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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

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NASA NTRS1979

Synthesis of perfluoroalkylether oxadiazole elastomers

A method for the simultaneous chain extension and crosslinking of perfluoroalkylethers which yields a thermally stable perfluoroalkylether oxadiazole elastomer crosslinked by trifunctional perfluoroalkylether-1,3,5-triazine is reported. In the preparation, hydroxylamine crystals prepared from hydroxylamine hydrochloride to which sodium butoxide had been added is mixed with perfluoroalkylether dinitrile to obtain the monomer, as the nitrile is converted to amidoxime. Monomers are heated at 140 to 200 C to form poly(perfluoroalkylether oxadiazole) with a 1,2,4-oxadiazole structure by a step-growth polymerization reaction. Simultaneous chain extension and crosslinking are observed to occur when the purified monomer is heated directly and when the remaining nitrile in the monomer is allowed to react with excess ammonia to form the corresponding amidine, which is then heated. Weight loss studies show the thermal stability of the perfluoroalkylether elastomer to be generally better than fluorosilicone or polyester elastomers, especially in air, indicating its potential usefulness for high-performance elastomeric applications.

Rosser, R. W.↗

NASA NTRS1979

Wipe-rinse technique for quantitating microbial contamination on large surfaces

The evaluation of an improved wipe-rinse technique for the bioassay of large areas was undertaken due to inherent inadequacies in the cotton swab-rinse technique to which assay of spacecraft is currently restricted. Four types of contamination control cloths were initially tested. A polyester-bonded cloth (PBC) was selected for further evaluation because of its superior efficiency and handling characteristics. Results from comparative tests with PBC and cotton swabs on simulated spacecraft surfaces indicated a significantly higher recovery efficiency for the PBC than for the cotton (90.4 versus 75.2%). Of the sampling area sites studied, PBC was found to be most effective on surface areas not exceeding 0.74 sq m (8.0 sq ft).

Kirschner, L. E.↗

NASA NTRS1980

Grid polarizers for infrared Fourier spectrometers

Infrared grid polarizers consisting of copper lines with a 3.6-micron grid constant on a 4-micron-thick Mylar polyester substrate have been prepared by the techniques of photolithography and sputter-etching. Their polarization properties have been measured and found to be suitable for use at infrared frequencies below 700/cm. The polarizers have been used to extend the useful frequency range of a Martin-Puplett polarizing interferometer designed for Fourier transform spectroscopy. The efficiency of the interferometer has been measured over a frequency range from 50 to 700/cm and compared to that of a conventional Michelson interferometer. The results are shown to be consistent with the measured properties of the polarizers. Methods are suggested for improving the efficiency of a Martin-Puplett interferometer which employs these polarizers.

Challener, W. A.↗

NASA NTRS1981

Development of molded, coated fabric joints: Fabric construction criteria for a spacesuit elbow joint

The design and fabrication of a molded, coated fabric elbow joint capable of operating reliably at 8 psi internal pressure for extended periods of flexure is considered. The overall design of the joint includes: (1) selection of heatsettable fiber of sufficient strengths; (2) choosing an optimum fabric construction; (3) a fatigue resistant; flexible coating; and (4) a molding technique. A polyester yarn of type 56 Dacron and a urethane coating system were selected. The relationships between yarn and weave parameters which lead to an optimum fabric construction for the 8 psi elbow joint are defined.

Olson, L. H.↗

NASA NTRS1980

Spectroscopic determination of the in-situ composition of epoxy matrices in glass fiber reinforced composites

Computerized infrared analysis is applied to the characterization of a glass-reinforced crosslinked polyester. The method of factor analysis determines the number of independent components which constitute the polymeric matrix. Subsequently, the spectra of those components are fitted by a least-squares criterion to spectra of the multicomponent matrix, or, if the glass spectrum is included as an additional component, to the spectra of composites. The least-squares coefficients yield the matrix composition in terms of the initial reactant composition and the extent of crosslinking.

