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At least 199 records · Page 11

Advances and Limitations of Atmospheric Boundary Layer Observations with GPS Occultation over Southeast Pacific Ocean

The typical atmospheric boundary layer (ABL) over the southeast (SE) Pacific Ocean is featured with a strong temperature inversion and a sharp moisture gradient across the ABL top. The strong moisture and temperature gradients result in a sharp refractivity gradient that can be precisely detected by the Global Positioning System (GPS) radio occultation (RO) measurements. In this paper, the Constellation Observing System for Meteorology, Ionosphere & Climate (COSMIC) GPS RO soundings, radiosondes and the high-resolution ECMWF analysis over the SE Pacific are analyzed. COSMIC RO is able to detect a wide range of ABL height variations (1-2 kilometer) as observed from the radiosondes. However, the ECMWF analysis systematically underestimates the ABL heights. The sharp refractivity gradient at the ABL top frequently exceeds the critical refraction (e.g., −157 N-unit per kilometer) and becomes the so-called ducting condition, which results in a systematic RO refractivity bias (or called N-bias) inside the ABL. Simulation study based on radiosonde profiles reveals the magnitudes of the N-biases are vertical resolution dependent. The N-bias is also the primary cause of the systematically smaller refractivity gradient (rarely exceeding −110 N-unit per kilometer) at the ABL top from RO measurement. However, the N-bias seems not affect the ABL height detection. Instead, the very large RO bending angle and the sharp refractivity gradient due to ducting allow reliable detection of the ABL height from GPS RO. The seasonal mean climatology of ABL heights derived from a nine-month composite of COSMIC RO soundings over the SE Pacific reveals significant differences from the ECMWF analysis. Both show an increase of ABL height from the shallow stratocumulus near the coast to a much higher trade wind inversion further off the coast. However, COSMIC RO shows an overall deeper ABL and reveals different locations of the minimum and maximum ABL heights as compared to the ECMWF analysis. At low latitudes, despite the decreasing number of COSMIC RO soundings and the lower percentage of soundings that penetrate into the lowest 500-m above the mean-sea-level, there are small sampling errors in the mean ABL height climatology. The difference of ABL height climatology between COSMIC RO and ECMWF analysis over SE Pacific is significant and requires further studies.

COSMIC RO↗

Chemistry of diagenetic features analyzed by ChemCam at Pahrump Hills, Gale crater, Mars

The Curiosity rover's campaign at Pahrump Hills provides the first analyses of lower Mount Sharp strata. We report ChemCam elemental composition of a diverse assemblage of post-depositional features embedded in, or cross-cutting, the host rock. ChemCam results demonstrate their compositional diversity, especially compared to the surrounding host rock: (i) Dendritic aggregates and relief enhanced features, characterized by a magnesium enhancement and sulfur detection, and interpreted as Mg-sulfates; (ii) A localized observation that displays iron enrichment associated with sulfur, interpreted as Fe-sulfate; (iii) Dark raised ridges with varying Mg- and Ca-enriched compositions compared to host rock; (iv) Several dark-toned veins with calcium enhancement associated with fluorine detection, interpreted as fluorite veins. (v) Light-toned veins with enhanced calcium associated with sulfur detection, and interpreted as Ca-sulfates. The diversity of the Pahrump Hills diagenetic assemblage suggests a complex post-depositional history for fine-grained sediments for which the origin has been interpreted as fluvial and lacustrine. Assessment of the spatial and relative temporal distribution of these features shows that the Mg-sulfate features are predominant in the lower part of the section, suggesting local modification of the sediments by early diagenetic fluids. Conversely, light-toned Ca-sulfate veins occur in the whole section and cross-cut all other features. A relatively late stage shift in geochemical conditions could explain this observation. The Pahrump Hills diagenetic features have no equivalent compared to targets analyzed in other locations at Gale crater. Only the light-toned Ca-sulfate veins are present elsewhere, along Curiosity's path, suggesting they formed through a common late-stage process that occurred at over a broad area.

