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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

The metrology of spherical shells using synchrotron x ray microtomography

With recent advances in solid state imaging technology and the increasing availability of synchrotron x-ray radiation sources, synchrotron x-ray microtomography is emerging as a nondestructive technique for the evaluation of the structure and composition of small specimens with spatial resolution in the micron range. Synchrotron radiation offers the following advantages over conventional x-ray sources: high brightness, continuous emission which is tunable over a large energy range, faster data collection rates, and a highly collimated beam of large cross section permitting the illumination of large specimens. Synchrotron x-ray microtomography enables the structure of individual spheres to be evaluated in order to reveal the concentricity and sphericity of the internal void and the uniformity of the shell wall in the case of high quality spherical shells for Sandia National Laboratories' Inertial Confinement Fusion project.

Hmelo, Anthony B.↗

Stressing Halide Perovskites with Light and Electric Fields

Understanding the light and electric field-induced effects underlying the local changes in optoelectronic properties in lead halide perovskites is crucial to establish a detailed structure–function relationship. Here, in this study, we use single-molecule absorption scanning tunneling microscopy (SMA-STM) to probe the local surface inhomogeneity of a mixed A-site cation/mixed halide perovskite under pulsed 532 nm photoexcitation to gain insight into the varying grain-to-grain absorption behavior at the nanoscale and reduction in the electronic bandgap under illumination. To correlate the observed changes in the absorption signal to structural ones, we utilize synchrotron X-ray STM (SX-STM) where we find that photoexcitation induces changes in the X-ray absorption spectral signatures. Lastly, using pump–probe time-resolved wide-angle X-ray scattering, we show the presence of nonthermal lattice deformations upon photoexcitation which indicate that the excited photocarriers distort the perovskite lattice, corroborating the local electronic changes observed by our STM measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Imaging system and method for enhanced visualization of near surface vascular structures

A sub-dermal structure visualization system and method is disclosed. The system may use an illumination module including: a near-infrared (NIR) light source adapted to substantially uniformly illuminate an imaged area including sub-dermal regions thereof with NIR light; and a first optical system including at least one optical element for controlling at least one of spectral and polarization properties of the NIR light prior to illuminating the imaged area. An imaging module rejects unwanted signals from an imaged area while passing desired optical signals that are to be received by an image acquisition module. The desired optical signals can comprise a vein visualization signal to assist in visualizing a vascular structure below a skin layer of a patient.

Demos, Stavros G.↗

Direct observation of oxygen vacancy ordering evolution in cerium oxide at varying concentrations via high-resolution transmission electron microscopy

Under illumination by a 300 keV electron beam, oxygen vacancy ordering structures are induced within cerium oxide grains. Here, our high-resolution transmission electron microscopy (HRTEM) study, supported by image simulation, reveals the evolution of these structures as vacancy concentration increases. The observed fluorite-type superlattice structures are identified as CeO 1.825 , CeO 1.75 , Ce 2 O 3 , displaying a gradient in oxygen vacancy concentration moving away from the grain surface. Correspondingly, the structural sequence transitions from Ce 2 O 3 to CeO 1.75 and then to CeO 1.825 . Without the constraints of surrounding grains, fluorite-type Ce 2 O 3 nanocrystals show a preference for transformation into an A-type trigonal structure. Notably, at temperatures up to 200°C, only the perfect fluorite structure is observed. Structural models were validated through both [110] and [001] projections. Our findings further confirm lattice expansion associated with local oxygen vacancy enrichment, which can be compensated by the formation of stacking faults, where a {111} oxygen plane is lost at defect sites.

Cerium oxide↗

Identification, characterization, and structure of a tRNA splicing enzyme RNA 5′-OH kinase from the pathogenic fungi Mucorales

