Heterogeneous Ice Nucleation in the Tropical Tropopause Layer
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Eric J. Jensen↗
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Seasonal differences of vertical‐transport efficiency in the tropical tropopause layer: On the interplay between tropical deep convection, large‐scale vertical ascent, and horizontal circulations
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John W. Bergman↗
Chemical discontinuity at the extratropical tropopause and isentropic stratosphere‐troposphere exchange pathways diagnosed using Aura MLS data
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J. J. Jin↗
Climatology and variability of trace gases in extratropical double‐tropopause regions from MLS, HIRDLS, and ACE‐FTS measurements
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M. J. Schwartz↗
Extratropical Stratosphere-Troposphere Mass Exchange
Global net mass flux between the troposphere and the stratosphere can be computed simply by estimating the heating rate along the 380K isentropic surface and the time rate of change of the lower most stratosphere (region between the tropopause and 380K). Given the net tropopause mass flux and the cross tropopause diabatic flux, the residual adiabatic mass flux can be estimated. These fluxes have been computed using three different meteorological data sets, the FVGCM and two assimilation data sets, FVDAS, and UKMO, using the 3.5 PVU defined tropopause. For all three data sets, the extratropical diabatic flux across the tropopause is generally to be larger than the net flux cross tropopause flux implying that there is a net extra-tropical adiabatic flux of air from the troposphere into the middle world stratosphere. This adiabatic flux is four to five times larger than the flux into the stratosphere across the tropical tropopause. For the FVDAS, the tropopause diabatic flux is smaller than UKMO as a result of colder tropopause temperatures. The difference in the diabatic mass fluxes by almost a factor of two between the two data assimilation meteorological analyses is much larger than the interannual variability in the UKMO or FVGCM data sets. Compared to radiosonde estimated tropopause temperatures, both data assimilation tropopause temperatures are warm biased due to a low bias in the tropopause heights. These comparisons point to the PV determination of the tropopause height as the source of the differences in the mass fluxes.
Schoeberl, Mark↗
NASA Experiment on Tropospheric-Stratospheric Water Vapor Transport in the Intertropical Convergence Zone
The following six papers report preliminary results obtained from a field experiment designed to study the role of tropical cumulo-nimbus clouds in the transfer of water vapor from the troposphere to the stratosphere over the region of Panama. The measurements were made utilizing special NOAA enhanced IR satellite images, radiosonde-ozonesondes and a NASA U-2 aircraft carrying. nine experiments. The experiments were provided by a group of NASA, NOAA, industry, and university scientists. Measurements included atmospheric humidity, air and cloud top temperatures, atmospheric tracer constituents, cloud particle characteristics and cloud morphology. The aircraft made a total of eleven flights from August 30 through September 18, 1980, from Howard Air Force Base, Panama; the pilots obtained horizontal and vertical profiles in and near convectively active regions and flew around and over cumulo-nimbus towers and through the extended anvils in the stratosphere. Cumulo-nimbus clouds in the tropics appear to play an important role in upward water vapor transport and may represent the principal source influencing the stratospheric water vapor budget. The clouds provide strong vertical circulation in the troposphere, mixing surface air and its trace materials (water vapor, CFM's sulfur compounds, etc.) quickly up to the tropopause. It is usually assumed that large scale mean motions or eddy scale motions transport the trace materials through the tropopause and into the stratosphere where they are further dispersed and react with other stratospheric constituents. The important step between the troposphere and stratosphere for water vapor appears to depend upon the processes occurring at or near the tropopause at the tops of the cumulo-nimbus towers. Several processes have been sugested: (1) The highest towers penetrate the tropopause and carry water in the form of small ice particles directly into the stratosphere. (2) Water vapor from the tops of the cumulonimbus clouds is transported somehow through the tropopause, the vapor pressure being controlled by the temperature at the tops of the clouds; the dryness of the stratosphere could be explained if most of the transport occurs in connection with very high clouds in regions with very high and cold tropopause. (3) Cumulo-nimbus anvils act as terrestrial-radiation shields allowing the ice particle temperatures near cloud tops to cool radiatively below the supersaturation point; this cooling would cause a vapor deposition on the ice particles which will settle out and thus act as water scavengers. The experiment was designed to collect information on these detailed physical processes near and above the tropopause in order to assess their importance and the role they play in controlling stratospheric water vapor humidity.
