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The Role of Radiation-Induced Non-Equilibrium Plutonium Oxidation States in Solution

Plutonium plays a key role in global actinide research and nuclear fuel cycle technologies, and yet, our fundamental understanding of its inherent radiation-induced chemical behavior is limited. These radiation-induced processes cannot simply be switched off, as they are as fundamentally inherent to plutonium as the impact of relativistic effects on its f-electrons. In less chemically complex actinide systems, such as aqueous solutions of neptunium and americium, both steady-state and transient radiolysis products play a significant role in the redox cycling of their oxidation states, which ultimately impacts their chemistry and transport. However, plutonium's multiple, coexisting, and chemically active oxidation states, which comprise of bare ions and dioxo cations, provide additional redox pathways that complicate the aforementioned radiation-induced competition kinetics. Mechanistically understanding the response of these multiple oxidation states, both equilibrium and non-equilibrium, to intense ionizing radiation fields is essential for predicting the behavior of plutonium under a host of conditions that support technological innovation in global nuclear energy and non-proliferation efforts. Here, advances in radiation-induced plutonium solution chemistry will be presented, including new results from time-resolved electron pulse and steady-state gamma and alpha irradiations.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Domestic and International Consensus Standards for Nuclear Criticality Safety - Overview & Status

The domestic and international consensus standards for nuclear criticality safety (NCS) were developed based on the lessons-learned from process criticality accidents. These consensus standards were developed to reduce the rate of process criticality accidents in facilities that process, store, handle, or transport fissionable materials by hand. After a significant increase in criticality accidents through the mid-1960s, the rate of criticality accidents decreased as a result of these standards, and the criticality accident rate is extremely low from an industrial safety perspective. The last known criticality accident inside the United States was in 1978 (nearly 47 years ago) at the Idaho Chemical Processing Plant, and outside the United States, an accident occurred at Tokai-mura, Japan, in 1999 (almost 26 years ago). The domestic consensus standards for NCS include the American National Standards (ANS) that are prepared and published by the American Nuclear Society and approved by the American National Standards Institute (ANSI). The ANS Standards Board, the NCS Consensus Committee, and the ANS-8 Subcommittee oversee the development and maintenance of these standards. There are currently 18 standards in the ANS-8 series. Nine ANS-8 standards are either in revision mode or planned for revision. A new standard for the use of nondestructive assay measurements (ANSI/ANS-8.28-2024) for NCS was approved in March of 2024. The international consensus standards for NCS calculations, procedures, and practices are maintained and developed within the International Organization for Standardization, Technical Committee 85 “Nuclear Energy,” Subcommittee 5, “Nuclear Fuel Technology,” and Working Group 8, “Nuclear Criticality Safety.” Eleven standards are currently available, four standards are proposed for revision, and four standards are at various stages of development. This paper provides the NCS community with a high-level overview and status report of domestic and international NCS consensus standards to stimulate interest and to support their continued development.

Bowen, Douglas G [ORNL] (ORCID:0000000212460026)↗

GAIN Base Presentation Slide Deck 2/12/25

The GAIN Base Slide Deck is a compilation of topics that GAIN presents routinely to outside entities to educate them on the GAIN program, technology, demonstrations, coal to nuclear, energy systems, Financing, Supply Chain, Legislation, Regulatory, and Consent Based Citing.

99 - GENERAL AND MISCELLANEOUS↗

Design and Prototyping of Advanced Control Systems for Advanced Reactors Operating in the Future Electric Grid (Final Report)

Despite its significant advantages as a baseload, low-carbon energy source, the U.S. nuclear power industry has faced increasing difficulties in maintaining economic competitiveness in a rapidly evolving energy market. The economic conditions faced by the current fleet of nuclear power plants (NPPs) in the U.S. deregulated electricity market require a concerted effort to mitigate specific cost factors. Many units are struggling to stay competitive, and some premature shutdowns have occurred. Besides, in response to the large penetration of renewable energy sources, the role of nuclear power plants as pure baseload units needs to be reconsidered. Based on these experiences, operational flexibility is considered a fundamental requirement for the next generation of nuclear reactors to be competitive in the future energy market. The deployment of advanced reactors capable of operating within a new power grid paradigm, known as the Integrated Energy System (IES) was investigated. This approach combines new reactor designs with Thermal Energy Storage (TES) technologies, allowing the nuclear reactor to maintain a steady power output without the need for constant adjustments in response to load demand fluctuations. With this configuration, the reactor operates as a baseload unit, experiencing only very gradual power transients, while the energy storage facility within the power conversion cycle acts as a peaking unit.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Feasibility Study of Advanced Manufacturing Techniques and Compositions of High Entropy Alloys

