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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Evaluation of the soil moisture prediction accuracy of a space radar using simulation techniques

Image simulation techniques were employed to generate synthetic aperture radar images of a 17.7 km x 19.3 km test site located east of Lawrence, Kansas. The simulations were performed for a space SAR at an orbital altitude of 600 km, with the following sensor parameters: frequency = 4.75 GHz, polarization = HH, and angle of incidence range = 7 deg to 22 deg from nadir. Three sets of images were produced corresponding to three different spatial resolutions; 20 m x 20 m with 12 looks, 100 m x 100 m with 23 looks, and 1 km x 1 km with 1000 looks. Each set consisted of images for four different soil moisture distributions across the test site. Results indicate that, for the agricultural portion of the test site, the soil moisture in about 90% of the pixels can be predicted with an accuracy of = + or - 20% of field capacity. Among the three spatial resolutions, the 1 km x 1 km resolution gave the best results for most cases, however, for very dry soil conditions, the 100 m x 100 m resolution was slightly superior.

Ulaby, F. T.↗

Quantifying the impact of climate change on erosion - 20397

The New York State Energy Research and Development Authority (NYSERDA) is the owner of the Western New York Nuclear Service Center (WNYNSC), a 1,351-ha (3,338-ac) site located approximately 48 km (30 mi) south of Buffalo, New York. In 1962, Nuclear Fuel Services, Inc. (NFS) entered into Agreements with the Atomic Energy Commission and New York State to construct the first commercial reprocessing plant of nuclear fuel in the United States. NFS, a private company, built and operated the spent fuel reprocessing plant and waste disposal facilities, processing 640 Mg (metric tons, or 705 short tons) of spent nuclear fuel from 1966 to 1972 under an Atomic Energy Commission license. Nuclear fuel reprocessing operations ended in 1972 and never reopened, leaving behind radioactive and chemical wastes. Erosion can play an important role in the fate and transport of waste at sites where disposal of long-lived waste is anticipated. The statistical characterization of key processes related to erosion is essential to the understanding of site stability through time. One of the key processes governing erosion is extreme precipitation and it is critical that trends in the distribution of extreme precipitation events through time be represented. The evidence of climate change is increasingly well documented and projected impacts on extreme precipitation events should be incorporated in performance assessment studies when relevant. Not evaluating future climate states in a performance assessment is contradictory to good modeling practice. Specifically, excluding climate change limits development of modeling information that could aid in effective decision making. The current climate literature provides both observational evidence and climate model projections of climate trends and/or climate change in the late 20. and early 21. centuries for North America and the northeast United States. In this work, this information was used to assess the impacts of potential changes in climate on erosion processes. The goal was to understand how projections of future climate relate to the performance of the WNYNSC through time. In the first stage of this work multi-temporal historical aerial images were analyzed in conjunction with orthophotography and Lidar data to develop probability distributions for variables representing important erosion processes. The information from these analyses was then used in conjunction with simulated data from the West Valley Erosion Working Group (EWG). Analysis of EWG simulations provides estimates for the change in erosion rates through time that is driven by changes in climate. The time-varying rates of erosion change were applied to the historical aerial imagery data in order to inform time-varying rates of erosion that are driven by changes in climate. Ultimately, this process resulted in the identification of locations for features like gully heads using both the Lidar dataset and projection of the estimated location from the historical aerial photo under consideration back to the Lidar dataset. The distance between the estimate of the location from the historical image and that of the Lidar dataset was the estimated distance the feature has moved. This distance was then divided by the number of years between the Lidar dataset and the year of the historical aerial image of interest to get a rate of movement through time. This was done for several dozen points on each historical aerial image. The analyses from the EWG were used to characterize the relative impact of climate change on the erosion rates. This relative impact was quantified by comparing the LEM based estimates of erosion that were derived using historical climate data with LEM based estimates of erosion that were derived using projections of future climate. The relative increase in the erosion rates was then applied to the historical estimates of erosion derived from the analysis of the historical aerial imagery. This approach was used since the LEM-based estimated of the historical erosion rates from the past century have a bias towards underestimating erosion. This underestimation is hypothesized to be a consequence of an inability of the LEMs to account for the impacts of land-use change (i.e. deforestation) which had been shown to significantly increase erosion in similar Northern hardwood forest ecosystems. In summary, gully head retreat rate and gully widening rate were characterized using statistical probability distributions from the historical aerial image analysis. Simulated data from the EWG was used to estimate the climatically-driven changes in erosion rates through time. The changes through time from the EWG were applied to the gully head retreat rate and gully widening rate characterized using the historical aerial image analysis. This information can be used to inform PPA models to project future risks from a given site. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Pan-Arctic daily streamflow at 0.5-degree resolution