Page, William A.↗
Seasonal Variability of Middle Latitude Ozone in the Lowermost Stratosphere Derived from Probability Distribution Functions
We present a study of the distribution of ozone in the lowermost stratosphere with the goal of characterizing the observed variability. The air in the lowermost stratosphere is divided into two population groups based on Ertel's potential vorticity at 300 hPa. High (low) potential vorticity at 300 hPa indicates that the tropopause is low (high), and the identification of these two groups is made to account for the dynamic variability. Conditional probability distribution functions are used to define the statistics of the ozone distribution from both observations and a three-dimensional model simulation using winds from the Goddard Earth Observing System Data Assimilation System for transport. Ozone data sets include ozonesonde observations from northern midlatitude stations (1991-96) and midlatitude observations made by the Halogen Occultation Experiment (HALOE) on the Upper Atmosphere Research Satellite (UARS) (1994- 1998). The conditional probability distribution functions are calculated at a series of potential temperature surfaces spanning the domain from the midlatitude tropopause to surfaces higher than the mean tropical tropopause (approximately 380K). The probability distribution functions are similar for the two data sources, despite differences in horizontal and vertical resolution and spatial and temporal sampling. Comparisons with the model demonstrate that the model maintains a mix of air in the lowermost stratosphere similar to the observations. The model also simulates a realistic annual cycle. Results show that during summer, much of the observed variability is explained by the height of the tropopause. During the winter and spring, when the tropopause fluctuations are larger, less of the variability is explained by tropopause height. This suggests that more mixing occurs during these seasons. During all seasons, there is a transition zone near the tropopause that contains air characteristic of both the troposphere and the stratosphere. The relevance of the results to the assessment of the environmental impact of aircraft effluence is also discussed.
Rood, Richard B.↗
Mechanisms for Midlatitude Ozone Loss: Heterogeneous Chemistry in the Lowermost Stratosphere?
The question of midlatitude ozone erosion by chlorine free radical catalysis is examined. We present and analyze simultaneous, high-resolution observations of ClO, H2O, tropopause height, particle reactive surface area, and ice saturation occurrence frequency obtained from the NASA ER-2 aircraft. The objective is to test the hypothesis that the existence of cirrus clouds or cold aerosols in the first few kilometers above the tropopause at midlatitudes is responsible for increasing the ratio of chlorine free radicals to total inorganic chlorine, thus amplifying the rate of catalytic ozone destruction. The observations reveal a sharp decrease in ice saturation frequency at the tropopause, a marked degree of undersaturation just above the tropopause, a corresponding sharp gradient in the product of cold aerosol reactive surface area and reaction probability, gamma-S(sub a), and, finally, the consistent absence of enhanced concentrations of ClO immediately above the tropopause. These results suggest that midlatitude ozone loss is not controlled in situ by the mechanism of cirrus cloud and/or cold aerosol enhancement of chlorine radicals in the vicinity of the tropopause.
Smith, Jessica B.↗
Dynamical response of the tropical total ozone to sea surface temperature changes
Interannual variations of total ozone in the equatorial region are discussed in terms of the lower-stratospheric dynamical processes associated with sea surface temperature (SST) changes on an El Nino-Southern Oscillation time scale. Tropospheric diabatic heating by the latent heat release in convective systems drives the interannual variations of tropopause height and atmospheric vertical motions. The adiabatic cooling associated with the dynamically forced ascending motion is subject to radiative heating, which further extends the upwelling motion into the stratosphere. SST variations can thus influence total ozone amounts by changing the tropopause height and vertical advection through modulation of tropospheric diabatic heating. Mechanistic relationships that describe total ozone fluctuations through the advection effect and the tropopause effect of SST variations are derived using the equivalent potential temperature. Total ozone fluctuations are estimated using a quantitative formulation of these mechanistic equations together with the observed SST data. These results indicate that the interannual variations of the zonal wave component of equatorial total ozone are governed by the tropopause effect of SST variations. Preliminary investigation suggests that the annual cycle of tropical total ozone is coupled to the tropopause height changes under the influence of the planetary wave-induced lower-stratospheric temperature rather than local SST.
