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At least 199 records · Page 11

A Relief Zone Architecture for Enhanced Durability of Ultrathin Membranes in Electrochemical Conversion Devices

Premature cell failures in electrochemical conversion systems often result when membrane electrode assemblies (MEAs) are prepared with ultra-thin (= 15 micrometer-thick) polymer electrolyte membranes (PEMs). These high-performance PEMs are susceptible to mechanical degradation from stress concentrations arising from component and device-level integration. Herein, a relief zone was developed to mitigate mechanical degradation by alleviating excess and non-uniform compression across the active area. Relief zones, created through the ablation of carbonaceous diffusion material achieves a seamless adaptation across a range of MEA dimensions and electrochemical applications without need for costly hardware modifications. This concept was demonstrated using fuel cells as a case study. Accelerated stress test (AST) validations yielded a 6-fold improvement for MEAs prepared with relief zones (i.e., lifetime approximately 1500 h) compared to those fabricated using conventional edge-protection techniques, showcasing the utility of this technique in decoupling integration and device-level engineering effects from intrinsic material limitations for durable electrochemical devices.

14 SOLAR ENERGY↗

Design and evaluation of an oxidant-fuel-ratio-zoned rocket injector for high performance and ablative engine compatibility

A method for temperature control of the combustion gases in the peripheral zone of a rocket combustor which would reduce ablative throat erosion, prevent melting of zirconia throat inserts, and maintain high combustion performance is discussed. Included are techniques for analyzing and predicting zoned injector performance, as well as the philosophy and method for accomplishing an optimum compromise between high performance and reduced effective gas temperature. The experimental work was done with a 1000-lbf rocket engine which used as propellants N2O4 and a blend of 50-percent N2H4 and 50-percent UDMH at 100-psia chamber pressure and an overall O/F of 2.0. The method selected to provide temperature control was to use 30 percent of the propellant to form a peripheral zone of combustion gases at an O/F of 1.31 and 2700 K. The remaining 70 percent of the propellant in the core was at an O/F of 2.45 to keep the overall O/F at 2.0.

Winter, J. M.↗

Inner-zone energetic-electron repopulation by radial diffusion.

Quantitative study of the intrusion of natural electrons into the inner radiation zone during and after the geomagnetic storm of Sept. 2, 1966. It is shown that the transport is consistent with a radial-diffusion mechanism in which the first two invariants are conserved. Except for the three-day period of the storm main phase when data were missing, the radial-diffusion coefficient is found to have a value which could be produced by a variation of a large-scale electric field across the magnetosphere having an amplitude of 0.28 mV/m and a period of 1600 sec. Electric fields having approximately these characteristics have been inferred from previous observations of the motion of whistler ducts within the plasmapause. If fields of this amplitude and period exist throughout the magnetosphere, the radial diffusion of all geomagnetically trapped particles except the high-energy inner-zone protons is strongly influenced by electric-field variations. A comprehensive review of previously reported radial-diffusion coefficients shows reasonable agreement for L less than about 3.0, but serious discrepancies among reported values exist for determinations made in the outer zone. These discrepancies cannot be explained by the simple theory of radial diffusion due to variation of large-scale electric or magnetic fields.

Tomassian, A. D.↗

Local-time survey of plasma at low altitudes over the auroral zones.

Local-time survey of the low-energy proton and electron intensities precipitated into the earth's atmosphere over the auroral zones during periods of magnetic quiescence. This survey was constructed by selecting a typical individual satellite crossing of this region in each of eight local-time sectors from a large library of similar observations with the polar-orbiting satellite Injun 5. The trapping boundary for more-energetic electron intensities, E greater than 45 keV, was found to be a 'natural coordinate' for delineating the boundary between the two major types of lower-energy, 50 less than or equal to E less than or equal to 15,000 eV, electron precipitation commonly observed over the auroral zones at low altitudes. Poleward of this trapping boundary inverted 'V' electron precipitation bands are observed in all local-time sectors. These inverted 'V' electron bands in the evening and midnight sectors are typically more energetic and have greater latitudinal widths than their counterparts in the noon and morning sectors. In general, the main contributors to the electron energy influx into the earth's atmosphere over the auroral zones are the electron inverted 'V' precipitation poleward of the trapping boundary in late evening, the plasma-sheet electron intensities equatorward of this boundary in early morning, and both of these precipitation events near local midnight.