Data was derived using daily runoff from models participating in the Coupled Model Intercomparison Project, version 6 (CMIP6) that have been routed through the Model for Scale Adaptive River Transport (MOSART) routing model to represent streamflow at individual streamflow gage locations. Data from 750 streamflow gage locations are represented, which are indexed by gage id according to the metadata.csv file. Streamflow gage location sites were based on gage records downloaded from the United States Geological Survey (USGS), National Water Data (HYDAT) Archive from Canada, and the State Hydrological Institute of Russia. Data are available from 11 Earth System Models (ESMs) in total at a daily timestep with a duration of 1920-2099 (1850-2014 for E3SM only). The spatial domain of the modeled data is 0.5 degree resolution. Earth System Models and Units of mean daily streamflow are presented in cubic meters per second (cms). Data files consist of 11 Earth System Model mean daily streamflow output per gage location in .csv format, 1 metadata file in .csv format and 1 Readme file in .docx format (13 files in total). These data were used to benchmark CMIP6 modeled representations of streamflow against gage records.

54 ENVIRONMENTAL SCIENCES↗

Utilizing Environmental Tracers to Reduce Groundwater Flow and Transport Model Parameter Uncertainties

Abstract Non‐uniqueness in groundwater model calibration is a primary source of uncertainty in groundwater flow and transport predictions. In this study, we investigate the ability of environmental tracer information to constrain groundwater model parameters. We utilize a pilot point calibration procedure conditioned to subsets of observed data including: liquid pressures, tritium ( 3 H), chlorofluorocarbon‐12 (CFC‐12), and sulfur hexafluoride (SF 6 ) concentrations; and groundwater apparent ages inferred from these environmental tracers, to quantify uncertainties in the heterogeneous permeability fields and infiltration rates of a steady‐state 2‐D synthetic aquifer and a transient 3‐D model of a field site located near Riverton, Wyoming (USA). To identify the relative data worth of each observation data type, the post‐calibration uncertainties of the optimal parameters for a given observation subset are compared to that from the full observation data set. Our results suggest that the calibration‐constrained permeability field uncertainties are largest when liquid pressures are used as the sole calibration data set. We find significant reduction in permeability uncertainty and increased predictive accuracy when the environmental tracer concentrations, rather than apparent groundwater ages, are used as calibration targets in the synthetic model. Calibration of the Riverton field site model using environmental tracer concentrations directly produces infiltration rate estimates with the lowest uncertainties, however; permeability field uncertainties remain similar between the environmental tracer concentration and apparent groundwater age calibration scenarios. This work provides insight on the data worth of environmental tracer information to calibrate groundwater models and highlights potential benefits of directly assimilating environmental tracer concentrations into model parameter estimation procedures.

54 ENVIRONMENTAL SCIENCES↗

Yb Substitution and Ultralow Thermal Conductivity of the Ca 3– x Yb x AlSb 3 (0 ≤ x ≤ 0.81(1)) System

Here, a series of Yb-substituted Zintl phases in the Ca 3–x Yb x AlSb 3 (0 ≤ x ≤ 0.81(1)) system has been synthesized by initial arc melting and post-heat treatment, and their isotypic crystal structures were characterized by both powder and single crystal X-ray diffraction analysis. All four title compounds adopted the Ca 3 AlAs 3 -type structure (space group Pnma, Pearson code oP28, Z = 4). The overall structure can be described as a combination of the 1-dimensional (1D) infinite chain of ∞ 1 [Al(Sb 2 Sb 2/2 )] formed by two vertices sharing [AlSb 4 ] tetrahedral moieties and three Ca 2+ /Yb 2+ mixed sites located in between these 1D chains. The charge balance and the resultant independency of the 1D chains in the title system were explained by the Zintl-Klemm formalism [Ca 2+ /Yb 2+ ] 3 [(4b-Al 1– )(1b-Sb 2– ) 2 (2b-Sb 1– ) 2/2 ]. A series of DFT calculations proved that (1) the band overlap between the d-orbital states from two types of cations and the p-orbital states from Sb at the high symmetry Γ point implied a heavily doped degenerate semiconducting behavior of the quaternary Ca 2 YbAlSb 3 model and (2) the site preference of Yb for the M1 site was due to the electronic-factor criterion based on the Q values of each atomic site. The electron localization function calculations also proved that the two different shapes of lone pairs of the Sb atoms—the “umbrella-shape” and the “C-shape”—are determined by local geometry and the coordination environment on the anionic frameworks. Thermoelectric measurements of the quaternary title compound Ca 2.19(1) Yb 0.81 AlSb 3 showed an approximately two times larger ZT value than that of ternary Ca 3 AlSb 3 at 623 K due to increased electrical conductivity and ultralow thermal conductivity originated from Yb substitution for Ca.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Unraveling Dimensional Tuning: From 2D to 3D in Covalent Organic Frameworks for Enhanced 2e – Oxygen Reduction Reaction

