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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Interoffice Memorandum RE-04-21 "Advanced Test Reactor Power History Through Cycle 169A-1"

Table 1 lists the Advanced Test Reactor (ATR) N-16 constrained power history data since the Beryllium VI Core Internals Changeout (CIC) Cycle 134A-1 through Cycle 169A-1. The powers tabulated for Cycles 159A-1, 163A-1, and 167A-1 are higher than powers observed during operation, because powers are computed from cycle exposure, which for these cycles includes operation during the low-power “soak” portion of each cycle; whereas cycle length in Effective Full Power Days (EFPD) includes only the high-power “casualty” portion occurring after NF is established. Table 2 lists the accumulated N-16 lobe and total core exposure, as obtained from the ATR Data Acquisition System (RDAS) for Cycles 134A-1 through 169A-1. Table 3 lists the startup and shutdown dates and times, as obtained from logbooks or RDAS, depending on availability. The ATR power history prior to Cycle 134A 1 is presented in references (a) through (d).

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Physics-Informed Deep Learning-Based Proof-of-Concept Study of a Novel Elastohydrodynamic Seal for Supercritical CO 2 Turbomachinery

Supercritical carbon dioxide (sCO 2 ) power cycles show promising potential of higher plant efficiencies and power densities for a wide range of power generation applications such as fossil fuel power plants, nuclear power production, solar power, and geothermal power generation. sCO 2 leakage through the turbomachinery has been one of the main concerns in such applications. To offer a potential solution, we propose an elastohydrodynamic (EHD) seal that can work at elevated pressures and temperatures with low leakage and minimal wear. The EHD seal has a very simple, sleeve-like structure, wrapping on the rotor with minimal initial clearance at micron levels. Here, in this work, a proof-of-concept study for the proposed EHD seal was presented by using the simplified Reynolds equation and Lame’s formula for the fluid flow in the clearance and for seal deformation, respectively. The set of nonlinear equations was solved by using both the conventional Prediction–Correction (PC) method and modern Physics-Informed Neural Network (PINN). It was shown that the physics-informed deep learning method provided good computational efficiency in resolving the steep pressure gradient in the clearance with good accuracy. The results showed that the leakage rates increased quadratically with working pressures and reached a steady-state at high-pressure values of 15~20 MPa, where Q = 300 g/s at 20 MPa for an initial seal clearance of 255 μm. This indicates that the EHD seal could be tailored to become a potential solution to minimize the sCO 2 discharge in power plants.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2023

Design of a Geothermal Power Plant With Solar Thermal Topping Cycle: Preprint

Geothermal power plants are a reliable source of low-carbon power generation. However, modern electricity markets comprise relatively large proportions of variable renewable energy generation that may require power plants to dispatch energy flexibly. The power output, efficiency, and dispatch flexibility of a geothermal plant can be enhanced by integrating solar thermal energy into the system, as well as possibly compensating against ambient temperature variations. Concentrating Solar Thermal (CST) can generate temperatures much higher than conventional geothermal systems. Using a solar topping cycle is one way to efficiently convert high-temperature solar heat to electricity while also adding lower-temperature heat to the geothermal power cycle, thereby increasing its power output and possibly its efficiency. A hybrid power cycle design is proposed and is simulated using SimTech IPSEpro process modelling software. The design configuration depends upon the expected temperature of the geothermal resource and the quantity of solar heat added at the design point. These design considerations are described and expected performance is calculated. The solar heat addition varies throughout the day and year, therefore off-design models are necessary to assess the impact of solar availability (and ambient temperature) on the power plant performance. Off-design models are developed and combined with hourly weather data to facilitate an evaluation of annual system performance.

concentrating solar power↗
DOE OSTI2021

Economic Analysis of an Electric Thermal Energy Storage System Using Solid Particles for Grid Electricity Storage

