LEED studies of oxygen adsorption on the /111/ and /110/ surfaces of aluminum
LEED studies of oxygen adsorption on /111/ and /110/ surfaces of Al single crystals
Bedair, S. M.↗
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Preferential polymerization and adsorption of L-optical isomers of amino acids relative to D-optical isomers on kaolinite templates.
Experiments on the polymerization of the L- and D-optical isomers of aspartic acid and serine using kaolinite as a catalyst showed that the L-optical isomers were polymerized at a much higher rate than the D-optical isomers; racemic (DL-) mixtures were polymerized at an intermediate rate. The peptides formed from the L-monomers were preferentially adsorbed by the clay. In the absence of kaolinite, no significant or consistent difference in the behavior of the L- and D-optical isomers was observed. In experiments on the adsorption of L- and D-phenylalanine by kaolinite, the L-optical isomer was preferentially adsorbed.
Jackson, T. A.↗
Operating Room Environment Control. Part A: a Valve Cannister System for Anesthetic Gas Adsorption. Part B: a State-of-the-art Survey of Laminar Flow Operating Rooms. Part C: Three Laminar Flow Experiments
An anesthetic gas flow pop-off valve canister is described that is airtight and permits the patient to breath freely. Once its release mechanism is activated, the exhaust gases are collected at a hose adapter and passed through activated coal for adsorption. A survey of laminar air flow clean rooms is presented and the installation of laminar cross flow air systems in operating rooms is recommended. Laminar flow ventilation experiments determine drying period evaporation rates for chicken intestines, sponges, and sections of pig stomach.
Meyer, J. S.↗
On the asymmetric adsorption of phenylalanine enantiomers by kaolin.
The attempt is described to verify a recent report that kaolin adsorbs D- and L-phenylalanine enantiomers to different extents from aqueous solutions at both pH 5.8 and pH 2. No evidence whatsoever could be found for the differential adsorption of D- versus L-phenylalanine by kaolin from either pH 6 or pH 2 solutions.
Bonner, W. A.↗
Hydrogen adsorption and diffusion, and subcritical-crack growth in high-strength steels and nickel base alloys
Coordinated studies of the kinetics of crack growth and of hydrogen adsorption and diffusion were initiated to develop information that is needed for a clearer determination of the rate controlling process and possible mechanism for hydrogen enhanced crack growth, and for estimating behavior over a range of temperatures and pressures. Inconel 718 alloy and 18Ni(200) maraging steel were selected for these studies. 18Ni(250) maraging steel, 316 stainless steel, and iron single crystal of (111) orientation were also included in the chemistry studies. Crack growth data on 18Ni(250) maraging steel from another program are included for comparison. No sustained-load crack growth was observed for the Inconel 718 alloy in gaseous hydrogen. Gaseous hydrogen assisted crack growth in the 18Ni maraging steels were characterized by K-independent (Stage 2) extension over a wide range of hydrogen pressures (86 to 2000 torr or 12 kN/m2 to 266 kN/m2) and test temperatures (-60 C to +100 C). The higher strength 18Ni(250) maraging steel was more susceptible than the lower strength 200 grade. A transition temperature was observed, above which crack growth rates became diminishingly small.
Wei, R. P.↗
Adsorption and condensation of Cu on W single-crystal surfaces
The adsorption and condensation of Cu up to several monolayers in thickness on tungsten 110 and 100 single-crystal surfaces are studied by combining low-energy electron diffraction, Auger electron spectroscopy, thermal desorption spectroscopy, work-function measurements, and quartz microbalance thickness measurements in one experimental system. The results show drastic differences in the evolution of the structure, work function, and desorption behavior between 110 and 100 surfaces. These differences are understandable in terms of the atomic roughness of the surfaces.
Bauer, E.↗
Adsorption of Ar on a nonuniform MgO surface
Data are presented for the adsorption of Ar and N2 on a strongly heterogeneous MgO surface at 84 K and for Ar at a range of temperatures between 130 and 250 K. The high-temperature data are analyzed according to a model which separates the contributions to the potential into bulk and surface terms, providing a method for the determination of the surface area from parameters characteristic of the bulk material. A solid-gas energy parameter and parameters indicating the strength of the impurity sites are also evaluated.
