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At least 199 records · Page 11

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NASA NTRS1983

Improved fabrication techniques for infrared bolometers

Techniques are described for producing improved infrared bolometers from doped germanium. Ion implantation and sputter metalization have been used to make ohmic electrical contacts to Ge:Ga chips. This method results in a high yield of small monolithic bolometers with very little low-frequency noise. When one of these chips is used as the thermometric element of a composite bolometer, it must be bonded to a dielectric substrate. The thermal resistance of the conventional epoxy bond has been measured and found to be undesirably large. A procedure for soldering the chip to a metalized portion of the substrate is described which reduced this resistance. The contribution of the metal film absorber to the heat capacity of a composite bolometer has been measured. The heat capacity of a NiCr absorber at 1.3 K can dominate the bolometer performance. A Bi absorber has significantly lower heat capacity. A low temperature blackbody calibrator has been built to measure the optical responsivity of bolometers. A composite bolometer system with a throughput of approx. 0.1 sr sq cm was constructed using the new techniques. In negligible background it has an optical NEP of 3.6 10((exp -15) W/sq root of Hz at 1.0 K with a time constant of 20 ms. The noise in this bolometer is white above 2.5 Hz and is somewhat below the value predicted by thermodynamic equilibrium theory. It is in agreement with calculations based on a recent nonequilibrium theory.

Lange, A. E.↗

NASA NTRS1993

Petrography, mineralogy, and Mg isotope composition of VICTA: A vigarano CaAl4O7-bearing type A inclusion

Thermodynamic calculations predict that Ca-dialuminate (CaAl4O7) condenses from a cooling gas of solar composition after hibonite and before melilite. Although Ca-dialuminate has now been recorded from Ca Al-rich inclusions (CAI's) in at least 9 meteorites, compared to hibonite it is a relatively rare phase. As pointed out by Michel-Levy et al., the absence of Ca-dialuminate from most hibonite-bearing inclusions poses a serious problem for the condensation model of CAI formation. Here we describe an inclusion which contains abundant CA-dialuminate partially altered to a hercynite-rich (FeAl2O4) assemblage. The evidence from VICTA indicates that compared to all other phases in type A inclusions, Ca-dialuminate is the most susceptible to secondary alteration; a feature which may explain its restricted occurrence. Unaltered Ca-dialuminate and melilite in VICTA display excess Mg-26 indicative of in situ decay of Al-26.

Greenwood, R. C.↗

NASA NTRS1993

Discovery Venera surface: Atmosphere geochemistry experiments mission concept

The phenomenal increase in our understanding of Venus provided by the Magellan Mission has raised a series of focused, fundamental scientific questions about the geochemistry of the surface of Venus, the nature of the lower atmosphere, and the relationship of the lower atmosphere and surface. First, surface geochemical measurements from the Venera/Vega spacecraft showed that widely spaced regions of the venusian plains are made of basalts; thus basalts are significant and may be the only component of the venusian crust. But we lack information on the composition of several key elements of Venus geology: (1) Tessera terrain (which may be outcrops of continental-like non-basaltic crustal material) and steep-sided domes/festoons are promising candidates for non-basaltic geochemically evolved material. The composition of the lower part of the Venusian crust is unknown: however, ejecta from large venusian craters provides us with the possibility of sampling this material on the surface; (2) bulk chemistry (structure and dynamics) of the venusian atmosphere are known. The altitude profiles of water vapor content and minor admixtures relevant to redox conditions in the lower atmosphere (less than 20 km altitude) remain uncertain. Lack of that knowledge means that we do not understand the fine chemical structure of the main mass of the Venusian atmosphere; and (3) thermodynamic models predict that igneous materials on the surface of Venus should react with gases of the venusian atmosphere. But because the water vapor content and redox conditions in the lower atmosphere are not well known, we do not understand the nature of venusian weathering: oxidation, sulfatization, carbonatization, and hydration. The answers to these questions are critical to the understanding of Venus, the most Earth-like of the terrestrial planets.

