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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Platinum and Gold Supported on Transition Metal Nitrides for Hydrogen Evolution in an Alkaline Electrolyte

Here, as the urgency to reduce reliance on fossil fuels increases due to carbon dioxide emissions, hydrogen produced by renewably powered water electrolysis has emerged as a promising technology. Alkaline electrolyzers typically exhibit lower current densities than acidic electrolyzers due to the slow kinetics of the hydrogen evolution reaction (HER) under alkaline conditions. This work developed Pt- and Au-modified transition metal nitride (TMN) thin films for improving alkaline HER kinetics. One monolayer Pt–VN, Pt–Mo 2 N, and Pt–TiN were the most promising thin-film catalysts, with alkaline HER activity approaching that of a bulk Pt foil. Additionally, the Gibbs free energy of adsorbed hydrogen was identified as a useful descriptor for alkaline HER activity on TMN and TMN-supported catalysts and has the potential to guide future studies on TMN-based catalysts for enhancing alkaline HER. For practical applications, the thin-film catalysts were then extended to Pt- and Au-modified TMN powders for alkaline HER. Both 5 wt % Pt/TiN and 2 wt % Pt/TiN powders exhibited lower overpotentials at 5 mA/cm 2 when normalized by the Pt electrochemical surface area than the commercial 5 wt % Pt/C benchmark, suggesting a Pt–TiN synergy that creates opportunities for more cost-effective alkaline HER cathodes. Moreover, 20 wt % Au/Mo 2 N also displayed an enhancement in HER activity when compared to the commercial 20 wt % Au/C benchmark.

58 GEOSCIENCES↗

Water Purifier

The Floatron water purifier combines two space technologies - ionization for water purification and solar electric power generation. The water purification process involves introducing ionized minerals that kill microorganisms like algae and bacteria. The 12 inch unit floats in a pool while its solar panel collects sunlight that is converted to electricity. The resulting current energizes a specially alloyed mineral electrode below the waterline, causing release of metallic ions into the water. The electrode is the only part that needs replacing, and water purified by the system falls within EPA drinking water standards.

Source record↗

Utilization of Porous Media for Condensing Heat Exchangers

The use of porous media as a mean of separating liquid condensate from the air stream in condensing heat exchangers has been explored in the past inside small plant growth chambers and in the Apollo Command Module. Both applications used a cooled porous media made of sintered stainless steel to cool and separate condensation from the air stream. However, the main issues with the utilization of porous media in the past have been the deterioration of the porous media over long duration, such as clogging and changes in surface wetting characteristics. In addition, for long duration usage, biofilm growth from microorganisms on the porous medial would also be an issue. In developing Porous Media Condensing Heat Exchangers (PMCHX) for future space applications, different porous materials and microbial growth control methods will need to be explored. This paper explores the work performed at JSC and GRC to evaluate different porous materials and microbial control methods to support the development of a Porous Media Condensing Heat Exchanger. It outlines the basic principles for designing a PMCHX and issues that were encountered and ways to resolve those issues. The PMCHX has potential of mass, volume, and power savings over current CHX and water separator technology and would be beneficial for long duration space missions.

Tuan, George C.↗

Electrolysis Propulsion for Spacecraft Applications

Electrolysis propulsion has been recognized over the last several decades as a viable option to meet many satellite and spacecraft propulsion requirements. This technology, however, was never used for in-space missions. In the same time frame, water based fuel cells have flown in a number of missions. These systems have many components similar to electrolysis propulsion systems. Recent advances in component technology include: lightweight tankage, water vapor feed electrolysis, fuel cell technology, and thrust chamber materials for propulsion. Taken together, these developments make propulsion and/or power using electrolysis/fuel cell technology very attractive as separate or integrated systems. A water electrolysis propulsion testbed was constructed and tested in a joint NASA/Hamilton Standard/Lawrence Livermore National Laboratories program to demonstrate these technology developments for propulsion. The results from these testbed experiments using a I-N thruster are presented. A concept to integrate a propulsion system and a fuel cell system into a unitized spacecraft propulsion and power system is outlined.

deGroot, Wim A.↗

Pioneering Microporous Layers for Proton-Exchange-Membrane Water Electrolyzers via Tape Casting