Fungal Trl1 is an essential tRNA splicing enzyme composed of C-terminal cyclic phosphodiesterase and central polynucleotide kinase end-healing domains that convert the 2′,3′-cyclic-PO 4 and 5′-OH ends of tRNA exons into the 3′-OH,2′-PO 4 and 5′-PO 4 termini required for sealing by an N-terminal ATP-dependent ligase domain. Trifunctional Trl1 enzymes are present in most human fungal pathogens and are untapped targets for antifungal drug discovery. Mucorales species, deemed high-priority human pathogens by WHO, elaborate a noncanonical tRNA splicing apparatus in which a stand-alone monofunctional RNA ligase enzyme joins 3′-OH,2′-PO 4 and 5′-PO 4 termini. Here we identify a stand-aloneMucor circinelloidespolynucleotide kinase (MciKIN) and affirm its biological activity in tRNA splicing by genetic complementation in yeast. Recombinant MciKIN catalyzes magnesium-dependent phosphorylation of 5′-OH RNA and DNA ends in vitro. MciKIN displays a strong preference for GTP as the phosphate donor in the kinase reaction, a trait shared with the stand-alone RNA kinase homologs from Mucorales speciesRhizopus azygosporus(RazKIN) andLichtheimia corymbifera(LcoKIN) and with the kinase domains of fungal Trl1 enzymes. We report a 1.65 Å crystal structure of RazKIN in complex with GDP•Mg 2+ that illuminates the basis for guanosine nucleotide specificity.

Biochemistry & Molecular Biology↗

Imaging radar investigations of the Sudbury structure

This paper reports preliminary results of airborne imaging radar studies of the Sudbury structure carried out in preparation for a CCRS European Remote Sensing Satellite (ERS-1) investigation. The data used were synthetic aperture radar (SAR) C-band (5.66 cm) images acquired from about 6 km altitude in 1987. They cover the Sudbury area in both wide and narrow swath modes, with east-west flight paths and north-south illumination directions. Narrow swath resolution is 6 m in range and azimuth; wide swath resolution is 20 m in range and 10 m in azimuth. The STAR imagery has proven highly effective for field use, providing excellent rendition of topography and topographically expressed structure. Reasons for this include the illumination geometry, notably the look azimuth normal to the long axis of the Sudbury structure and Penokean fold axes, the good spatial resolution, and the short wavelength. Forested areas in the Sudbury area tend to be uniformly rough at C-band wavelength, with backscatter dominated by local incidence angle (i.e., topography). Field work using the SAR imagery has to date been concentrated in the North Range and Superior Province as far north as the Benny greenstone belt. This area was chosen for initial investigation of the original size and shape of the Sudbury structure because the effects of the Penokean Orogeny were minimal there. Field work using SAR indicates that there has been little postimpact deformation of the North Range or adjacent Superior Province rock. There appears to be no evidence for an outer ring concentric with the North Range as indicated by early Landsat imagery. The apparent ring shown by Landsat is visible on the SAR imagery as the intersection of two regional fracture patterns not related to the Sudbury structure. There is no outer ring visible southwest of the structure. This can reasonably be explained by Penokean deformation, but there is no outer ring to the northeast cutting the relatively undeformed Huronian sediments of the Cobalt Embayment.

Lowman, P. D.↗

Laser Light Sheet Flow Visualization of the Space Launch System Booster Separation Test

Planar flow visualizations were obtained in a wind tunnel test in the NASA Langley Research Center’s Unitary Plan Wind Tunnel using the laser-light-sheet method. This method uses a laser to illuminate fine particles generated in the wind tunnel to visualize flow structures. The test article was designed to simulate the separation of the two solid rocket boosters (SRBs) from the core stage of the NASA Space Launch System (SLS) at Mach 4 using a scale model. The test was run on of the SLS Block 1B Cargo (27005) configuration and the SLS Block 1B Crew (28005) configuration. Planar flow visualization was obtained only on the crew configuration. Air at pressures up to 1500 psi was used to simulate plumes from the booster separation motors (BSMs) located at the nose, and aft skirt of the two boosters. The facility free stream was seeded with water vapor, which condensed and froze into small ice crystals in the tunnel nozzle expansion. A continuous wave green (532 nm) laser sheet was used to illuminate the ice crystals, and the resulting Mie-scattered light was collected with a camera. The resulting images clearly identify shock waves and other flow features including BSM plume shapes. Measurements were acquired for different BSM pressures and booster separation locations.