Surkov, Yuri A.↗

NASA NTRS1994

Troilite formation kinetics and growth mechanism in the solar nebula

Troilite formation via the reaction Fe(s) + H2S(g) + H2(g) is the major mechanism for S retention in grains in the solar nebula. Thermodynamic calculations predict that troilite condenses from a solar composition gas. We present experimental results on the kinetics and growth of troilite crystals on Fe metal at temperature (450-650 C) and composition (50-1000 ppm H2S in H2) conditions similar to those in the solar nebula. The fraction of Fe reacted (based on gravimetric data) is plotted at 450, 505, 575, and 650 C. The thickness change of unreacted iron (measured by optical microscopy) is plotted at 575 and 650 C vs. time. the weight change per unit area varies as the square root of time at the lower temperatures and varies linearly with time at the highest temperature. The growth behavior along the lower isotherms is due to diffusion. This behavior suggests sulfide diffusion to the metal-sulfide interface and suggests Fe(2+) diffusion to the sulfide-gas interface. The reaction along the highest isotherm appears to be interface controlled. The formation of troilite crystals is a rapid process forming measurable layers in a few hours. The crystalgrowth is complicated. Initially there are intergrowths of troilite into the pure Fe metal. As the reaction progresses two distinct layers of troilite crystals form. One is in contact with the Fe metal and consists of small randomly oriented crystals with pore space between them. The outermost layer contains large crystals that are all oriented in the same direction. The intergrowth layer is much smaller at 650 C than at 575 C. This suggest that FeS nucleation is inhibited at the higher temperature, accounting for the initially slower reaction rate. Once nucleated, the reaction kinetics are apparently controlled by the growth of the crystals at the interface.

Lauretta, D. S.↗

NASA NTRS2002

Power System for Venus Surface Exploration

A radioisotope power and cooling system is designed to provide electrical power for a probe operating on the surface of Venus. Most foreseeable electronics devices and sensors cannot operate at the 450 C ambient surface temperature of Venus. Because the mission duration is substantially long and the use of thermal mass to maintain an operable temperature range is likely impractical, some type of active refrigeration may be required to keep electronic components at a temperature below ambient. The fundamental cooling parameters are the cold sink temperature, the hot sink temperature, and the amount of heat to be removed. In this instance, it is anticipated that electronics would have a nominal operating temperature of 300 C. Due to the highly thermal convective nature of the high-density (90 bar CO2) atmosphere, the hot sink temperature was assumed to be 50 C, which provided a 500 C temperature of the cooler's heat rejecter to the ambient atmosphere. The majority of the heat load on the cooler is from the high temperature ambient surface environment on Venus, with a small contribution of heat generation from electronics and sensors. Both thermoelectric (RTG) and dynamic power conversion systems were analyzed, based on use of a standard isotope (General-purpose heat source, or GPHS) brick. For the radioisotope Stirling power converter configuration designed, the Sage model predicts a thermodynamic power output capacity of 478.1 watts, which slightly exceeds the required 469.1 watts. The hot sink temperature is 1200 C, and the cold sink temperature is 500 C. The required heat input is 1740 watts. This gives a thermodynamic efficiency of 27.48 %. It is estimated that the mechanical efficiency of the power converter design is on the order of 85 %, based on experimental measurements taken from 500-watt power class, laboratory-tested Stirling engines. The overall efficiency is calculated to be 23.36 %. The mass of the power converter is estimated at approximately 21.6 kg. Additional information is included in the original extended abstract.

Landis, Geoffrey A.↗

NASA NTRS2004

Venus Surface Power and Cooling System Design

A radioisotope power and cooling system is designed to provide electrical power for the a probe operating on the surface of Venus. Most foreseeable electronics devices and sensors simply cannot operate at the 450 C ambient surface temperature of Venus. Because the mission duration is substantially long and the use of thermal mass to maintain an operable temperature range is likely impractical, some type of active refrigeration may be required to keep certain components at a temperature below ambient. The fundamental cooling requirements are comprised of the cold sink temperature, the hot sink temperature, and the amount of heat to be removed. In this instance, it is anticipated that electronics would have a nominal operating temperature of 300 C. Due to the highly thermal convective nature of the high-density atmosphere, the hot sink temperature was assumed to be 50 C, which provided a 500 C temperature of the cooler's heat rejecter to the ambient atmosphere. The majority of the heat load on the cooler is from the high temperature ambient surface environment on Venus. Assuming 5 cm radial thickness of ceramic blanket insulation, the ambient heat load was estimated at approximately 77 watts. With an estimated quantity of 10 watts of heat generation from electronics and sensors, and to accommodate some level of uncertainty, the total heat load requirement was rounded up to an even 100 watts. For the radioisotope Stirling power converter configuration designed, the Sage model predicts a thermodynamic power output capacity of 478.1 watts, which slightly exceeds the required 469.1 watts. The hot sink temperature is 1200 C, and the cold sink temperature is 500 C. The required heat input is 1740 watts. This gives a thermodynamic efficiency of 27.48 %. The maximum theoretically obtainable efficiency is 47.52 %. It is estimated that the mechanical efficiency of the power converter design is on the order of 85 %, based on experimental measurements taken from 500 watt power class, laboratory-tested Stirling engines at GRC. The overall efficiency is calculated to be 23.36 %. The mass of the power converter is estimated at approximately 21.6 kg.