In line with the objectives of Department of Energy’s Office of Nuclear Energy Advanced Materials and Manufacturing technologies program (AMMT), this work focuses on new materials development and qualification research and development for next-generation, high-temperature nuclear reactors. While the currently qualified nuclear materials have demonstrated significant irradiation resistance at high temperatures, the community is still interested in materials that can sustain the harsh environments found in nuclear reactors for temperatures up to 1,000°C for nearly 100,000 hours. High entropy alloys (HEAs) have the potential to serve in these extreme environments of next generation nuclear reactors due to their unique phase transformation pathways and nanoscale and mesoscale microstructures. The current work focuses on understanding such nuclear energy relevant HEAs through a detailed literature survey and developing a decision matrix with criteria for identification of HEAs with may have most impact and value for further examination.

36 MATERIALS SCIENCE↗

Advanced Materials and Manufacturing Technologies (AMMT) 2025 Roadmap

The mission of the Advanced Materials and Manufacturing Technologies (AMMT) program is to accelerate the development, qualification, demonstration, and deployment of advanced materials and manufacturing technologies in support of the United States (US) leadership in a broad range of nuclear energy applications. The vision of the AMMT program is the expansion of reliable and economical nuclear energy enabled by advanced materials and manufacturing technologies. Four major goals were set to realize the mission and vision of the AMMT program, including: (1) develop advanced materials and manufacturing technologies that have cross-reactor applications, (2) establish and demonstrate a rapid qualification framework that supports diverse materials and manufacturing technology needs, (3) evaluate materials performance in a range of nuclear environments, and (4) accelerate commercialization of new technologies through technology maturation. The program is designed to deliver solutions that support a wide range of reactor technologies.

36 MATERIALS SCIENCE↗

DOE Fffice of Nuclear Energy cybersecurity research, development and demonstration program plan

This document describes the Cybersecurity Research Development and Demonstration (RD&D) Program, established by the Department of Energy Office of Nuclear Energy (NE) to provide sciencebased methods and technologies necessary for cost-effective, cyber-secure digital instrumentation, control and communication in collaboration with nuclear energy stakeholders. It provides an overview of program goals, objectives, linkages to organizational strategies, management structure, and stakeholder and cross-program interfaces.

97 MATHEMATICS AND COMPUTING↗

Nu Tools: Exploring Practical Roles for Neutrinos in Nuclear Energy and Security

For decades, physicists have used neutrinos from nuclear reactors to advance basic science. These pursuits have inspired many ideas for application of neutrino detectors in nuclear energy and security. While developments in neutrino detectors are now making some of these ideas technically feasible, their value in the context of real needs and constraints has been unclear. This report seeks to help focus the picture of where neutrino technology may find practical roles in nuclear energy and security. This report is the final product of the Nu Tools study, commissioned in 2019 by the DOE National Nuclear Security Administration (NNSA) Office of Defense Nuclear Nonproliferation Research and Development (DNN R&D). The study was conducted over two years by a group of neutrino physicists and nuclear engineers. A central theme of the study and this report is that useful application of neutrinos will depend not only on advancing physics and technology but also on understanding the needs and constraints of potential end-users. The Study Approach emphasized broad end-user engagement. The major effort, undertaken from May to December 2020, was a series of engagements with the wider nuclear energy and security communities. Interviews with 41 experts revealed points of common understanding, which this report captures in three Cross-Cutting Findings, a Framework for Evaluating Utility, and seven Use Case Findings. The report concludes with two Recommendations. The findings and recommendations are summarized below. The respective ordering within each category does not represent a prioritization or implied value judgement.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Nuclear Technology Selection and Preliminary Integration at St. Charles and Carrollton Chemical Plants