Hinman, D. C.↗
The adsorption and early stages of condensation of Ag and Au on W single-crystal surfaces
Silver and gold were evaporated up to several monolayers in thickness onto W single-crystal surfaces of the 110 and 100 plane types in the temperature range between 300 and 1300 K. The mode of growth and the structure of the layers were studied by Auger electron spectroscopy and low-energy electron diffraction. The results are compared with thermal desorption spectroscopy data and work-function change measurements. They show certain similarities but also some striking differences between the two systems Ag/W and Au/W as well as a strong crystallographic anisotropy of adsorption and condensation.
Bauer, E.↗
A helium adsorption pump for temperatures between 0.71 and 1.2 K
The construction and method of working of a helium adsorption pump are described. The flux of helium-2 film can be suppressed by an appropriate construction, which permits it to reach temperatures down to 0.71 K. By total utilization of the pump's cross-section, temperatures from 1.2 K to 0.71 K remain constant for several hours with a precision of 0.001 K.
Frommann, G.↗
Mars - Regolith adsorption and the relative concentrations of atmospheric rare gases
Laboratory measurements of Kr and Xe adsorption on samples of ground montmorillonite, limonite and basalt at -77 C have been performed. Results suggest that (1) most degassed martian Xe could be adsorbed on a regolith with a large effective surface area, and (2) if this is the case the elemental composition of martian nonradiogenic rare gas (counting that in the regolith) may be virtually identical to that of ordinary chondrites.
Fanale, F. P.↗
Adsorption of hydrogen chloride on microcrystalline silica
The interaction of hydrogen chloride with quartz was studied to determine the extent to which silica can irreversibly remove hydrogen chloride from the atmosphere. Adsorption isotherms were measured at 30 C for hydrogen chloride on silica outgassed between 100 C and 400 C. Readsorption isotherms were also measured. The silica surface was characterized further by infrared spectroscopy, electron spectroscopy for chemical analysis, scanning electron microscopy, and immersional calorimetry. Ground debris samples obtained from the Kennedy Space Center, were likewise examined.
Kang, Y.↗
Adsorption bed models used in simulation of atmospheric control systems
Two separate techniques were used to obtain important basic data for the adsorption of seven liquid and eight gaseous trace contaminants. A columetric system used in previous HSC studies was modified to determine the HSC capacity of all the contaminants. A second study of six of the liquids was performed in a gas chromatorgraph. The results of these two studies are reported in two parts. First, a brief summary of the chromatographic results are given. Second, a thesis is given which reports in some detail the results of the volumetric studies. Comparison of the data that are common to both studies are also included.
Davis, S. H.↗
Some effects of gas adsorption on the high temperature volatile release behavior of a terrestrial basalt, tektite and lunar soil
Mass pyrograms obtained from high-temperature, mass psectrometric pyrolysis of a glassy theoleiitic submarine basalt and a tektite, ground in air to less than 64 microns, have shown N2 and SO release patterns very similar to those from the pyrolysis of mature lunar soil fines. The N2 and CO release behavior from the terrestrial samples reproduces the biomodal, high-temperature (approximately 700 and 1050 C) features from the lunar samples. Unground portions of the basalt and tektite show no release of N2 and CO during pyrolysis. Grinding also alters the release behavior and absolute amounts of H2O and CO2. It is suggested that adsorption of atmospheric gases in addition to solar wind implantation of ions may account for the wide range of values in previously reported concentrations of carbon and nitrogen from lunar fines.
Graham, D. G.↗
An experimental study of adsorption interference in binary mixtures flowing through activated carbon
The isothermal transmission through activated carbon adsorber beds at 25 C of acetaldehyde-propane and acetylene-ethane mixtures in a helium carrier gas was measured. The inlet concentration of each component was in the range between 10 ppm and 500 ppm. The constant inlet volumetric flow rate was controlled at 200 cc (STP)/min in the acetaldehyde-propane experiments and at 50 cc (STP)/min in the acetaldehyde-ethane experiments. Comparison of experimental results with the corresponding single-component experiments under similar conditions reveals interference phenomena between the components of the mixtures as evidenced by changes in both the adsorption capacity and the dispersion number. Propane was found to displace acetaldehyde from the adsorbed state. The outlet concentration profiles of propane in the binary mixtures tend to become more diffuse than the corresponding concentration profiles of the one-component experiments. Similar features were observed with mixtures of acetylene and ethane; however, the displacement of acetylene by ethane is less pronounced.