Frank, L. A.↗

Effect of fuel zoning and fuel nozzle design on pollution emissions at ground idle conditions for a double-annular ram-induction combustor

An exhaust emission survey was conducted on a double-annular ram induction combustor at simulated ground idle conditions. The combustor was designed for a large augmented turbofan engine capable of sustained flight speeds up to Mach 3.0. The emission levels of total hydrocarbon (THC), carbon monoxide, carbon dioxide, and nitric oxide were measured. The effects of fuel zoning, fuel nozzle design, and operating conditions (inlet temperature and reference Mach number) on the level of these emissions were determined. At an overall combustor fuel/air ratio of 0.007, fuel zoning reduced THC emissions by a factor of 5 to 1. The reduction in THC emissions is attributed to the increase in local fuel/air ratio provided by the fuel zoning. An alternative method of increasing fuel/air ratio would be to operate with larger-than-normal compressor overboard bleed; however, analysis on this method indicated an increase in idle fuel consumption of 20 percent. The use of air-atomizing nozzles reduced the THC emissions by 2 to 1.

Clements, T. R.↗

Impact of ERTS-1 images on management of New Jersey's coastal zone

The thrust of New Jersey's ERTS investigation is development of procedures for operational use of ERTS-1 data by the Department of Environmental Protection in the management of the State's coastal zone. Four major areas of concern were investigated: detection of land use changes in the coastal zone; monitoring of offshore waste disposal; siting of ocean outfalls; and allocation of funds for shore protection. ERTS imagery was not useful for shore protection purposes; it was of limited practical value in the evaluation of offshore waste disposal and ocean outfall siting. However, ERTS imagery shows great promise for operational detection of land use changes in the coastal zone. Some constraints for practical change detection have been identified.

Feinberg, E. B.↗

Zone plate interferometer

A developed form of the Fresner zone-plate interferometer is described. Three basic configurations are distinguished, associated with the real and virtual first order foci of a zone plate. Related versions and higher order variants are also educed. Compensated phase zone plates used in this application are found to produce uniform amplitude wavefronts. The properties of the interferometer in this form are discussed and an example given of its high-quality performance.

Smartt, R. N.↗

The effect of droplets in the air-sea transition zone on the sea brightness temperature

A model is presented which shows that, for a fully developed sea driven by the wind with speeds above 5 m/sec the air in the transition zone immediately above the air-sea interface is mixed with sea water droplets from bursting air bubbles. The absorptive droplet concentration in the zone is assumed to have a profile tapering off from the interface to zero at a certain height. The dielectric constant of the absorptive inhomogeneous droplet profile is thus both a function of the wind speed and the height above the interface. Both the inhomogeneity effect and the absorption-emission effect of the droplet concentration have been considered. Theoretical calculations show that the presence of the absorptive inhomogeneous droplet transition zone significantly increases the sea brightness temperature as wind speed rises. Combined effects of both the droplet areas and the foam areas on sea surface have also been considered.

Tang, C. C. H.↗

Analysis of surface tension driven flow in floating zone melting

Surface tension driven flow in a cylindrical melt suspended between two rods was investigated by numerical solution of the steady state differential equations for heat and momentum transfer. Radiation heating and electron beam heating were considered approximately. For small values of the driving force, one rotating ring was formed in the top half of the zone, and its mirror image in the bottom half. At larger driving forces, secondary cells form which probably would undergo oscillatory motion. The influence of Prandtl number, zone movement, and buoyancy on the convection was also studied. The primary resistance to mass transfer in the laminar regime was in the center of the zone rather than at the solid-liquid interfaces.

