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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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3,192 records · Page 115
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Eliminating chemo-mechanical degradation of lithium solid-state battery cathodes during >4.5 V cycling using amorphous Nb2O5 coatings

Abstract Lithium solid-state batteries offer improved safety and energy density. However, the limited stability of solid electrolytes (SEs), as well as irreversible structural and chemical changes in the cathode active material, can result in inferior electrochemical performance, particularly during high-voltage cycling (>4.3 V vs Li/Li + ). Therefore, new materials and strategies are needed to stabilize the cathode/SE interface and preserve the cathode material structure during high-voltage cycling. Here, we introduce a thin (~5 nm) conformal coating of amorphous Nb 2 O 5 on single-crystal LiNi 0.5 Mn 0.3 Co 0.2 O 2 cathode particles using rotary-bed atomic layer deposition (ALD). Full cells with Li 4 Ti 5 O 12 anodes and Nb 2 O 5 -coated cathodes demonstrate a higher initial Coulombic efficiency of 91.6% ± 0.5% compared to 82.2% ± 0.3% for the uncoated samples, along with improved rate capability (10x higher accessible capacity at 2C rate) and remarkable capacity retention during extended cycling (99.4% after 500 cycles at 4.7 V vs Li/Li + ). These improvements are associated with reduced cell polarization and interfacial impedance for the coated samples. Post-cycling electron microscopy analysis reveals that the Nb 2 O 5 coating remains intact and prevents the formation of spinel and rock-salt phases, which eliminates intra-particle cracking of the single-crystal cathode material. These findings demonstrate a potential pathway towards stable and high-performance solid-state batteries during high-voltage operation.

Science & Technology - Other Topics↗
NASA NTRS1991

Eutelsat 2: SAR-10009 nickel-hydrogen battery

The topics are presented in viewgraph form and include SAR-10009 design features, specific energy, analyses and testing, redundant structural insulation, electronics, corrosion protection, battery cell life cycle tests, and spacecraft launches.

Miller, Lee↗
DOE OSTI2025

Energy 101 - Wind [Slides]

The Energy 101: Wind presentation, developed for the Energy Technology Innovation Partnership Project (ETIPP), provides an overview of wind energy. It covers fundamental concepts, technologies, considerations, case studies, and additional resources.

17 WIND ENERGY↗
NASA NTRS1990

NASA Aerospace Flight Battery Systems Program

The major objective of the NASA Aerospace Flight Battery Systems Program is to provide NASA with the policy and posture to increase and ensure the safety, performance and reliability of batteries for space power systems. The program plan has been modified in the past year to reflect changes in the agency's approach to battery related problems that are affecting flight programs. Primary attention in the Battery Program is being devoted to the development of an advanced nickel-cadmium cell design and the qualification of vendors to produce cells for flight programs. As part of a unified Battery Program, the development of a nickel-hydrogen standard and primary cell issues are also being pursued to provide high-performance NASA Standards and space qualified state-of-the-art primary cells. The resolution of issues is being addressed with the full participation of the aerospace battery community.

Manzo, Michelle A.↗
DOE OSTI2026

Assembly bias and local Primordial non-Gaussianity from DESI DR1 quasars

The analysis of the large-scale clustering of quasars (QSO) observed by the Dark Energy Spectroscopic Instrument (DESI) represents a promising avenue for constraining local Primordial non-Gaussianity (PNG), parameterized by f NL . The signal to be constrained is the scale-dependent bias induced in the 2-point clustering of the considered tracer sample. The resulting constraints on f NL , however, are fully degenerate with the local PNG bias parameter b ϕ , dependent on the assembly bias parameter p. Using IllustrisTNG hydrodynamical simulations, we select a QSO sample reflecting the selection criteria and properties of DESI QSOs, and provide a robust prior for p, and thus for b ϕ , building on the findings of Fondi et al. 2024. We find a distribution with mean p̅ ≃ 1.4 with weak redshift dependence, stable to selection noise and consistent with the expected recent merger history typical of quasar-hosting halos. By comparing with the CAMELS simulations we demonstrate that this prior is robust to astrophysical assumptions and cosmic variance. Finally, applying this prior to the DESI DR1 dataset, we derive updated constraints on local PNG, obtaining f NL = -3.3±9.2.

cosmological parameters from LSS↗
DOE OSTI2022

Internet of Things Data Characterization Process: Pattern of Life Behavioral Data Study

The HoneyBee™ TARDIS LDRD team completed a data scoping study that identified the initial processes and procedures to baseline the normal and expected behaviors during operability and interoperability of Internet of Things (IoT) device networks. This research is the initial step in developing a process (or methodology) to inform a much broader information framework incorporating machine learning to determine device pattern-of-life which enables the detection of abnormal IoT behaviors on an individual device, as well as in the context of a larger network.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2026

