Search NASA⌕ Search

SEARCH · Search NASA

Results for “ultraviolet fluorescence”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Satellite measurements of nitric oxide in the polar region

Ultraviolet measurements of the (1, 0) gamma band of nitric oxide in fluorescence by a satellite at high latitudes show nitric oxide concentrations which are highly variable in both time and space. The average nitric oxide concentration is 3 to 4 times higher at high latitudes than at midlatitudes. If auroral activity is responsible for the larger nitric oxide densities and if the reaction N(2D) + O2 is the source of NO, then auroral processes must be more efficient in the production of N(2D) atoms than dayglow processes.

Rusch, D. W.↗
NASA NTRS1976

An optical sensor for the drag-free satellite

An optical sensor for drag-free satellites is described. It is based on using fluorescent re-emission from the proof mass excited by a pulsed ultraviolet source, a technique that separates the frequencies of the excited and excitant light fluxes. A theoretical analysis of the performance and linearity of the sensor was verified by the results on a laboratory prototype. The sensor provided a measure of the position of a 4 cm radius proof mass in a 10 cm cavity to an accuracy of 1 mm. Null drift and thermal gradients caused errors less than 0.05 mm.

De Hoff, R. L.↗
NASA NTRS1991

Laser Raman diagnostics in subsonic and supersonic turbulent jet diffusion flames

Ultraviolet (UV) spontaneous vibrational Raman scattering combined with laser-induced predissociative fluorescence (LIPF) is developed for temperature and multi-species concentration measurements. Simultaneous measurements of temperature, major species (H2, O2, N2, H2O), and minor species (OH) concentrations are made with a 'single' narrow band KrF excimer laser in subsonic and supersonic lifted turbulent hydrogen-air diffusion flames. The UV Raman system is calibrated with a flat-flame diffusion burner operated at several known equivalence ratios from fuel-lean to fuel-rich. Temperature measurements made by the ratio of Stokes/anti-Stokes signal and by the ideal gas law are compared. The single shot measurement precision for concentration and temperature measurement is 5 to 10 pct. Calibration constants and bandwidth factors are determined from the flat burner measurements and used in a data reduction program to arrive at temperature and species concentration measurements. These simultaneous measurements of temperature and multi-species concentrations allow a better understanding of the complex turbulence-chemistry interactions and provide information for the input and validation of CFD models.

Cheng, T. S.↗
DOE OSTI2022

Observation of Long-Lived UV-Induced Fluorescence from Environmental Materials Using the HVeV Detector as Developed for SuperCDMS

Here, we describe recent experiments using a SuperCDMS HVeV single-charge sensitive detector illuminated with an ultraviolet LED (275 nm) and a monochromatic laser(650 nm) using a dual fiber optic system installed in a small dilution refrigerator at Stanford University. We observed a population of fluorescence background events after UV exposure but not after exposure to the laser source. The fluorescence was likely due to scattered UV photons absorbed outside the detector. We discuss the possibility of fluorescence being a contributor to the low energy excess background observed in above-ground Dark Matter experiments.

36 MATERIALS SCIENCE↗
NASA NTRS2012

Spectroscopic Chemical Analysis Methods and Apparatus

This invention relates to non-contact spectroscopic methods and apparatus for performing chemical analysis and the ideal wavelengths and sources needed for this analysis. It employs deep ultraviolet (200- to 300-nm spectral range) electron-beam-pumped wide bandgap semiconductor lasers, incoherent wide bandgap semiconductor lightemitting devices, and hollow cathode metal ion lasers. Three achieved goals for this innovation are to reduce the size (under 20 L), reduce the weight [under 100 lb (.45 kg)], and reduce the power consumption (under 100 W). This method can be used in microscope or macroscope to provide measurement of Raman and/or native fluorescence emission spectra either by point-by-point measurement, or by global imaging of emissions within specific ultraviolet spectral bands. In other embodiments, the method can be used in analytical instruments such as capillary electrophoresis, capillary electro-chromatography, high-performance liquid chromatography, flow cytometry, and related instruments for detection and identification of unknown analytes using a combination of native fluorescence and/or Raman spectroscopic methods. This design provides an electron-beampumped semiconductor radiation-producing method, or source, that can emit at a wavelength (or wavelengths) below 300 nm, e.g. in the deep ultraviolet between about 200 and 300 nm, and more preferably less than 260 nm. In some variations, the method is to produce incoherent radiation, while in other implementations it produces laser radiation. In some variations, this object is achieved by using an AlGaN emission medium, while in other implementations a diamond emission medium may be used. This instrument irradiates a sample with deep UV radiation, and then uses an improved filter for separating wavelengths to be detected. This provides a multi-stage analysis of the sample. To avoid the difficulties related to producing deep UV semiconductor sources, a pumping approach has been developed that uses ballistic electron beam injection directly into the active region of a wide bandgap semiconductor material.