Hasebe, Fumio↗
Origin and Variability of Upper Tropospheric Nitrogen Oxides and Ozone at Northern Mid-Latitudes
Measurements of NO(x) and ozone performed during the NOXAR project are compared with results from the coupled chemistry-climate models ECHAM4.L39(DLR)/CHEM and GISS-model. The measurements are based on flights between Europe and the East coast of America and between Europe and the Far East in the latitude range 40 deg N to 65 deg N. The comparison concentrates on tropopause altitudes and reveals strong longitudinal variations of seasonal mean NO,, of 200 pptv. Either model reproduced strong variations 3 km below but not at the tropopause, indicating a strong missing NO(x) or NO(y) sink over remote areas, e.g. NO(x) to HNO3 conversion by OH from additional OH sources or HNO3 wash-out. Vertical profiles show maximum NO(x) values 2-3 km below the tropopause with a strong seasonal cycle. ECHAM4.L39(DLR)/CHEM reproduces a maximum, although located at the tropopause with a less pronounced seasonal cycle, whereas the GISS model reproduces the seasonal cycle but not the profile's shape due to its coarser vertical resolution. A comparison of NO(x) frequency distributions reveals that both models are capable of reproducing the observed variability, except that ECHAM4.L39(DLR)/CHEM shows no very high NO(x) mixing ratios. Ozone mean values, vertical profiles and frequency distributions are much better reproduced in either model, indicating that the NO(x) frequency distribution, namely the most frequent NO(x) mixing ratio, is more important for the tropospheric photochemical ozone production than its mean value. Both models show that among all sources, NO(x) from lightning contributes most to the seasonal cycle of NO(x) at tropopause altitudes. The impact of lightning in the upper troposphere on NO(x) does not vary strongly with altitude, whereas the impact of surface emissions decreases with altitude. However, the models show significant differences in lightning induced NO(x) concentrations, especially in winter, which may be related to the different treatment of the lower stratospheric coupling between dynamics and chemistry.
Grewe, V.↗
Constituent Data Assimilation: Challenges and Limitations
The assimilation of observations of atmospheric constituents naturally divides into two major pieces. The first is the assimilation of trace gases whose variability is related to atmospheric motions. The second is the assimilation of trace gases which are sharply influenced by chemical exchange between different constituents. In order to advance beyond the initial successes of explorative investigation of assimilation techniques, tremendous challenges must be met to improve the geophysical integrity of assimilated data products. A subject of special interest is ozone near the tropopause. At the tropopause the information from both the observations and the model simulation becomes most uncertain. However a number of important geophysical parameters, e.g. stratosphere-troposphere exchange and tropospheric ozone, require the assimilation to have high accuracy at the tropopause. This talk will review the current status of the quality of assimilated data products near the tropopause, what must be done to improve the assimilation near the tropopause, and the intrinsic limitations that will require additional sources of information in order for the field to advance.