Landis, Geoffrey A.↗

NASA NTRS2019

Complex Intergrowths of Non-Stoichiometric Defect-Structured Hibonite and Al-Rich Spinel in an Allende Ca-Al-Rich Inclusion

Hibonite is a primary ultra-refractory mineral occurring in many Ca-Al-rich inclusions (CAIs) and is predicted to condense as the second major phase from a cooling gas of solar composition. Our previous microstructural studies of hibonite in carbonaceous chondrites revealed its unique microstructures consisting of numerous defects that contain Mg-enriched, wider spinel blocks in stoichiometric hibonite. Han, J. et al. [2 items] demonstrated experimentally that defect-structured hibonites can grow easily in the presence of minor Mg and are kinetically more stable than equilibrium assemblages predicted by thermodynamic calculations. However, a thermo-dynamic vs. structural stability of defect-structured hibonite relative to other early-condensed Al-rich phases such as corundum, grossite, and spinel remains poorly constrained. Here, we present the results of atomic resolution TEM (Transmission Electron Microscopy) imaging of hibonite in a compact Type A CAI in the Allende CV3 chondrite in order to better understand the crystal structure and chemistry of defect-structured hibonite and its associated Al-rich phases, especially non-stoichiometric, Al-rich spinel, in the context of the formation of first refractory solids in the early solar nebula.

Han, J.↗

NASA NTRS2020

Mineralogy and Petrology of Fine-Grained Calcium-Aluminum-Rich Inclusions from the Reduced CV3 Chondrite Thiel Mountains 07007

Calcium-Aluminum-rich inclusions (CAIs) are among the oldest Solar System solids, and studies of these objects have played an essential role in developing an understanding of chemical and physical processes that initiated and characterized key events related to the Solar System’s formation and evolution. CAIs occur as μm- to cm-sized inclusions in chondritic meteorites, particularly in carbonaceous chondrites, and consist of various refractory silicate and oxide phases (e.g., melilite, spinel, Al-Ti-rich diopside, hibonite, and corundum) that are predicted by thermodynamic models to be among the first solids to con-dense from a cooling gas of solar composition. Fine grained CAIs (FGIs) are important samples to probe volatility-driven condensation processes in the solar nebula, because they have escaped thermal processes (e.g., melting) experienced by coarse-grained CAIs. In order to explore the primary nebular history of FGIs, a detailed mineralogical and petrologic study is necessary. In this research effort, we constrained the mineralogy and petrology of two CAIs 07-10 and -11 from the reduced CV3 chondrite Thiel Mountains (TIL) 07007, with the aim of evaluating their provenance as nebular condensates.

Anderkin, C. J.↗

NASA NTRSDate not supplied

Hybrid NEP-Chemical Vehicle and Propulsion Technology Study for Crewed Mars Missions

Nuclear Electric Propulsion (NEP) is a suite of technologies with the potential to enable crewed opposition-class missions to Mars. Each subsystem comprising an NEP system has multiple technology options that present tradeoffs in vehicle sizing and technology development risk. Multiple vehicle concepts have been studied in the past and are currently being studied at NASA. Three models have been developed to illustrate the impact of key technology parameters on overall sizing for a crewed Mars transportation vehicle. Vehicle mass required to close the mission as a function of NEP system alpha (kWe/kg) and specific impulse (Isp) is estimated with a detailed trajectory model. A power system mass model estimates alpha as a function of power and radiator mass assumption. A power conversion system thermodynamic model predicts the radiator area required to close a Brayton cycle power conversion system. Combined with the architecture mass required for mission closure, the radiator area and alpha model provide insight into how technology development may impact the mission. Our focus is on parametric sweeps of the whole design space rather than any particular point design. Results from the mission model comparing electric propulsion technology (Hall, Ion, Magnetoplasmadynamic) and both 2039 and 2042 opposition-class mission launch windows are included. The results of the study illustrate the technology parameters that can result in mission closure and illustrate where the architecture is sensitive to variations in technology performance or requirements.