Chang, C. E.↗

Float-zone processing in a weightless environment

The results were reported of investigations to: (1) test the validity of analyses which set maximum practical diameters for Si crystals that can be processed by the float zone method in a near weightless environment, (2) determine the convective flow patterns induced in a typical float zone, Si melt under conditions perceived to be advantageous to the crystal growth process using flow visualization techniques applied to a dimensionally scaled model of the Si melt, (3) revise the estimates of the economic impact of space produced Si crystal by the float zone method on the U.S. electronics industry, and (4) devise a rational plan for future work related to crystal growth phenomena wherein low gravity conditions available in a space site can be used to maximum benefit to the U.S. electronics industry.

Fowle, A. A.↗

Spectroscopic far ultraviolet observations of transition zone instabilities and their possible role in a pre-flare energy build-up

Highly flare-productive newly emerging active regions are characterized by numerous small low-lying loops which frequently show a chaotic pattern. Flare activity in such a region subsides as the chaotic loop structures relax and expand into a bipolar configuration. The transition zone in such an active region is highly unstable, as shown by broadened and shifted nonthermal line profiles of medium-ionized elements like Si III, Si IV, and C IV. These transition-zone instabilities, which occur as isolated events in active regions of low flare productivity, are often observed prior to flares. Transition-zone instabilities can be traced to the footpoints of active loops and seem to be accompanied by heating of the loop. The loops vary in size and show differing degrees of activity, with the brightest and most compact ones seemingly being in a pre-flare state which results in the catastrophic energy release along the loop during a flare.

Brueckner, G. E.↗

A statistical study of crater-associated wind streaks in the north equatorial zone of Mars

The physical characteristics of all crater-related streaks within the north equatorial zone of Mars (between 0 and 30 deg N) are studied. The survey includes 25% of the Martian surface area and covers the latitude band of major interest to the Viking missions. Nine characteristic parameters are measured for each of 2325 streaks, of which 82.3% are classified as light tone, 8.1% as dark tone, and 9.6% as mixed tone. The location of streaks in the investigated zone is considered together with the indicated wind regimes, and the characteristics of the streaks and of their associated craters are discussed. The results show that: (1) the streaks are not uniformly distributed throughout the north equatorial zone but are strongly concentrated in certain areas; (2) the density of streaks displays a significant latitude variation not apparently related to terrain type between 0 and 30 deg N; (3) the percentage of craters with streaks reaches a maximum between 10 and 15 deg N and falls off significantly toward both the equator and higher latitudes; and (4) the density of streaks correlates well with geological terrain type.

Veverka, J.↗

EUV spectra from Skylab /1175-1940 A/ - Mass motions in the transition zone in regions of solar activity

The profiles of spectral lines in the 1100-2000-A range emitted by transition-zone ions in regions of solar activity are discussed. The data were recorded by the NRL spectrograph on Skylab. At the spatial resolution of the Skylab spectrograph (2 x 60 arcsec), it is shown that the line profiles result from the superposed emission of a number of physically distinct regions at different electron densities and with different mass motions. Although high densities are found for some surgelike phenomena at transition-zone temperatures, the densities can also be comparable to normal active-region densities. Line profiles, as well as spectral line intensities, must be considered if meaningful theoretical models of dynamic activity in the transition zone are to be constructed.