Hug, William F.↗
NASA NTRS1998

Molecular Processes in Comets

The research focused on molecular hydrogen and its response to ultraviolet radiation, photoelectron impact excitation and X-ray radiation and on the interpretation of the ultraviolet spectra of the Jupiter dayglow and auroras. A systematic effort was made to obtain reliable rate coefficients for rovibrational energy transfer of H2, particularly in collisions with hydrogen atoms. We carried out elaborate quantum-mechanical calculations of the scattering of H and H2 on what had been characterized as a reliable potential energy surface of the H3 molecular system. These calculations took into account reactive channels and rate coefficients for ortho-para transitions were obtained. Quantal calculations are too complex to be applied to all the possible rovibrational transitions and we turned to a semi-classical method. With it we calculated rate coefficients for transitions, reactive and non-reactive, for all the rovibrational levels. We carried out the calculations for three of the available H3 potential energy surfaces. We discovered an unexpected sensitivity of the rate coefficients for the non-reactive channels to the potential energy surface. This discovery stimulated more thorough investigations of the potential energy surface elsewhere and to the construction of a new surface. We have used it in further semi-classical calculations in work that will shortly be 2 completed and which, together with new quantum-mechanical calculations should comprise a set of reliable rate coefficients that can be used in discussions of H2 on the Jovian planets. We carried out a detailed study of the Jovian ultraviolet dayglow. There has been a long-running argument about the dayglow on Jupiter. There are two sources of excitation: fluorescence and photoelectron impact excitation. It had been argued that a third source "the electron glow" was needed to bring theory and observation into agreement. We believe we have shown conclusively that the third source is unnecessary. We have achieved a close quantitative agreement between the predicted spectrum arising from fluorescence and photoelectrons and the measured spectrum. We also demonstrated a method by which the presence of HD could be established observationary. Similar calculations were carried out of the ultraviolet spectra of the Jovian auroras. We again found close agreement. Indeed, the agreement was so detailed we were able to derive the temperature of the atmosphere. We found, contrary to the standard model of the time, a high temperature between 400 K and 600 K and established the presence of a significant temperature gradient. A large temperature gradient was indeed found by direct sampling with the Jupiter probe.

Dalgarno, A.↗
NASA NTRS1972

Photodissociation of CS2 in the vacuum ultraviolet - Determination of bond dissociation energy from the lowest vibrational level of the ground state CS2.

Photolysis in the vacuum ultraviolet results almost exclusively in the production of S(super-3)P atoms, which is in apparent violation of spin conservation. The threshold energy of incident photons required to produce fluorescence was used to calculate the bond dissociation energy (from the lowest vibrational level of the ground state), and the result agrees with the value previously derived from the photoionization of CS2. The fluorescence excitation spectrum shows peaks corresponding to Rydberg series I and II, indicating that the observed photodissociation of CS2 in the vacuum ultraviolet is mainly the result of predissociation from Rydberg states. The absorption coefficient of CS2 was measured in the region of 1200 to 1400 A.

Okabe, H.↗
NASA NTRS1981

The ultraviolet variability of the T Tauri star RW Aurigae

Between 1978 and 1979 the visible brightness of RW Aurigae increased by 0.9 mag. During this time (1) CIV and SiIV increased by factors of 2 to 4 while the lower ionization lines remained unchanged; (2) the fluorescent OI line increased by a factor of 8; (3) the shell spectrum changed from emission to absorption; and (4) the ultraviolet continuum brightened by 2.3 mag. On a time scale of a week the continuum varied by as much as 0.8 mag., but the MgII emission lines showed no variability over 10 percent. An active chromosphere, transition region, and envelope cooled by mass loss are hypothesized in order to explain the ultraviolet observations of RW Aur.