As renewable power generation becomes the mainstream new-built energy source, energy storage will become an indispensable need to complement the uncertainty of renewable resources to firm the power supply. When phasing out fossil-fuel power plants to meet the carbon neutral utility target in the midcentury around the world, large capacity of energy storage will be needed to provide reliable grid power. The renewable power integration with storage can support future carbon-free utility and has several significant impacts including increasing the value of renewable generation to the grid, improving the peak-load response, and balancing the electricity supply and demand. Long-duration energy storage (10–100 hours duration) can potentially complement the reduction of fossil-fuel baseload generation that otherwise would risk grid security when a large portion of grid power comes from variable renewable sources. Current energy storage methods based on pumped storage hydropower or batteries have many limitations. Thermal energy storage (TES) has unique advantages in scale and siting flexibility to provide grid-scale storage capacity. A particle-based TES system has promising cost and performance for the future growing energy storage needs. This paper introduces the system and components required for the particle TES to be technically and economically competitive. A technoeconomic analysis based on preliminary component designs and performance shows that the particle TES integrated with an efficient air-Brayton combined cycle power system can provide power for several days by low-cost, high-performance storage cycles. It addresses grid storage needs by enabling large-scale grid integration of intermittent renewables like wind and solar, thereby increasing their grid value. The design specifications and cost estimations of major components in a commercial scale system are presented in this paper. The cost model provides insights for further development and cost comparison with competing technologies.

27 ARPA - Advanced Research Projects Agency-Energy↗
DOE OSTI2021

Economic Analysis of a Novel Thermal Energy Storage System Using Solid Particles for Grid Electricity Storage: Preprint

As renewable power generation becomes the mainstream new-built energy source, energy storage will become an indispensable need to complement the uncertainty of renewable resources to firm the power supply. When phasing out fossil-fuel power plants to meet the carbon neutral utility target in the midcentury around the world, large capacity of energy storage will be needed to provide reliable grid power. The integration of renewable power and storage to support future carbon-free utility has several significant and positive impacts including expanding the renewable generation into the grid, improving the peak-load response, and balancing the electricity supply and demand. Long-duration energy storage (10–100 hours duration) can potentially complement the reduction of fossil-fuel baseload generation that otherwise would risk grid security when a large portion of grid power comes from variable renewable sources. Current energy storage methods based on pumped storage hydropower or batteries have many limitations. Thermal energy storage (TES) has unique advantages in scale and siting flexibility to provide grid-scale storage capacity. A particle-based TES system has promising cost and performance for the future growing energy storage needs. This paper introduces the system and components required for the particle TES to be technically and economically competitive. A technoeconomic analysis based on preliminary component designs and performance shows that the particle TES integrated with an efficient air-Brayton combined cycle power system can provide power for several days by low-cost, high-performance storage cycles. It addresses grid storage needs by enabling large-scale grid integration of intermittent renewables like wind and solar, thereby increasing their grid value. The design specifications and cost estimations of major components in a commercial scale system are presented in this paper. The cost model provides insights for further development and cost comparison with competing technologies.

27 ARPA - Advanced Research Projects Agency-Energy↗
DOE OSTI2023

Internal carburization and scale formation on austenitic steels in supercritical carbon dioxide

Direct-fired supercritical CO 2 (sCO 2 ) power cycles are being commercialised to revolutionise fossil energy as a low-emission power source. In order to lower the cost of this technology, less expensive steels are needed in the lower temperature segments of the cycle. However, there are concerns about internal carburisation of steels in sCO 2 . A consistent observation is that thin, Cr-rich oxides appear to reduce C ingress compared to thick Fe-rich oxides formed on 9–12% Cr ferritic-martensitic steels. Advanced austenitic stainless steels (SS) like alloy 709 (20Cr-25Ni) are able to continue to form Cr-rich oxides at 650°C, while a conventional type 316 H SS formed a Fe-rich scale. The C diffusion profiles in SS specimens were quantified at 550°C–650°C using glow discharge optical emission spectroscopy and electron probe microanalysis. Analytical transmission electron microscopy was used to compare the thin protective Cr-rich oxide formed on alloy 709 in sCO 2 at 650°C to that formed in ambient air.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Design of a 2 MW ZrC/W-based molten-salt-to-sCO 2 PCHE for concentrated solar power

