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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

ElectroCat: Platinum-Group-Metal-Free Engineered Framework Nano-Structure Catalyst (Final Technical Report)

Traditional synthesis methodologies that produce durable, highly active PGM-free electrocatalysts typically consist of a top-down approach utilizing a nitrogen-coordinating precursor, a metal precursor, and a support material. Nitrogen-coordinated transition metal complexes typically are absorbed onto a support material, which is then activated via high-temperature pyrolysis. Selection of the support and the nitrogen coordinating precursor has long been the focal point of efforts to maximize the number of accessible, catalytically active sites. In this project, GWE in collaboration with SRNL and NU will develop durable, highly active, low-cost, PGM-free electrocatalysts for polymer electrolyte membrane fuel cells designed and synthesized using a unique, bottom-up, rationally designed approach. Electrocatalysts are produced via polymerization reaction followed by a high-temperature pyrolysis step. Additionally, this project focuses on catalyst site and ORR mechanistic modeling to better understand the structure-property relationship.

08 HYDROGEN↗
NASA NTRS2002

SHEEP: The Search for the High Energy Extragalactic Population

We present the SHEEP survey for serendipitously-detected hard X-ray sources in ASCA GIS images. In a survey area of approx. 40 sq deg, 69 sources were detected in the 5-10 keV band to a limiting flux of approx. 10(exp -13) erg/sq cm/s. The number counts agree with those obtained by the similar BeppoSAX HELLAS survey, and both are in close agreement with ASCA and BeppoSAX 2-10 keV surveys. Spectral analysis of the SHEEP sample reveals that the 2-10 and 5-10 keV surveys do not sample the same populations, however, as we find considerably harder spectra, with an average Gamma approx. 1.0 assuming no absorption. The implication is that the agreement in the number counts is coincidental, with the 5-10 keV surveys gaining approximately as many hard sources as they lose soft ones, when compared to the 2-10 keV surveys. This is hard to reconcile with standard AGN "population synthesis" models for the X-ray background, which posit the existence of a large population of absorbed sources. We find no evidence of the population hardening at faint fluxes, with the exception that the few very brightest objects are anomalously soft. 53 of the SHEEP sources have been covered by ROSAT in the pointed phase. Of these 32 were detected. An additional 3 were detected in the RASS. As expected the sources detected with ROSAT are systematically softer than those detected with ASCA alone, and of the sample as a whole. Although they represent a biased subsample, the ROSAT positions allow relatively secure catalog identifications to be made. We find associations with a wide variety of AGN and a few clusters and groups. At least two X-ray sources identified with high-z QSOs present very hard X-ray spectra indicative of absorption, despite the presence of broad optical lines. A possible explanation for this is that we are seeing relatively dust-free "warm absorbers" in high luminosity/redshift objects. Our analysis defines a new, hard X-ray selected sample of objects - mostly active galactic nuclei - which is less prone to bias due to obscuration than previous optical or soft X-ray samples. They are therefore more representative of the population of AGN in the universe in general, and the SHEEP survey should produce bright examples of the sources that make up the hard X-ray background, the majority of which has recently been resolved by Chandra. This should help elucidate the nature of the new populations.

Nandra, K.↗
NASA NTRS2008

Multi-terrain Vertical Drop Tests of a Composite Fuselage Section

A 5-ft-diameter composite fuselage section was retrofitted with four identical blocks of deployable honeycomb energy absorber and crash tested on two different surfaces: soft soil, and water. The drop tests were conducted at the 70-ft. drop tower at the Landing and Impact Research (LandIR) Facility of NASA Langley. Water drop tests were performed into a 15-ft-diameter pool of water that was approximately 42-in. deep. For the soft soil impact, a 15-ft-square container filled with fine-sifted, unpacked sand was located beneath the drop tower. All drop tests were vertical with a nominally flat attitude with respect to the impact surface. The measured impact velocities were 37.4, and 24.7-fps for soft soil and water, respectively. A fuselage section without energy absorbers was also drop tested onto water to provide a datum for comparison with the test, which included energy absorbers. In order to facilitate this type of comparison and to ensure fuselage survivability for the no-energy-absorber case, the velocity of the water impact tests was restricted to 25-fps nominal. While all tests described in this paper were limited to vertical impact velocities, the implications and design challenges of utilizing external energy absorbers during combined forward and vertical impact velocities are discussed. The design, testing and selection of a honeycomb cover, which was required in soft surface and water impacts to transmit the load into the honeycomb cell walls, is also presented.