Covalent organic frameworks (COFs) with a two-dimensional (2D) topology have recently emerged as promising catalyst systems for the electrosynthesis of hydrogen peroxide (H 2 O 2 ) from oxygen (O 2 ). However, designing 2D catalysts to achieve higher H 2 O 2 selectivity presents a significant challenge because of the extensive layer stacking and the aggregated active sites located in the basal planes. It results in lower atom utilization, which requires attention. In this study, we present two functionally similar COFs: one with a 2D rhombus topology (2D@BT_TPA-COF) and another with a three-dimensional (3D) noninterpenetrated pts topology (3D@BT_TPA-COF). Both COFs were utilized for the 2e – oxygen reduction reaction (2e – ORR). Tunning the dimensionality from 2D to 3D resulted in an increase in H 2 O 2 selectivity from approximately ~56% to approximately ~96% (at 0.4 V) and a rise in the turnover frequency (TOF) from 0.05 to 0.08 s –1 at 0.3 V. Nonaggregated active site distribution over 3D topology, featuring higher active site exposure, provides better access to the O 2 /electrolyte and facilitates electron transfer leading to higher 2e – ORR activity and selectivity compared to the 2D counterpart.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Managing Subsurface Pressure Buildup and Interference in Commercial-Scale CO 2 Storage Project with Proximal Injection Wells

Large-scale decarbonization using carbon capture and storage (CCS) is likely to involve many commercial-scale CO 2 storage projects located in close proximity to each other. This close proximity raises concerns over pressure interference among the storage projects. Pressure interference between injection and storage efforts can reduce the practicable CO 2 storage resource and force wells to inject CO 2 at a lower rate to avoid the fracture pressure thresholds per United States Environmental Protection Agency (EPA) Class VI well regulations to preserve injection and confining zone integrity and potentially mitigate against inducing seismic activity. These analyses employ numerical full-physics reservoir modeling to evaluate how pressure buildup fronts and CO 2 plumes evolve under commercial-scale injection volumes of CO 2 in which multiple storage sites located in close proximity occur in tandem. The simulation models mimic injection at pseudo basin-scale and assume homogeneous saline formation(s) as storage targets with a pair of upper and lower homogeneous seal layer/s. These analyses specifically investigate the efficacy of two basin-wide reservoir pressure management strategies in addressing the technical challenges associated with pressure buildup and CO 2 plume commingling. The strategies explored include: 1) enlarging the area of injection well spacing (WS) and 2) storing CO 2 in a stacked sequence (SSS) of saline formations compared to a single formation. The storage and confining zones properties assumed were held common across the scenarios, unless specified otherwise. Analyses results show that after injecting 4 million tons per year for 30 years using 4 separate wells (each injecting 1 million metric tons per year), the radius of CO 2 plume extends to a mere 3 km or less from injection wells. Meanwhile, the radius of pressure buildup ranges on the order of tens to a few hundreds of kilometers, depending on the magnitude of pressure buildup threshold that one would use to define the front. CO 2 plume commingling from different injection wells appears to occur 50 years post-injection, especially under scenarios with narrowly spaced (i.e., < 5 km apart) injection well locations. Findings from sensitivity cases on the well spacing suggest that storage formations modeled would require different well spacing to avoid fracture pressure thresholds. For instance, modeled storage formations with high fracture gradients (i.e., 0.8 psi/ft) would need less than 5–km well spacing, whereas those with lower fracture gradients (i.e., 0.7 psi/ft) would need approximately 20–km well spacing, based on assumed modeling parameters. Under stacked injection, the pressure challenges (described above) still exist but are more alleviated due to distributing the same injection volume across more available reservoir volume. These analyses demonstrate that stacked-sequence storage can effectively address the challenges, while still providing the same target CO 2 storage volumes and allowing a large number of storage projects to be deployed in the same basin by better utilizing the available storage resource across different reservoir depths. Among cases modeled, the resulting pressure buildup front is most suppressed when each storage project distributes injection volumes over several wells, each of which injects a portion of the total CO 2 across the stacked sequence. This strategy results in the smallest CO 2 aerial footprint amongst scenarios evaluated but also shows the largest reduction in the pressure buildup at the top of perforation at the injection wells (upwards of approximately 42 percent compared to the commercial-scale single-formation storage), the result of which is crucial to maintain caprock integrity. The findings presented by this research draw attention to the importance of greater coordination among storage operators and regulatory stakeholders to foster the upscaling and deployment of CCS. These analyses provide insights into required decision-making when considering multi-project deployment in a shared basin. Because these analyses evaluate a very specific geologic situation, they bear further investigations across other geologic situations.