58 GEOSCIENCES↗

Random walks with the 6420- and 6825-A features of methane: Lost in the wilderness

A feature near 6420 A which appears in the spectra of Uranus and Neptune, and was recently detected in the spectrum of Titan is investigated. When originally identified, it was assigned to the pressure induced 4 to 0 band of molecular hydrogen. Not only did the wavelength agree--a small apparent shift was arm waved away, but when the feature was reduced using a dipole-induced strength, it gave results for H2 column densities consistent with best estimates for the sharp quadrupole lines. In studying the long path spectra of methane, that same feature was also present. A second similar problem exists with a Uranian feature--indeed, a general planetary feature centered near 6825 A.

Lutz, B. L.↗

Diffraction by Sharp Edges of Noncanonical Shape with Mean Flow and Surface Impedance

This paper presents a study on diffraction by sharp edges of noncanonical edge shape in the presence of mean flow and surface impedance, which are important features for aircraft noise but have not been accounted for in previous studies on sharp-edge diffraction. An analytical formula for the diffracted pressure is derived by applying asymptotic analysis to the integral representation of the total pressure scattered by a geometry that contains sharp edges. The asymptotic analysis is presented as a systematic process that can be carried out to any order, if needed. An illustration is given to use a higher-order result to eliminate the singularity in the first-order result to make the solution regular in the entire parameter domain. The formula for the diffracted pressure is validated by experimental data and is applied to parametric studies to reveal the effects of noncanonical edge shape, mean flow and surface impedance, as well as the impact of these effects on the total scattered pressure in the presence of other scattering components.

Yueping Guo↗

A New Method of Deriving Time-Averaged Tropospheric Column Ozone over the Tropics Using Total Ozone Mapping Spectrometer (TOMS) Radiances: Intercomparison and Analysis Using TRACE A Data

Error analysis of archived total 03 from total ozone mapping spectrometer (TOMS) (version 6) presented. Daily total 03 maps for the tropics, from the period October 6-21, 1992, are derived from TOMS radiances following correction for these errors. These daily maps, averaged together, show a wavelike feature, which is observed in all latitude bands, underlying sharp peaks which occur at different longitudes depending on the latitude. The wave pattern is used to derive both time-averaged stratospheric and tropospheric 03 fields. The nature of the wave pattern (stratospheric or tropospheric) cannot be determined with certainty due to missing data (no Pacific sondes, no lower stratospheric Stratospheric Aerosol and Gas Experiment (SAGE) ozone for 18 months after the Mt. Pinatubo eruption) and significant uncertainties in the corroborative satellite record in the lower stratosphere (solar backscattered ultraviolet (SBUV), microwave limb sounder (MLS)). However, the time- averaged tropospheric ozone field, based on the assumption that the wave feature is stratospheric, agrees within 10% with ultraviolet differential absorption laser Transport and Atmospheric Chemistry near the Equator-Atlantic) (TRACE A) 03 measurements from the DC-8 and with ozonesonde measurements over Brazzaville, Congo, Ascension Island, and Natal, Brazil, for the period October 6-21, 1992. The derived background (nonpolluted) Indian Ocean tropospheric ozone amount, 26 Dobson units (DU), agrees with the cleanest African ozonesonde profiles for September-October 1992. The assumption of a totally tropospheric wave (flat stratosphere) gives 38 DU above the western Indian Ocean and 15-40% disagreements with the sondes. Tropospheric column 03 is high from South America to Africa, owing to interaction of dynamics with biomass burning emissions. Comparison with fire distributions from advanced very high resolution radiometer (AVHHR) during October 1992 suggests that tropospheric 03 produced from biomass burning in South America and Africa dominates the 03 budget in the tropical southern hemisphere during the study period.

