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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
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NASA NTRS1987

Transport and photochemical modeling. Studies of atmospheric species

A program of research studies related to the photochemistry, radiative transfer, and dynamics of the stratosphere is described. Investigations were conducted in two broad areas: (1) studies of the stratospheric processes and their response to external perturbations, and (2) analysis of satellite measurements in conjunction with theoretical models. Contemporary one dimensional photochemical, radiative-convective model was used to assess the impact of perturbations such as solar flux variability, increases in atmospheric carbon dioxide, chlorofluoromethanes and other greenhouse gases. Data from satellite experiments such as LIMS and SBUV, were used along with theoretical models to develop a climatology of trace species in the stratosphere. The consistency of contemporary ozone photochemistry was examined in the light of LIMS data. Research work also includes analysis of stratospheric nitrogen dioxide distributions from different satellite experiments, investigation of the wintertime latitudinal gradients in NO2, estimation of the stratospheric odd nitrogen level and its variability, and studies related to the changes in ozone in the Antarctic, and mid latitude Southern Hemisphere.

Natarajan, M.↗
NASA NTRS1986

Photochemical damping of inertio-gravity waves

A simple model is developed for the coupling effect of radiative heating and ozone photochemistry on inertio-gravity waves in the region 16-70 km. It is found that the photochemical damping rate is the weighted sum of the rates caused by two individual processes. One, suggested by Craig and Ohring, involves the temperature dependence of ozone reaction rate coefficients; the other, suggested by Leovy, involves the vertical gradient of the ozone mixing ratio. The relative importance of these two processes depends on the ratio of dynamical and chemical relaxation times. Calculations show that the most important region for coupling is near 48 km where the total relaxation time is 8 days for equinox and 6 days for summer midlatitude.

Zhu, Xun↗
NASA NTRS1987

Chemical kinetics and photochemical data for use in stratospheric modeling evaluation Number 8

This is the eighth in a series of evaluated sets of rate constants and photochemical cross sections compiled by the NASA Panel for Data Evaluation. The primary application of the data is in the modeling of stratospheric processes, with particular emphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena. Copies of this evaluation are available from the Jet Propulsion Laboratory, Documentation Section, 111-116B, California Institute of Technology, Pasadena, California, 91109.

Demore, W. B.↗
NASA NTRS1988

A photochemical equilibrium model for ionospheric conductivity

A photochemical equilibrium model of the high-latitude ionosphere has been developed. This model provides densities of the ionospheric constituents, N2(+), O2(+), O(+), and NO(+), from 85 km to approximately 220 km. These densities are then used to calculate Pedersen and Hall conductivities. A comparison of the model results with Arecibo and Chatanika radar observations was made, covering periods of solar minimum and solar maximum. The comparison showed the model to predict ionospheric densities to within 50 percent and conductivities to within 40 percent in the illuminated portion of the ionosphere. In regions of electron precipitation, the model showed good agreement with measurements. Results of this study indicate the following: (1) ionospheric conductivity increases by a factor of about 1.6 from solar minimum to solar maximum conditions, (2) the portion of the ionosphere above 170 km can contribute as much as 40 percent during daylight and 80 percent during nighttime to the total height-integrated Pedersen conductivity, and (3) the ratio of the height-integrated Hall to Pedersen conductivities is approximately 1.1-1.3 for sunlit conditions; this is appreciably lower than the value of 2 found in previous studies. These and other factors indicate that, under certain conditions, the height-integrated Pedersen conductivity may be as much as 2-3 times larger than previously reported.

Rasmussen, C. E.↗
NASA NTRS1988

Photochemical and thermal evolution of interstellar/precometary ice analogs

The photochemical and thermal evolution of H2O-, CH3OH-, NH3-, and CO-containing ices whose relative proportions in mixture are consistent with those of interstellar ice are presently studied experimentally. The UV photolysis of these ice analogs invariably generates H2CO, CO2, CO, CH4, and HCO, largely through the photofragmentation of CH3OH. CO and CH4 leave the samples as warmup proceeds to 100 K; most of the parent ice molecules are found to have sublimed upon the reaching of 200 K, with only a mixture of more refractory substances remaining. A residue of CH2 groups remains even after warmup to 300 K.

Allamandola, L. J.↗
NASA NTRS1988

Cloud pumping in a one-dimensional photochemical model

Cloud pumping data based on tropical maritime updraft statistics are incorporated in a one-dimensional steady-state eddy diffusive photochemical model of the troposphere. It is suggested that regions with weaker convection, such as the midlatitudes, may also experience substantial effects from cloud pumping. The direct effects of cloud pumping on CO were found to be more significant than implied by sensitivity studies. The (CH3)2S profile computed with cloud pumping agrees well with previous data.