42 ENGINEERING↗

Area South of K7-516, SWMU 100 Operations, Maintenance, and Monitoring Report Kennedy Space Center, Florida

This Operations, Maintenance, and Monitoring Report documents groundwater interim measure activities from March 30, 2019 through December 31, 2019 at the Area South of K7-516 site located at Kennedy Space Center (KSC), Florida. An air sparge (AS) system consisting of 16 AS wells was installed along the Barge Canal in 2012 to be protective of the Outstanding Florida Waters (OFW). The AS system was expanded in 2015 by installing 40 AS wells to remediate the hot spot (HS) area. Additional expansion activities were performed in 2018 through the installation of eight additional AS wells along the Barge Canal. Currently 24 OFW and 40 HS AS wells are in operation. This report includes performance monitoring events for the OFW and HS areas, along with an annual Interim Groundwater Monitoring (IGWM) event in the Western Area. The 516S site has been designated Solid Waste Management Unit 100 under KSC’s Resource Conservation and Recovery Act Corrective Action program. This document was prepared by Tetra Tech, Inc., for the National Aeronautics and Space Administration under Indefinite Delivery Indefinite Quantity Contract 80KSC019D0011/80KSC019F0068. The OFW and HS AS systems are meeting the performance criteria and IM objectives of preventing contaminant migration and remediating groundwater within the treatment zone. Team consensus was reached to continue operation of the combined OFW and HS AS systems (Meeting Minute 2002-M02, Decisions 2002-D06, D09 and D04). Team consensus was also reached to continue semi-annual OFW performance monitoring and annual monitoring for the IGWM Western Area for the same wells sampled during 2019 events. In the eastern area, MW13, MW14, and MW15 will be reduced from semi-annual to annual frequency. For the HS Area, team consensus was reached to continue the current annual/biennial monitoring program (Meeting Minute 2002-M02, Decisions 2002-D02, D03, D05, D07 and D08).

Patrice L. Lehocky↗

Estimating Future Changes of Energy Demand for Heating and Cooling Buildings at NASA Centers GC23J-1198

With its unique and trusted earth observations, NASA is a critical source in informing decisions that will help achieve the U.S. goal of Net-Zero Greenhouse Gas (GHG) Emissions by 2050. NASA’s Prediction of Worldwide Energy Resource (POWER) project facilitates the use of NASA Earth Science data holdings within the energy, agricultural, and building heating/cooling design industries. POWER packages solar and meteorological data from several NASA projects in a user friendly GIS-enabled web services system (https://power.larc.nasa.gov). As part of the development of new data products to support the energy and building heating/cooling design communities, we estimate the changes in energy required to heat and cool buildings in the future climate at 14 different NASA site locations spread throughout the continental United States, as projected by CMIP6 climate models under different emissions scenarios. Bias-corrected downscaled time series of meteorological variables are taken from NASA Earth Exchange (NEX) Global Daily Downscaled Projections (GDDP-CMIP6) downscaled climate model data. The spread between the different model projections is accounted for by analyzing both the ensemble average of 22 CMIP6 models and 6 representative models with different climate sensitivities and different interannual variability. Changes in energy use are estimated in two ways. First, changes in the total annual heating and cooling degree days (HDD and CDD, respectively) are calculated relative to the current climate. This is done at all 14 sites. Second, the downscaled time series are used as inputs into RETScreen(R), a clean energy management decision tool, to give an estimate of heating/cooling energy use for a typical office building. We use this estimation method with model data at Langley Research Center. In the next 50 years, the annual total of HDD (CDD) is projected to decrease by 8-38% (increase by 5-28%) at all sites, with the increase in CDD typically a larger magnitude the decrease in HDD. For a typical small office building at Langley Research Center, the amount of energy needed to cool increases by 33-54% and the amount of energy to heat decreases by 29-40%. POWER is working to develop long term climate data services based on these results to include in future data products to provide to users.

