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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Program Instrumentation and Trace Analysis

Several attempts have been made recently to apply techniques such as model checking and theorem proving to the analysis of programs. This shall be seen as a current trend to analyze real software systems instead of just their designs. This includes our own effort to develop a model checker for Java, the Java PathFinder 1, one of the very first of its kind in 1998. However, model checking cannot handle very large programs without some kind of abstraction of the program. This paper describes a complementary scalable technique to handle such large programs. Our interest is turned on the observation part of the equation: How much information can be extracted about a program from observing a single execution trace? It is our intention to develop a technology that can be applied automatically and to large full-size applications, with minimal modification to the code. We present a tool, Java PathExplorer (JPaX), for exploring execution traces of Java programs. The tool prioritizes scalability for completeness, and is directed towards detecting errors in programs, not to prove correctness. One core element in JPaX is an instrumentation package that allows to instrument Java byte code files to log various events when executed. The instrumentation is driven by a user provided script that specifies what information to log. Examples of instructions that such a script can contain are: 'report name and arguments of all called methods defined in class C, together with a timestamp'; 'report all updates to all variables'; and 'report all acquisitions and releases of locks'. In more complex instructions one can specify that certain expressions should be evaluated and even that certain code should be executed under various conditions. The instrumentation package can hence be seen as implementing Aspect Oriented Programming for Java in the sense that one can add functionality to a Java program without explicitly changing the code of the original program, but one rather writes an aspect and compiles it into the original program using the instrumentation. Another core element of JPaX is an observation package that supports the analysis of the generated event stream. Two kinds of analysis are currently supported. In temporal analysis the execution trace is evaluated against formulae written in temporal logic. We have implemented a temporal logic evaluator on finite traces using the Maude rewriting system from SRI International, USA. Temporal logic is defined in Maude by giving its syntax as a signature and its semantics as rewrite equations. The resulting semantics is extremely efficient and can handle event streams of hundreds of millions events in few minutes. Furthermore, the implementation is very succinct. The second form of even stream analysis supported is error pattern analysis where an execution trace is analyzed using various error detection algorithms that can identify error-prone programming practices that may potentially lead to errors in some different executions. Two such algorithms focusing on concurrency errors have been implemented in JPaX, one for deadlocks and the other for data races. It is important to note, that a deadlock or data race potential does not need to occur in order for its potential to be detected with these algorithms. This is what makes them very scalable in practice. The data race algorithm implemented is the Eraser algorithm from Compaq, however adopted to Java. The tool is currently being applied to a code base for controlling a spacecraft by the developers of that software in order to evaluate its applicability.

Havelund, Klaus↗
NASA NTRS1976

Chemical evidence for the genesis of the ureilites, the achondrite Chassigny and the nakhlites

An investigation has been conducted of the ureilites and the achondrite Chassigny to elucidate differences in their petrogenesis. The experimental studies reported include the determination of elemental abundances by instrumental neutron activation analysis. Attention is given to lithophile elements in ureilites, lithophile elements in Chassigny, the relationship between Chassigny and the nakhlites, and siderophile trace elements in the ureilites.

Boynton, W. V.↗
NASA NTRS1977

Chemical characterization of lunar core 60010

Twenty-eight major, minor, and trace-element abundances have been determined in nine fines fractions of core 60010 by instrumental thermal and 14 MeV neutron activation analysis. With the exception of the elements Fe, Co, and Ni, core section 60010 exhibits a much more uniform composition than the lower section (60009) of the double drive tube collected at the Apollo 16 LM site. The siderophilic meteorite indicator elements Fe, Co, and Ni are significantly enriched in subsample 40, which is located 3.0-4.5 cm below the lunar surface, and are highly variable throughout the 60010 core section. Microscopic examination of subsample 40 revealed the presence of numerous metallic fragments including an approximately 1-mm metal fragment exhibiting only Fe, Co, Ni, and Ir gamma-ray peaks and having a composition typical of a coarse octahedrite. Composition profiles of 60010 exhibit small variations in lithophilic element abundances which can be related to most of the seven stratigraphic units of Duke and Nagle (1976). Although the basal portion of 60010 has been described as texturally similar to the upper unit of 60009, the present chemical studies show a marked compositional difference at this interface.

