Search NASA⌕ Search

SEARCH · Search NASA

Results for “nitrous oxide”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11

Laboratory simulation of tropospheric pollution sensing with a pressure modulator radiometer /PMR/

The optical properties of carbon monoxide gas uniformly distributed in the atmosphere have been simulated in a 20.48 cm long cell in the laboratory. The altitude of the peak of the weighting function for several concentrations was found using a Pressure Modulator Radiometer (PMR). The effect of a fluctuating background radiance and gaseous nitrous oxide on the carbon monoxide signals were examined.

Hinton, D. E.↗

Fourier spectroscopy of the stratospheric emission

Stratospheric emission spectra in the submillimeter range have been recorded with a resolution of 0.0033/cm with a balloon-borne interferometer. Several minor atmospheric constituents have been identified in a preliminary analysis of the spectra; these are water vapor, oxygen, ozone isotopes, nitric acid, nitrous oxide, hydrofluoric and hydrochloric acids, and carbon monoxide.

Carli, B.↗

Thunderstorm hazards flight research: Storm hazards 1980 overview

A highly instrumented NASA F-106B aircraft, modified for the storm hazards mission and protected against direct lightning strikes, was used in conjunction with various ground based radar and lightning measurement systems to collect data during thunderstorm penetration flights. During 69 thunderstorm penetrations, there were 10 direct lightning strikes to the aircraft. No problems were encountered with any of the aircraft's systems as a result of the strikes and the research instrumentation performed as designed. Electromagnetic characteristics of nine strikes were recorded, and the results of other experiments confirm the theory that X-ray radiation and nitrous oxide gas are being produced by processes associated directly with thunderstorm electric fields and lightning discharges. A better understanding of aircraft lightning attachment mechanisms and strike zones is being accomplished by careful inspection, identification, and documentation of lightning attachment points and swept stroke paths following each strike to the aircraft.

Deal, P. L.↗

The 1980 stratospheric-tropospheric exchange experiment

Data are presented from the Stratospheric-Tropospheric Water Vapor Exchange Experiment. Measurements were made during 11 flights of the NASA U-2 aircraft which provided data from horizontal traverser and samplings in and about the tops of extensive cirrus-anvil clouds produced by overshooting cumulus turrets. Aircraft measurements were made of water vapor, ozone, ambient and cloud top temperature, fluorocarbons, nitrous oxide, nitric acid, aerosols, and ice crystal populations. Balloonsondes were flown about twice daily providing data on ozone, wind fields, pressure and temperature to altitudes near 30 km. Satellite photography provided detailed cloud and cloud top temperature information. Descriptions of individual experiments and detailed compilations of all results are provided.

Margozzi, A. P.↗

A radiative transfer model for surface radiation budget studies

A high resolution spectral radiative transfer model of the troposphere for computing downwelling radiance and flux density at the surface in the 5-200 micron region has been developed. The model is fast and accurate and takes into consideration all major and minor constituents active in this region, namely, water vapor, carbon dioxide, ozone, nitrous oxide, and methane. It uses the quasi-random band model of absorption for computing atmospheric transmittances due to various bands. Continuum absorption by water vapor in the 8-14 micron region has also been taken into account. The model has been used to examine the sensitivity of downwelling flux to variations of surface water vapor pressure (or surface relative humidity), water vapor scale-height and concentrations of other gaseous constituents of the atmosphere. In addition, sensitivity to changes in a number of cloud parameters, namely, fractional cloud cover, cloud height, and high-cloud emissivity, has also been examined. Results obtained with the present model compare well with those from the empirical and semi-empirical correlations. The present work demonstrates, for the first time, the feasibility of using a high-resolution narrow-band model for computing this flux for a meteorological application.

Gupta, S. K.↗

Nitrite reduction in paracoccus halodenitrificans: Evidence for the role of a cd-type cytochrome in ammonia formation

Cell-free extracts prepared from Paracoccus halodenitrificans catalyzed the reduction of nitrate to ammonia in the presence of dithionite and methyl viologen. Enzyme activity was located in the soluble fraction and was associated with a cytochrome whose spectral properties resembled those of a cd-type cytochrome. Unlike the sissimilatory cd-cytochrome nitrate reductase associated with the membrane fraction of P. halodenitrificans, this soluble cd-cytochrome did not reduce nitrite to nitrous oxide.