Nuclear energy is identified as a valuable candidate for decarbonizing industrial facilities as a non-emitting baseload energy source capable of dispatching energy as needed for an integrated facility. As industrial facilities are unique, analyzing what nuclear technology is the best candidate should be evaluated on a case-by-case basis. For two identified facilities of the Dow Chemical Company, an ideal mix of nuclear energy resources is calculated, and integration strategies are put forward. This research was funded through a Gateway for Accelerated Innovation in Nuclear (GAIN) Nuclear Energy Voucher, specifically seeking near-term engineering solutions for the technical issue of introducing nuclear generated energy into the Dow chemical facilities. The research is split into four main phases: background on reactors and chemical facilities, preliminary engineering analysis determining how reactor technologies may be integrated with specific facilities, site characterization and discrete hazards analysis, and finally an optimization of reactor-facility selection through the use of Framework for Optimization of ResourCes and Economics (FORCE) tools.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

AI-based design of a nuclear reactor core

The authors developed an artificial intelligence (AI)-based algorithm for the design and optimization of a nuclear reactor core based on a flexible geometry and demonstrated a 3× improvement in the selected performance metric: temperature peaking factor. The rapid development of advanced, and specifically, additive manufacturing (3-D printing) and its introduction into advanced nuclear core design through the Transformational Challenge Reactor program have presented the opportunity to explore the arbitrary geometry design of nuclear-heated structures. The primary challenge is that the arbitrary geometry design space is vast and requires the computational evaluation of many candidate designs, and the multiphysics simulation of nuclear systems is very time-intensive. Therefore, the authors developed a machine learning-based multiphysics emulator and evaluated thousands of candidate geometries on Summit, Oak Ridge National Laboratory’s leadership class supercomputer. The results presented in this work demonstrate temperature distribution smoothing in a nuclear reactor core through the manipulation of the geometry, which is traditionally achieved in light water reactors through variable assembly loading in the axial direction and fuel shuffling during refueling in the radial direction. The conclusions discuss the future implications for nuclear systems design with arbitrary geometry and the potential for AI-based autonomous design algorithms.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Evaluating advanced nuclear fission technologies for future decarbonized power grids

Advanced nuclear fission, which encompasses various innovative nuclear reactor designs, could contribute to the decarbonization of the United States electricity sector. However, little is known about how cost-competitive these reactors would be compared to other technologies, or about which aspects of their designs offer the most value to a decarbonized power grid. We employ an electricity system optimization model and a case study of a decarbonized U.S. Eastern Interconnection circa 2050 to generate initial indicators of future economic value for advanced reactors and the sensitivity of future value to various design parameters, the availability of competing technologies, and the underlying policy environment. These results can inform long-term cost targets and guide near-term innovation priorities, investments, and reactor design decisions. We find that advanced reactors should cost $\$5.7$–$\$7.3$/W to gain an initial market share (assuming 30 year asset life and 3.5 %–6.5 % real weighted average cost of capital), while those that include thermal storage in their designs can cost up to $\$6.0$/W–$\$7.7$/W (not including cost of storage). Since the marginal value of advanced fission reactors declines as market penetration increases, break-even costs fall ~32 % at 100 GW of cumulative capacity and ~51 % at 300 GW. Additionally, policies that provide investment tax credits for nuclear energy create the most favorable environment for advanced nuclear fission. In conclusion, these findings can inform near-term resource allocation decisions by stakeholders, innovators and investors working in the energy technology sector.