The imperative shift towards decarbonization necessitates the production of clean hydrogen through water electrolysis, powered by renewable energy sources. Among electrolyzer technologies, proton-exchange-membrane (PEM) systems emerge as a promising option for large-scale hydrogen generation due to their modular design and rapid response, aligning well with the intermittency of renewable energy. In this study, we employ a tape casting method to fabricate microporous layers (MPLs), both as a single layer and as a bilayer over commercial porous transport layers (PTLs), to further enhance performance of water electrolyzers. We demonstrate that microporous layers require adequate pore sizes to facilitate gas removal, preventing gas flooding and preserving electrolyzer performance. Our single layer microporous layers exhibit lower overpotentials compared to commercial sintered Ti PTLs by 142 mV at 4 A·cm ⁻2 . Moreover, we show that having an effective microporous layer enhances electrolyzer performance irrespective of the substrate used, offering avenues for cost reduction. We also investigate novel PTL structures with reduced tortuosity and integrated MPL fabricated via phase inversion tape casting, resulting in a performance enhancement of 92 mV. Our findings unravel the critical role of microporous layer structures and their impact on electrolyzer performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Future evolution of virtual water trading in the United States electricity sector

Abstract Future transformations in the electricity sector could entail major shifts in power sector technology mixes and electricity trade, with consequences for the trading of virtual water. Previous virtual water trade studies largely focus on historical timeframes. We explore, for the first time, future—through 2050—virtual water trade driven by electricity trade under a range of future electricity sector transformation scenarios using the United States as an example. Under a business-as-usual scenario, virtual water trading in 2050 decreases by 3% relative to 2015 levels. By contrast, virtual water trading increases respectively by 3%, 26%, and 32%, in scenarios characterized by higher socioeconomic growth, higher potential for transmission expansion, and low-carbon transitions. These increases are driven by electricity generation expansion in the western U.S., resulting in higher virtual water trade to the east. In addition, we find that as electricity generation shifts west, an increased amount of nonrenewable groundwater will be consumed to generate electricity that is supplied to the east. Independent of scenario, the US electricity grid largely relies on virtual water exports from only a few states. Our study highlights the need for integrated and national strategies to manage the water and electric systems.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Climate-Water-Electricity Interactions in the U.S. Under Alternative Decarbonized Futures

The U.S. electric sector is rapidly evolving, with widespread renewable energy deployment, building and transport electrification, and nuanced decarbonization policies. Climate change influences the supply and demand for electricity by altering water resources for cooling and hydropower, thermal plant efficiencies, and heating and cooling demand. This research combines global climate model data, asset-level water and streamflow modeling, and electric sector capacity expansion modeling to study climate-water-electricity interactions across myriad future climate and electricity scenarios that consider electrification and decarbonization using renewable, hydrogen, carbon capture, and nuclear technologies. Multi-model integration leads to insights into power-water sector interactions and their impacts on grid economics and environmental outcomes.

climate change↗

Utilizing Solar Power Technologies for On-Orbit Propellant Production

The cost of access to space beyond low Earth orbit may be reduced if vehicles can refuel in orbit. The cost of access to low Earth orbit may also be reduced by launching oxygen and hydrogen propellants in the form of water. To achieve this reduction in costs of access to low Earth orbit and beyond, a propellant depot is considered that electrolyzes water in orbit, then condenses and stores cryogenic oxygen and hydrogen. Power requirements for such a depot require Solar Power Satellite technologies. A propellant depot utilizing solar power technologies is discussed in this paper. The depot will be deployed in a 400 km circular equatorial orbit. It receives tanks of water launched into a lower orbit from Earth, converts the water to liquid hydrogen and oxygen, and stores up to 500 metric tons of cryogenic propellants. This requires a power system that is comparable to a large Solar Power Satellite capable of several 100 kW of energy. Power is supplied by a pair of solar arrays mounted perpendicular to the orbital plane, which rotates once per orbit to track the Sun. The majority of the power is used to run the electrolysis system. Thermal control is maintained by body-mounted radiators; these also provide some shielding against orbital debris. The propellant stored in the depot can support transportation from low Earth orbit to geostationary Earth orbit, the Moon, LaGrange points, Mars, etc. Emphasis is placed on the Water-Ice to Cryogen propellant production facility. A very high power system is required for cracking (electrolyzing) the water and condensing and refrigerating the resulting oxygen and hydrogen. For a propellant production rate of 500 metric tons (1,100,000 pounds) per year, an average electrical power supply of 100 s of kW is required. To make the most efficient use of space solar power, electrolysis is performed only during the portion of the orbit that the Depot is in sunlight, so roughly twice this power level is needed for operations in sunlight (slightly over half of the time). This power level mandates large solar arrays, using advanced Space Solar Power technology. A significant amount of the power has to be dissipated as heat, through large radiators. This paper briefly describes the propellant production facility and the requirements for a high power system capability. The Solar Power technologies required for such an endeavor are discussed.