Bradley M. Hegyi↗

Recent streamflow trends across permafrost basins of North America: Datasets

Climate change impacts, including changing temperatures, precipitation, and vegetation, are widely anticipated to cause major shifts to the permafrost with resulting impacts to hydro-ecosystems across the high latitudes of the globe. However, it is challenging to examine streamflow shifts in these regions owing to a paucity of data, discontinuity of records, and other issues related to data consistency and accuracy. We looked at recent changes in streamflow over 1976-2021 in watersheds affected by varying degrees of permafrost coverage to characterize trends and drivers for a range of watersheds across North America. Data sets are described in detail in the paper associated with this data set, Bennett et al. 2023, Front. Water - Water and Critical Zone, DOI: 10.3389/frwa.2023.1099660.These data contain CSV files of the streamflow, climate, and land surface characteristics for several sites located across the high latitude regions of North America. Both observed and reanalysis data products are provided. These files can be opened using Excel or a text editor, or they can be read, and analyzed in software tools such as Python or R. A brief description of the files is below, and more details can be found in the Methods section.rabpro_stats_north_select_74_55m.csv - This file describes the observed gages used in the analysis.GF31_23_metadat.csv - This file describes the 23 permafrost systems. Columns are as described in rabpro_stats_north_select_74_55m.csv above, with rabpro_id, the id used for the timeseries file mapping in GF31_23_time_series.csv.GF31_23_time_series.csv - This file contains the time series data for the stations described in GF31_23_metadat.csv.GF31_random_reaches_1583.csv - This file describes the 1583 randomly selected permafrost-dominant sites for machine learning analysis.era5_GF31_monthly_vars_random_reaches_1583.csv - This file contains the monthly ERA5 land data for the 1583 randomly selected permafrost-dominant sites.observed.zip: USGS and Hydat station data for the 74 gages analyzed in this study. Monthly, seasonal, and annual streamflow observations for minimum streamflow, mean streamflow, and maximum streamflow. Units are m3/sec. 1975-2022.streamflow_daily_GF31_infilled_1979_2022.csv - infilled daily streamflow data (infilled using GloFAS v 3.1) for 55 gages. Units are m3/sec. 1979-2022.glofas_23.zip - Glofas v3.1 file for the 23 permafrost-dominant gages in the study. Monthly, seasonal, and annual streamflow observations for minimum streamflow, mean streamflow, and maximum streamflow. Units are m3/sec. 1979-2021.glofas_1583.zip - Glofas v3.1 file for the 1583 randomly selected permafrost-dominant gages in the study. Monthly, seasonal, and annual streamflow observations for minimum streamflow, mean streamflow, and maximum streamflow. Units are m3/sec. 1979-2021.

54 ENVIRONMENTAL SCIENCES↗

Laboratory and Airborne BRDF Analysis of Vegetation Leaves and Soil Samples

Laboratory-based Bidirectional Reflectance Distribution Function (BRDF) analysis of vegetation leaves, soil, and leaf litter samples is presented. The leaf litter and soil samples, numbered 1 and 2, were obtained from a site located in the savanna biome of South Africa (Skukuza: 25.0degS, 31.5degE). A third soil sample, number 3, was obtained from Etosha Pan, Namibia (19.20degS, 15.93degE, alt. 1100 m). In addition, BRDF of local fresh and dry leaves from tulip tree (Liriodendron tulipifera) and acacia tree (Acacia greggii) were studied. It is shown how the BRDF depends on the incident and scatter angles, sample size (i.e. crushed versus whole leaf,) soil samples fraction size, sample status (i.e. fresh versus dry leaves), vegetation species (poplar versus acacia), and vegetation s biochemical composition. As a demonstration of the application of the results of this study, airborne BRDF measurements acquired with NASA's Cloud Absorption Radiometer (CAR) over the same general site where the soil and leaf litter samples were obtained are compared to the laboratory results. Good agreement between laboratory and airborne measured BRDF is reported.