Capacity expansion↗

Initial Results of PostProcess NDE Using Advanced Techniques

The U.S. Department of Energy, Office of Nuclear Energy Advanced Materials and Manufacturing Technologies Program is developing advanced materials and manufacturing technologies that will enable the safe and economical operation of both the current fleet and the next generation of advanced nuclear reactors. Post-process nondestructive evaluation capabilities are a key enabling technology that will be required to qualify and verify the condition of components produced using advanced materials and manufacturing technologies.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A Technical and Economic Assessment of LWR Flexible Operation for Generation and Demand Balancing to Optimize Plant Revenue

With increased penetration of subsidized variable renewable energy (VRE) resources and competition from low natural gas prices, existing light water reactor (LWR) nuclear power plants (NPPs) are struggling to remain economically competitive. This work examines the potential economic competitiveness of various thermal energy storage (TES) technologies when coupled directly or indirectly with a NPP. To highlight their relative economic competitiveness, we contrast several energy storage solutions in stochastic dispatch optimization. We leverage data from recent work analyzing a range of TES technologies with varying capital costs, performance, and technology readiness level (TRL) to establish our case. We explore inserting these technologies into an electricity market with existing nuclear generation and large projected variable renewable energy (VRE) penetration. Although these technologies' projected capital costs may make them unlikely candidates in their current state, this analysis demonstrates a high-fidelity techno-economic analysis of energy storage. Furthermore, as the projected cost of energy storage technologies evolves, this analysis sets a precedent for similar future investigations. One region with projected trends that may be unfavorable for existing nuclear capacity is the New York Independent System Operator (NYISO) market. New York state’s baseload generation has been historically provided by fossil-fired and nuclear assets. However, amid economic pressures from subsidized VREs and low natural gas prices, the state has recently deactivated Indian Point nuclear power plant units 2 and 3. Furthermore, the state plans to meet its zero-emission generation target by 2040 by replacing fossil-fired capacity with significant investments in VRE resources like wind and solar photovoltaic (PV) and battery storage. Increased intermittent resource penetration lowers the baseload power requirement, adding further economic pressure to the state’s three remaining NPPs still in operation. With three NPPs still in operation in New York, this work analyzes potential economic benefits to NPPs on the New York grid when directly or indirectly coupled with various TES technologies. This work requires two modeling steps to analyze the potential economic benefits of various system configurations of the TES directly or indirectly coupled with nuclear. First, this analysis leverages capacity expansion modeling by experts at the Electric Power Research Institute (EPRI). Using their deterministic capacity expansion model, U.S. Regional Economy, Greenhouse Gas, and Energy (US-REGEN), EPRI analysts evaluated the capacity and generation evolution of the New York state energy market under four projection scenarios. These four projection scenarios were developed to represent the potential evolution of the capacity and generation in NYISO from 2015 to 2050 under various economic, technology, and policy constraints. The results from these capacity expansion models are then used as boundary conditions in the second modeling step. The second modeling step uses the Holistic Energy Resource Optimization Network (HERON) for a set of stochastic techno-economic analyses (STEAs) to investigate the potential increase in the economic viability of various configurations of the TES. With no current capacity expansion capabilities, HERON takes the data generated from US-REGEN for 2050 to generate synthetic load, solar, and wind data. Then HERON economically optimizes the capacity and dispatch of the various TES configurations. The potential economic benefit is the differential net present value (NPV) of the TES configurations from the no-TES baseline. As a stochastic techno-economic analysis package, HERON introduces uncertainty into the economic metrics, while US-REGEN trades resolution for reduced computational complexity. Using HERON also allows the modeling of direct thermal coupling, a feature not common in capacity and dispatch models. As expected, with high capital costs, the costs of introducing energy storage for all the technologies considered outweighed the potential economic benefit of this strategy for flexible plant operation. The benefit of this analysis is primarily in demonstrating a workflow that examines innovative solutions to increase NPP revenue via TES coupling. HERON’s stochastic capacity and dispatch optimization process used in this work has proven an effective tool in observing and evaluating the impact of introducing storage technologies in a grid energy system.