Costen, Robert C.↗
NASA NTRS1989

Comparison of parameterized nitric acid rainout rates using a coupled stochastic-photochemical tropospheric model

A major tropospheric loss of soluble species such as nitric acid results from scavenging by water droplets. Several theoretical formulations have been advanced which relate an effective time-independent loss rate for soluble species to statistical properties of precipitation such as the wet fraction and length of a precipitation cycle. In this paper, various 'effective' loss rates that have been proposed are compared with the results of detailed time-dependent model calculations carried out over a seasonal time scale. The model is a stochastic precipitation model coupled to a tropospheric photochemical model. The results of numerous time-dependent seasonal model runs are used to derive numerical values for the nitric acid residence time for several assumed sets of preciptation statistics. These values are then compared with the results obtained by utilizing theoretical 'effective' loss rates in time-independent models.

Stewart, Richard W.↗
NASA NTRS1989

Lagrangian photochemical modeling studies of the 1987 Antarctic spring vortex. I - Comparison with AAOE observations

Results from the Lagrangian photochemical model integrated along computed air parcel trajectories intersected by the ER-2 aircraft are presented and compared with AAOE observations. According to the model, the BrO observations made from the ER-2 within the dehydrated denitrified region are consistent with there being approximately 5 parts per trillion by volume of BrO(y) at 428 K in spring. Within the high ClO region, ozone destruction rates are expected to exceed 2 percent/d with approximately 80 percent due to the ClO dimer mechanism.

Jones, R. L.↗
NASA NTRS1990

Photochemical Degradation Of Organic-Solvent Fumes

Quality of air in laboratory or industrial ventilation airstream enhanced by proposed technique. Source of ultraviolet light placed in airstream to degrade fumes photochemically. If fumes acceptable in degraded form, no further processing needed.

Herzstock, James J.↗
NASA NTRS1989

An influence of solar activity on latitudinal distribution of atmospheric ozone and temperature in 2-D radiative-photochemical model

On the basis of the 2-D radiative-photochemical model of the ozone layer at heights 0 to 60 km in the Northern Hemisphere there are revealed and analyzed in detail the characteristic features of the season-altitude-latitude variations of ozone and temperature due to changes of the solar flux during the 11 year cycle, electron and proton precipitations.

Dyominov, I. G.↗
NASA NTRS1989

Upper limits on possible photochemical hazes on Pluto

The suggestion by Elliot et al., (1989) that a haze layer near the surface of Pluto may be photochemical in origin and similar to the aerosol hazes in the atmospheres of other outer solar system bodies is evaluated. The nature of hazes which may be produced in the Hubbard et al., (1989) atmosphere is explored as well. It is concluded that the very low pressure in Pluto's atmosphere requires an aerosol production rate equal to the total maximum methane photolysis rate expected at Pluto.

Stansberry, John A.↗
NASA NTRS1990

A photochemical model of ozone interference effects in laser detection of tropospheric OH

Laser-generated interference in the laser-induced fluorescence detection of tropospheric hydroxyl is addressed by a detailed photochemical model. This phenomenon arises through photolysis of ozone by the detection laser and subsequent reaction of O(1D) with H2O to form OH. The approach is direct time integration of the coupled differential equations describing the pertinent chemical reactions, collisional energy transfer, and photolytic and spectroscopic processes, including an assessment of limitations due to uncertainties in the input parameters. The goal is to use the model to quantitatively design OH detection methods so that the experimental results need not rely on such a model for interpretation. Previously reported measurements of tropospheric OH appear to have been contaminated by ozone interference effects and by optical saturation of the monitoring transition. However, suggested improvements can reduce the problem to interference levels below 200,000 OH molecules/cu cm, permitting measurements useful for testing theories of fast tropospheric photochemistry.

Smith, Gregory P.↗
NASA NTRS1991

Impact of interannual variability (1979-1986) of transport and temperature on ozone as computed using a two-dimensional photochemical model

Values of the monthly mean heating rates and the residual circulation characteristics were calculated using NMC data for temperature and the solar backscattered UV ozone for the period between 1979 and 1986. The results were used in a two-dimensional photochemical model in order to examine the effects of temperature and residual circulation on the interannual variability of ozone. It was found that the calculated total ozone was more sensitive to variations in interannual residual circulation than in the interannual temperature. The magnitude of the modeled ozone variability was found to be similar to the observed variability, but the observed and modeled year-to-year deviations were, for the most part, uncorrelated, due to the fact that the model did not account for most of the QBO forcing and for some of the observed tropospheric changes.