Ali, M. Z.↗
NASA NTRS1991

X-ray optics. II - A technique for high resolution spectroscopy

A novel combination of optical elements and properties is combined to achieve high-spectral resolution using grazing incidence optics of modest quality. Analysis and ray tracing of examples show that using radial groove gratings at high blaze angles in the manner of an echelle spectrograph can provide high spectral resolution. This arrangement is compared to the conventional in-plane designs to show that the off-plane is superior in nearly every respect. Cross dispersion can be provided by the energy resolution of a CCD detector. Additional resolution can be squeezed from the system by strategic placement of gratings to take advantage of the azimuthal response of a Wolter X-ray optic.

Cash, Webster C., Jr.↗
NASA NTRS1994

Preparation And Analysis Of Specimens Of Ablative Materials

Procedure for chemical analysis of specimens of silicone-based ablative thermal-insulation materials SLA-561 and MA25 involves acid digestion of specimens to prepare them for analysis by inductively-coupled-plasma/atomic-emission spectroscopy (ICP/AES). In comparison with atomic-absorption spectroscopy (AAS), ICP/AES is faster and more accurate than AAS. Results of analyses stored in data base, used to trace variations in concentrations of chemical elements in materials during long-term storage, and used in timely manner in investigations of failures. Acid-digestion portion of procedure applied to other thermal-insulation materials containing room-temperature-vulcanizing silicones and enables instrumental analysis of these materials.

Solomon, William C.↗
NASA NTRS1989

Petrogenetic modeling of 74220 high-Ti orange volcanic glasses and the Apollo 11 and 17 high-Ti mare basalts

An INAA analysis of 16 individual spherules of orange volcanic glass extracted from the 74220,680 soil was performed in order to determine trace element signatures in a primary high-Ti mare magma. The composition of these glasses is shown to be nearly identical to that of 74220 bulk soil, indicating a general absence of constituents other than volcanic glass in the soil. The results suggest that the evolving lunar mantle included processes of cumulate-mass transport and/or segregation of the primordial lunar magma ocean into separate differentiating zones, allowing commingling of early and late components.

Hughes, S. S.↗
NASA NTRS2004

Integrated Modeling Activities for the James Webb Space Telescope: Structural-Thermal-Optical Analysis

The James Web Space Telescope (JWST) is a large, infrared-optimized space telescope scheduled for launch in 2011. This is a continuation of a series of papers on modeling activities for JWST. The structural-thermal-optical, often referred to as STOP, analysis process is used to predict the effect of thermal distortion on optical performance. The benchmark STOP analysis for JWST assesses the effect of an observatory slew on wavefront error. Temperatures predicted using geometric and thermal math models are mapped to a structural finite element model in order to predict thermally induced deformations. Motions and deformations at optical surfaces are then input to optical models, and optical performance is predicted using either an optical ray trace or a linear optical analysis tool. In addition to baseline performance predictions, a process for performing sensitivity studies to assess modeling uncertainties is described.

Johnston, John D.↗
DOE OSTI2025

Hyperspectral x-ray imaging mapping capabilities for nuclear forensics

Nuclear forensics relies on the integration of complementary signatures to constrain the origins and history of materials. Outcomes benefit from the timeliness and precision of the disparate methods that form typical analysis chains. Sample forms are often either minute in quantity or contain signatures like morphology or composition heterogeneity encoded on a microscale, so many analysis techniques focus on resolving signatures on ever-smaller length scales. The new hyperspectral x-ray imaging (HXI) instrument developed at Los Alamos National Laboratory seeks to improve the information available from scanning electron microscopy (SEM) x-ray spectrum analysis through superior spectral energy resolution vs. typical energy dispersive spectroscopy (EDS) systems in common use in nuclear forensics and other microanalysis fields. Based on arrays of transition-edge sensor (TES) microcalorimeter detectors, this instrument achieves a typical energy resolution of 7 eV full-width at half-maximum (FWHM) at 2 keV, opening new possibilities in trace element detection/analysis and chemical state determination through spectral shape shifts. We present here some of the first applications of the HXI instrument to actinide samples and discuss potential maturation of this nascent technology for future analysis pipelines.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1977