25 ENERGY STORAGE↗

Space Nuclear Propulsion for Deep Space Science Missions

The use of nuclear thermal propulsion (NTP) 1 and nuclear electric propulsion (NEP) 2 systems on deep space science missions to the outer planets and into the interstellar medium 3 can yield significant spacecraft system and mission performance benefits and improvements relative to the use of conventional chemical propulsion systems. Several recent and ongoing programs are developing the technologies and systems required to realize a near-term deep space nuclear propulsion capability. NTP provides improved propulsion efficiencies compared to chemical propulsion, while also providing substantial thrust. This combination of high thrust and increased specific impulse (I_sp) provides high acceleration and extended thrusting periods, enabling greatly reduced trip-times on certain types of missions compared to various propulsive alternatives. For examples, compared to a baseline mission using chemical propulsion, NTP-powered missions to Jupiter or Uranus could deliver approximately 2.4-3.6 times more payload (in the case of Jupiter, the payload delivery is significantly larger than the Juno spacecraft). In this comparison, the higher end of the payload advantage is obtained when the trip time is held equal for the NTP-powered vehicle and a vehicle using a chemical propulsion departure stage. NTP systems are presently under development by multiple government agencies. NASA’s Space Nuclear Propulsion (SNP) project aims to demonstrate a hydrogen-fed NTP engine at 900 s specific impulse (I_sp) and approximately 10-15 klb_f of thrust. DARPA’s Demonstration Rocket for Agile Cislunar Operations (DRACO) program is targeting a demonstration of an NTP system in the cislunar space between the Earth and the Moon. An appropriately phased development plan that applies the development of the reactor technology for an NTP engine in this performance class and leverages mature, existing liquid rocket component hardware provides a path to a lower cost propulsion system that can be realized on a shorter development schedule. NEP, with high Isp in the 2,000-8,000 s range, can also provide advantages over chemical propulsion, including a much greater payload delivery mass and the flexibility for planners to trade between delivered mass and a wider window of mission trajectory options. Electric propulsion (EP) systems have demonstrated great utility, performing notably on the Dawn mission to enable rendezvous and orbital insertion at two separate bodies, Vesta and Ceres. An NEP-powered vehicle would have a similar capability to visit multiple bodies, loitering at each before moving to the next. A 10 kW_e NEP system provides a power- rich environment on the spacecraft that is simply not possible using present radioisotope power systems, giving mission planners more scientific instrument and communication hardware options. Several programs and projects are presently developing NEP systems and subsystems in the 10 kW_e power range, leveraging past reactor work and recent nuclear power generation risk-reduction demonstration activities such as the Demonstration Using Flattop Fission (DUFF) and the Kilopower Reactor Using Stirling TechnologY (KRUSTY). The goal of the Air Force Research Laboratory’s Joint Energy Technology Supplying On-Orbit Nuclear Power (JETSON) program is an in-space demonstration vehicle that has a 10 kW_e -class fission power source. These past and present efforts can be combined with the ongoing development of 10 kW_e -class electric propulsion systems (notably the NEXT-C ion thruster or the Hall-effect thrusters for Power and Propulsion Element of the Lunar Gateway) to provide a pathway to a low-cost, reliable NEP system for deep space science application.