Imhoff, C. L.↗
NASA NTRS1994

The Origins of Polycyclic Aromatic Hydrocarbons: Are They Everywhere?

During the past 15 years considerable progress in observational techniques has been achieved in the middle-infrared region (5000-500 per centimeter, 2-20 micron), the region where most diagnostic molecular vibrations occur. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds and others at their edges, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas and solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. The two lectures will focus on the evidence that polycyclic aromatic hydrocarbons (PAHs) are an important, ubiquitous and abundant interstellar species. PAHs are. extremely stable species which can range in size from a few angstroms across to several hundred angstroms (PAHs are also the building blocks of amorphous carbon particles). This identification rests on the suggestive agreement between the laboratory spectra of PAHs with a set of IR emission bands which emanate from many different sources where ultraviolet starlight impinges on a "dusty" region. The picture is that individual PAHs are first pumped into highly vibrationally excited states and relax by fluorescence at their fundamental vibrational frequencies. That PAHs are a ubiquitous interstellar component has serious ramifications in other spectral regions as well, including the strong extinction in the ultraviolet, and the classic visible diffuse interstellar bands discovered more than 50 years ago (but unexplained to this day) The first part of the course will focus on the interpretation of astronomical spectra. The second lecture will start by showing how recent laboratory data on PAHs taken under realistic interstellar conditions has con borated the PAH hypothesis and led to great insight into the conditions in the PAH containing regions. This lecture will end by reviewing the ever-increasing evidence for interstellar PAHs in meteorites and interplanetary dust particles. This in conjunction with the recent suggestion that PAHs are abundant in Jupiter's atmosphere will make the point that "PAHs are Everywhere".

Allamandola, L. J.↗
NASA NTRS1973

Investigation of gas temperature measurements using ultraviolet excitation

A high resolution spectrographic study has been made of the nitrogen first negative system as induced by ultraviolet radiation. The radiation used in this experiment was the neutral helium resonance radiation at 584 A. Nitrogen molecules at approximately 300 K and at a pressure of one torr were ionized by the ultraviolet radiation with the aid of a windowless experimental configuration. The resulting nitrogen fluorescence was analyzed with sufficient resolution to enable study of the intensities of the R branch rotational lines of the 0-0 vibrational band of the first negative system. The data indicate that the induced population of the upper levels approximates a Boltzmann Distribution at the ambient temperature of the gas.

Ofelt, G. S.↗
NASA NTRS1980

The effect of solar-cycle ultraviolet flux variations on cometary gas

The effects on comet gas of variations in the solar ultraviolet flux during solar cycle 21 are discussed. The photoionization, photodissociation, and resonance fluorescence and scattering rates of individual atoms and molecules increase by factors ranging up to 4, leading to potential order of magnitude variations in emission-line fluxes between minimum and maximum solar activity. These effects are illustrated for H2O and CO. Recent observations of comet Bradfield (1979) are discussed, and it is suggested that comets appearing near solar maximum be extensively observed to provide information on the response of cometary gas to solar flux variations, which can be used to discriminate between cometary models.

Oppenheimer, M.↗
NASA NTRS1993

Photoabsorption and photodissociation of molecules important in the interstellar medium

The photo absorption, photo dissociation, and fluorescence cross sections of interstellar molecules and radicals were measured in the vacuum ultraviolet region. These quantitative optical data are useful for understanding of the formation and destruction processes of molecules under the intense interstellar W radiation field. Infrared (IR) emissions from W excitation of aromatic molecules were also observed in this research program. The research results are useful for studying the sources of the 'unidentified' interstellar infrared (UIR) emission bands.

Lee, Long C.↗
NASA NTRS1985

The internal state distribution of CN radicals produced in the photolysis of HC2CN and CH3CN

The energy partitioning in CN radicals produced by the vacuum ultraviolet photodissociation of HC2CN and CH3CN is studied by means of laser-induced fluorescence of the B-X transition. Experiments are performed in two collision regimes: (1) in the low-collision number regime, the energy partitioning in CN(X) is measured; (2) in the high-collision number regime, the formation of CN(A) is monitored. It is shown that photodissociation of HC2CN in its linear predissociative 1Sigma(+) state produces predominantly ground-state CN in rotationally and vibrationally excited states. The vibrational population ratios and the temperatures computed from a Boltzmann fit of the rotational levels are given in a table. The excitation of CH3CN produces CN radicals almost entirely in the first excited A-state with vibrational excitation.