Kim, J. H.↗

On a nonlocal Cahn–Hilliard model permitting sharp interfaces

A nonlocal Cahn–Hilliard model with a non-smooth potential of double-well obstacle type that promotes sharp interfaces in the solution is presented. To capture long-range interactions between particles, a nonlocal Ginzburg–Landau energy functional is defined which recovers the classical (local) model as the extent of nonlocal interactions vanish. In contrast to the local Cahn–Hilliard problem that always leads to diffuse interfaces, the proposed nonlocal model can lead to a strict separation into pure phases of the substance. In this work, the lack of smoothness of the potential is essential to guarantee the aforementioned sharp-interface property. Mathematically, this introduces additional inequality constraints that, in a weak formulation, lead to a coupled system of variational inequalities which at each time instance can be restated as a constrained optimization problem. We prove the well-posedness and regularity of the semi-discrete and continuous in time weak solutions, and derive the conditions under which pure phases are admitted. Moreover, we develop discretizations of the problem based on finite element methods and implicit–explicit time-stepping methods that can be realized efficiently. Finally, we illustrate our theoretical findings through several numerical experiments in one and two spatial dimensions that highlight the differences in features of local and nonlocal solutions and also the sharp interface properties of the nonlocal model.

97 MATHEMATICS AND COMPUTING↗

Direct Exchange Mechanism for Interlayer Ions in Non-Swelling Clays

The mobility of radiocesium in the environment is largely mediated by cation exchange in micaceous clays, in particular Illite—a non-swelling clay mineral that naturally contains interlayer K + and has high affinity for Cs + . Although exchange of interlayer K + for Cs + is nearly thermodynamically nonselective, recent experiments show that direct, anhydrous Cs + -K + exchange is kinetically viable and leads to the formation of phase-separated interlayers through a mechanism that remains unclear. Here, using classical atomistic simulations and density functional theory calculations, we identify a molecular-scale positive feedback mechanism in which exchange of the larger Cs + for the smaller K + significantly lowers the migration barrier of neighboring K + , allowing exchange to propagate rapidly once initiated at the clay edge. Barrier lowering upon slight increase in layer spacing (~0.7 Å) during Cs + exchange is an example of “chemical-mechanical coupling” that likely explains the observed sharp exchange fronts leading to interstratification. Interestingly, we find that these features are thermodynamically favored even in the absence of a heterogeneous layer charge distribution.

Ruiz Pestana, Luis↗

Diagenetic Features Analyzed by ChemCam/Curiosity at Pahrump Hills, Gale Crater, Mars

Onboard the Mars Science Laboratory (MSL) Curiosity rover, the ChemCam instrument consists of : (1) a Laser-Induced Breakdown Spectrometer (LIBS) for elemental analysis of targets and (2) a Remote Micro Imager (RMI), which provides imaging context for the LIBS. The LIBS/ChemCam performs analysis typically of spot sizes 350-550 micrometers in diameter, up to 7 meters from the rover. Within Gale crater, Curiosity traveled from Bradbury Landing toward the base of Mount Sharp, reaching Pahrump Hills outcrop circa sol 750. This region, as seen from orbit, represents the first exposures of lower Mount Sharp. In this abstract we focus on two types of features present within the Pahrump Hills outcrop: concretion features and light-toned veins.

Nachon, M.↗

Near infrared spectroscopy of SN 1987A using the Kuiper Airborne Observatory

An IR spectrum (1.5-3.0 microns) of SN 1987A was obtained on UT April 16.3, 1987 with the University of Arizona Fourier-transform spectrometer on the NASA Kuiper Airborne Observatory. The dominant spectral features were a double-peaked P-alpha emission line and a sharp absorption edge in the continuum at 2.7 microns, both of which would have been obscured by strong telluric H2O absorptions at ground-based observatories. These IR features relate to models of the SN shell and to the role of dust in SN.