Sotirios, Kellas↗
NASA NTRS2008

Multi-Terrain Vertical Drop Tests of a Composite Fuselage Section

A 5-ft-diameter composite fuselage section was retrofitted with four identical blocks of deployable honeycomb energy absorber and crash tested on two different surfaces: soft soil, and water. The drop tests were conducted at the 70-ft. drop tower at the Landing and Impact Research (LandIR) Facility of NASA Langley. Water drop tests were performed into a 15-ft-diameter pool of water that was approximately 42-in. deep. For the soft soil impact, a 15-ft-square container filled with fine-sifted, unpacked sand was located beneath the drop tower. All drop tests were vertical with a nominally flat attitude with respect to the impact surface. The measured impact velocities were 37.4, and 24.7-fps for soft soil and water, respectively. A fuselage section without energy absorbers was also drop tested onto water to provide a datum for comparison with the test, which included energy absorbers. In order to facilitate this type of comparison and to ensure fuselage survivability for the no-energy-absorber case, the velocity of the water impact tests was restricted to 25-fps nominal. While all tests described in this paper were limited to vertical impact velocities, the implications and design challenges of utilizing external energy absorbers during combined forward and vertical impact velocities are discussed. The design, testing and selection of a honeycomb cover, which was required in soft surface and water impacts to transmit the load into the honeycomb cell walls, is also presented.

Kellas, Sotiris↗
NASA NTRS2022

Inferring iron-oxide species content in atmospheric mineral dust from DSCOVR EPIC observations

The iron-oxide content of dust in the atmosphere and most notably its apportionment between hematite (α-Fe2O3) and goethite (α-FeOOH) are key determinants in quantifying dust’s light absorption, its top of atmosphere UV radiances used for dust monitoring, and ultimately shortwave dust direct radiative effects (DRE). Hematite and goethite column mass concentrations and iron-oxide mass fractions of total dust mass concentration were retrieved from the DeepSpace Climate Observatory (DSCOVR) Earth Polychromatic Imaging Camera (EPIC) measurements in the ultraviolet–visible (UV–Vis) channels. The retrievals were performed for dust-identified aerosol plumes over land using aerosol optical depth (AOD) and spectral imaginary refractive index provided by the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm over six continental regions (North America, North Africa, West Asia, Central Asia, EastAsia, and Australia). The dust particles are represented as an internal mixture of non-absorbing host and absorbing hematite and goethite. We use the Maxwell–Garnett effective medium approximation with carefully selected complex refractive indices of hematite and goethite that produce mass fractions of iron oxides species consistent with in situ values found in the literature to derive the hematite and goethite volumetric/mass concentrations from MAIAC EPIC products. We compared the retrieved hematite and goethite concentrations with in situ dust aerosol mineralogical content measurements, as well as with published data. Our data display variations within the published range of hematite, goethite, and iron-oxide mass fractions for pure mineral dust cases. A specific analysis is presented for 15 sites over the main dust source regions. Sites in the central Sahara, Sahel, and Middle East exhibit a greater temporal variability of iron oxides relative to other sites. Niger site(13.52°N, 2.63°E) is dominated by goethite over Harmattan season with median of ~2 weight percentage (wt.%) of iron-oxide. Saudi Arabia site (27.49°N, 41.98°E) over Middle East also exhibited surge of goethite content with the beginning of Shamal season. The Sahel dust is richer in iron-oxide than Saharan and northern China dust except in Summer. The Bodélé Depression area shows a distinctively lower iron-oxide concentration (~1 wt.%) throughout the year. Finally, we show that EPIC data allow to constrain the hematite refractive index. Specifically, we select 5 out of 13 different number of hematite refractive indices widely variable in published laboratory studies by constraining the iron-oxide mass ratio to the known measured values. Provided climatology of hematite and goethite mass fractions across main dust regions of the Earth will be useful for dust shortwave DRE studies and climate modeling.