Fikes, John C.↗

Supercritical water desalination and oxidation (SCWDO): Effectiveness on complex solutions, technoeconomic, and CO 2 impact for produced water treatment

The modern energy-economy is increasingly causing the production of highly saline brines, including from produced water. Supercritical water desalination can concentrate and extract minerals from these brines, but the effects of mixed salt interactions, organic degradation with additives, and the technology's economics are not well understood at supercritical condition. The present study evaluated and experimentally studied an integrated supercritical water desalination and oxidation (SCWDO) process for treating real-produced water samples from oil/natural gas field. The complex interactions between the various anions and cations in produced water were extensively evaluated. Most of the divalent and trivalent ions were extracted below 250 °C while the majority of the monovalent salt were removed between 380 to 410 °C. The treated real produced water was of drinking water quality, with <500 mg/l of total dissolved solid (TDS) and with 100% organics removal. Furthermore, the heat liberated during the organic oxidation could be utilized internally and for electricity generation for enhanced the energy efficiency and lower cost of produced water treatment. With system optimization, the proposed SCWDO process can essentially be made a net zero energy process. A novel process flow diagram for the commercial scale self-powered hybrid SCWDO technology was proposed as a cost-effective produced water treatment to mitigate the environmental crises. Techno-economic analysis showed that produced water treatment cost with SCWDO can be reduced to 2–3 $/m 3 and can be up to 60 % cheaper to traditional deep well reinjection. Additionally, the proposed SCWDO process could achieve net negative CO 2 emission.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

In-Space Cryogenic Propellant Depot Potential Commercial and Exploration Applications

The key goals and objectives for an In-Space Cryogenic Propellant Depot are to support a safe, reliable, affordable and effective future human and robotic space exploration initiative. Previous studies have been conducted at the NASA Marshall Space Flight Center to determine technical requirements and feasibility for exploration and commercial potential of an in-space cryogenic propellant depot in low-Earth-orbit (LEO), low-Lunar orbit (LLO) and/or on the lunar surface. Results indicate that in-space cryogenic propellant depots are technically feasible given continued technology development and that there is a substantial growing market that depots could support. Systems studies showed that the most expensive part of transferring payloads to geo-synchronous-orbit (GEO) is the fuel. A cryogenic propellant production and storage depot stationed in LEO could lower the cost of missions to GEO and beyond. Propellant production separates water into hydrogen and oxygen through electrolysis. This process requires large amounts of power which is enabled by Space Solar Power technologies. Recent analysis indicate that in the coming decades there could be a significant demand for water-based propellants from Earth, moon, or asteroid resources if in-space transfer vehicles (upper stages) transitioned to reusable systems using water based propellants. This type of strategic planning move could create a substantial commercial market for space resources development, and ultimately lead toward significant commercial infrastructure development within the Earth-Moon system.

Howell, Joe T.↗

Evaporator Development for an Evaporative Heat Pipe System

As fossil fuel resources continue to deplete, research for alternate power sources continues to develop. One of these alternate technologies is fuel cells. They are a practical fuel source able to provide significant amounts of power for applications from laptops to automobiles and their only byproduct is water. However, although this technology is over a century old and NASA has been working with it since the early 1960 s there is still room for improvement. The research I am involved in at NASA's Glenn Research Center is focusing on what is called a regenerative fuel cell system. The unique characteristic of this type of system is that it used an outside power source to create electrolysis of the water it produces and it then reuses the hydrogen and oxygen to continue producing power. The advantage of this type of system is that, for example, on space missions it can use solar power to recharge its gas supplies between periods when the object being orbited blocks out the sun. This particular system however is far from completion. This is because of the many components that are required to make up a fuel cell that need to be tested individually. The specific part of the system that is being worked on this summer of 2004 is the cooling system. The fuel cell stack, that is the part that actually creates the power, also produces a lot of heat. When not properly cooled, it has been known to cause fires which, needless to say are not conducive to the type of power that is trying to be created. In order to cool the fuel cell stack in this system we are developing a heat pipe cooling system. One of the main components of a heat pipe cooling system is what is known as the evaporator, and that is what happens to be the part of the system we are developing this summer. In most heat pipe systems the evaporator is a tube in which the working fluid is cooled and then re-circulated through the system to absorb more heat energy from the fuel cell stack. For this system, instead of a tube, the evaporator is made up of a stack-up of screen material and absorbent membranes inside a stainless steel shell and held together by a film adhesive and epoxy. There is an initial design for this flat plate evaporator, however is has not yet been made. The components of the stack-up are known, so all testing is focused on how it will all go together. This includes finding an appropriate epoxy to make the evaporator conductive all the way through and finding a way to hold the required tight tolerances as the stainless steel outer shell is put together. By doing the tests on smaller samples of the stack-ups and then testing the fill size component, the final flat plate evaporator will reach its final design so that research can continue on other parts of the regenerative fue1 cell system, and another step in the improvement of fue1 cell technology can be made.