Results of special mechanical analyses of Luna 16 material

The studies carried out on the Luna 16 regolith have confirmed the data that were already published internationally. By means of activation analysis under irradiation in the reactor, activation analysis with a 14 MeV U-generator, and mass spectroscopy on samples of 10 or 20 mg, six main and 63 trace elements were quantitatively determined and compared with known data.

Stiller, H.↗
NASA NTRS1980

An interactive modular design for computerized photometry in spectrochemical analysis

An interactive, top-down structured program design is described which produces a general flexible description of totally automatic photometry of emission spectra in an operating environment in which sample compositions and analysis procedures are low-volume and nonroutine. The use of this type of programming is illustrated by a project to computerize trace elemental determinations including the automated reading of spectrographic plates produced by a 3.4-m Ebert mount spectrograph using a dc-arc in an argon atmosphere.

Bair, V. L.↗
NASA NTRS1996

Automated SEM Modal Analysis Applied to the Diogenites

Analysis of volume proportions of minerals, or modal analysis, is routinely accomplished by point counting on an optical microscope, but the process, particularly on brecciated samples such as the diogenite meteorites, is tedious and prone to error by misidentification of very small fragments, which may make up a significant volume of the sample. Precise volume percentage data can be gathered on a scanning electron microscope (SEM) utilizing digital imaging and an energy dispersive spectrometer (EDS). This form of automated phase analysis reduces error, and at the same time provides more information than could be gathered using simple point counting alone, such as particle morphology statistics and chemical analyses. We have previously studied major, minor, and trace-element chemistry of orthopyroxene from a suite of diogenites. This abstract describes the method applied to determine the modes on this same suite of meteorites and the results of that research. The modal abundances thus determined add additional information on the petrogenesis of the diogenites. In addition, low-abundance phases such as spinels were located for further analysis by this method.

Bowman, L. E.↗
NASA NTRSDate not supplied

Preliminary Characterization of Spinel Troctolite Clast Identified in Apollo Next Generation Sample Analysis (ANGSA) Core 73002

The lunar magnesian (Mg-) suite is a diverse lithological group composed of Mg-rich mafic minerals. The Mg-suite consists primarily of troctolites, norites, gabbronorites, and spinel troctolites. These rocks exhibit contradictory geochemical traits, with mafic minerals bearing high Mg# (molar 100×Mg/[Mg+Fe]) indicating primitive parental magmas, but also plagioclase saturation and enrichments in incompatible trace elements (i.e., KREEP) indicate more evolved parental magmas. A variety of models have been invoked to explain the occurrence and petrogenesis of the Mg-suite. Here, we report on a new spinel troctolite clast found in Apollo Next Generation Sample Analysis (ANGSA) program core 73002. Sample 73002 was acquired at Station 3 during Apollo 17 as the upper part of a double-drive tube with sample 73001. During processing, the spinel troctolite clast (0.066 g) was found at the 4.0–4.5 cm depth interval.

A. C. Stadermann↗
NASA NTRS1981

Computations of ion diffusion coefficients from the Boltzmann-Fokker-Planck equation

The Boltzmann-Fokker-Planck equation is solved with the Chapman-Enskog method of analysis for the velocity distribution functions of helium, carbon, nitrogen, and oxygen. The analysis is a perturbation scheme based on the assumption of a collision-dominated gas, and the calculations are carried out to first order. The elements considered are treated as trace constituents in an electron-proton gas. From the resulting distribution functions, diffusion coefficients are computed which are found to be 20-30% less than those obtained by Chapman and Burgers. In addition, it is shown that the return current of cold electrons needed to maintain quasi-neutrality in a plasma with a temperature gradient contributes a term in the thermal diffusion coefficient omitted erroneously in previous works. This added term resolves the longstanding controversy over the discrepancy between the coefficients of Chapman and Burgers, which are seen to be completely equivalent in the light of this analysis. The viscosity coefficient for an electron-proton gas is also computed and found to be 7% less than that obtained by Braginskii.