Hochstein, L. I.↗

Halocarbon concentration patterns associated with frontal passages

The atmospheric mixing ratios of CCl2F2 (F-12) and CCl3F (F-11) increase abruptly up to 14 ppt (F-12) and 8 ppt (F-11) after strong cold fronts pass and decrease abruptly after warm fronts pass at a semicontinuous monitoring station near Pullman, WA (46 deg 42 min N, 117 deg 10 min W). It is concluded that air masses from higher latitudes (above 60 deg N) can have F-12 and/or F-11 concentrations as much as 5 percent higher than mid-latitude air masses. Conversely, nitrous oxide shows no significant changes during frontal passages and is uniformly distributed between air masses.

Carter, M. W.↗

A dissimilatory nitrite reductase in Paracoccus halodenitrificans

Paracoccus halodenitrificans produced a membrane-associated nitrite reductase. Spectrophotometric analysis showed it to be associated with a cd-cytochrome and located on the inner side of the cytoplasmic membrane. When supplied with nitrite, membrane preparations produced nitrous oxide and nitric oxide in different ratios depending on the electron donor employed. The nitrite reductase was maximally active at relatively low concentrations of sodium chloride and remained attached to the membranes at 100 mM sodium chloride.

Grant, M. A.↗

Biogeochemical cycling and remote sensing

Research is underway at the NASA Ames Research Center that is concerned with aspects of the nitrogen cycle in terrestrial ecosystems. An interdisciplinary research group is attempting to correlate nitrogen transformations, processes, and productivity with variables that can be remotely sensed. Recent NASA and other publications concerning biogeochemical cycling at global scales identify attributes of vegetation that could be related or explain the spatial variation in biologically functional variables. These functional variables include net primary productivity, annual nitrogen mineralization, and possibly the emission rate of nitrous oxide from soils.

Peterson, D. L.↗

Global N2O cycles - Terrestrial emissions, atmospheric accumulation and biospheric effects

Recent findings concerning the budget and cycles of nitrous oxide on earth are summarized, and the sources and sinks for N2O on land, in the ocean, and in the atmosphere are examined in view of the N2O concentration increase of 0.2-0.4 percent per year, observed over the period of 1975-1982. Possible atmospheric and biospheric consequences of the N2O concentration increase are evaluated. N2O emission values are given for several major ecosystem types, such as forest, desert, cultivated land; values from different sources are compared and discussed. Analysis shows an excess of documented sources over sinks by 0-51 Tg N2O-N/yr.

Banin, A.↗

Role of chemotaxis in the ecology of denitrifiers

It has been recognized that the process of denitrification represents a major sequence in the nitrogen cycle. It involves the anaerobic reduction of nitrate or nitrite to nitrous oxide or elemental nitrogen. This process is responsible for significant losses of nitrogen from agricultural soils. Up to now, little attention has been paid to the ecology of the organisms responsible for denitrification. It is pointed out that chemotaxis would probably offer a strong competitive mechanism for denitrifiers, since chemotaxis would allow denitrifiers to actively reach nitrate by directed motility, rather than by random movement or diffusion of nitrate. The present investigation was initiated to examine the chemotactic responses of several denitrifiers to nitrate and nitrite. Attention is given to bacterial strains, culture media and cell preparation, chemotaxis assays, and competition experiments. It was found that several denitrifiers, including P. aeruginosa, P. fluorescens, and P. Stutzeri, were strongly attracted to NO3(-) and NO2(-).

Kennedy, M. J.↗

Denitrification by extremely halophilic bacteria

Extremely halophilic bacteria were isolated from widely separated sites by anaerobic enrichment in the presence of nitrate. The anaerobic growth of several of these isolates was accompanied by the production of nitrite, nitrous oxide, and dinitrogen. These results are a direct confirmation of the existence of extremely halophilic denitrifying bacteria, and suggest that such bacteria may be common inhabitants of hypersaline environments.

Hochstein, L. I.↗

Biogeochemical cycling in terrestrial ecosystems - Modeling, measurement, and remote sensing

The use of modeling, remote sensing, and measurements to characterize the pathways and to measure the rate of biogeochemical cycling in forest ecosystems is described. The application of the process-level model to predict processes in intact forests and ecosystems response to disturbance is examined. The selection of research areas from contrasting climate regimes and sites having a fertility gradient in that regime is discussed, and the sites studied are listed. The use of remote sensing in determining leaf area index and canopy biochemistry is analyzed. Nitrous oxide emission is investigated by using a gas measurement instrument. Future research projects, which include studying the influence of changes on nutrient cycling in ecosystems and the effect of pollutants on the ecosystems, are discussed.