Sujung Go↗
DOE OSTI2022

Search for Higgs Portal Scalars and Heavy Neutral Leptons Decaying in the MicroBooNE Detector

This thesis presents a search for Higgs Portal Scalars (HPS) and Heavy Neutral Leptons (HNL) decaying in the MicroBooNE liquid argon time projection chamber (LArTPC). The measurement was performed using data collected in-time with the Neutrino at the Main Injector (NuMI) beam with a total exposure corresponding to 7.01x10^20 protons on target. Mono-energetic HPS and HNL would be produced from kaons decaying at rest in the NuMI hadron absorber, before travelling ~100 m to the MicroBooNE detector where they decay. A single selection and search strategy is used to target decays of HPS to muon-muon pairs and HNL to muon-pion pairs. The results are expressed as limits, at the 90% confidence level, on the mixing angles that control the rates of production and decay for each new particle. For the HNL model, upper limits are set on the mixing parameter |U\mu4|^2 in the range [12.9 x 10^-8, 0.54 x 10^-8] for HNL with masses in the region 246 - 385 MeV. For the HPS model, limits on the scalar-Higgs mixing angle \theta^2 are set, excluding a region with a lower boundary between [31.3 x 10^-9, 1.09 x 10^-9] and an upper boundary between [2.50 x 10^-5, 5.05 x 10^-9] for scalars with a mass of 212-275 MeV. These results set the first constraints in this region of parameter space from a dedicated experimental search for HPS.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2002

Optical Properties of Thin Film Molecular Mixtures

Thin films composed of molecular mixtures of metal and dielectric are being considered for use as solar selective coatings for a variety of space power applications. By controlling the degree of molecular mixing, the solar selective coatings can be tailored to have the combined properties of high solar absorptance, alpha, and low infrared emittance, epsilon. On orbit, these combined properties would simultaneously maximize the amount of solar energy captured by the coating and minimize the amount of thermal energy radiated. Mini-satellites equipped with solar collectors coated with these cermet coatings may utilize the captured heat energy to power a heat engine to generate electricity, or to power a thermal bus that directs heat to remote regions of the spacecraft. Early work in this area identified the theoretical boundary conditions needed to operate a Carnot cycle in space, including the need for a solar concentrator, a solar selective coating at the heat inlet of the engine, and a radiator. A solar concentrator that can concentrate sunlight by a factor of 100 is ideal. At lower values, the temperature of the solar absorbing surface becomes too low for efficient heat engine operation, and at higher values, cavity type heat receivers become attractive. In designing the solar selective coating, the wavelength region yielding high solar absorptance must be separated from the wavelength region yielding low infrared emittance by establishing a sharp transition in optical properties. In particular, a sharp transition in reflectance is desired in the infrared to achieve the desired optical performance. For a heat engine operating at 450C, a sharp transition at 1.8 micrometers is desired. The radiator completes the heat flow through the Carnot cycle. Additional work has been done supporting the use of molecular mixtures for terrestrial applications. Sputter deposition provides a means to apply coatings to the tubes that carry a working fluid at the focus of trough-style collectors. Sputtering offers considerable flexibility in coating conditions, including a wide variety of metal and dielectric targets. Coating designs range from simple two or three layer coatings to complex coatings that are purposely graded to be metal-rich at their base and oxide-rich at their surface in order to yield the desired solar selective properties. In these cermet coatings, molecular islands of metal are thought to be embedded in a three dimensional matrix of dielectric. Recent work has identified the use of custom made ion beam sputter deposition targets to produce coatings containing molecular mixtures of metal and dielectric. The targets are cylindrical and the surface consists of a gradually changing composition of metal and dielectric. Rotating the cylinder under the beam during ion beam sputter deposition yields a coating that is a molecular mixture of metal and dielectric, with the composition changing through the thickness of the coating. The optical properties of these coatings are not only dependent on their thickness and chemical composition, but are also dependent on the extent of the through thickness gradient established during deposition. This paper presents a summary of the optical properties of several thin film molecular mixtures designed as solar selective coatings. Optical performance is first identified as a function of wavelength, from the ultraviolet to the visible and infrared. Coating composition, thickness, and gradient from metal to dielectric also play an important role. Additional work for future activities is also identified.