Danehy, Paul M.↗

Structural Instability in Electrically Stressed, Oxygen Deficient BaTiO 3 Nanocrystals

The dynamics of oxygen vacancies under external stimuli dominates the performance of many solid-state devices, including capacitors, oxide memristors, anionic conductors, etc. By means of in-situ Transmission Electron Microscopy, we found in BaTiO 3 perovskite nanocrystals that formation of oxygen vacancies due to electrical stressing renders the oxide amorphizable under electron beam illumination, suggesting the presence of a threshold concentration of oxygen vacancy affecting the structural stability of BaTiO 3 crystals upon high energy radiation. In contrast to the structural change, the resistivity of the nanocrystal seems not liable to the amorphization prior to dielectric breakdown at higher voltage bias. Here, we propose that an increase in oxygen vacancy content promotes oxygen mobility in the perovskite structure allowing electron beam induced electric field to modify the local structural and composition. Our in-situ observations reveal the central role of oxygen vacancies in the structural stability of perovskites which is of paramount importance to their applications in extreme environments and suggest a potential new route to micro-processing perovskite oxides using the electron beam via oxygen vacancy management without severely compromising the electric property.

36 MATERIALS SCIENCE↗

The Wizard Staff: A Mobile Tool Supporting Human Exploration on The Lunar Surface

The Wizard Staff is a rechargeable, battery powered mobile tool with multiple uses for lunar surface exploration. It supports human activity as a surface survey tool, provides external illumination to enhance safety, delivers networking, communications, and navigation features to remote sites, and assists crew rescue with an emergency beacon and rigid splint structure. As a survey tool, it assists crewed geologic field site exploration with external lights, cameras, and LiDAR to illuminate, map, and record the sample collection process. As a relay station, it provides a surface intranet communications and navigation node for extended exploration far from the lander or habitation module. A separately developed Search-and-Rescue (SAR) handheld device can broadcast a signal to the Gandalf Staff containing crew position and biometric data. The staff then formats the message and sends it orbiting satellite(s) for emergency response via the LunaNET on a dedicated frequency similar to terrestrial applications using an Emergency Position-Indicating Radiobeacon (EPIRB). The staff is designed with an upper and lower segment. Components in the upper segment are the LiDAR, external lighting arrays, cameras, communications equipment, intelligence devices, and user interface for crew operations. The lower segment is a set of FeLiPO4 battery cells packed into the 2” diameter carbon fiber tube. When the battery pack is discharged, a spring connector (designed for the dusty lunar environment) easily disconnects the two segments for replacement with another fully charged battery pack. The lower segment can be used for Incapacitated Crew Rescue (ICR) as a rigid splint. As a stand-alone science platform, the Wizard Staff provides infrastructure for instruments and sensors to record the lunar environment over long periods of time. After a crew installs the components on the lunar surface, the platform delivers data to the lunar lander or base station for analysis. The stand-alone mode requires an auxiliary power source (e.g. solar array) and energy storage system (e.g. battery), so it could also be used as an electrical recharging station. A working prototype of Wizard Staff has been developed with collaboration between NASA (JSC, MSFC, and GSFC), Texas Space Technology Applications and Research (T STAR), and Texas A&M University (TAMU) using $300k of innovation funding in FY’21 and FY’22. The functional staff weights 36# on Earth (6# on the Moon), stands 2.1m tall and delivers external lighting with an array of 40 LED bulbs generating 1460 Lux at 2m range (near field), or 2 Lux at 50m (far field).

Gandalf Staff↗

Side-looking airborne radar image interpretation and geological mapping: Problems and results

Geological experiments and surveys conducted by BRGM and GDTA members to evaluate interest in SLAR image interpretation are summarized. Two surveys were selected for presentation: Les Vans (Massif central, France) and Guyana (South America). They have permitted a comparison between different types of SLAR: Goodyear, Motorola, JPL, and Vigie in term of lithological and structural applications. On the Les Vans test site conclusions reached concern radiometry, which is better on L-band imagery, polarization, HV being more useful than HH for geological mapping in an L-band system, wavelength and illuminations. Over Guyana, the use of Goodyear X-band SLAR enables satisfactory geological and structural mapping under heavy equatorial forest with cloud cover conditions. A differential program was developed for fracture filtering and image enhancement with a coherent light laser, and significant results were obtained.