Antoon, M. K.↗

NASA NTRS1981

Quantitative broadband ultrasonic backscatter - An approach to nondestructive evaluation in acoustically inhomogeneous materials

The use of a broadband backscatter technique to obtain the frequency dependence of the longitudinal-wave ultrasonic backscatter coefficient from a collection of scatterers in a solid is investigated. Measurements of the backscatter coefficient were obtained over the range of ultrasonic wave vector magnitude-glass sphere radius product between 0.1 and 3.0 from model systems consisting of dilute suspensions of randomly distributed crown glass spheres in hardened polyester resin. The results of these measurements were in good agreement with theoretical prediction. Consequently, broadband measurements of the ultrasonic backscatter coefficient may represent a useful approach toward characterizing the physical properties of scatterers in intrinsically inhomogeneous materials such as composites, metals, and ceramics, and may represent an approach toward nondestructive evaluation of these materials.

Odonnell, M.↗

NASA NTRS1981

Spectroscopic determination of the in-situ composition of epoxy matrices in glass-fiber-reinforced composites

Antoon, M. K.↗

NASA NTRS1981

Incorporation of metal related materials into electrically neutral polymers

Developments in the field of metal-containing polymers are reviewed with emphasis on neutral polymers incorporating dissolved metal salts, metal complexes, organometallic compounds, and metals. Polymer systems discussed include: polyamides, polyimides, polyalcohols, polyesters, polyacetylene, polyethylene, and polysiloxane. Most of the studies focus on the modification of polymer properties such as adhesive properties, thermal behavior, electrical conductivity, polymer flammability, and mechanical properties.

St. Clair, A. K.↗

NASA NTRS1981

A conceptual design study of point focusing thin-film solar concentrators

Candidates for reflector panel design concepts, including materials and configurations, were identified. The large list of candidates was screened and reduced to the five most promising ones. Cost and technical factors were used in making the final choices for the panel conceptual design, which was a stiffened steel skin substrate with a bonded, acrylic overcoated, aluminized polyester film reflective surface. Computer simulations were run for the concentrator optics using the selected panel design, and experimentally determined specularity and reflectivity values. Intercept factor curves and energy to the aperture curves were produced. These curves indicate that surface errors of 2 mrad (milliradians) or less would be required to capture the desired energy for a Brayton cycle 816 C case. Two test panels were fabricated to demonstrate manufacturability and optically tested for surface error. Surface errors in the range of 1.75 mrad and 2.2 mrad were measured.

Source record↗

NASA NTRS1982

Toxicity of thermal degradation products of spacecraft materials

Three polymeric materials were evaluated for relative toxicity of their pyrolysis products to rats by inhalation: Y-7683 (LS 200), Y-7684 (Vonar 3 on Fiberglass), and Y-7685 (Vonar 3 on N W Polyester). Criteria employed for assessing relative toxicity were (1) lethality from in-chamber pyrolysis, (2) lethality from an outside-of-chamber pyrolysis MSTL Procedure, and (3) disruption of trained rats' shock-avoidance performance during sub-lethal exposures to in-chamber pyrolysis of the materials.

Lawrence, W. H.↗

NASA NTRS1981

Defect design of insulation systems for photovoltaic modules

A defect-design approach to sizing electrical insulation systems for terrestrial photovoltaic modules is presented. It consists of gathering voltage-breakdown statistics on various thicknesses of candidate insulation films where, for a designated voltage, module failure probabilities for enumerated thickness and number-of-layer film combinations are calculated. Cost analysis then selects the most economical insulation system. A manufacturing yield problem is solved to exemplify the technique. Results for unaged Mylar suggest using fewer layers of thicker films. Defect design incorporates effects of flaws in optimal insulation system selection, and obviates choosing a tolerable failure rate, since the optimization process accomplishes that. Exposure to weathering and voltage stress reduces the voltage-withstanding capability of module insulation films. Defect design, applied to aged polyester films, promises to yield reliable, cost-optimal insulation systems.

Mon, G. R.↗

NASA NTRS1982

Kinetics of the Humid Aging of Magnetic Recording Tape

The kinetics of the hydrolysis of polyester urethane binders of magnetic recording tape is described. Kinetic data were generated from measurements of acetone-extractable hydrolyzed binder products versus time for various humidity-temperature environments. These data can be described by a linear, single product, reversible rate equation. This equation, coupled with measurements on the effect of hydrolysis on recorded tape performance, is used to predict proper environmental storage conditions for magnetic tape.

Bertram, H. N.↗

NASA NTRS1983

Measuring Tension in Transistor Suspensions

Vibration analyis is nondestructive and noninvasive. Transistor isolated from heat (or cold) of surroundings by filament suspension. Filaments made of polyester are (0.005 in) 0.127 mm in diameter. Transistor lead wires are wrapped around certain filaments. Applicable for testing filament mounts too delicate for testing by tension probes.