Jaworske, Donald A.↗
NASA NTRS2003

Optical Properties of Thin Film Molecular Mixtures

Thin films composed of molecular mixtures of metal and dielectric are being considered for use as solar selective coatings for a variety of space power applications. By controlling the degree of molecular mixing, the solar selective coatings can be tailored to have the combined properties of high solar absorptance, , and low infrared emittance, . On orbit, these combined properties would simultaneously maximize the amount of solar energy captured by the coating and minimize the amount of thermal energy radiated. Mini-satellites equipped with solar collectors coated with these cermet coatings may utilize the captured heat energy to power a heat engine to generate electricity, or to power a thermal bus that directs heat to remote regions of the spacecraft. Early work in this area identified the theoretical boundary conditions needed to operate a Carnot cycle in space, including the need for a solar concentrator, a solar selective coating at the heat inlet of the engine, and a radiator.1 A solar concentrator that can concentrate sunlight by a factor of 100 is ideal. At lower values, the temperature of the solar absorbing surface becomes too low for efficient heat engine operation, and at higher values, cavity type heat receivers become attractive. In designing the solar selective coating, the wavelength region yielding high solar absorptance must be separated from the wavelength region yielding low infrared emittance by establishing a sharp transition in optical properties. In particular, a sharp transition in reflectance is desired in the infrared to achieve the desired optical performance. For a heat engine operating at 450 C, a sharp transition at 1.8 micrometers is desired.2 The radiator completes the heat flow through the Carnot cycle.

Jaworske, Donald A.↗
DOE OSTI2021

Solar cell contacts: quantifying the impact of interfacial layers on selectivity, recombination, charge transfer, and V oc

Interfacial layers (IFLs) are ubiquitous in solar cells, but their precise impact on carrier transfer rates and the relation of these rates to performance metrics and the concepts of selectivity and recombination is lacking. We report the use of a well-defined interdigitated back-contact (IBC) silicon solar cell to determine the precise role of such IFLs. We characterize the action of the common IFL spiro-OMeTAD by making it a third contact to the IBC cell. This architecture creates three solar cells within a single structure that, with numerical simulation, provide the exchange current densities (i.e., charge transfer rates) for electrons ( J 0n ) and holes ( J 0p ) and the quasi Fermi-level splitting in the absorber, which measures the balance of generation and recombination. Further, we describe the relation of V oc to contact recombination, the asymmetry in electron/hole collection rates at a single contact (contact selectivity), and the asymmetry in collection rates of the same carrier at separate contacts (carrier selectivity). Relative to bare gold, neat spiro-OMeTAD reduces J 0n and J 0p (their geometric mean ( J 0n J 0p ) 0.5 decreases by 10 4 ), decreasing contact recombination. Addition of the common dopant Li-TFSI and air increase J 0p / J 0n by 10 6 with little effect on ( J 0n J 0p ) 0.5 , increasing contact hole selectivity. The significant increase in V oc observed by introducing spiro-OMeTAD/Li-TFSI IFLs into the cells studied, however, is due to an increase in the carrier selectivity rather than the contact selectivity or recombination of the spiro-OMeTAD-modified contact. Operando measurements further show voltage-dependent changes in the J 0 s, demonstrating that spiro-OMeTAD contributes to hysteresis. Broader context : Solar cells operate by photogenerating excess charge carriers in an absorber material and, in competition with recombination, asymmetrically extracting them at so-called carrier-selective contacts, one that ideally collects only electrons and the other, only holes. Particularly in emerging photovoltaics such as perovskites, thin layers of organic semiconductors or related materials are introduced between the absorber and contact to improve power conversion efficiency. In terms of interfacial charge transfer, a prevailing view is that such interfacial layers improve performance by helping block the collection of the undesired carrier, considered a form of recombination. We use a novel platform to study the simultaneous impact of spiro-OMeTAD, a common interfacial layer, on the collection of electrons, the collection of holes, and on the recombination of electrons and holes. We quantitatively demonstrate that spiro-OMeTAD layers indeed passivate the contact toward recombination, but that larger improvements in the open-circuit voltage, a key cell metric, can come not only from this but also from increasing the asymmetry of the collection of electrons in the system. Further, operando measurements show transient changes in the properties of spiro-OMeTAD which suggest that it contributes to hysteresis phenomena commonly observed in perovskite and other solar cells.