Peters, Leigh C.↗

Development of advanced fuel cell system

An experimental program was conducted continuing the development effort to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. These advanced technology cells operate with passive water removal which contributes to a lower system weight and extended operating life. Endurance evaluation of two single cells and two, two-cell plaques was continued. Three new test articles were fabricated and tested. A single cell completed 7038 hours of endurance testing. This cell incorporated a Fybex matrix, hybrid-frame, PPF anode, and a 90 Au/10 Pt cathode. This configuration was developed to extend cell life. Two cell plaques with dedicated flow fields and manifolds for all fluids did not exhibit the cell-to-cell electrolyte transfer that limited the operating life of earlier multicell plaques.

Gitlow, B.↗

Selection Factors for Space Crops

NASA is actively researching space crop production to determine its potential to contribute to food system security on long duration missions beyond Low Earth Orbit. Our near-term focus is on nutrient and variety supplementation of prepackaged food with fresh produce that requires little or no processing. The longer-term goal is caloric replacement to become less dependent on Earth, and this will require cultivation of staple crops, processing and cooking equipment, integration with spacecraft air, water, and power systems, and automation. There are numerous technology and knowledge gaps remaining for sustainable space crop production systems, but one high-impact area is in the development of crops specifically customized to meet the needs of controlled environment crop production, astronaut health and well-being, and space-unique environments. Modern crop breeding and genome engineering tools are allowing for rapid development of new genotypes with incredible specificity. Targeted aspects to optimize crops for space have been identified and characterized into five categories: plant growth and development, plant physiology, produce nutrition, produce organoleptic acceptability, and postharvest characteristics. Within each category there are several targets that further the development of crop production systems for spaceflight, such as crop size and harvest index, tolerance to specific environmental stresses, optimizing target nutrients that are low or degrade in the packaged diet, maintenance time requirements, and less indigestible structural material. NASA-funded PIs are already beginning to develop candidate crops, and spaceflight testing and validation of novel space crops is on the horizon. Crops developed for space also have the potential to benefit terrestrial controlled environment agriculture crop production systems. This research was supported by NASA’s Space Biology and Human Research Programs.

Space Crop Production↗

Selection Factors for Space Crops

NASA is actively researching space crop production to determine its potential to contribute to food system security on long duration missions beyond Low Earth Orbit. Our near-term focus is on nutrient and variety supplementation of prepackaged food with fresh produce that requires little or no processing. The longer-term goal is caloric replacement to become less dependent on Earth, and this will require cultivation of staple crops, processing and cooking equipment, integration with spacecraft air, water, and power systems, and automation. There are numerous technology and knowledge gaps remaining for sustainable space crop production systems, but one high-impact area is in the development of crops specifically customized to meet the needs of controlled environment crop production, astronaut health and well-being, and space-unique environments. Modern crop breeding and genome engineering tools are allowing for rapid development of new genotypes with incredible specificity. Targeted aspects to optimize crops for space have been identified and characterized into five categories: plant growth and development, plant physiology, produce nutrition, produce organoleptic acceptability, and postharvest characteristics. Within each category there are several targets that further the development of crop production systems for spaceflight, such as crop size and harvest index, tolerance to specific environmental stresses, optimizing target nutrients that are low or degrade in the packaged diet, maintenance time requirements, and less indigestible structural material. NASA-funded PIs are already beginning to develop candidate crops, and spaceflight testing and validation of novel space crops is on the horizon. Crops developed for space also have the potential to benefit terrestrial controlled environment agriculture crop production systems. This research was supported by NASA’s Space Biology and Human Research Programs.