Rood, Richard B.↗
Observations of Overshooting Convective Tops and Dynamical Implications
Convective tops overshooting the tropopause have been suggested in the literature to play an important role in modifying the tropical tropopause. The structure of thunderstorm tops overshooting the tropopause have been difficult to measure due to the intensity of the convection and aircraft safety. This paper presents remote observations of overshooting convective tops with the high-altitude ER-2 aircraft during several of the Tropical Rain Measuring Mission (TRMM) and (Convection and Moisture Experiment) CAMEX campaigns. The ER-2 was instrumented with the down-looking ER-2 Doppler Radar (EDOP), a new dropsonde system (ER-2 High Altitude Dropsonde, EHAD), and an IR radiometer (Modis Airborne Simulator, MAS). Measurements were collected in Florida and Amazonia (Brazil). In this study, we utilize the radar cloud top information and cloud top infrared temperatures to document the amount of overshoot and temperature difference relative to the soundings provided by dropsondes and conventional upsondes. The radar measurements provide the details of the updraft structure near cloud top, and it is found that tops of stronger convective cells can overshoot by 1-2 km and with temperatures 5C colder than the tropopause minimum temperature. The negatively buoyant cloud tops are also evidenced in the Doppler measurements by strong subsiding flow along the sides of the convective tops . These findings support some of the conceptual and modeling studies of deep convection penetrating the tropopause.
Heymsfield, Gerald M.↗
An Aircraft-Based Upper Troposphere Lower Stratosphere O3, CO, and H2O Climatology for the Northern Hemisphere
We present a climatology of O3, CO, and H2O for the upper troposphere and lower stratosphere (UTLS), based on a large collection of high ]resolution research aircraft data taken between 1995 and 2008. To group aircraft observations with sparse horizontal coverage, the UTLS is divided into three regimes: the tropics, subtropics, and the polar region. These regimes are defined using a set of simple criteria based on tropopause height and multiple tropopause conditions. Tropopause ]referenced tracer profiles and tracer ]tracer correlations show distinct characteristics for each regime, which reflect the underlying transport processes. The UTLS climatology derived here shows many features of earlier climatologies. In addition, mixed air masses in the subtropics, identified by O3 ]CO correlations, show two characteristic modes in the tracer ]tracer space that are a result of mixed air masses in layers above and below the tropopause (TP). A thin layer of mixed air (1.2 km around the tropopause) is identified for all regions and seasons, where tracer gradients across the TP are largest. The most pronounced influence of mixing between the tropical transition layer and the subtropics was found in spring and summer in the region above 380 K potential temperature. The vertical extent of mixed air masses between UT and LS reaches up to 5 km above the TP. The tracer correlations and distributions in the UTLS derived here can serve as a reference for model and satellite data evaluation
Tilmes, S.↗
Altitude variations in stratospheric aerosols of a tropical region
To investigate the possibility that significant amounts of tropical tropospheric air may be convectively introduced into the stratosphere, aerosol samplings over Panama were made at various altitudes using a wire impactor collector. The percentage of particle sizes less than the mean mode decreases with height above the tropopause, suggesting depletion of small particles, possibly due to coagulation. Larger aerosols (greater than 0.3 micron in diam.) are more abundant farther above the tropopause, indicating growth, mainly by condensation. The total particle concentration decreases with increasing height above the tropopause, and also with increasing temperature. Aerosols containing smaller-size particles are thus found closer to the tropopause, and larger-size, more-evolved aerosols occur at higher altitudes. These data indicate that convective activity at the Intertropical Convergence Zone may be a source mechanism for stratospheric aerosols.
Goodman, J.↗
Observational evidence and dynamical interpretation of the total ozone variations in the equatorial region
The total ozone amount is sensitive to the general circulation changes in the lower stratosphere due to the photochemically inactive nature of ozone there. In the equatorial region, such circulation changes arise from the quasi-biennial oscillation (QBO) of the stratospheric zonal wind and the El Nino/Southern Oscillation (ENSO). In the first half of this study we present observational results of the long-term variations in the equatorial ozone field using the 11 year Total Ozone Mapping Spectrometer (TOMS) data, by paying special attention to the longitudinal structure. In the latter half we try to understand quantitatively these variations by using a simple mechanistic relationship. We hypothesis that the ozone modulating processes are attributable to two dynamical effects, the advection effect and tropopause effect, owing to the strong vertical stratification of ozone existing just above the tropopause. The advection effect comes from the vertical motion which maintains the temperature structure, compensating for the radiative damping. The tropopause effect is associated with the altitude change of the tropopause. The total ozone variations in the tropics is discussed in terms of these two dynamical processes with the aid of mechanistic equations combined with the wind and sea surface temperature (SST) observations. The interactions between tropical and extratropical latitudes are beyond the scope of this study. Photochemical effects are also neglected. Details of this study are given by Shiotani (1992) and Hasebe (1992).
