition (all rotational energy states are assigned the mean energy level obtained at equilibrium with a Boltzmann distribution at the translational temperature), and (3) nonequipartition (the mean rotational energy is different from the equilibrium mean value with respect to the translational energy states). In all cases investigated the present model satisfactorily simulated the principal features of the relaxation effects in nonequilibrium flow of diatomic molecules.
Yoshikawa, K. K.↗