To increase the power cycle efficiency and lower the levelized cost of electricity (LCOE) of concentrated solar power (CSP) plants, printed circuit heat exchangers (PCHEs) capable of operating above 700 °C with molten chloride salt and a sCO 2 -based fluid are needed. In this paper, the design of a high-pressure, high-temperature, 2 MW PCHE comprised of a thermomechanically-robust, zirconium carbide/tungsten (ZrC/W) composite is conducted for CSP plants. The ZrC/W composite is a material with high thermal conductivity, high stiffness, and high failure strength at high temperatures, along with excellent resistance to thermal cycling and thermal shock. In this work, a thermomechanical design analysis was conducted to select appropriate material thicknesses of the ZrC/W plates, and to determine the geometrical dimensions and the thermal performance of the PCHE. The influences of the plate number and heat exchanger length on power density and pressure drop have also been systematically investigated. Economic analyses were conducted to compare the cost of ZrC/W-based PCHEs to those comprised of IN740H (a state-of-the-art, nickel-based superalloy) and 316 stainless steel (316SS). Finally, at a sufficiently high plate production rate, the manufacturing cost of ZrC/W-based PCHEs can be significantly lower, while achieving a much higher power density, compared with state-of-the-art, nickel alloy-based and stainless steel-based PCHEs.

14 SOLAR ENERGY↗
DOE OSTI2023

Sub-two-cycle gigawatt-peak-power LWIR OPA for ultrafast nonlinear spectroscopy of condensed state materials

The application of high-power, few-cycle, long-wave infrared (LWIR, 8–20 µm) pulses in strong-field physics is largely unexplored due to the lack of suitable sources. However, the generation of intense pulses with >6 µm wavelength range is becoming increasingly feasible with the recent advances in high-power ultrashort lasers in the middle-infrared range that can serve as a pump for optical parametric amplifiers (OPA). Here we experimentally demonstrate the feasibility of this approach by building an OPA pumped at 2.4 µm that generates 93 µJ pulses at 9.5 µm, 1 kHz repetition rate with sub-two-cycle pulse duration, 1.6 GW peak power, and excellent beam quality. The results open a wide range of applications in attosecond physics (especially for studies of condensed phase samples), remote sensing, and biophotonics.

Leshchenko, Vyacheslav (ORCID:0000000199708559)↗
DOE OSTI2023

Performance Test Code for Determining and Reporting Annual Heat Rate and CO2 for Coal Fueled EGUs

This material is based upon work supported by the Department of Energy under Award Number DEFE0031933. The US Department of Energy (DOE) has retained the services of ASME Standards Technology LLC (ASME ST-LLC) to develop a standardized test method and calculation protocol for determining and reporting annual/long-term heat rate for coal-fueled plants electricity generating units. ASME ST-LLC has retained the services of McHale & Associates, Inc. and Licata Energy & Environmental Consultants, Inc. to provide the technical input to this study. This code applies to hydrocarbon fueled Rankine cycle power generating facilities of any size. It is intended to be used for the determination of continuous power output and heat rate of a generating facility in its operating load cycle and in its operational lineup during the reporting period.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2021

Dynamic Simulation of a Sub-Critical Coal Fired Power Plant

In order to address the demanding operating conditions for remaining coal-fired power plants, a dynamic model and a suite of tools have been developed for studying load cycling and to find optimization opportunities. A sub-critical steam cycle power plant was modeled in a flow-sheet modeling tool, APROS™. The model represented the firing system, economizer, evaporator, superheat, and reheat systems. Four loads from 100% TMCR to 25% TMCR were calibrated and tested such that low-to-high cycling could be studied. The model was run through various load cycles; one of which is presented here. This modeling is a prototype for general use in developing cutting edge controls products and for maximizing economic, low-emissions, and efficient operation of the existing coal power fleet.