Scanvic, J. Y.↗

Geologic Structures in Crater Walls on Vesta

The Framing Camera (FC) on the Dawn spacecraft has imaged most of the illuminated surface of Vesta with a resolution of apporpx. 20 m/pixel through different wavelength filters that allow for identification of lithologic units. The Visible and Infrared Mapping Spectrometer (VIR) has imaged the surface at lower spatial resolution but high spectral resolution from 0.25 to 5 micron that allows for detailed mineralogical interpretation. The FC has imaged geologic structures in the walls of fresh craters and on scarps on the margin of the Rheasilvia basin that consist of cliff-forming, competent units, either as blocks or semi-continuous layers, hundreds of m to km below the rims. Different units have different albedos, FC color ratios and VIR spectral characteristics, and different units can be juxtaposed in individual craters. We will describe different examples of these competent units and present preliminary interpretations of the structures. A common occurrence is of blocks several hundred m in size of high albedo (bright) and low albedo (dark) materials protruding from crater walls. In many examples, dark material deposits lie below coherent bright material blocks. In FC Clementine color ratios, bright material is green indicating deeper 1 m pyroxene absorption band. VIR spectra show these to have deeper and wider 1 and 2 micron pyroxene absorption bands than the average vestan surface. The associated dark material has subdued pyroxene absorption features compared to the average vestan surface. Some dark material deposits are consistent with mixtures of HED materials with carbonaceous chondrites. This would indicate that some dark material deposits in crater walls are megabreccia blocks. The same would hold for bright material blocks found above them. Thus, these are not intact crustal units. Marcia crater is atypical in that the dark material forms a semi-continuous, thin layer immediately below bright material. Bright material occurs as one or more layers. In one region, there is an apparent angular unconformity between the bright material and the dark material where bright material layers appear to be truncated against the underlying dark layer. One crater within the Rheasilvia basin contains two distinct types of bright materials outcropping on its walls, one like that found elsewhere on Vesta and the other an anomalous block ~200 m across. This material has the highest albedo; almost twice that of the vestan average. Unlike all other bright materials, this block has a subdued 1 micron pyroxene absorption band in FC color ratios. These data indicate that this block represents a distinct vestan lithology that is rarely exposed.

Mittlefehldt, David W.↗

Illumination requirements for operating a space remote manipulator

Critical issues and requirements involved in illuminating remote manipulator operations in space help establish engineering designs for these manipulators. A remote manipulator is defined as any mechanical device that is controlled indirectly or from a distance by a human operator for the purpose of performing potentially dangerous or hazardous tasks to increase safety, reliability, and efficiency. Future space flights will rely on remote manipulators for a variety of tasks including satellite repair and servicing, structural assembly, data collection and analysis, and performance of contingency tasks. Carefully designed illumination of these manipulators will assure that these tasks will be completed efficiently and successfully. Studies concerning the influence of illumination on operation of a remote manipulator are few. Available results show that illumination can influence how successfully a human operates a remote manipulator. The intent of this study was to more fully examine this topic.

Chandlee, George O.↗

Light-Driven Charge Transport and Optical Sensing in Molecular Junctions

Probing charge and energy transport in molecular junctions (MJs) has not only enabled a fundamental understanding of quantum transport at the atomic and molecular scale, but it also holds significant promise for the development of molecular-scale electronic devices. Recent years have witnessed a rapidly growing interest in understanding light-matter interactions in illuminated MJs. These studies have profoundly deepened our knowledge of the structure–property relations of various molecular materials and paved critical pathways towards utilizing single molecules in future optoelectronics applications. In this article, we survey recent progress in investigating light-driven charge transport in MJs, including junctions composed of a single molecule and self-assembled monolayers (SAMs) of molecules, and new opportunities in optical sensing at the single-molecule level. We focus our attention on describing the experimental design, key phenomena, and the underlying mechanisms. Specifically, topics presented include light-assisted charge transport, photoswitch, and photoemission in MJs. Emerging Raman sensing in MJs is also discussed. Finally, outstanding challenges are explored, and future perspectives in the field are provided.

36 MATERIALS SCIENCE↗

Geologic interpretation of Apollo 6 stereophotography from Baja California to west Texas

Excellent space photography of parts of the southwestern United States and northwestern Mexico was obtained during the unmanned Apollo 6 spaceflight. Two features of this photography made it useful for geologic interpretations: its vertical stereocoverage and its exposure under a relatively low angle of solar illumination through an unusually cloud-free and clear atmosphere. The structural patterns, which were topographically enhanced by the longer shadows, were annotated on the photographs, in order to analyze their trends with respect to the continental tectonic framework, and to attempt to correlate the pattern with known copper or other base metal deposits. The annotated fracture patterns showed the regional trends and their distribution. The area studied was a 100- to 105-mile swath of terrain covering a total land area of approximately 60,000 square statute miles. The coverage began from a point centered on Punta Colnett on the Pacific coast of Baja California and extended to the Sacramento Mountains of New Mexico and west Texas.