In Situ UV–vis Quantification of Chlorobasicity in Binary Molten Chlorides

Optical basicity measurements provide a basis for determining the relative chlorobasicity of a given molten salt composition. This study uses Bi3+ as a spectroscopic probe to investigate optical basicity across three binary molten chloride systems (LiCl-KCl, MgCl2–KCl, and ZnCl2–KCl) through in situ UV–vis spectroscopy measurements of the 1S0→3P1 transition. LiCl-KCl systems exhibit the highest optical basicity with minimal compositional dependence, while both divalent systems show stronger, yet nonlinear, dependence that is reminiscent of acid–base titration curves. The influence of cation electronegativity and polarizing power (Li+ < Mg2+ < Zn2+) directly reflects the basicity curves, with ZnCl2–KCl displaying the steepest gradients and lowest basicity values. Nonlinear dependencies in divalent systems indicate formation of chloride-bridged network structures with coordination states dictated by the amount of KCl in a salt composition, which was further investigated and validated by molecular dynamics simulations of polymeric structures formed in ZnCl2 and MgCl2-based salts using machine learning force fields. The temperature dependence of chlorobasicity in terms of optical basicity was investigated, and a loose, positive correlation between the two was revealed. These findings establish Bi3+ as a sensitive probe for understanding electronic environments in molten chloride systems and provide insights for predicting the chemical behavior of molten salts for use in high-temperature environments.

Buttice, Kailee [Department of Nuclear Engineering↗
NASA NTRS2026

Updated global and regional trends of stratospheric ozone profiles

We present updated evaluation of stratospheric ozone profile trends in the 60° S–60°N latitude range using long-term ground-based and satellite climate data records, as well as simulations by chemistry-climate models. The trends are evaluated using the LOTUS (Long-term Ozone Trends and Uncertainties in the Stratosphere) regression model. Analyses of satellite data confirm the statistically significant positive ozone trends in the period 2000–2024 in the upper stratosphere of ~1–3% per decade, with larger trends at mid-latitudes compared to the tropics. The trends are slightly positive or close to zero in the middle stratosphere, and mostly negative, -1 to -2% per decade, in the lower stratosphere, but they are not statistically significant. The morphology and magnitude of ozone trends are similar to previous analyses (2000–2020 trends). Ozone trends in 2000–2024 predicted by chemistry-climate model simulations are in good agreement with combined satellite trends. In the upper stratosphere, models predict a slightly stronger ozone recovery than observations. In the lower stratosphere, both models and satellite observations report negative trends in the tropics, while modelled ozone trends are slightly positive at mid-latitudes. Ozone profile trends over several stations estimated from ground-based records capture the same overall vertical pattern of ozone trends as merged gridded satellite datasets. Analyses of regional ozone profile trends in 2003–2024 using merged satellite datasets confirmed the previous observations of a longitudinal structure in ozone trends in the NH mid-latitude stratosphere, with positive trends over Scandinavia and negative trends over Siberia. However, the magnitude of this dipole-like structure is reduced compared to previous analyses.

trends↗
NASA NTRS1994

Thermal Testing of High Performance: Thermal Barrier Coatings for Turbine Blades

A 350 micron thick 7 wt.% Y 2 O 3 -ZrO 2 (7YSZ) ceramic Thermal Barrier Coating (TBC) was manufactured in an argon atmosphere and with a strictly controlled substrate temperature on flat IN 600 samples and on IN 100 aircraft turbine blades. This new atmosphere and temperature controlled spraying (ATCS) allows the reduction of the residual stresses and an improvement in the microstructure and in the mechanical properties of the coating. The good performance of these new TBC's was assessed in thermal fatigue and in thermal shock tests carried out in air at 1100°C and at 1280°C respectively. The oxidation rate of the metal-ceramic interface was measured at 1100°C. Failure of the TBC's was induced only by the deterioration (like oxidation, cracking, ...) of the uncoated parts of the samples, as testing temperature was too severe for the base metals. Spalling was thereafter driven by compressive stresses near the aluminum oxide layer at the metal-ceramic interface. The results of these tests underline the good quality of the ceramic coating manufactured by the new ATCS technology.

L Bertamini↗
NASA NTRS2026

Simulating the Lunar Thermal Environment for the Surface-Deployed LEMS Artemis III TVAC Test

The Lunar Environment Monitoring Station (LEMS) is an autonomous, survive-the lunar-night seismic suite to be deployed on the Lunar surface by the Artemis III crew and designed to operate continuously for two years. It will see the extremes of the Lunar south pole thermal environment where surface temperatures range from -200°C to +20°C and where nighttime duration is at least 354 hours. Given power and mass constraints, the thermal system is limited to 2.5 Watts of heat during the lunar night. Presented is the system thermal vacuum test plan and configuration to validate the thermal control system performance in a flight-like environment. The test will measure the nighttime heat leaks for the bus and 18 seismometers to ensure lunar night survival and operability.