Georgiev, Georgi T.↗

Generalized shading analysis for paraboloidal collector fields

This paper presents the development and results of a generalized shading analysis for a field of point-focus parabolic dish concentrators. Shading of one concentrator by another with attendant loss of energy is a function of the position of the sun and the relative locations of the concentrators within the field. A method is presented for determining the annualized energy loss which includes a trade-off of system life-cycle energy as a function of concentrator spacing and field geometric layout. System energy output is computed on an annualized basis, employing 15 minute-increment environmental data tapes for the year 1976 at Barstow, California. For a land cost of $5000 per acre, lowest system energy cost occurs at about a 25 percent packing fraction (concentrator area/land area) for a typical 1-MWe dish-Stirling solar thermal power plant. Basic equations are given for computing the shading and concomitant energy loss as a function of concentrator center-to-center spacing, field layout site location.

Osborn, D. B.↗

SPRUCE Diurnal and Seasonal Patterns of Water Potential in S1 Bog and SPRUCE Experimental Plot Vegetation beginning in 2010

This data set reports on water potential from excised terminal shoots or leaves (Mainthemum only) of vegetation at the SPRUCE site located in the S1 bog. Pretreatment measurements were collected from outside plots within the S1 bog. Post treatments were collected from inside SPRUCE plots. Water potential was measured on the overstory canopy species, consisting of the evergreen Picea mariana (Mill.) B.S.P. (black spruce) and deciduous Larix laricina (Du Roi) K. Koch (tamarack) trees, and ericaceous shrubs < 1 m tall, consisting of the evergreen Rhododendron groenlandicum (Oeder) Kron & Judd (Labrador tea) and Chamaedaphne calyculata (L.) Moench. (leatherleaf). Some measurement campaigns also included the evergreen Kalmia polifolia, Wangenh. (bog laurel), the deciduous Vaccinium angustifolium (Aiton) (blueberry), and the herbaceous Maianthemum trifolium (L.) Sloboda (three-leaf false Solomon’s seal). This dataset contains one data file in comma-separated (*.csv) format. This is the second release of water potential data from the site with additional data from 2018 and 2019. These data cover 2010-06-22 to 2019-07-16. Further results will be added to this data set and released to the public periodically as quality assurance and publication of results are accomplished. There are 10 experimental plots in SPRUCE: five temperature treatments (+0, +2.25, +4.5, +6.75, +9°C) at ambient CO2, and the same five temperature treatments at elevated CO2 (+500 ppm). These data span the pre- and post-treatment periods when enclosed plots were exposed to warming and elevated carbon dioxide (CO2) within the SPRUCE experiment. The pretreatment samples were collected from south end of the S1 bog prior to SPRUCE boardwalk construction, then throughout the bog once the boardwalks were completed.

54 ENVIRONMENTAL SCIENCES↗

TCL3 UTM (UAS Traffic Management) Flight Tests, Airspace Operations Laboratory (AOL) Report

The Technology Capability Level-3 (TCL3) flight tests were conducted at six different test sites located across the USA from March to May of 2018. The campaign resulted in over 830 data collection flights using 28 different aircraft and involving 20 flight crews. Flights not only varied in duration, but also in the environments and terrains over which they flew. The TCL3 tests highlighted four different types of tests: three tests focused on Communication, Navigation and Surveillance (CNS); six tests focused on Sense and Avoid (SAA) technologies; six tests focused on USS Data and Information Exchange (DAT); and five tests focused on exploring fundamental Concepts of the project (CON). This document presents data collected during the TCL3 tests that informed the operator’s experiences—the quality of the unmanned aerial system (UAS) Service Supplier (USS) information that the operator was provided with, the usefulness of this information, and the usability of the automation, both while airborne and on the ground. It is intended to complement the reports written by the test sites and the quantitative reports and presentations of the UAS Traffic Management (UTM) project. With the goal of instructing what the minimum information requirements and/or best practices might be in TCL3 operations, the driving enquiry was: How do you get the information you need, when you need it, to successfully fly a UAS in UTM airspace? This enquiry touches on two requirements for displays, which are to provide adequate situation awareness (SA) and to share information through a USS. The six test sites participating in the TCL3 tests flew a subset of the 20 tests (outlined above), with most sites working on a subset of each of the four types: Communications, Navigation and Surveillance (CNS); DAT; CON; and Sense and Avoid (SAA). The, mainly qualitative, data addressed in this report was collected by the AOL (Airspace Operations Laboratory) both on-site and remotely for each test. The data consists of the contents of end-of-day debriefs, end-of-day surveys, observer notes, and flight test information, all submitted as part of the Data Management Plan (DMP).