36 MATERIALS SCIENCE↗
DOE OSTI2025

The "Fake" Supernova Neutrinos of SBND: Using Muons Decaying at Rest to Study the Charged Current MeV-Scale $V_e$-Ar Cross Section

In a Type-II core collapse supernova, 99% of the total amount of energy is released in the form of neutrinos. However, the nearest supernova explosion in the last few hundred years was in 1987, over thirty years ago. It was also the first from which particle detectors around the world managed to detect the neutrino flux, yielding important information about their properties and the explosion mechanism. Neutrinos are the most weakly interacting subatomic fundamental particles known to date, and they act as a cooling mechanism for the star. Out of the six neutrino flavours currently known, the majority exiting the explosion are electron neutrinos, ve. Neutrino experiments using liquid argon (LAr) as their detector medium are unique at probing this specific channel. In the meantime, however, until the next explosion, we can still practise for the big event. With the Short Baseline Near Detector (SBND) experiment at Fermilab, we can study how electron neutrinos of the same energy coming from the Booster Neutrino Beam (BNB) interact in LAr, and measure the cross section. As BNB measurements are mostly tailored to higher energy neutrinos, I will present an overview of how SBND is aiming to select the low-energy neutrino candidates from muons Decaying At Rest (DAR) in the absorber and target within the BNB beam pipe. This is not a straightforward feat, encompassing special difficulties that include beam and flux systematic uncertainty simulation, system trigger needs and particular reconstruction efforts, and so I will present how each challenge is being addressed in SBND. This will be a novel measurement in the neutrino particle physics community, and will prove fundamental for the next generation of supernova neutrino detectors.

Kotsiopoulou, Lucy [Edinburgh U.]↗
NASA NTRS2004

Improving UV Resistance of High Strength Fibers Used In Large Scientific Balloons

For the last three decades, NASA has been involved in the development of giant balloons that are capable of lifting heavy payloads of equipment (such as large telescopes and scientific instruments) to the upper atmosphere. While the use of such balloons has led to scientific discoveries, the demand for competitive science payloads and observational programs continues to rise. The NASA Balloon Program Office has entered a new phase of research to develop an Ultra Long Duration Balloon (ULDB) that will lift payloads of up to 3,600 kg to altitudes of up to 40 km. The flight duration is targeted to ranges between 30 to 100 days. Attaining these target durations requires the development of a super-pressure balloon design. The use of textile structures have already been established in these missions in the form of high strength tendons essential for the super pressure pumpkin design. Unfortunately, high strength fibers lose significant strength upon exposure to Ultra Violet (UV) radiation. Such UV degradation poses a serious challenge for the development of the ULDB. To improve the mission performance of the ULDB, new methods for protecting the tendons from the environmental effects need to be developed. NASA and NC State University College of Textiles are undertaking a research program to address these issues. Four tracks have been identified to prepare finishes that are believed to enhance the resistance of high strength fibers to UV. These tracks are: (a) self-polymerizing, (b) diffusion application, (c) polymer-filled with 30-40% UV absorber, and (d) combination of dyeing plus surface application. Four high performance fibers have been selected for this research investigation. These are Vectran (trademark), Spectra (trademark), Kevlar (trademark) and, PBO (Zylon (trademark)). This work will address the current progress of evaluating the performance of the UV finishes. This will be accomplished by comparing the tensile properties (strength, breaking elongation, modulus, etc) of untreated, unexposed to UV fibers; untreated exposed to UV fibers; and treated exposed to UV fibers.