Larson, H. P.↗

Sharp-B01: An Important Element of NASA's Launch Vehicle Development Program

Sharp body designs for future reusable launch vehicles offer a number of attractive features including allowing zero staging, enabling airbreathing and lofting ascents, and potentially providing global cross range re-entries with continuous communications. The Slender Hypersonic Aerothermodynamic Research Program (SHARP) was initiated by NASA Ames to demonstrate sharp, passive leading edge designs for hypersonic vehicles, incorporating new ultra-high temperature ceramics. This paper will discuss how SHARP will provide an important technology base for making sharp body hypersonic vehicle designs a reality, and how this activity fits into NASA's overall program for developing next generation reusable launch vehicles.

Rasky, Daniel J.↗

Synthesis and Characterization of MoNb Films Superconducting at 100-200 mK

We have developed a new transition-edge sensor material with critical temperature (T-c) in the range 100-200 mK. The new material is a solid solution of two superconducting components, MoxNb1-x, co-sputtered from two high-purity single-component targets (Mo and Nb). The T-c has a minimum (dT(c)/dx = 0) at an intermediate concentration of the components. We have optimized the deposition parameters and composition to provide films with a sharp superconducting transition at ~ 150 mK. We investigated structural features of the films and surface morphology using X-ray diffraction (XRD) and scanning electron microscopy. The XRD measurements indicate that the grown films are polycrystalline, with a preferred orientation along the (110) crystal direction and a clear correlation between superconducting properties and film microstructure.

superconducting alloys↗

Chromium versus Aluminum: Impact of Nickel Alloy Composition and Interfacial Kinetics on High-Temperature Passivating Oxide Formation

High-temperature corrosion resistance depends critically on the formation of a passivating surface oxide, which is highly sensitive to alloy composition and structure. Such details often elude experimental investigation, and simplified analytical models fail to provide a truly chemical view of passivating oxide evolution. Here, we explicitly compare the fundamental chemistry of Cr and Al as prototypical passivating elements in Ni alloys by directly simulating competing reaction and diffusion processes within the oxide film using kinetic Monte Carlo and density functional theory. We find that the origin and expression of passivating behavior during early-stage thermal oxidation are qualitatively different between the two alloy systems. Ni–Cr alloys feature a sudden onset of passivation associated with a sharp phase transition upon Cr enrichment that directly couples oxidation kinetics to phase transformation behavior. In contrast, Ni–Al alloys display more continuous oxide phase variation with Al enrichment, ultimately resulting in a lower composition threshold for passivation and a thinner passivating layer. In addition, we elucidate the nonobvious role of metal exchange within the alloy near the oxide boundary, which fundamentally alters film composition and passivating behavior. Furthermore, our results have key implications for engineering improved corrosion-resistant alloys, both in terms of compositional variation and processing.

Alloys↗

Relativistic electron beam driven longitudinal wake-wave breaking in a cold plasma

Space-time evolution of a relativistic electron beam driven wake-field in a cold, homogeneous plasma is studied using 1D-fluid simulation techniques. It is observed that the wake wave gradually evolves and eventually breaks, exhibiting sharp spikes in the density profile and sawtooth like features in the electric field profile [Bera et al., Phys. Plasmas 22, 073109 (2015)]. It is shown here that the excited wakefield is a longitudinal Akhiezer-Polovin mode [A. I. Akhiezer and R. V. Polovin, Sov. Phys. JETP 3, 696 (1956)] and its steepening (breaking) can be understood in terms of phase mixing of this mode, which arises because of relativistic mass variation effects. Further, the phase mixing time (breaking time) is studied as a function of beam density and beam velocity and is found to follow the well known scaling presented by Mukherjee and Sengupta [Phys. Plasmas 21, 112104 (2014)].

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Positive ions in the mesosphere.