Madey, R.↗
Interaction of metal ions and amino acids - Possible mechanisms for the adsorption of amino acids on homoionic smectite clays
A semiempirical molecular orbital method is used to characterize the binding of amino acids to hexahydrated Cu(2+) and Ni(2+), a process presumed to occur when they are adsorbed in the interlamellar space of homoionic smectite clays. Five alpha-amino acids, beta-alanine, and gamma-aminobutyric acid were used to investigate the metal ion and amino acid specificity in binding. It was assumed that the alpha, beta, and gamma-amino acids would bind as bidentate anionic ligands, forming either 1:1 or 1:2 six-coordinated five, six, and seven-membered-ring chelate complexes, respectively. Energies of complex formation, optimized geometries, and electron and spin distribution were determined; and steric constraints of binding of the amino acids to the ion-exchanged cations in the interlamellar spacing of a clay were examined. Results indicate that hexahydrated Cu(2+) forms more stable complexes than hexahydrated Ni(2+) with all the amino acids studied. However, among these amino acids, complex formation does not favor the adsorption of the biological subset. Calculated energetics of complex formation and steric constraints are shown to predict that 1:1 rather than 1:2 metal-amino acid complexes are generally favored in the clay.
Gupta, A.↗
Miniature J-T refrigators using adsorption compressors
More sophisticated cooling systems for the employed detectors will be needed to satisfy the demand for higher resolution and sensitivity of various detectors used in space missions. The design of the cooling system must take into consideration the unique environment of space vehicles. It is pointed out that a deep space vehicle usually has an ample supply of waste heat from a radioisotope thermoelectric generator (RTG) and has a heat sink near zero Kelvin. Passive radiative coolers have been used for cooling temperatures above 90 K. Cooling below 90 K is currently handled by phase changes of solid or liquid cryogens or mechanical refrigeration. However, the weight of the cryogen may be a problem in a long duration space mission. Refrigerators of small cooling capacity are required in many spacecraft applications. For some future NASA missions, a multistage Joule-Thomson refrigerator using adsorption compressors appears particularly attractive. A study is discussed of four different refrigeration stages which use charcoal as the adsorbent. The adsorbed gases are nitrogen, helium, hydrogen, and neon.
Chan, C. K.↗
CO adsorption on (111) and (100) surfaces of the Pt sub 3 Ti alloy. Evidence for parallel binding and strong activation of CO
The CO adsorption on a 40 atom cluster model of the (111) surface and a 36 atom cluster model of the (100) surface of the Pt3Ti alloy was studied. Parallel binding to high coordinate sites associated with Ti and low CO bond scission barriers are predicted for both surfaces. The binding of CO to Pt sites occurs in an upright orientation. These orientations are a consequence of the nature of the CO pi donation interactions with the surface. On the Ti sites the orbitals donate to the nearly empty Ti 3d band and the antibonding counterpart orbitals are empty. On the Pt sites, however, they are in the filled Pt 5d region of the alloy band, which causes CO to bond in a vertical orientation by 5 delta donation from the carbon end.
Mehandru, S. P.↗
Adsorption and recombination of hydrogen atoms on a model graphite surface
The adsorption and recombination of atomic hydrogen on a model graphite grain have been examined in a series of calculations in which a modified, iterative, extended Hueckel program was used. The hydrogen atom is found to be chemisorbed at a site with a zero-point binding energy of 0.7 eV and at an equilibrium distance of 2.25 A above the site. Despite a barrier of about 0.4 eV between adjacent sites, calculations suggest that at temperatures as low as 10 K, an H atom will tunnel through to adjacent sites in less than one nanosecond. However, a potential barrier to the recombination of two hydrogen atoms has been found which displays high sensitivity to the mutual arrangement of the two hydrogen atoms with respect to the graphite surface. Results show that at very low temperatures, recombinations can occur only by tunneling. Consistent with experiment, the region in which H2 begins to form exhibits a repulsive potential with respect to possible chemisorption of the incipient H2 entity.
Aronowitz, S.↗