Martin, Lynne↗

SPRUCE Precipitation Chemistry and Bulk Atmospheric Deposition Beginning in 2013

This data set reports the chemistry of precipitation water that was collected at the SPRUCE site located in the S1 bog and calculated values of bulk atmospheric deposition of solutes in precipitation. Sample collection and analyses started during December of 2013 and will continue for the duration of the experiment. Precipitation samples were collected year round on an event-basis from up to three individual collectors. Samples were either composited or individually analyzed, depending on the total volume of water available relative to the amount needed to complete all laboratory analyses. Funnel/bottle collectors were used to collect rainfall and buckets were used to collect snowfall and mixed precipitation. Samples were analyzed for pH, specific conductivity, nutrient concentrations (ammonium, nitrate, soluble reactive phosphorus, total nitrogen), cation concentrations (calcium, magnesium), anion concentrations (chloride, sulfate), total organic carbon concentrations, and natural-abundance stable isotopes of water (δ18O-H2O and δD-H2O). Bulk deposition was calculated by multiplying rainfall amount by solute concentration for ammonium, nitrate, soluble reactive phosphorus (SRP), total nitrogen, calcium, magnesium, chloride, sulfate, and total organic carbon. All measurements were made at the 8.1-ha S1 bog forest site in northern Minnesota, 40 km north of Grand Rapids, in the USDA Forest Service Marcell Experimental Forest (MEF).

54 ENVIRONMENTAL SCIENCES↗

Uncertainty in Soil Moisture Retrievals: an Ensemble Approach Using SMOS L-Band Microwave Data

The uncertainty of soil moisture (SM) retrievals from satellite brightness temperature (TB) observations depends primarily on the choice of radiative transfer model (RTM) parameters, prior SM information and TB inputs. This paper studies the sensitivity of several (quasi-)operational and experimental SM retrieval products from the Soil Moisture Ocean Salinity (SMOS) mission to these choices at 11 reference sites, located in 7 watersheds across the United States (US). Different literature-based RTM parameter sets cause large biases between retrievals. Whereas typical RTM parameter sets are calibrated for SM retrievals, it is shown that a parameter set carefully optimized for TB forward modeling can also be used for retrieving SM. It is also shown that the inclusion of dynamic prior SM estimates in a Bayesian retrieval scheme can strongly improve SM retrievals, regardless of the choice of RTM parameters, and that the use of multi-angular and multi-polarization TB does not necessarily lead to superior retrievals compared to retrievals based on TB data at a single incidence angle and polarization. The second part of this paper evaluates ensemble uncertainty metrics for SM retrievals obtained by propagating a wide range of RTM parameters through the RTM. As expected for bounded variables, the spread in the ensemble SM retrievals is smallest for wet and dry SM values and highest for intermediate SM values. After removal of the strong long-term mean bias associated with the RTM parameter values for individual ensemble members, the remaining anomaly ensemble SM spread of 0.037 cu m/cu m approximates the actual time series unbiased root-mean-square-difference of 0.042 cu m/cu m between ensemble mean retrievals and in situ reference data across the reference sites. However, the temporal variability in the anomaly ensemble spread reveals higher-order biases in the retrieval error, which should be accounted for when characterizing retrieval error.

Jan Quets↗

Separation of CO 2 from Flue Gas and Potential for Geologic Sequestration

The objectives of this study were to review various methods reported in the literature for the separation and geologic sequestration of carbon dioxide and evaluate the potential of TVA fossil fuel-burning plant locations for onsite geologic sequestration of CO 2 from stack emissions. Several conventional and nonconventional technologies for the separation of CO 2 from flue gas, including absorption, adsorption, cryogenic distillation, membranes, hydrate formation and dissociation, and ammonia carbonation, have been reviewed in terms of separation mechanisms, flow diagrams, and costs. Most of the technologies that have been reviewed are still at the research and development stage. Critical information needed to assess and compare these technologies is still lacking. In addition, information on some of the technologies that have been tested at a pilot or industrial scale has not been fully disclosed in the open literature. Because of this lack of data, it is difficult to make a critical assessment of each of the separation technologies. Based on limited information, it was concluded that the most promising methods are membrane separation and the Mitsubishi process for chemical absorption. Both processes involve separating CO 2 at high temperature, minimizing the cost for cooling prior to separation. Physical and chemical geologic formations of CO 2 were also reviewed. It was concluded that due to the geologic time scale of CO 2 sequestration periods, relatively safe conditions, general proximity to CO 2 sources, and extensive knowledge of underground conditions, sequestration of CO 2 in underground aquifers and coal beds is a very promising method of mitigating greenhouse gas emissions. The cost is predicted to be relatively low and the suitable sites are numerous for this application, with many of these sites located close to the plants.