Thermal↗
NASA NTRS2026

Simulating the Lunar Thermal Environment for the Surface-Deployed LEMS Artemis III TVAC Test

The Lunar Environment Monitoring Station (LEMS) is an autonomous, survive-the lunar-night seismic suite to be deployed on the Lunar surface by the Artemis III crew and designed to operate continuously for two years. It will see the extremes of the Lunar south pole thermal environment where surface temperatures range from -200°C to +20°C and where nighttime duration is at least 354 hours. Given power and mass constraints, the thermal system is limited to 2.5 Watts of heat during the lunar night. Presented is the system thermal vacuum test plan and configuration to validate the thermal control system performance in a flight-like environment. The test will measure the nighttime heat leaks for the bus and 18 seismometers to ensure lunar night survival and operability.

Thermal↗
NASA NTRS2026

Simulating the Lunar Thermal Environment for the Surface-Deployed LEMS Artemis III TVAC Test

The Lunar Environment Monitoring Station (LEMS) is an autonomous, survive-the lunar-night seismic suite to be deployed on the Lunar surface by the Artemis III crew and designed to operate continuously for two years. It will see the extremes of the Lunar south pole thermal environment where surface temperatures range from -200°C to +20°C and where nighttime duration is at least 354 hours. Given power and mass constraints, the thermal system is limited to 2.5 Watts of heat during the lunar night. Presented is the system thermal vacuum test plan and configuration to validate the thermal control system performance in a flight-like environment. The test will measure the nighttime heat leaks for the bus and 18 seismometers to ensure lunar night survival and operability.

TVAC↗
NASA NTRS1994

Orbital Processing of High-Quality CdTe Compound Semiconductors

CdZnTe crystals were grown in one-g and in micro-g for comparative analysis. The two micro-g crystals were grown in the Crystal Growth Furnace during the First United States Microgravity Laboratory mission (USML-1). The samples were analyzed for chemical homogeneity, structural perfection, and optoelectronic performance (infrared transmission). Fourier Transform Infrared (FTIR) transmission of both ground and flight materials showed that the infrared transmission was close to theoretical, 63% versus 66%, suggesting that the material was close to the stochiometric composition during both the ground and flight experiments. Infrared microscopy confirmed that the principal precipitates were Te and their size (1-10 microns) and density suggested that the primary flight and ground base samples experienced similar cooling rates. Macrosegregation was predicted, using scaling analysis, to be low even in one-g crystals and this was confirmed experimentally, with nearly diffusion controlled growth achieved even in the partial mixing regime on the ground. Radial segregation was monitored in the flight samples and was found to vary with fraction solidified, but was disturbed due to the asymmetric grvitational and thermal fields experienced by the flight samples. The flight samples, however, were found to be much higher in structural perfection than the ground samples produced in the same furnace under identical growth conditions except for the gravitational level. Rocking curve widths were found to be substantially reduced, from 20/35 (one-g) to 9/20 (micro-g) for the best regions of the crystals. The full width at half maximum (FWHM) of 9 arc seconds is as good as the best reported terrestrially for this material. The ground samples were found to have a fully developed mosaic structure consisting of subgrains, whereas the flight sample dislocations were discrete and no mosaic substructure was evident. The defect density was reduced from 50-100,000 (one-g) to 500-25000 EPD (micro-g). These results were confirmed using rocking curve analysis, synchrotron topography, and etch pit analysis. The low dislocation density is thought to have resulted from the near-absence of hydrostatic pressure which allowed the melt to solidify with minimum or no wall contact, resulting in very low stress being exerted on the crystal during growth or during post-solidification cooling.

D J Larson, Jr.↗
NASA NTRS2023

Satellite characterization of global stratospheric sulfate aerosols released by Tonga volcano

Large volcanic eruptions create an enhanced layer of sulfate aerosols in the stratosphere. These sulfuric acid droplets persist for many months, altering the climate and stratospheric chemistry. Sulfate aerosols scatter sunlight back to space, cooling the surface of the Earth and absorb outgoing thermal radiation, heating the stratosphere. The calculation of the climate impact of sulfate aerosols depends on their physical properties such as droplet size and chemical composition. These properties are not well known, and this uncertainty contributes to the errors in climate model predictions. Here we derive the first empirical formula that predicts the composition of stratospheric sulfate aerosols from volcanic eruptions from the air temperature and water vapor pressure. Measurements of atmospheric infrared transmittance of the Hunga Tonga-Hunga Ha'apai sulfate aerosol plume by the Atmospheric Chemistry Experiment (ACE) satellite were analyzed to determine composition (weight percent of sulfuric acid) and median particle radius. These data are supplemented by measurements of the Raikoke and Nabro eruptions. Our analysis allows the properties of volcanic aerosols in the stratosphere to be predicted reliably in atmospheric models.