Gawarecki, S. J.↗

Thunderstorm observations from Space Shuttle

Results of the Nighttime/Daytime Optical Survey of Lightning (NOSL) experiments done on the STS-2 and STS-4 flights are covered. During these two flights of the Space Shuttle Columbia, the astronaut teams of J. Engle and R. Truly, and K. Mattingly II and H. Hartsfield took motion pictures of thunderstorms with a 16 mm cine camera. Film taken during daylight showed interesting thunderstorm cloud formations, where individual frames taken tens of seconds apart, when viewed as stereo pairs, provided information on the three-dimensional structure of the cloud systems. Film taken at night showed clouds illuminated by lightning with discharges that propagated horizontally at speeds of up to 10 to the 5th m/sec and extended for distances on the order of 60 km or more.

Vonnegut, B.↗

Integrated Requirements Analysis and Technology Roadmaps

In fiscal year 1997, Strategic Insight performed analytical studies for NASA's Highly Reusable Space Transportation (HRST) program, creating program documents which illuminated technical requirements and critical research opportunities. Studies were performed to structure and confirm HRST's evolving technical requirements, building on Marshall's Phase 1 work, which defined HRST system concepts, analytical tools and high-level issues for assessment in Phase 2. Specifically, Strategic Insight: (1) Performed a requirements analysis to update HRST: An Advanced Concepts Study, Study Guidelines, Version 2.0 of January 22, 1996; only minor changes were recommended for the given parameters of interest to concept designers; (2) Conducted mini-workshops during HRST Working Group meetings on April 14-15, 1997 and July 22-24, 1997; and (3) Created structures for technology road maps of candidate HRST concepts, both subsystem and end-to-end concepts, emerging from the 13 cooperative agreement projects.

Source record↗

Illumination Conditions at the Lunar Poles: Implications for Future Exploration

We produced 400 x 400 km Digital Terrain Models (DTMs) of the lunar poles from Lunar Orbiter Laser Altimeter (LOLA) ranging measurements. To achieve consistent, high-resolution DTMs of 20 m/pixel the individual ranging profiles were adjusted to remove small track-to-track o sets. We used these LOLADTMs to simulate illumination conditions at surface level for 50 x 50 km regions centered on the poles. Illumination was derived in one-hour increments from 01 January, 2017 to 01 January, 2037 to cover the lunar precessional cycle of 18.6 years and to determine illumination conditions over several future mission cycles. We identified three regions receiving high levels of illumination at each pole, e.g. the equator-facing crater rims of Hinshelwood, Peary and Whipple for the north pole and the rim of Shackleton crater, and two locations on a ridge between Shackleton and de Gerlache crater for the south pole. Their average illumination levels range from 69.5% to 82.9%, with the highest illumination levels found at the north pole on the rim of Whipple crater. A more detailed study was carried out for these sites as targets for a lander and/or rover equipped with solar arrays. For this purpose we assumed a lander with a structural height of two meters above the ground (height of the solar panels). Here average illumination levels range from 77.1% to 88.0%, with the maximum found at the ridge between Shackleton and de Gerlache crater on the south pole. Distances, sizes and slopes of nearby Permanently Shadowed Regions (PSRs) as a prime science target were also assessed in this case.

LOLA↗

Variation in spectral response of soybeans with respect to illumination, view, and canopy geometry

Comparisons of the spectral response for incomplete (well-defined row structure) and complete (overlapping row structure) canopies of soybeans indicated a greater dependence on Sun and view geometry for the incomplete canopies. Red and near-IR reflectance for the incomplete canopy decreased as solar zenith angle increased for a nadir view angle until the soil between the plant rows was completely shaded. Thereafter for increasing solar zenith angle, the red reflectance leveled off and the near-IR reflectance increased. A 'hot spot' effect was evident for the red and near-IR reflectance factors. The 'hot spot' effect was more pronounced for the red band based on relative reflectance value changes. The ratios of off-nadir to nadir acquired data reveal that off-nadir red band reflectance factors more closely approximated straightdown measurements for time periods away from solar noon. Normalized difference generally approximated straightdown measurements during the middle portion of the day.

Ranson, K. J.↗