Cody, R. J.↗
NASA NTRS1993

Voyager 2 observations of NGC 7023 - Dust scattering shortward of 1600 A

We report the first observational determination of the nebular-to-stellar flux ratio out to wavelengths as short as 1000 A for the reflection nebula NGC 7023, using a combination of spectroscopic data from Voyager 2 and from the Hopkins Ultraviolet Telescope (HUT) on the Astro 1 mission. After accounting for contributions by H2 fluorescence to the nebular flux, the wavelength variation of the ratio of the residual dust scattered flux to that observable from the embedded star is consistent with a reduction of the dust albedo by 25 percent over the wavelength interval 1300-1000 A. This is most easily interpreted, if the particles responsible for the FUV rise in the extinction curve are low-albedo, not necessarily zero-albedo, grains. The direct proportionality between the nebular surface brightness, measured at 22 arcsec offset by HUT, and the nebular flux suggests that the phase function of scattering does not vary in the 2000-1000 A range.

Witt, A. N.↗
NASA NTRS1995

Contamination detection NDE for cleaning process inspection

In the joining of multilayer materials, and in welding, the cleanliness of the joining surface may play a large role in the quality of the resulting bond. No non-intrusive techniques are currently available for the rapid measurement of contamination on large or irregularly shaped structures prior to the joining process. An innovative technique for the measurement of contaminant levels in these structures using laser based imaging is presented. The approach uses an ultraviolet excimer laser to illuminate large and/or irregular surface areas. The UV light induces fluorescence and is scattered from the contaminants. The illuminated area is viewed by an image-intensified CCD (charge coupled device) camera interfaced to a PC-based computer. The camera measures the fluorescence and/or scattering from the contaminants for comparison with established standards. Single shot measurements of contamination levels are possible. Hence, the technique may be used for on-line NDE testing during manufacturing processes.

Marinelli, W. J.↗
NASA NTRS2007

Advancement of the Wide-angle JEM-EUSO Optical System with Holographic and Fresnel Lenses

JEM-EUSO is a space mission to observe extremely high-energy cosmic rays, evolved from the previous design studies of EUSO. It is adjusted for the Japan Experiment Module (JEM) of the International Space Station (ISS). JEM-EUSO uses a wide-angle refractive telescope in near-ultraviolet wavelength region to observe from ISS the time-and-space-resolved atmospheric fluorescence images of the extensive air showers. The JEM-EUSO optics is re-designed after the ESA-Phase A studies to upgrade the light-collecting-power by using a new material CYTOP, and its overall light-collecting power is about 1.5 times higher than the ESA-Phase A baseline optics. We describe in this paper an optimized optics design that maximizes the sensitivity of JEM-EUSO, and the results of the optics manufacturing tests.

Takizawa, Y.↗
NASA NTRS2019

A New Class of Flares from Accreting Supermassive Black Holes

Accreting supermassive black holes (SMBHs) can exhibit variable emission across the electromagnetic spectrum and over a broad range of timescales. The variability of active galactic nuclei (AGNs) in the ultraviolet and optical is usually at the few tens of per cent level over timescales of hours to weeks1. Recently, rare, more dramatic changes to the emission from accreting SMBHs have been observed, including tidal disruption events2,3,4,5, ‘changing look’ AGNs6,7,8,9 and other extreme variability objects10,11. The physics behind the ‘re-ignition’, enhancement and ‘shut-down’ of accretion onto SMBHs is not entirely understood. Here we present a rapid increase in ultraviolet–optical emission in the centre of a nearby galaxy, marking the onset of sudden increased accretion onto a SMBH. The optical spectrum of this flare, dubbed AT 2017bgt, exhibits a mix of emission features. Some are typical of luminous, unobscured AGNs, but others are likely driven by Bowen fluorescence—robustly linked here with high-velocity gas in the vicinity of the accreting SMBH. The spectral features and increased ultraviolet flux show little evolution over a period of at least 14 months. This disfavours the tidal disruption of a star as their origin, and instead suggests a longer-term event of intensified accretion. Together with two other recently reported events with similar properties, we define a new class of SMBH-related flares. This has important implications for the classification of different types of enhanced accretion onto SMBHs.

Benny Trakhtenbrot↗