Peterson, D. L.↗

Halobacterium denitrificans sp. nov., an extremely halophilic denitrifying bacterium

Halobacterium denitrificans was one of several carbohydrate-utilizing, denitrifying, extremely halophilic bacteria isolated by anaerobic enrichment in the presence of nitrate. Anaerobic growth took place only when nitrate (or nitrite) was present and was accompanied by the production of dinitrogen. In the presence of high concentrations of nitrate (i.e., 0.5 percent), nitrous oxide and nitrite were also detected. When grown aerobically in a mineral-salts medium containing 0.005 percent yeast extract, H. denitrificans utilized a variety of carbohydrates as sources of carbon and energy. In every case, carbohydrate utilization was accompanied by acid production.

Tomlinson, G. A.↗

Atmospheric trace gases - Trends and distributions over the last decade

Concentrations of the halocarbons CCl3F (F-11), CCl2F2 (F-12), CCl4, and CH3CCl3, methane (CH4), and nitrous oxide (N2O) over the decade between 1975 and 1985 are reported, based on measurements taken every January at the South Pole and in the Pacific Northwest. The concentrations of F-11, F-12, and CH3CCl3 in both hemispheres are now more than twice their concentrations 10 years ago. However, the annual rates of increase of F-11, F-12, and CH3CCl3 are now considerably slower than earlier in the decade, reflecting in part the effects of a ban on their nonessential uses. Continued increases in these trace gas concentrations may warm the earth and deplete the stratospheric ozone layer, which may cause widespread climatic changes and affect global habitability.

Rasmussen, R. A.↗

Halobacterium denitrificans sp. nov. - An extremely halophilic denitrifying bacterium

Halobacterium denitrificans was one of several carbohydrate-utilizing, denitrifying, extremely halophilic bacteria isolated by anaerobic enrichment in the presence of nitrate. Anaerobic growth took place only when nitrate (or nitrite) was present and was accompanied by the production of dinitrogen. In the presence of high concentrations of nitrate (i.e., 0.5 percent), nitrous oxide and nitrite were also detected. When grown aerobically in a mineral-salts medium containing 0.005 percent yeast extract, H. denitrificans utilized a variety of carbohydrates as sources of carbon and energy. In every case, carbohydrate utilization was accompanied by acid production.

Tomlinson, G. A.↗

Meridional distribution of stratospheric trace constituents

Vertically stratified tracers such as methane and nitrous oxide tend to have constant mixing ratio surfaces that slope downward toward the poles in the meridional plane. The equilibrium tracer slope results from the competition between the slope steepening effects of advection by the diabatic circulation and the slope flattening effects of quasi-isentropic eddy transport and photochemical loss. The diabatic circulation iself is, however, driven primarily by eddy transports, which maintain the departure of stratospheric temperatures from radiative equilibrium. If the eddy transports are weak, the diabatic circulation is also weak and the slope is small. Using a simple beta-plane channel model and an eddy diffusion parameterization for the eddy potential vorticity and tracer transports, it is shown that the slope is a maximum for a value of eddy diffusion such that the dynamical time scale lies between the radiative and chemical time scales.

Holton, J. R.↗

Emissions of N2O, CH4 and CO2 from tropical forest soils

Emissions of nitrous oxide, methane, and carbon dioxide were measured at diverse locations in tropical forests of Brazil, Ecuador, and Puerto Rico using a static open chamber technique. Mean fluxes to the atmosphere were 1.7 x 10 to the 10th, -0.7 x 10 to the 10th, and 1.5 x 10 to the 14th molecules/sq cm per s for N2O, CH4, and CO2, respectively. The data indicate that tropical forests contribute a significant fraction of the global source for atmospheric N2O, about 40 percent of the current source, and possibly 75 percent of the preindustrial source. Methane is consumed by soils on average, but the sink is an insignificant part (less than 5 percent) of the atmospheric cycle for the gas. Emissions of CO2 from forest soils are higher at equatorial sites than at middle or high latitudes, as expected from ecological considerations. Soils emit CO2 at rates more than twice as large as the rate of carbon infall in litter; hence much of the emitted CO2 must arise from root metabolism.

Keller, Michael↗