Said, M.↗
DOE OSTI2022

Search for Higgs Portal Scalars and Heavy Neutral Leptons Decaying in the MicroBooNE Detector

This thesis presents a search for Higgs Portal Scalars (HPS) and Heavy Neutral Leptons (HNL) decaying in the MicroBooNE liquid argon time projection chamber (LArTPC). The measurement was performed using data collected in-time with the Neutrino at the Main Injector (NuMI) beam with a total exposure corresponding to $7.01 \times 10^{20}$ protons on target. Mono-energetic HPS and HNL would be produced from kaons decaying at rest in the NuMI hadron absorber, before travelling ${\sim}100$~m to the MicroBooNE detector where they decay. A single selection and search strategy is used to target decays of HPS to $\mu\mu$ pairs and HNL to $\mu\pi$ pairs. The results are expressed as limits, at the $90\%$ confidence level, on the mixing angles that control the rates of production and decay for each new particle. For the HNL model, upper limits are set on the mixing parameter $\mumix$ in the range [$12.9 \times 10^{-8}$, $0.54 \times 10^{-8}$] for HNL with masses in the region $246$--$385$~MeV. % This represents an order of magnitude increase in sensitivity to the previous MicroBooNE HNL result. For the HPS model, limits on the scalar-Higgs mixing angle $\theta^2$ are set, excluding a region with a lower boundary between [$31.3 \times10^{-9}$, $1.09 \times 10^{-9}$] and an upper boundary between [$2.50 \times 10^{-5}$, $5.05 \times 10^{-9}$] for scalars with a mass of $212$--$275$ MeV. These results set the first constraints in this region of parameter space from a dedicated experimental search for HPS.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Value Proposition of UV-Absorbers in PV Module Encapsulation

Various common crystalline silicon cell technologies were exposed to UVA radiation (1.24 Wm-2 nm-1 at 340 nm peak) on the front and back faces at 45 degrees Celsius for periods up to 3000 h, representing about 3 y of solar exposure in Phoenix, Arizona, USA. The resulting degradation of the open-circuit voltage and short-circuit current is presented. Of the various cell types examined, significant levels of degradation were seen in all cases. Less degradation was generally found after UV irradiation of cell fronts and older cell types, whereas a bifacial PERC type exposed on the rear showed about 25% degradation in short circuit current, attributable to lack of a diffused surface field. Selected cells were exposed to UV irradiation with the addition of long pass UV filters to replicate UV-absorbers in encapsulants. Modern cell designs are sensitive to UV-ID because of reduced or eliminated front and back surface field and increased dependence on high quality surface passivation. Single transformation of the independent variable (t, kW h/m^2) could be used to achieve a linear model of the data to extrapolate to 50 y. Solar Advisor Model (SAM) shows appropriate filtering of UV-irradiation can improve LCOE and net present value of plant. Some advanced cell types are seen to be UV-resistant (cell level solutions also exist). Solutions therefore exist on the cell, glass, and encapsulant level. Changes over time in each of these would also need to be considered (solarization, encapsulant browning...).