20 FOSSIL-FUELED POWER PLANTS↗

Current Ground Test Options for Nuclear Thermal Propulsion (NTP)

About 20 different NTP engines/ reactors were tested from 1959 to 1972 as part of the Rover and Nuclear Engine for Rocket Vehicle Application (NERVA) program. Most were tested in open air at test cell A or test cell C, at the Nevada Test Site (NTS). Even after serious engine breakdowns of the reactor (e.g., Phoebus 1A), the test cells were cleaned up for other engine tests. The engine test stand (ETS) was made for high altitude (approximately 1 psia) testing of an NTP engine with a flight configuration, but still had the exhaust released to open air. The Rover/NERVA program became aware of new environmental regulations which would prohibit the release of any significant quantity of radioactive particulates and noble gases into the open air. The nuclear furnace (NF-1) was the last reactor tested before the program was cancelled in 1973, but successfully demonstrated a scrubber concept on how to filter the NTP exhaust. The NF-1 was demonstrated in the summer of 1972. The NF-1 used a 44MW reactor and operated each run for approximately 90 minutes. The system cooled the hot hydrogen exhaust from the engine with a water spray before entering a particle filter. The exhaust then passed through a series of heat exchangers and water separators to help remove water from the exhaust and further reduce the exhaust temperatures. The exhaust was next prepared for the charcoal trap by passing through a dryer and effluent cooler to bring exhaust temperatures close to liquid nitrogen. At those low temperatures, most of the noble gases (e.g., Xe and Kr made from fission products) get captured in the charcoal trap. The filtered hydrogen is finally passed through a flare stack and released to the air. The concept was overall successful but did show a La plating on some surfaces and had multiple recommendations for improvement. The most recent detailed study on the NTP scrubber concept was performed by the ARES Corporation in 2006. The concept is based on a 50,000 lbf thrust engine (approximately 1 GW) with a maximum burn time of 1 hour. The concept utilized lessons learned from NF-1. The strategy breaks down the exhaust into parallel paths to allow flexibility with engine size and mass flow of exhaust. Similar to NF-1, the exhaust is slowed down, cooled, filtered of particulates, filtered of noble gases, and then the clean hydrogen is flared to open air. Another concept proposed by Steve Howe (currently Director of the Center for Space Nuclear Research) to simplify the NTP exhaust filtering is to run the hydrogen exhaust into boreholes underground to filter the exhaust. The two borehole site locations proposed are at the NTS and at the Idaho National Laboratory (INL). At NTS, the boreholes are 8' diameter and 1200' deep. The permeability of hydrogen through the soil and its buoyancy will allow it to rise up through the soil and allow the filtering of noble gases and radioactive particulates. The exhaust needs to be cooled to 600C before entering the borehole to avoid soil glazing. Preliminary analysis shows a small buildup of back pressure with time which depends on permeability. Noble gases entering the borehole walls deep can take a long time before reaching the surface. Other factors affecting permeability include borehole pressure, water saturation, and turbulence. Also, a possible need to pump out contaminated water collected at the bottom of the borehole. At INL, the borehole concept is slightly different. The underground borehole has openings to the soil at special depths which have impermeable interbeds above the water table and below the surface to allow the exhaust to travel horizontal between the impermeable layers. Preliminary results indicate better permeability than at NTS. The last option is total containment of the exhaust during the test run. The concept involves slowing down the flow to subsonic in a water cooled diffuser. The hydrogen is burned off in an oxygen rich afterburner with the only products being steam, oxygen, and some noble gases. A heat exchanger and water spray pulls heat from the steam and lowers the temperature for condensation. The optimum ratio between the two is being investigated, with a goal to minimize the total volume of the water hold tanks. A water tank farm collects the contaminated water. The amount of water produced from burning the hydrogen is approximately 100,000 gallons (not including cooling water) for a 25k lbf engine operating for 50 minutes. Residual gases (e.g., oxygen and some noble gases) can be captured at cryogenic levels with a liquid nitrogen cooled dewar. After a few weeks post-test, the radiation levels can drop to more favorable levels before slowly draining each capture tank and using existing filters. With today's environmental regulations, the NTP exhaust is filtered to meet 10 mrem/year exposure to the general public (at a DOE site) or 100 mrem/year (via NRC when tested elsewhere), when natural background radiation exposure to the general public is 300- 600 mrem per year. The current society feels more comfortable with filtering even lower to as low as reasonably achievable (ALARA).

Gerrish, Harold P., Jr.↗