Hubbard, W. P.↗

NASA NTRS1983

Light, Serviceable Insulation Blanket

Lightweight insulation blanket with aluminized, reinforced polyester facing resists crushing and weighs less than previous insulation blankets with textured stainless steel facing. New hook-and loop fasteners facilitate installation and removal. Useful in vehicle construction and other application in which low weight, easy removability for repairs, and long service life are important.

Swirsley, A. J.↗

NASA NTRS1982

Modelling of dimensional stability of fiber reinforced composite materials

Various methods of predicting the expansion and diffusion properties of composite laminates are reviewed. The prediction equations for continuous fiber composites can be applied to SMC composites as the effective fiber aspect ratio in the latter is large enough. The effect of hygrothermal expansion on the dimensional stability of composite laminates was demonstrated through the warping of unsymmetric graphite/epoxy laminates. The warping is very sensitive to the size of the panel, and to the moisture content which is in turn sensitive to the relative humidity in the environment. Thus, any long term creep test must be carried out in a humidity-controlled environment. Environmental effects in SMC composites and bulk polyester were studied under seven different environments. The SMC composites chosen are SMC-R25, SMC-R40, and SMC-R65.

Hahn, H. T.↗

NASA NTRS1983

Evaluation of high-contact-ratio spur gears with profile modification

Scoring tests, surface fatigue tests, and single-tooth bending fatigue tests were conducted with four sets of spur gears of standard design and three sets of spur gears of the new tooth form (NTF) design. Scoring tests were conducted in a gear test rig at a speed of 10,000 rpm using a synthetic polyester C5, C6, C7 substituted pentaerythritol oil. Surface fatigue tests were conducted in the same rig at a speed of 10,000 rpm and Hertz stresses of 173 x 10 to the 7th power and 143 x 10 to the 7th power Pa (250,000 and 214,000 psi). Single tooth bending fatigue tests were conducted on both the standard and NTF gears at an initial load that produced a 10.35 x 10 to the eight power Pa (150,000-psi) bending stress. The gears were load cycled to failure or for 3 x 10 to the 6th power cycles, whichever occurred first. The load was increased after test until failure occurred at 3 x 10 to the 6th power cycles or less. Both the standard and NTF gears scored at a gear bulk temperature of approximately 409 K (277 F). At this temperature the load on the NTF gears was 22 percent less than the load on the standard gears. The scoring failure was a function of gear bulk temperature, where for a given lubricant the temperature is a function of gear design, operating load, and speed.

Townsend, D. P.↗

NASA NTRS1982

A compliant, high failure strain, fibre-reinforced glass-matrix composite

A glass-matrix composite reinforced by discontinuous graphite fibers was produced by hot pressing glass-powder-impregnated two-dimensional arrays of in-plane randomly oriented graphite fibers held together by approximately 5-10% by weight of organic binder (generally polyester). The composite tensile behavior is characterized by a highly nonlinear stress-strain curve which differs markedly from that of either unreinforced glass or a similarly reinforced epoxy-matrix composite. By virtue of this nonlinearity, the composite is able to redistribute applied stresses to achieve a high load-carrying capacity. The fibrous microstructure and the low fiber-matrix bond provide a mechanism for achieving high fracture toughness and unusually high compliance. For a 96%-silica-matrix composite, the strength is retained to over 1000 C.

Prewo, K. M.↗

NASA NTRS1982

Progress report on the infrared astronomical satellite cryogenic system

The main cryogen tank is sized to hold 70 kg of superfluid helium with 12 percent ullage at a temperature of 1.8 K. The insulation system surrounds the main cryogen tank with four blankets of multilayer insulation spaced by means of three vapor-cooled shields. It is noted that the multilayer insulation is 6.4 micron double-aluminized Mylar separated by polyester net. The main shell provides the primary structural integrity of the system. In orbit the main shell is cooled to 170 K using insulation blankets on one side and second surface paint on the opposite side. The aperture cover subassembly is the vacuum seal for the main shell during operation on the ground. It is also a gas condensation trap before and during cooldown of the main cryogen tank during launch hold. It contains 6 kg of supercritical helium, which permits 14 days on orbit with a 48-hour launch pad hold.

Urbach, A. R.↗