Doschek, G. A.↗

The 1977 intertropical convergence zone experiment

Data are presented from the 1977 Intertropical Convergence Zone (ITCZ) Experiment conducted in the Panama Canal Zone in July 1977. Measurements were made daily over a 16-day period when the ITCZ moved across the Canal Zone. Two aircraft (Learjet and U-2) flew daily and provided data from horizontal traverses at several altitudes to 21.3 km of ozone, temperature, pressure, water vapor, aerosols, fluorocarbons, methane, nitrous oxide, nitric oxide, and nitric acid. Balloonsondes flown four times per day provided data on ozone, wind fields, pressure, temperature, and humidities to altitudes near 30 km. Rocketsondes provided daily data to altitudes near 69 km. Satellite photography provided detailed cloud information. Descriptions of individual experiments and detailed compilations of all results are provided.

Poppoff, I. G.↗

Dynamics of the solar transition zone

Time-resolved profiles of the 1548-A C IV line arising from the solar transition region are analyzed in order to determine whether the 300-sec oscillations characteristic of the photosphere and chromosphere penetrate into the transition zone and to measure the rms amplitude of transition-zone disturbances as well as their dependence on solar activity. The rms velocity amplitude is used to set limits on the mechanical energy flux available for solar heating. A power-spectrum analysis indicates that acoustic waves appear to have been detected in the transition zone, that at least one case of a strong 200- to 300-sec oscillation was observed, but that strong periodicities are not found on the average in either the intensity or the velocity field. It is suggested that the rms velocity that may be attributed to directly observable wave motion is between 3 and 7 km/s, depending on whether the individual emission elements seen in rocket spectra are coherent or independent in phase.

Bruner, E. C., Jr.↗

The energy balance and pressure in the solar transition zone for network and active region features

The electron pressure and energy balance in the solar transition zone are determined for about 125 network and active region features on the basis of high spectral and spatial resolution extreme ultraviolet spectra. Si III line intensity ratios obtained from the Naval Research Laboratory high-resolution telescope and spectrograph during a rocket flight are used as diagnostics of electron density and pressure for solar features near 3.5 x 10 to the 4th K. Observed ratios are compared with the calculated dependence of the 1301 A/1312 A and 1301 A/1296 A line intensity ratios on electron density, temperature and pressure. Electron densities ranging from 2 x 10 to the 10th/cu cm to 10 to the 12th/cu cm and active region pressures from 3 x 10 to the 15th to 10 to the 16th/cu cm K are obtained. Energy balance calculations reveal the balance of the divergence of the conductive flux and turbulent energy dissipation by radiative energy losses in a plane-parallel homogeneous transition zone (fill factor of 1), and an energy source requirement for a cylindrical zone geometry (fill factor less than 0.04).

Nicolas, K. R.↗

Rocket measurements of energetic particles in the midlatitude precipitation zone

Measurements of energetic ion and electron properties as a function of altitude in the midlatitude zone of nighttime energetic particle precipitation are reported. The measurements of particle fluxes, energy spectra and pitch angle distributions were obtained by a Langmuir probe, six energetic particle spectrometers and an electrostatic analyzer on board a Nike Apache rocket launched near the center of the midlatitude zone during disturbed conditions. It is found that the incident flux was primarily absorbed rather than backscattered, and consists of mainly energetic hydrogen together with some helium and a small energetic electron component. Observed differential energy spectra of protons having an exponential energy spectrum, and pitch angle distributions at various altitudes indicate that the energetic particle flux decreases rapidly for pitch angles less than 70 deg. An energetic particle energy flux of 0.002 ergs/sq cm per sec is calculated which indicates the significance of energetic particles as a primary nighttime ionization source for altitudes between 120 and 200 km in the midlatitude precipitation zone.

Voss, H. D.↗

Science Requirements Working Group (SRWG) in float zone materials processing in space: A review

A summary and history of the Float Zone Working Group was presented. The functions of this working group are to: provide an informal forum of scientific investigators for the exchange of information and ideas in the approach of the solution of common problems in float zone processing, help plan the research and development necessary to place the float zone process on a firm base of scientific understanding and advanced technological development, establish the science requirements for the AFZES for Spacelab, and seek ways to maximize the advantages of the space environment in the pursuit of these goals.

Fowle, A. A.↗