Positive ions have been measured using the parachute borne blunt probe, a subsonic system launched on meteorological rockets, which measures polar electrical conductivities in the 30 to 80 km altitude range. A central feature of the daytime positive conductivity profiles is a sharp break occurring between 60 and 70 km which indicates the transition from galactic cosmic ray to solar ultraviolet ionization, and, hence provides information about the nitric oxide density. In the 50-60 km region the positive ion conductivity is relatively constant with altitude and correlates well with atmospheric temperature down to 35 km. Using temperature and pressure profiles and a reduced mobility, the conductivity profiles may be converted to density profiles. The average mid-latitude daytime profile at intermediate solar zenith angles showed a minimum at 63.5 km.

Hale, L. C.↗

M551 metals melting experiment

Electron beam welding studies were conducted in the Skylab M551 metals melting experiment, on three different materials; namely 2219-T87 aluminum alloy, 304L stainless steel, and commercially pure tantalum (0.5 wt % columbium). Welds were made in both one gravity and zero gravity (Skylab) environments. Segments from each of the welds were investigated by microhardness, optical microscopy, scanning microscopy, and electron probe techniques. In the 2219-T87 aluminum alloy samples, macroscopic banding and the presence of an eutectic phase in the grain boundaries of the heat affected zone were observed. The stainless steel samples exhibited a sharp weld interface and macroscopic bands. The primary microstructural features found in the tantalum were the presence of either columnar grains (ground base) or equiaxed grains (Skylab). The factors contributing to these effects are discussed and the role of reduced gravity in welding is considered.

Busch, G.↗

Spontaneous Raman scattering as a high resolution XUV radiation source

A type of high resolution XUV radiation source is described which is based upon spontaneous anti-Stokes scattering of tunable incident laser radiation from atoms excited to metastable levels. The theory of the source is summarized and two sets of experiments using He (1s2s)(1)S atoms, produced in a cw hollow cathode and in a pulsed high power microwave discharge, are discussed. The radiation source is used to examine transitions originating from the 3p(6) shell of potassium. The observed features include four previously unreported absorption lines and several sharp interferences of closely spaced autoionizing lines. A source linewidth of about 1.9 cm(-1) at 185,000 cm(-1) is demonstrated.

Rothenberg, J. E.↗

Spontaneous Raman scattering as a high-resolution XUV radiation source

A type of high resolution XUV radiation source is described which is based upon spontaneous anti-Stokes scattering of tunable incident laser radiation from atoms excited to metastable levels. The theory of the source is summarized and two sets of experiments using He (1s2s)(1)S atoms, produced in a CW hollow cathode and in a pulsed high power microwave discharge, are discussed. The radiation source is used to examine transitions originating from the 3p(6) shell of potassium. The observed features include four previously unreported absorption lines and several sharp interferences of closely spaced autoionizing lines. A source linewidth of about 1.9 cm(-1) at 185,000 cm(-1) is demonstrated. Previously announced in STAR as N83-18422

Rothenberg, J. E.↗

Observations of stratospheric aerosols associated with the El Chichon eruption

Lidar observations of aerosols were carried out at Aberystwyth between Nov. 1982 and Dec. 1985 using a frequency doubled and frequency tripled Nd/Yag laser and a receiver incorporating a 1 m diameter in a Newtonian telescope configuration. In analyses of the experimental data attention is paid to the magnitude of the coefficient relating extinction and backscatter, the choice being related to the possible presence of aerosols in the upper troposphere and the atmospheric densities employed in the normalisation procedure. The aerosol loading showed marked day to day changes in early months and an overall decay was apparent only after April 1983, this decay being consistent with an e sup -1 time of about 7 months. The general decay was accompanied by a lowering of the layer but layers of aerosols were shown intermittently at heights above the main layer in winter months. The height variations of photon counts corrected for range, or of aerosol backscatter ratio, showed clear signatures of the tropopause. A strong correlation was found between the heights of the tropopause identified from the lidar measurements and from radiosonde-borne temperature measurements. A notable feature of the observations is the appearance of very sharp height gradients of backscatter ratio which seem to be produced by differential advection.

Thomas, L.↗