Braun, Timothy↗
DOE OSTI2023

Liquid Air Combined Cycle TM for Power and Storage

Liquid Air Combined Cycle (LACC) is a hybrid liquid air energy storage (LAES) system combining energy storage with a combustion turbine to enable large-scale, long-duration energy storage (LDES) while reducing fuel intensity compared to the current state-of-the-art. The LACC technical approach employs proven equipment (cryogenic refrigeration, storage, tanks, pumps, gas turbines, exhaust heat recovery equipment, and turbines) to limit technical risk to a novel organic Rankine cycle (ORC), which was evaluated during this project and found to be feasible. Moreover, LACC storage is safe and relatively compact, to facilitate siting close to loads and within metropolitan regions. The air storage medium is freely available and eliminates supply chain constraints. LACC uses cryogenic air as a storage medium and a gas turbine as the source of heat to drive the discharge process. LACC is distinguished from other LAES technologies by several factors. The charge and discharge processes are decoupled so that cryogenic liquid air is the only storage medium. Other systems also store the higher temperature thermal energy from the liquefaction process in an additional medium. Subsequently, LACC focuses on maximization of the discharge energy and power. LACC also permits the use of commercially available cryogenic refrigeration and storage technologies to increase competition. This project identified product requirements to support market entry and commercialization of the LACC in modular units of approximately 117 MW, each drawing liquid air from customary cryogenic storage tanks capable of storing 75 GWh of dispatchable energy, more than pumped storage hydro or compressed air energy storage technologies. An economic analysis identified the specific liquid air consumption (quantity of liquid air per unit of discharge energy) as a critical parameter. Minimizing the air consumption reduces the specific capital cost ($\$ $/kW) for charging and discharging equipment by reducing the size of piping and turbomachinery. Likewise, the specific cost of energy capacity ($\$ $/kWh) is reduced by increasing the energy deliverable from a given size tank. The cycle was analyzed to identify the optimal equipment selection and operating conditions, which in turn were combined with quotes and cost estimates to calculate the cost of energy from an LACC system. A substantial effort was focused on the ORC, which draws low-temperature heat from the gas turbine exhaust and condenses at low temperature using the cryogenic liquid air as a heat sink. Alternative turbomachinery arrangements were evaluated for feasibility and cost. A technology maturation plan lays out a low-risk approach to development of the novel ORC components and demonstration of LACC technology at pilot scale.

25 ENERGY STORAGE↗
DOE OSTI2024

High energy density picoliter-scale zinc-air microbatteries for colloidal robotics

The recent interest in microscopic autonomous systems, including microrobots, colloidal state machines, and smart dust, has created a need for microscale energy storage and harvesting. However, macroscopic materials for energy storage have noted incompatibilities with microfabrication techniques, creating substantial challenges to realizing microscale energy systems. Here, we photolithographically patterned a microscale zinc/platinum/SU-8 system to generate the highest energy density microbattery at the picoliter (10 −12 liter) scale. The device scavenges ambient or solution-dissolved oxygen for a zinc oxidation reaction, achieving an energy density ranging from 760 to 1070 watt-hours per liter at scales below 100 micrometers lateral and 2 micrometers thickness in size. The parallel nature of photolithography processes allows 10,000 devices per wafer to be released into solution as colloids with energy stored on board. Within a volume of only 2 picoliters each, these primary microbatteries can deliver open circuit voltages of 1.05 ± 0.12 volts, with total energies ranging from 5.5 ± 0.3 to 7.7 ± 1.0 microjoules and a maximum power near 2.7 nanowatts. We demonstrated that such systems can reliably power a micrometer-sized memristor circuit, providing access to nonvolatile memory. We also cycled power to drive the reversible bending of microscale bimorph actuators at 0.05 hertz for mechanical functions of colloidal robots. Additional capabilities, such as powering two distinct nanosensor types and a clock circuit, were also demonstrated. The high energy density, low volume, and simple configuration promise the mass fabrication and adoption of such picoliter zinc-air batteries for micrometer-scale, colloidal robotics with autonomous functions.

Robotics↗
DOE OSTI2025

Integrate Power Conversion Unit with MAGNET to Enable Integrated Microreactor Heat Transfer System Testing

Idaho National Laboratory obtained a closed, Brayton-cycle, power conversion unit (PCU) from Sandia National Laboratories. This PCU began as a commercially available, 30 kWe, C30, gas turbine from Capstone. The C30 was modified to use heat from an electric heater in a closed-loop system pressurized with nitrogen or dry air. INL has modified the unit further to integrate it with MAGNET and use heat from a microreactor test article.