Matthew Duchek↗

NASA NTRS2021

The Effect of Transfer Line Length and Heat Rejection Temperature Distribution on the Thales Linear Pulse Tube (LPT) Cryocoolers

Four Thales LPT9310 and four Thales LPT9510 commercial off-the-shelf (COTS) cryocoolers were parametrically performance tested. The LPT9310 coolers had transfer lines of various lengths while the LPT9510 coolers all had the same transfer line geometry. The LPT9510 test results revealed unit-tounit thermodynamic performance variation, quantified the effect of compressor temperature on thermodynamic performance and quantified the heat flow distribution between the compressor and expander as a function of their temperature distribution. The LPT9310 test results revealed the optimal drive frequency as a function of transfer line length, quantified the effect of heat rejection temperature distribution on thermodynamic performance and enabled the development and verification of a thermodynamic performance prediction tool that accounted for cold tip temperature, heat lift, heat rejection temperature and transfer line length.

Rodriguez, J.I.↗

NASA NTRSDate not supplied

Evaluating GXS Impact in the Context of International Coordination

The proposed NOAA/NASA Geostationary eXtended Observations (GeoXO) program plans to include a hyperspectral infrared (IR) sounder on its central satellite. Expected to launch in the mid-2030s, the GeoXO Sounder (GXS) will join international counterparts in a geostationary orbit. Ahead of launch, the NASA Global Modeling and Assimilation Office (GMAO) assessed the potential effectiveness of GXS both as a single GEO IR sounder and as part of a global ring of such instruments, including those already being built by international agencies. Using an observing system simulation experiment (OSSE) framework, GXS was assessed from a global numerical weather prediction (NWP) perspective. The ability of GXS, both alone and as part of a global ring of GEO sounders, to improve weather prediction of thermodynamic variables was evaluated globally and regionally. Compared to a control, GXS dominated regional analysis and forecast improvements, and contributed significantly to global increases in forecast skill. However, more sustained global improvements on the order of 4 days rely on international partnerships. Using the FSOI metric over CONUS, the GXS observations provide the strongest radiance impact on the moist energy error norm reduction. Additionally, GXS shows the capability to improve hurricane forecast track errors, resulting in improved forecast warnings. Overall, the persistent atmospheric profile information from GXS over much of the western hemisphere provide an opportunity to improve the representation of weather systems and their forecasts.

Erica McGrath-Spangler↗

NASA NTRSDate not supplied

Evaluating the Impact of Geostationary Sounders in the Context of International Coordination

The proposed NOAA/NASA Geostationary eXtended Observations (GeoXO) program plans to include a hyperspectral infrared (IR) sounder (GXS) on its central satellite, joining international counterparts. Ahead of launch, the NASA Global Modeling and Assimilation Office (GMAO) assessed the potential effectiveness of GXS both as a lone sounder in a GEO orbit and as part of a global ring of such instruments. Using an observing system simulation experiment (OSSE) framework from a global numerical weather prediction (NWP) perspective, the ability of GXS and the global ring to improve weather prediction of thermodynamic variables was assessed both globally and regionally. GXS dominated regional analysis and forecast improvements and contributed significantly to global increases in forecast skill. However, more sustained global improvements on the order of 4 days rely on international partnerships. Over CONUS, the FSOI metric showed the GXS observations provide the strongest radiance impact on the moist energy error norm reduction. Additionally, GXS shows the capability to improve hurricane forecast track errors, resulting in improved forecast warnings. Overall, the persistent atmospheric profile information from GXS over much of the western hemisphere provide an opportunity to improve the representation of weather systems and their forecasts.

Erica L. McGrath-Spangler↗

NASA NTRSDate not supplied

Investigating Fifth Oxide Effect on CMXAS Glass Properties

Coatings for hot section aero turbine engine structural materials are subject to thermochemical degradation after interacting with calcium-magnesium-aluminosilicates (CMAS). Molten CMAS viscosity is the primary glass property of importance, correlating with coating infiltration and reaction depth. CMAS viscosity was measured using a spindle-dipped viscometer at temperatures between 1300-1550°C in 25°C increments. Experimental data were compared to Thermo-Calc and FactSage computational models, which showed good agreement with experimental trends. CMXAS compositions, where X denotes a fifth oxide, of Ca30.75-Mg9-X5-Al13-Si42.25 (single cation oxide mol%) for X = Fe2+, Fe3+, Gd3+, Hf4+, Na1+, Ti4+, Y3+, Yb3+, Zr4+ additions were used. Oxide precipitation was observed in X = Hf4+ , Zr4+ CMXAS specimens, indicating coating dissolution is an increased threat for T ≥ 1390°C. Molten CMAS and CMXAS viscosity measurements were shown to correlate with net cation field strength, offering an alternative in property prediction where thermodynamic data are unavailable.

