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At least 199 records · Page 11

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NASA NTRS1976

Energy requirements of a biosphere

The question is considered of whether a biosphere similar to that on earth could exist in the region of the outer planets, where relatively little light is available for photosynthetic processes. The type of photosynthesis most abundant on earth is discussed along with light conversion in photosynthesis, the light-harvesting system in plants, photosynthetic efficiency, and carbon production in nature. The dynamic range of metabolic rates is examined, and photosynthesis in anaerobic organisms is described. It is suggested that organisms having very large photosynthetic pigment units would thrive in the light intensities prevailing on Titan and that the surface of Titan might well be able to maintain a biosphere driven by oxygen-generating photosynthesis.

Kok, B.↗

NASA NTRS1978

Measurement of total organic concentration in water

Instrument for determining total organic concentration in water uses no corrosive reagents or gases. Instead continuous ultraviolet photolysis process converts organic compounds to carbon dioxide (CO2). CO2 electrode is used to measure CO2 content. Only reagent necessary is oxygen, generated in situ by electrolyzing some water. In addition to application in aerospace industry, system has potential uses in pollution monitoring and in laboratory analyses.

Winkler, E.↗

NASA NTRS1980

The fate of the hydroxyl radical in the earth's primitive atmosphere and implications for the production of molecular oxygen

Behavior of the hydroxyl radical produced by the photolysis of water vapor in the earth's early atmosphere is examined. Because of the substantial OH radical reactivity with trace species (CO, HCl, SO2, H2S, NH3, and CH4) the formation of molecular oxygen may be prevented, even at a trace species mixing ratio. The photolysis rate of H2O, with corrections for hydrogen exospheric escape, is capable of describing the oxidation of the atmosphere and crust but may not be used to determine the rate of molecular oxygen generation without consideration of the various OH-trace species reactions.

Vander Wood, T. B.↗

NASA NTRS1980

Lightside Atmospheric Revitalization System

The system was studied as a replacement to the present baseline LiOH system for extended duration shuttle missions. The system consists of three subsystems: a solid amine water desorbed regenerable carbon dioxide removal system, a water vapor electrolysis oxygen generating system, and a Sabatier reactor carbon dioxide reduction system. The system is designed for use on a solar powered shuttle vehicle. The majority of the system's power requirements are utilized on the Sun side of each orbit, when solar power is available.

Colling, A. K.↗

NASA NTRS1980

Fractional capacity electrolyzer development for CO2 and H2O electrolysis

The electrolyzer module was designed to produce 0.24 kg/d (0.53 lb/d) of breathable oxygen from the electrolysis of metabolic carbon dioxide and water vapor. The fractional capacity electrolyzer module is constructed from three electrochemical tube cells and contains only three critical seals. The module design illustrated an 84 percent reduction in the total number of seals for a one person capacity oxygen generating system based on the solid electrolyte carbon dioxide and water vapor electrolysis concept. The electrolyzer module was successfully endurance tested for 71 days.

Wynveen, R. A.↗

NASA NTRS1981

Electrophotolysis oxidation system for measurement of organic concentration in water

Methods and apparatus for determining organic carbon in aqueous solution are described. The method comprises subjecting the aqueous solution to electrolysis, for generating oxygen from water, and simultaneously to ultraviolet radiation, for oxidation of substantially all organic carbon to carbon dioxide. The carbon dioxide is measured and the value is related to the concentration of organic carbon in the aqueous solution.

Winkler, H. E.↗

NASA NTRS1982

An integrated regenerative air revitalization system for spacecraft

Progress towards development of an air revitalization system (ARS) for spacecraft breathable atmosphere regeneration is assessed, and a preliminary design for a one-person ARS is described. The ARS is considered a necessary component of any permanently manned orbital station, and studies have demonstrated that penalties for expendable air supplies justify an ARS for missions longer than 40 days. CO2 must be removed and O2 returned along with N2, which can be extracted from hydrazine, with the H2 component returning to the operation of the CO2 reduction subsystem. An experimental ARS (ARX-1) features a cabin humidity control unit, a CO2 concentrator, an air-cooled CO2 reduction reactor, an oxygen generator (electrolysis), the hydrazine N2 generator, and a water handling unit. A 120-day test demonstrated one-button startup and 480 hr operation in a normal mode.