42 - ENGINEERING↗
DOE OSTI2021

Effect of High Temperature CO 2 on Haynes 230 Alloy (Updated Jan 2021)

The supercritical carbon dioxide (sCO 2 ) Brayton cycle is a promising candidate for future nuclear reactors due to its ability to improve power cycle energy conversion efficiency. The sCO 2 Brayton cycle can operate with an efficiency of 45-50% at operating temperatures of 550-700 C. One of the greatest hurdles currently faced by sCO 2 Brayton cycles is the corrosivity of sCO 2 and the lack of long-term alloy corrosion and mechanical performance data, as these will be key to enhancing the longevity of the system, and thus the levelized cost of electricity. Past studies have shown that sCO 2 corrosion occurs through the formation of metal carbonates, oxide layers, and carburization, and alloys with Cr, Mo and Ni generally exhibit less corrosion. While stainless steels may offer sufficient corrosion resistance at the lower range of temperatures seen by the sCO 2 Brayton cycles, more expensive nickel-based alloys are typically needed for the higher temperature regions. This study investigates the effects of corrosion on the Haynes 230 alloy, with a preliminary view on changes in the mechanical properties. High temperature CO 2 is used for this study as the corrosion products are similar to that of supercritical CO 2 , allowing for an estimation of the susceptibility towards corrosion without the need for high pressure experimentation.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Techno-Economic Performance of Eavor Loop 2.0

This project evaluated techno-economic performance for a sample Eavor-Loop 2.0 design for electricity production and direct-use heating. The Eavor-Loop 2.0 design investigated is a 7.5-km deep closed-loop geothermal system consisting of 12 laterals for a total of more than 90 km of downhole well and lateral length. Both a high geothermal gradient scenario of 60 degrees C/km and a low geothermal gradient scenario of 30 degrees C/km were considered. With pure water injected at 60 degrees C and 80 kg/s, reservoir simulations with the Slender-Body Theory simulator indicate average production temperatures over a 30-year lifetime of ~125 degrees C and ~210 degrees C for the low and high geothermal gradient scenario, respectively. These correspond to heat production of ~22 M Wth and ~51 M Wth, respectively. Using IPSEpro simulations, we find average power production of ~2.2 M We and ~8.6 M We, respectively, for a subcritical organic Rankine cycle power plant with air-cooled condensers. Cost estimates indicate the overall capital and levelized costs are dominated by the lateral drilling cost. Obtaining a levelized cost of electricity below $70/M Wh requires a geothermal gradient of 60 degrees C/km, a discount rate below 9%, and lateral drilling cost below $400/m. A well cost model indicates that ~$400/m for the Eavor-Loop 2.0 design investigated can be obtained for a drilling rate of penetration about 40 ft/hr (with bit life of 50 hours), and omitting casing and cement. Traditional (geothermal) well drilling has achieved these drilling rate conditions, including the Utah FORGE project where the rate of penetration has exceeded 50 ft/hr in granite. However, it is unclear if these conditions are still valid for drilling the Eavor-Loop 2.0 laterals (i.e., ~82 km of laterals at 4 to 7.5-km vertical depth with rock temperatures up to 460 degrees C), as such downhole completion has never been developed before. Competitive levelized cost of heat values ($1.2-$8.2/GJ) are calculated, even for the low geothermal gradient scenario (30 degrees C/km) and lateral drilling cost of $600/m.

advanced geothermal system↗
DOE OSTI2021

Pulse Detonation Engine for Advanced Oxy-Combustion of Coal-Based Fuel for Direct Power Extraction Applications