Roussel-Dupre, R.↗
NASA NTRS1973

Elemental abundances of Apollo 16 samples

Results are presented for the multielement analysis of samples of lunar soil (60501 and 64501), igneous rock (60315), and the light portion of breccia 60017. A mixing model for soil compositions has been proposed consisting of linear combinations of the KREEP basalt 60315 and the anorthositic gabbroic sample 60017. A comparison of trace elements in lunar soils from different missions indicates the marked depletion of the LIL elements in the Apollo 16 samples.

Morrison, G. H.↗
NASA NTRS1974

Quantitation and detection of vanadium in biologic and pollution materials

A review is presented of special considerations and methodology for determining vanadium in biological and air pollution materials. In addition to descriptions of specific analysis procedures, general sections are included on quantitation of analysis procedures, sample preparation, blanks, and methods of detection of vanadium. Most of the information presented is applicable to the determination of other trace elements in addition to vanadium.

Gordon, W. A.↗
NASA NTRS1979

Measurement techniques for trace metals in coal-plant effluents: A brief review

The strong features and limitations of techniques for determining trace elements in aerosols emitted from coal plants are discussed. Techniques reviewed include atomic absorption spectroscopy, charged particle scattering and activation, instrumental neutron activation analysis, gas/liquid chromatography, gas chromatographic/mass spectrometric methods, X-ray fluorescence, and charged-particle-induced X-ray emission. The latter two methods are emphasized. They provide simultaneous, sensitive multielement analyses and lend themselves readily to depth profiling. It is recommended that whenever feasible, two or more complementary techniques should be used for analyzing environmental samples.

Singh, J. J.↗
NASA NTRS1984

On the chondrite-achondrite transition - Mineralogy and chemistry of Yamato 74160 (LL7)

Petrology, mineralogic properties and contents of major elements and trace elements Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Se, Te, Tl, U and Zn are reported (determined by radiochemical neutron activation analysis) in Yamato 74160, interpreted as an LL7 chondrite. All properties are consistent with this meteorite having been recrystallized and partially melted locally once at temperatures well above 1090 C under conditions such that some minerals (e.g. plagioclase, euhedral pyroxene, tetrataenite) grew from melt pockets and siderophilic and chalcophilic elements were lost by extraction into eutectic melt that drained away. Inhomogeneous plagioclase compositions and mobile element loss suggest shock as the most likely heat source. Yamato 74160, while inferentially chondritic, is a larval achondrite: even higher temperatures and longer times would have been required to cause the separations necessary to transform it to an identifiable achondrite type.

Takeda, H.↗
NASA NTRS2004

Integrated Modeling Activities for the James Webb Space Telescope (JWST): Structural-Thermal-Optical Analysis

This is a continuation of a series of papers on modeling activities for JWST. The structural-thermal- optical, often referred to as "STOP", analysis process is used to predict the effect of thermal distortion on optical performance. The benchmark STOP analysis for JWST assesses the effect of an observatory slew on wavefront error. The paper begins an overview of multi-disciplinary engineering analysis, or integrated modeling, which is a critical element of the JWST mission. The STOP analysis process is then described. This process consists of the following steps: thermal analysis, structural analysis, and optical analysis. Temperatures predicted using geometric and thermal math models are mapped to the structural finite element model in order to predict thermally-induced deformations. Motions and deformations at optical surfaces are input to optical models and optical performance is predicted using either an optical ray trace or WFE estimation techniques based on prior ray traces or first order optics. Following the discussion of the analysis process, results based on models representing the design at the time of the System Requirements Review. In addition to baseline performance predictions, sensitivity studies are performed to assess modeling uncertainties. Of particular interest is the sensitivity of optical performance to uncertainties in temperature predictions and variations in metal properties. The paper concludes with a discussion of modeling uncertainty as it pertains to STOP analysis.

Johnston, John D.↗