Noyes, G. P.↗

NASA NTRS1983

Advanced air revitalization system testing

A previously developed experimental air revitalization system was tested cyclically and parametrically. One-button startup without manual interventions; extension by 1350 hours of tests with the system; capability for varying process air carbon dioxide partial pressure and humidity and coolant source for simulation of realistic space vehicle interfaces; dynamic system performance response on the interaction of the electrochemical depolarized carbon dioxide concentrator, the Sabatier carbon dioxide reduction subsystem, and the static feed water electrolysis oxygen generation subsystem, the carbon dioxide concentrator module with unitized core technology for the liquid cooled cell; and a preliminary design for a regenerative air revitalization system for the space station are discussed.

Heppner, D. B.↗

NASA NTRS1984

Extended mission life support systems

The life support systems employed in manned space missions have generally been based on the use of expendables, such as, for instance, liquid oxygen. For the conducted space missions, such systems have advantages related to volume, weight, and economy of power consumption. However, this situation will change in connection with Shuttle Orbiter missions of extended duration, permanent manned facilities in low-earth orbit, and ultimately manned planetary vehicles. A description is given of suitable regenerative life support systems for such extended manned space missions. Attention is given to advanced life support systems technology, air revitalization, CO2 reduction, oxygen generation, nitrogen generation, trace contaminant control, air revitalization system integration, control/monitor instrumentation, water reclamation, solid waste management, manned testing and life support integration, an enhanced duration orbiter, a space operations center, manned interplanetary life support systems, and future development requirements.

Quattrone, P. D.↗

NASA NTRS1984

The development status of candidate life support technology for a space station

The establishment of a permanently-manned Space Station has recently been selected as the next major step in the U.S. space program. The requirements of a manned operations base in space appear to be best satisfied by on-board Environmental Control/Life Support Systems (ECLSS) which are free from, or have minimum dependence on, use of expendables and the frequent earth resupply missions which are part of systems using expendables. The present investigation is concerned with the range of regenerative life support system options which NASA is developing to be available for the Space Station designer. An air revitalization system is discussed, taking into account devices concerned with the carbon dioxide concentration, approaches of CO2 reduction, oxygen generation, trace contaminant control, and atmospheric quality monitoring. Attention is also given to an independent air revitalization system, nitrogen generation, a water reclamation system, a waste management system, applications of the technology, and future development requirements.

Samonski, F. H., Jr.↗

NASA NTRS1984

Environmental control/life support

It is pointed out that the life support systems technology used on projects Mercury, Gemini, Apollo, and Space Shuttle required an employment of expendables. Skylab was the only manned space project which made use of regenerable life support technology, taking into account the employment of a silica gel/molecular sieve for carbon dioxide removal. A number of investigations indicate that significant launch weight and volume as well as recurring cost savings can be realized by using regenerative life support processes for a Space Station. A number of developed regenerative processes are believed to be applicable to a Space Station. Aspects of air revitalization are discussed, taking into account carbon dioxide reduction, oxygen generation, trace contaminant control, temperature and humidity control, instrumentation, and nitrogen supply. Attention is also given to water reclamation, solid waste treatment, and future development and testing programs.

Quattrone, P. D.↗

NASA NTRS1986

Oxygen/hydrogen Space Station propulsion system concept definition for IOC

The potential for the reduction in propulsion system life cycle costs through the use of on-board water electrolysis to generate oxygen and hydrogen propellants, as well as the potential advantages of improved system safety and contamination impact, led to a study to evaluate candidate oxygen-/hydrogen-based propulsion systems. In this study a representative set of propulsion system requirements were compiled and candidate oxygen/hydrogen-based propulsion systems synthesized. These candidate concepts were screened and a systems evaluation was performed on the remaining eight candidate concepts. Detailed system schematics were prepared. Operational design conditions were determined and system weight, volume, energy requirements, and costs were calculated. Evaluation results indicated that the oxygen/hydrogen propulsion systems can provide simple, low cost, and viable systems for the IOC Space Station. Based on these data, a relative concept evaluation was conducted using as selection criteria reliability, safety, cost, technical risk, contamination, operational utility, growth potential, and integration potential. Top ranked candidate systems were recommended to NASA/MSFC for consideration for the IOC Space Station.