Pressure gain combustion and magnetohydrodynamic (MHD) systems have the potential to provide a step increase in the efficiency of combined-cycle power plants. Specific advantages include a net pressure increase to the system instead of a pressure drop, the high temperature of the detonation waves can increase the efficiency of power extraction compared to other processes, significant thermal energy can be released in a compact region, and the high velocities of the flow increase extraction of electrical power. In summary, a pressure gain combustor coupled with a MHD has the potential to be transformative. Despite the potential advantages, relatively little research has been conducted considering coupled pressure gain combustion systems with MHD systems. With this background and motivation, the overall goal of this effort was to advance the knowledge, technology, and computational tools associated with coupled detonation and MHD systems. A joint experimental and computational approach was used while seeking to accomplish the goals of this work. Specifically, two pulse detonation engines were developed and used for the experiments to produce detonations. Detonation speeds were measured for a variety of flow and fuel conditions (e.g., methane, propane, with coal particles). Preliminary electrical conductivity measurements were collected. An extensive amount of research was performed to identify sensitivities of detonation behaviors to the presence of combustion products. Computationally, a twofold approach was used in this work. First, a solver was developed for solving the governing equations for a reactive flow with coupled detonation and ionization chemistry. The solver was applied to study the impacts of seed material ionization on detonation. Second, a conservation element-solution element (CE-SE) based numerical solver for detonation studies with a reduced reaction mechanism for oxy-methane combustion was developed and verified on standard test cases. Key findings and contributions from this work are as follows. A system was developed for injecting powderized coal, or other seeding material, into a pulse-detonation system. The influence of a combustion product (i.e., CO 2 ) on detonation behavior was identified. Knowledge gained from this work is applicable to devices such as rotating detonation engines, where combustion products mix with fresh reactants. A system for measuring the electrical conductivity of the exhaust from a pulse-detonation engine was developed. The open-source solver, Clawpack, was extended to solve the reactive Euler equations for simulating detonations. A coupled combustion and ionization chemistry was developed in a single chemical kinetic model for methane oxidation. This model can be used to solve coupled MHD and detonation simulations. It was found that parasitic interactions from ionization chemistry with the magnetic field can reduce the detonation velocity by up to 8%, with a potential impact on power extraction of 15%. It is recommended that interactions between the detonation front and MHD field be considered. Higher gas temperatures and velocities were achieved owing to oxy-fuel detonations. Use of radical dissociation reactions in the reduced reaction mechanism, was found to be critical in predicting detonation temperature and velocity accurately.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2020

Steady-state off-design modeling of the supercritical carbon dioxide recompression cycle for concentrating solar power applications with two-tank sensible-heat storage

Concentrating solar power researchers are evaluating the potential of the supercritical carbon dioxide recompression cycle to improve the thermal efficiency and decrease the capital costs of next-generation systems. This analysis investigates the steady-state off-design performance of a recompression cycle integrated with two-tank sensible-heat thermal energy storage as the ambient temperature and heat-transfer fluid (HTF) inlet conditions to the cycle change. This paper presents off-design component models and then cycle convergence and control models to maximize net cycle power output while constraining the high-side pressure and air-cooler fan power to their respective design values and fixing the cycle HTF outlet temperature to its design value. Results show that inventory control and air-cooler fan power are important control parameters that can be optimized to maximize off-design power output as the ambient temperature and HTF mass flow rate diverge from design. The high-side pressure and fan power constraints cause the cycle net power to degrade when the ambient temperature is warmer than the design value, and this study calculates a maximum mass flow rate for hot days above which the cycle cannot achieve the design HTF outlet temperature. Finally, the analysis shows that optimizing compressor shaft speeds can improve cold-day performance by around 1.5 percentage points and part-load performance by up to 2.5 percentage points versus a baseline case with no active compressor control.

14 SOLAR ENERGY↗
DOE OSTI2021

Conventional Rib Turbulators For SCO 2 Turbine Internal Cooling (Report)

This report documents experimental work in the NETL Heat Exchange and Experimental Testing (HEET) rig. The heat transfer performance of additively manufactured internal cooling features in supercritical CO 2 were characterized. It was demonstrated that the thermal performance factor of conventional angled rib turbulators remains independent of Reynolds number up to 3.1 x 10 5 indicating that these features may be employed to enhance heat transfer in sCO 2 turbine blades and vanes. This augmentation of heat transfer in the internal cooling passages decreases the required turbine coolant and improves the power cycle efficiency.

20 FOSSIL-FUELED POWER PLANTS↗