Space Crop Production↗

Analysis of Water-Energy Issues for Nuclear Power with Industry Perspective

The water-energy nexus is a dynamic, ever evolving challenge involving technological changes, regulatory updates, economic constraints, environmental issues, and political attributes. This report expands on a previous report that gave an initial assessment of the water-energy nexus challenges facing the U.S. commercial industry. This follow-up report provides analysis and insights from stakeholder interviews focusing on the issues faced by the U.S. commercial nuclear energy industry within the water-energy nexus space. This report updates and expand the “Cooling Water Issues and Opportunities at U.S. Nuclear Power Plants” This report includes analysis on water withdrawal and consumption by operating nuclear reactors, evolving policy risks that could impact the operation of the existing commercial nuclear fleet, implications of water markets, trading and water rights, the changing energy grid, progressing environmental risks (including analysis on the possible impact of climate change on water availability and nuclear power plant performance), and opportunities to reduce water related risk. The feedback from the stakeholders’ interviews helps incorporate viewpoints from within the nuclear and related industry that can lack representation in other research areas, without constituting a comprehensive opinion survey. Stakeholders interviewed include nuclear power plants operators, water treatment providers, developers, and vendors of reactor technologies.

99 GENERAL AND MISCELLANEOUS↗

A Fecal Processing Technology Trade Study for Water Recovery in Various Mission Duration Scenarios

To achieve long endurance human space missions such as a trip to Mars, a fully recycled or “closed loop” water system is almost essential. Even for shorter duration missions in Earth orbit, lunar orbit, or on the surface of the moon, recovering and recycling water from as many sources as possible may prove beneficial. One source of water that has not been exploited to date is human solid waste. Herein, a trade study is performed to evaluate the ability of several fecal processing technologies to recover >80% of the water content within the waste. Human solid waste (feces) contains approximately 75% water by mass, which upon quantification, translates to ~170 g of recoverable water per crewmember per day and can scale to values of ~680 kg for a crew of 4 persons on a 1,000-day long exploration mission. Several fecal processing technologies (i.e., steam reforming, vacuum drying, freeze-drying, pyrolysis, ultrasonic drying, etc.) are analyzed using an equivalent system mass (ESM) approach to assess and compare the estimated cost for recovering fecal water – in terms of mass, power, and volume equivalents – against the water recovery mass savings for each technology. Post-use volume is also used as a secondary metric for comparison to quantify the benefits of volume reduction resulting from the fecal drying process. From said analysis, clear patterns and benefits emerge that may prove helpful for future fecal processing technology development and application to space exploration missions.

Trade study↗

Space Resource Requirements for Future In-Space Propellant Production Depots

In 2000 and 2001 studies were conducted at the NASA Marshall Space Flight Center on the technical requirements and commercial potential for propellant production depots in low Earth orbit (LEO) to support future commercial, NASA, and other Agency missions. Results indicate that propellant production depots appear to be technically feasible given continued technology development, and there is a substantial growing market that depots could support. Systems studies showed that the most expensive part of transferring payloads to geosynchronous orbit (GEO) is the fuel. A cryogenic propellant production and storage depot stationed in LEO could lower the cost of missions to GEO and beyond. Propellant production separates water into hydrogen and oxygen through electrolysis. This process utilizes large amounts of power, therefore a depot derived from advanced space solar power technology was defined. Results indicate that in the coming decades there could be a significant demand for water-based propellants from Earth, moon, or asteroid resources if in-space transfer vehicles (upper stages) transitioned to reusable systems using water based propellants. This type of strategic planning move could create a substantial commercial market for space resources development, and ultimately lead toward significant commercial infrastructure development within the Earth-Moon system.

Smitherman, David↗

Comparative techno-economic assessment of osmotically-assisted reverse osmosis and batch-operated vacuum-air-gap membrane distillation for high-salinity water desalination

New developments in pressure- and thermally driven membrane desalination technologies offer the potential to cost-effectively treat high-salinity waters, especially when powered by low-cost solar electricity and thermal energy. This paper presents a comparative techno-economic assessment of the state-of-the-art most promising pressure- and thermally driven membrane technologies for high recovery desalination, namely, osmotically-assisted reverse osmosis (OARO) and batch-operated vacuum-air-gap membrane distillation (batch V-AGMD), to produce potable water while concentrating brine within the range of 140–290 g/L TDS for minimum-liquid-discharge (MLD) and zero-liquid-discharge (ZLD) applications. It is shown that both OARO and batch V-AGMD can treat feedwater and brines with TDS in the range of 30–125 g/L with corresponding fresh water recovery rates of 85–25%. When low cost solar electricity and thermal energy are used, the resulting levelized cost of water (LCOW) from OARO is in the range of 0.70–6.28 $/m 3 , and that from batch-V-AGMD is in the range of 1.74–2.77 $/m 3 . OARO is more cost-effective than batch V-AGMD when feedwater salinity is below 70 g/L and recovery below 75%, whereas batch V-AGMD is more cost-effective at higher recovery rates and salinity levels. Finally, the sensitivity of this comparison on energy prices and module costs is discussed.

42 ENGINEERING↗