Shoji, J. M.↗

NASA NTRS1987

Electrochemical generation of useful chemical species from lunar materials

A high temperature electrolytic cell which simultaneously generates oxygen at the anode and liquid alkali metals at the cathode is electrochemically characterized. The electrolytic technology being investigated utilizes the oxygen vacancy conducting solid electrolyte, yttria stabilized zirconia, which effectively separates the oxygen evolving (at La0.89Sr0.10MnO3) and alkali metal (Li, Na) reducing (from a molten salt at either Pt or FeSi2) half cell reactions. In the finally engineered cell liquid alkali metal would be continuously removed from the cathode compartment and used as an effective reductant for the direct thermochemical refining of lunar ores to their metallic state with simultaneous oxidation of the alkali metal to its oxide. The alkali metal oxide would then be reintroduced into the electrolytic cell to complete the overall system cycle.

Sammells, Anthony F.↗

NASA NTRS1987

Performance evaluation of SPE electrolyzer for Space Station life support

An static water-vapor feed electrolyzer has been developed as a candidate for Space Station life-support oxygen generation. The five-cell electrolysis module has eliminated the need for phase separation devices, pumps, and deionizers by transporting only water vapor to the solid polymer electrolyte cells. The introduction of an innovative electrochemical hydrogen pump allows the use of low-pressure reclaimed water to generate gas pressures of up to 230 psia. The electrolyzer has been tested in a computer-controlled test stand featuring continuous, cyclic, and standby operation (including automatic shutdown with fault detection).

Erickson, A. C.↗

NASA NTRS1988

The electrochemical generation of useful chemical species from lunar materials

Sammells, Anthony F.↗

NASA NTRS1991

Monatomic-Oxygen Reactors For Materials Testing And Surface Chemistry

Two kinds of gas-flow reaction chambers expose specimens of materials to spatially even fluxes of monatomic oxygen. Monatomic oxygen diffuses along side-arm tubes attached to flowing-after-glow apparatus. If rate of diffusion high enough, specimens at ends of these tubes receive uniform doses. Monatomic oxygen generated by photolysis in pulsed laser beam diffuses sideways out of laser beam and onto nearby surfaces of specimens.

Koontz, Steve↗

NASA NTRS1991

Chemically Layered Porous Solids

Aerogels and other porous solids in which surfaces of pores have chemical properties varying with depth below macroscopic surfaces prepared by sequences of chemical treatments. Porous glass or silica bead treated to make two depth zones having different chemical properties. Beads dropped along tube filled with flowing gas containing atomic oxygen, generated in microwave discharge. General class of materials treatable include oxides of aluminum, silicon, zirconium, tin, titanium, and nickel, and mixtures of these oxides. Potential uses of treated materials include chromatographic separations, membrane separations, controlled releases of chemicals, and catalysis.

Koontz, Steve↗

NASA NTRS1991

Electrolytic production of oxygen from lunar resources

Oxygen is a valuable commodity in space. Substantial savings have been projected for future missions if oxygen could be produced on the moon from local resources. Some of the most promising approaches to extract oxygen from lunar resources involve electrochemical oxygen generation. In a straight-forward concept called "magma electrolysis", suitable oxides (silicates) are molten at 1300-1500 °C and the melt electrolyzed. Residual melt can be discarded after partial electrolysis. Alternatively, lunar soil may be dissolved in a molten salt and electrolyzed. In this approach, temperatures are lower and melt conductances higher, but electrolyte constituents need to be preserved. Both possibilities are being studied in the laboratory. In a different approach, ilmenite is reduced by hydrogen and the resulting water electrolyzed (Carbotek Process TM). Although know-how from terrestrial technology can be applied, the process task is unconventional and requires many innovative solutions. Time and effort needed for successful development should not be underestimated.

Rudolf Keller↗