ENGINEERING,SOLAR ENERGY↗
DOE OSTI2025

Mechanism of Lithium Ion Exchange Into Spinel Manganese Oxide

Lithium manganese oxide (LMO) is an effective absorbent for lithium recovery from brines, characterized by its high adsorption capacity, excellent regeneration performance, and selectivity. Here, this study investigates the mechanisms of material degradation during lithium loading and unloading in LMO, employing a combination of time‐resolved Raman spectroscopy, X‐ray diffraction, and X‐ray photoelectron spectroscopy. Key findings reveal that the A 1g vibrational mode wavenumber shifts from 635 cm −1 at the onset of lithium ion exchange to 656 cm −1 after 12 min, indicating local symmetry loss and manganese (Mn) loss during lithium intercalation. The proposed lithium exchange mechanism involves initial occupation of tetrahedral interstitial voids, followed by migration into interstitial sites between Mn octahedral sites. Computational modeling suggests that the loss of symmetry in MnO cubane‐like groups occurs as lithium migrates, significantly affecting the Raman spectra. Importantly, the study demonstrates that after 100 cycles of lithium/hydrogen loading, a 24% loss in Mn is observed, which correlates with decreased structural stability; however, the structural integrity of LMO is enhanced when subjected to multiple cycles without complete loading. Here, these insights contribute to the understanding of LMO's performance in lithium recovery applications and highlight potential strategies to optimize its use in future technologies.

15 GEOTHERMAL ENERGY↗
DOE OSTI2021

The PshX subunit of the photochemical reaction center from Heliobacterium modesticaldum acts as a low-energy antenna

The anoxygenic phototrophic bacterium Heliobacterium modesticaldum contains a photochemical reaction center protein complex (called the HbRC) consisting of a homodimer of the PshA polypeptide and two copies of a newly discovered polypeptide called PshX, which is a single transmembrane helix that binds two bacteriochlorophyll g molecules. Here, to assess the function of PshX, we produced a ΔpshX strain of Hbt. modesticaldum by leveraging the endogenous Hbt. modesticaldum Type I-A CRISPR-Cas system to aid in mutant selection. We optimized this system by separating the homologous recombination and CRISPR-based selection steps into two plasmid transformations, allowing for markerless gene replacement. Fluorescence and low-temperature absorbance of the purified HbRC from the wild-type and ΔpshX strains showed that the bacteriochlorophylls bound by PshX have the lowest site energies in the entire HbRC. This indicates that PshX acts as a low-energy antenna subunit, participating in entropy-assisted uphill energy transfer towards the P 800 special bacteriochlorophyll g pair. We further discuss the role that PshX may play in stability of the HbRC, its conservation in other heliobacterial species, and the evolutionary pressure to produce and maintain single-TMH subunits in similar locations in other reaction centers.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2026

Water as a gas separation membrane

Efficient gas separation membranes are essential for carbon capture, biogas upgrading, and hydrogen purification. Inspired by how plants absorb CO 2 through water, we present a membrane platform that uses liquid water as the selective layer. Hydrophilic sub-100-nm pores stabilize water through strong capillary forces, enabling operation at feed pressures above 72 bar under dry and humid conditions. Selectivity is governed by gas solubility in water, while permeance is tuned by adjusting the water layer thickness. Reducing this thickness below 200 nm yields CO 2 permeances up to 11,600 gas permeation units with CO 2 :N 2 , CO 2 :CH 4 , and CO 2 :H 2 selectivities of 40, 26, and 31, respectively, surpassing the performance of state-of-the-art membranes. Operation is sustained for over a week without water loss, and performance scales using commercially available porous polymer supports under mixed-gas crossflow conditions. Water’s dissolution-based transport avoids saturation and reaction-rate limits, enabling a robust, high-performance, and environmentally benign gas separation platform.

08 HYDROGEN↗
NASA NTRS1973

Annoyance judgements of aircraft with and without acoustically treated nacelles

A series of subjective response laboratory tests were conducted to determine the effectiveness of reducing aircraft noise by treating the aircraft engine nacelles with acoustically absorbent material. A total of 108 subjects participated in the magnitude estimation tests. The subjects were selected from persons who had previously been interviewed and classified according to selected psychological characteristics. The subjects lived in three general areas located at three specified distances from New York's Kennedy Airport. The aircraft signals used in the tests consisted of tape recordings of the landing approach noise of a B-727 aircraft under normal operating conditions. These recordings were electronically altered to simulate an aircraft with acoustically treated nacelles to achieve noise reductions of approximately 6 EPNdB and 12 EPNdB. The results from these tests indicate that significant reductions in annoyance resulted from the synthesized nacelle treatments.

Borsky, P. N.↗