Clark Avery Luckhardt↗

NASA NTRSDate not supplied

Evaluating the Impact of Geostationary Sounders in the Context of International Coordination

Erica McGrath-Spangler↗

NASA NTRSDate not supplied

Evaluating GXS Impact in the Context of International Coordination

Erica McGrath-Spangler↗

DOE OSTI2022

Increasing the Thermodynamic Driving Force of the Phosphofructokinase Reaction in Clostridium thermocellum

Glycolysis is an ancient, widespread, and highly conserved metabolic pathway that converts glucose into pyruvate. In the canonical pathway, the phosphofructokinase (PFK) reaction plays an important role in controlling flux through the pathway. Clostridium thermocellum has an atypical glycolysis and uses pyrophosphate (PP i ) instead of ATP as the phosphate donor for the PFK reaction. The reduced thermodynamic driving force of the PP i -PFK reaction shifts the entire pathway closer to thermodynamic equilibrium, which has been predicted to limit product titers. Here, in this study, we replace the PP i -PFK reaction with an ATP-PFK reaction. We demonstrate that the local changes are consistent with thermodynamic predictions: the ratio of fructose 1,6-bisphosphate to fructose-6-phosphate increases, and the reverse flux through the reaction (determined by 13 C labeling) decreases. The final titer and distribution of fermentation products, however, do not change, demonstrating that the thermodynamic constraints of the PP i -PFK reaction are not the sole factor limiting product titer.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2022

Homologous Alkali Metal Copper Rare-Earth Chalcogenides A 2 Cu 2 n Ln 4 Q 7+ n ( n = 1, 2, 3)

Twenty-seven new members of the A 2 Cu 2n Ln 4 Q 7+n (A = Cs, Rb; Ln = La-Nd, Sm, Gd-Yb; Q = S, Se) homologous series were synthesized in one of three structural types (indicated by n = 1, 2, 3). All the compounds contained 3D frameworks with alkali-metal-containing tunnels. For each increment in n, one Cu 2 Q was added, which was incorporated into the framework as an edge-sharing tetrahedron by replacing a square planar chalcogenide site. High-throughput DFT calculations predicted many of the phases to be thermodynamically stable. These predictions were compared with the synthesis results for the phases formed in each composition space. In the syntheses, heavier lanthanides showed a preference to start forming the n = 3 ACu 3 Ln 2 Q 5 , which is consistent with the predictions. RbCuNd 2 Se 4 and RbCuTb 2 Se 4 were found to be thermally stable under vacuum at temperatures up to 1000 °C. Optical measurements revealed band gaps of 1.55(5) and 1.62(5) eV for CsCuCe 2 Se 4 and RbCuTb 2 Se 4 , respectively, and a work function of 4.83(5) eV for CsCuPr 2 Se 4 . Additionally, some n = 3 ACu 3 Ln 2 Qs compounds exhibit a negative phonon mode because of a copper atom coordination, which may distort to a trigonal planar geometry at sufficiently low temperatures. The dynamic instabilities and the predicted distortion in the copper tetrahedra for the n = 3 ACu 3 Ln 2 Q 5 compounds were found to have a linear relationship with the atomic number of the lanthanides and the electronegativity of the lanthanides. In conclusion, the A 2 Cu 2 n Ln 4 Q 7+n compounds can potentially find application as high-temperature thermoelectric materials and other semiconductors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Development of Transformational Solvents for CO2 Separations

The primary objective of this CRADA activity is to use a combined molecular modeling and experimental validation approach to refine and develop transformational solvents for carbon capture. PNNL’s role on this project is currently funded by the Department of Energy’s (DOE) Office of Fossil Energy (OFE). PNNL is developing advanced molecular modeling based on their CO2BOLs solvent platform as a demonstration solvent for the activity; the model was developed and compared against measured data for CO2BOL derivatives. Here, a CRADA with PNNL and GE will leverage their current molecular models and apply them to solvent classes that operate on carbamate chemistry, specifically GE’s aminosilicone solvent class. The molecular models will be used to predict physical and thermodynamic properties, such as viscosity, as a means to predict advanced formulations with reduced viscosity compared to current aminosilicone derivatives, enabling optimized thermodynamic and kinetic metrics for economical carbon capture for this class of materials. Together, PNNL and GE will develop a comprehensive means of linking molecular modeling parameters to intermediate physical properties as a means to improve solvent performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