Shiotani, Masato↗
A Study of the Vertical Structure of Tropical (20 deg S-20 deg N) Optically Thin Clouds from SAGE II Observations
The tropical cloud data obtained by the satellite instrument of the Stratospheric Aerosol and Gas Experiment (SAGE) II from October 1984 to May 1991 have been used to study cloud vertical distribution, including thickness and multilayer structure, and to estimate cloud optical depth. The results indicate that the SAGE-II-observed clouds are generally optically thin clouds, corresponding to a range of optical depth between approximately 8 x 10(exp -4) and 3 x 10(exp -1) with a mean of about 0.035. Two-thirds are classified as subvisual cirrus and one-third thin cirrus. Clouds between 2- to 3-km thick occur most frequently. Approximately 30% of the SAGE II cloud measurements are isolated single-layer clouds, while 65% are high clouds contiguous with an underlying opaque cloud that terminates the SAGE II profile. Thin clouds above detached opaque clouds at altitudes greater than 6.5 km occur less often. Only about 3% of the SAGE II single-layer clouds are located above the tropopause, while 58% of the cloud layers never reach the tropopause. More than one-third of the clouds appear at the tropopause. This study also shows that clouds occur more frequently and extend higher above the tropopause over the western Pacific than than over the eastern Pacific, especially during northern winter. The uncertainty of the derived results due to the SAGE II sampling constraints, data processing, and cloud characteristics is discussed.
Wang, Pi-Huan↗
Three Dimensional Model Simulation of Constituent Transport in the Lowermost Stratosphere
The composition, transport and photochemistry of the lowermost stratosphere, i.e., that part of the atmosphere which is above the tropopause, poleward of the tropics, and at potential temperature lower than the potential temperature of the tropical tropopause (about 380K) are of practical interest for understanding global ozone behavior. Because this region is a transition between transport regimes characterized by different scales of dynamics, it is especially difficult to model realistically. Through comparisons of observations of ozone, carbon dioxide and water vapor with results from a chemistry and transport model using winds from a global meteorological assimilation system, we have established that the model provides a good representation of several important aspects of constituent behavior. These include the constituent gradients near the tropopause as well as the annual cycle of constituents and the altitude dependence of the annual cycle from the tropopause into the middle stratosphere. This talk draws together these results to form a unified picture of transport into the lowermost extratropical stratosphere. In particular, the importance of convective transport to the distribution of both short-lived, and long-lived constituents in the lowermost stratosphere will be evaluated.
Douglass, Anne R.↗
Implications of Enhanced Relative Humidity in Cold Tropical Cirrus
In situ measurements of water vapor concentration and temperature in tropical cirrus during the CRYSTAL-FACE and Pre-AVE missions indicate that the steady-state relative humidity within cirrus at T less than 200 K is about 20-30% higher than ice saturation. These measurements challenge the conventional belief, that any water vapor in excess of ice saturation should be depleted by crystal growth given sufficient time. Detailed simulations of thin cirrus near the tropopause indicate that this enhanced steady-state relative humidity increases ice number densities, decreases crystal sizes and extends cloud lifetimes. The areal coverage of thin cirrus in the tropics is increased rather than decreased as indicated by simpler conceptual models. Perhaps most significantly, the increased steady-state H2O saturation mixing ratio over ice in thin cirrus near the tropopause results in about a 0.5-1 ppmv increase in the amount of water that can enter the stratosphere across the tropical tropopause cold trap. Hence, the enhanced steady-state relative humidity in cold cirrus implies that lower tropopause temperatures are required to explain the observed stratospheric water vapor mixing ratios than previously assumed.
Jensen, Eric↗