Kurt A. Polzin↗

Space Nuclear Propulsion for Deep Space Science Missions

The use of nuclear thermal propulsion (NTP) 1 and nuclear electric propulsion (NEP) 2 systems on deep space science missions to the outer planets and into the interstellar medium 3 can yield significant spacecraft system and mission performance benefits and improvements relative to the use of conventional chemical propulsion systems. Several recent and ongoing programs are developing the technologies and systems required to realize a near-term deep space nuclear propulsion capability. NTP provides improved propulsion efficiencies compared to chemical propulsion, while also providing substantial thrust. This combination of high thrust and increased specific impulse (I_sp) provides high acceleration and extended thrusting periods, enabling greatly reduced trip-times on certain types of missions compared to various propulsive alternatives. For examples, compared to a baseline mission using chemical propulsion, NTP-powered missions to Jupiter or Uranus could deliver approximately 2.4-3.6 times more payload (in the case of Jupiter, the payload delivery is significantly larger than the Juno spacecraft). In this comparison, the higher end of the payload advantage is obtained when the trip time is held equal for the NTP-powered vehicle and a vehicle using a chemical propulsion departure stage. NTP systems are presently under development by multiple government agencies. NASA’s Space Nuclear Propulsion (SNP) project aims to demonstrate a hydrogen-fed NTP engine at 900 s specific impulse (I_sp) and approximately 10-15 klb_f of thrust. DARPA’s Demonstration Rocket for Agile Cislunar Operations (DRACO) program is targeting a demonstration of an NTP system in the cislunar space between the Earth and the Moon. An appropriately phased development plan that applies the development of the reactor technology for an NTP engine in this performance class and leverages mature, existing liquid rocket component hardware provides a path to a lower cost propulsion system that can be realized on a shorter development schedule. NEP, with high Isp in the 2,000-8,000 s range, can also provide advantages over chemical propulsion, including a much greater payload delivery mass and the flexibility for planners to trade between delivered mass and a wider window of mission trajectory options. Electric propulsion (EP) systems have demonstrated great utility, performing notably on the Dawn mission to enable rendezvous and orbital insertion at two separate bodies, Vesta and Ceres. An NEP-powered vehicle would have a similar capability to visit multiple bodies, loitering at each before moving to the next. A 10 kW_e NEP system provides a power- rich environment on the spacecraft that is simply not possible using present radioisotope power systems, giving mission planners more scientific instrument and communication hardware options. Several programs and projects are presently developing NEP systems and subsystems in the 10 kW_e power range, leveraging past reactor work and recent nuclear power generation risk-reduction demonstration activities such as the Demonstration Using Flattop Fission (DUFF) and the Kilopower Reactor Using Stirling TechnologY (KRUSTY). The goal of the Air Force Research Laboratory’s Joint Energy Technology Supplying On-Orbit Nuclear Power (JETSON) program is an in-space demonstration vehicle that has a 10 kW_e -class fission power source. These past and present efforts can be combined with the ongoing development of 10 kW_e -class electric propulsion systems (notably the NEXT-C ion thruster or the Hall-effect thrusters for Power and Propulsion Element of the Lunar Gateway) to provide a pathway to a low-cost, reliable NEP system for deep space science application.

Kurt A. Polzin↗

Additive Manufacturing in the Nuclear Reactor Industry

This article discusses the application of additive manufacturing in the nuclear reactor industry.Additive manufacturing for nuclear applications increased significantly in the late 2010s due to rapid progress in technology, particularly with methods using metals and ceramics.Because these manufacturing technologies are uniquely data-rich, they allow for an advanced understanding of materials, and they offer the potential to predict part performance based on build data. The inherent characteristics of additive manufacturing technologies allow for rapid prototyping and geometric freedom, making it possible to implement an accelerated agile design process for advanced nuclear reactor applications. Predictive high-fidelity multiphysics simulations are crucial to fully leverage this geometric flexibility. Qualification and regulator acceptance ultimately determine the breadth and scope of applications for these technologies. The US Department of Energy Office of Nuclear Energy Transformational Challenge Reactor program integrates many of these elements to accelerate the deployment of additive manufacturing technologies to industry.

Betzler, Benjamin↗

NuTools: Exploring Practical Roles for Neutrinos in Nuclear Energy and Security

For decades, physicists have used neutrinos from nuclear reactors to advance basic science. These pursuits have inspired many ideas for application of neutrino detectors in nuclear energy and security. While developments in neutrino detectors are now making some of these ideas technically feasible, their value in the context of real needs and constraints has been unclear. This report seeks to help focus the picture of where neutrino technology may find practical roles in nuclear energy and security. This report is the final product of the Nu Tools study, commissioned in 2019 by the DOE National Nuclear Security Administration (NNSA) Office of Defense Nuclear Nonproliferation Research and Development (DNN R\&D). The study was conducted over two years by a group of neutrino physicists and nuclear engineers. A central theme of the study and this report is that useful application of neutrinos will depend not only on advancing physics and technology but also on understanding the needs and constraints of potential end-users.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Gas Turbine Energy Conversion Systems for Lunar and Planetary Nuclear Power Plants Including Ground Based Applications Using LiFTR "Liquid Fluoride Thorium Reactor" Technology

The background and motivation for this presentation is the Advanced Nuclear Power named in Energy Policy Act of 2005 (Gen IV Nuclear Systems Initiative), Thorium Energy Independence & Security Act of 2008 (S.3680), Gen IV Candidate Advanced Nuclear Power Plants, and high temperature gas turbine power plants offer large thermal efficiency improvement over steam plants.

Juhasz, Albert J.↗