Jackman, Charles H.↗
NASA NTRS1991

Stratospheric photochemical studies with Atmospheric Trace Molecule Spectroscopy (ATMOS) measurements

The photochemical partitioning of stratospheric odd chlorine and odd nitrogen is examined utilizing diurnal model calculations and data from the ATMOS experiment. This experiment, conducted during April-May 1985, employed a solar occultation method to obtain vertical profiles of temperature and various other trace constituents at 30 deg N and 48 deg S latitudes. The ATMOS data set confirms the presence of N2O5 in the stratosphere; however, the observed mixing ratios at sunset are more than a factor of 2 less than the calculated values. It is shown that the conversion of N2O5 into HNO3 could take place in the presence of aerosol surfaces quickly enough to affect the N2O5 mixing ratio below 30 km. Inclusion of the heterogeneous reaction brings the calculated N2O5 profile below 30 km into closer agreement with the ATMOS data.

Natarajan, Murali↗
NASA NTRS1991

Linear stability of free planetary waves in the presence of radiative-photochemical feedbacks

The diabatic effects of Newtonian cooling and ozone-dynamics interaction on the linear stability of free planetary waves in the atmosphere have been studied using a simple beta-plane model. The model couples radiative transfer, ozone advection, and ozone photochemistry with the quasi-geostrophic dynamical circulation. An analytical expression is derived which demonstrates the following: (1) the influence of meridional ozone advection on wave growth or decay depends on the wave and basic state vertical structures; and (2) photochemically accelerated cooling, which predominates in the upper stratosphere, augments the Newtonian cooling rate and is stabilizing. Attention is also given to the 1D linear stability problem which is numerically solved for a Charney basic state and for zonal mean basic states. It is shown that ozone heating generated by ozone-dynamics interaction in the stratosphere can reduce (enhance) the damping rates due to Newtonian cooling by as much as 50 percent for planetary waves of large vertical scale and maximum amplitude in the stratosphere.

Nathan, Terrence R.↗
NASA NTRS1992

Photochemical model for NH3 in an early Martian atmosphere

A warm and wet climate scenario for early Mars has been explained by invoking a 5-bar CO2 atmosphere; however, Kasting has shown that CO2 will condense in the Martian atmosphere at these pressures. The formation of CO2 clouds will reduce the convection lapse rate and reduce the magnitude of the greenhouse effect. It is possible that additional greenhouse gases such as methane and ammonia were present in the early Mars atmosphere. We are using a one dimensional photochemical model to estimate the magnitude of the ammonia source required to maintain a given ammonia concentration in a dense CO2 atmosphere. Because CO2 is 2.5 times more efficient at Rayleigh scattering than Earth's N2 atmosphere, we anticipate increased scattering opacities and decreased photolytic destruction rates of ammonia on early Mars. The reduced gravity on Mars means that a 1 bar atmosphere will be approximately 3 times as thick as on Earth. It is possible that ammonia could have been shielded from photolysis by hydrocarbon aerosols which form as a product of methane photolysis.

Brown, L. L.↗
NASA NTRS1992

A three-dimensional axisymmetric photochemical flow model of the cometary 'inner' shock layer

Assuming the Newtonian thin layer approximation to describe the structure of the shock layer between the cometary 'ionopause' and the inner shock, a 3D axisymmetric photochemical flow model of this layer is constructed. While sources of ions in this layer are the flow across the inner shock and photoionization of neutrals within it, the sinks are the flow into the flanks and dissociative recombination, the latter being the dominant one. For Halley's comet at the time of the Giotto encounter, the calculated thickness of the layer is very small, typically about 100 km for expected values of the dissociative-recombination coefficient. This is not inconsistent with the observations. The lateral flow speed near the point of encounter (inbound) is about 0.9 km/s, while the sonic line is at an angle of about 50 deg to the sun-comet line. Testing the validity of this model will have to await a cometary rendezvous mission such as the proposed CRAF/Cassini mission.

Damas, M. C.↗
NASA NTRS1992

Chemical kinetics and photochemical data for use in stratospheric modeling

As part of a series of evaluated sets, rate constants and photochemical cross sections compiled by the NASA Panel for Data Evaluation are provided. The primary application of the data is in the modeling of stratospheric processes, with particular emphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena. Copies of this evaluation are available from the Jet Propulsion Laboratory.

Demore, W. B.↗