P Bernath↗
DOE OSTI2024

3D Printing ofThermally Responsive Shape Memory LiquidCrystalline Epoxy Networks

Abstract A two-component liquid crystalline epoxy network (LCEN) with shape memory behavior was developed and evaluated as a candidate material for 3D printing. The cure kinetics of the uncured material and the shape memory properties of the cured LCEN were investigated by using parallel plate rheology and dynamic mechanical analysis, respectively. A commercially available fumed silica additive was introduced to the neat, uncured material to improve the rheological properties for 3D printing. The addition of fumed silica was found to increase the yield stress, shear-thinning behavior, and toughness of the uncured epoxy ink. Polarized light microscopy, differential scanning calorimetry, and wide-angle X-ray scattering measurements between the neat and additive-modified LCEN suggested a reduction in liquid crystalline alignment in the modified LCEN, owing to interactions between crystalline domains and fumed silica, which in turn influenced the mechanical behavior. Overall, the additive was found to be successful in preserving the shape memory properties of LCEN while improving its printability.

Chemistry↗
DOE OSTI2026

Techno-Economic Evaluation of a 600MW Pumped Storage Hydropower Plant using the Pumped Storage Hydropower Valuation Tool

This paper presents a techno-economic evaluation of the proposed 600 MW, 8-hour Craig – Hayden pumped storage hydropower project using the U.S. Department of Energy’s Pumped Storage Hydropower Valuation Tool. The analysis integrates plant technical characteristics, regional grid conditions, and market-based operating assumptions to quantify stacked value streams from energy arbitrage, capacity, ancillary services, transmission congestion relief, and reliability. Both price taker and price influencer frameworks are applied to examine the impact of market participation and system interactions on lifecycle economic performance using Benefit - Cost Analysis and Multi - Criteria Decision Analysis. The results show that the price taker approach provides higher revenue estimates based on exogenous price signals, while the price influencer approach captures production cost savings, renewable curtailment reduction, and market price formation, yielding more conservative but system-representative outcomes. The study demonstrates the strategic value of long-duration PSH for enhancing operational flexibility, resource adequacy, and grid reliability in a high-renewable Western Interconnection.

Bhattacharyya, Arjun [ORNL] (ORCID:000900060976046↗
DOE OSTI2024

Effect of Biomass Water Dynamics in Cosmic-Ray Neutron Sensor Observations: A Long-Term Analysis of Maize–Soybean Rotation in Nebraska

Precise soil water content (SWC) measurement is crucial for effective water resource management. This study utilizes the Cosmic-Ray Neutron Sensor (CRNS) for area-averaged SWC measurements, emphasizing the need to consider all hydrogen sources, including time-variable plant biomass and water content. Near Mead, Nebraska, three field sites (CSP1, CSP2, and CSP3) growing a maize–soybean rotation were monitored for 5 (CSP1 and CSP2) and 13 (CSP3) years. Data collection included destructive biomass water equivalent (BWE) biweekly sampling, epithermal neutron counts, atmospheric meteorological variables, and point-scale SWC from a sparse time domain reflectometry (TDR) network (four locations and five depths). In 2023, dense gravimetric SWC surveys were collected eight (CSP1 and CSP2) and nine (CSP3) times over the growing season (April to October). The N0 parameter exhibited a linear relationship with BWE, suggesting that a straightforward vegetation correction factor may be suitable (fb). Results from the 2023 gravimetric surveys and long-term TDR data indicated a neutron count rate reduction of about 1% for every 1 kg m−2 (or mm of water) increase in BWE. This reduction factor aligns with existing shorter-term row crop studies but nearly doubles the value previously reported for forests. This long-term study contributes insights into the vegetation correction factor for CRNS, helping resolve a long-standing issue within the CRNS community.

Chemistry↗
NASA NTRS1983

The Galileo probe Li/SO2 battery: The safest battery on Jupiter

The unique power requirement of NASA's Galileo Jupiter Probe are most readily met by a Li/SO2 battery; however, because this battery system is not space flight proven, extensive effort was required to qualify this device from the stand point of performance and safety. Due to the rather checkered safety record of the Li/SO2 system, safety has been foremost among the design considerations and has been addressed at the cell, battery and system level. The mission requirements which led to the choice of the Li/SO2 battery and the safety engineering which went into the battery and power system design are described.

Marcoux, L. S.↗