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At least 217 records · Page 12

First estimate of annual mercury flux at the Kilauea main vent

Mercury and sulphur dioxide analyses were conducted from 1971 to 1980 on air samples collected immediately downwind of Halemaumau, the Kilauea main vent, in Hawaii. On the basis of these measurements, an Hg/SO2 ratio of 0.00051 has been derived which, when applied to the recently determined SO2 mass output of Halemaumau, yields a calculated Hg flux of 2.6 x 10 to the 8th g annually. This rate is consistent with Varekamp and Busek's (1981) evidence suggesting that volcanogenic Hg significantly contributes to the atmospheric total.

Siegel, S. M.↗

Tropospheric sources of NO(x) - Lightning and biology

Laboratory tests were performed to quantify the expected NO(x) production by lightning and biological processes. Attention was focused on energy deposition by lightning and the oxygen partial pressure of soil, and one-dimensional photochemical models were defined for the tropospheric distributions of NO and HNO3 for various NO source strengths. The Lightning Facility data were compared with air samples of N2O production gathered during over 2 yr of flights through storms. Soil NO(x) productions were studied in terms of nitrification processes involving Nitrosomonas europaea and Alcaligenes faecalis bacteria, which change ammonium to nitrite and release NO and N2O as byproducts. The results indicate that atmospheric NO(x) is generated at two tropospheric levels, with lightning and soil bacteria being significant contributors.

Levine, J. S.↗

Global atmospheric concentrations and source strength of ethane

A study of the variation in ethane (C2H6) concentration between northern and southern latitudes over three years is presented together with a new estimate of its source strength. Ethane concentrations vary from 0.07 to 2 p.p.b.v. (parts per billion by volume) in air samples collected in remote surface locations in the Pacific (latitude 71 N-47 S) in all four seasons between September 1984 and June 1985. The variations are consistent with southerly transport from sources located chiefly in the Northern Hemisphere, further modified by seasonal variations in the strength of the reaction of C2H6 with OH radicals. These global data can be combined with concurrent data for CH4 and the laboratory reaction rates of each with OH to provide an estimate of three months as the average atmospheric lifetime for C2H6 and 13 + or - 3 Mtons for its annual atmospheric release.

Blake, D. R.↗

C-13/C-12 ratio in methane from the flooded Amazon forest

The C1-C4 hydrocarbon concentrations and the C-13/C-12 ratio in CH4 detected in air samples collected in the Amazon region (3.5 deg S latitude and 5.9 deg W longitude) are analyzed. It is observed that the CH4 concentrations of each sample are enhanced over the background concentration for remote locations, and the C-13/C-12 ratio in this biogenic methane is depleted in C-13 relative to atmospheric CH4. It is concluded, from the C2-C4 hydrocarbon data, that minor yields of C2-C4 hyrocarbons are released coincident with CH4; however, the minor yields do not contribute to the regionally enhanced concentrations of hydrocarbons found in Amazonia and the global atmosphere release of C2-C4 compounds.

Tyler, Stanley C.↗

Infrared spectroscopic measurements of halogenated source gases in the stratosphere with the ATMOS instrument

The volume mixing ratios of the six most important halogenated source species (CH3Cl, CF2Cl2, CFCl3, CHF2Cl, CCl4, and CF4) have been retrieved over the 10- to 30-km altitude range from the analysis of 0.01/cm resolution infrared solar occultation spectra recorded near 30 deg N and 47 deg S latitudes with the ATMOS (Atmospheric Trace Molecule Spectroscopy) instrument, operating from on board Spacelab 3 (April-May 1985). The results reported here, although in satisfactory agreement with recent in situ values obtained from air sampling techniques, are limited in accuracy by the limited absorption representative of most of the species and by uncertainties in the spectroscopic parameters currently available for these gases. They demonstrate, however, the power of the IR remote sensing approach for evaluating on a global scale the total chlorine budget of the atmosphere, and they provide an independent set of simultaneous data acquired for the important source and reservoir halogenated molecular species in the upper atmosphere.

Zander, R.↗

Calibration-Tube Dewar

Container maintains reference material for gas chromatography at constant temperature for extended periods. Developed for holding peroxyacetylnitrate (PAN), material unstable at room temperature but stable at 0 degree C. Keeps vial of PAN at this temperature by immersing in mixture of water and ice. Perforated tube surrounds vial, protects from damage by ice but allows cold water to circulate around. Plug with handle removable so ice added through filler tube. O-rings seal joints around removable parts. Substances undergoing phase changes at other temperatures substituted for ice and water if different reference materials and storage temperatures used. Used on research aircraft collecting and analyzing air samples in troposphere and stratosphere.

Herlth, Donald B.↗

In-situ measurements of total reactive nitrogen, total water vapor, and aerosols in polar stratospheric clouds in the Antarctic stratosphere

Measurements of total reactive nitrogen, NOy, total water vapor, and aerosols were made as part of the Airborne Antarctic Ozone Experiment. The measurements were made using instruments located onboard the NASA ER-2 aircrafts which conducted twelve flights over the Antarctic continent reaching altitudes of 18 km at 72 S latitude. Each instrument utilized an ambient air sample and provided a measurement up to 1 Hz or every 200 m of flight path. The data presented focus on the flights of Aug. 17th and 18th during which Polar Stratospheric Clouds (PSCs) were encountered containing concentrations of 0.5 to 1.0 micron diameter aerosols greater than 1 cm/cu. The temperature pressure during these events ranged as low as 184 K near 75 mb pressure, with water values near 3.5 ppm by volume (ppmv). With the exception of two short periods, the PSC activity was observed at temperatures above the frost point of water over ice. The data gathered during these flights are analyzed and presented.

Fahey, D. W.↗

Measurements of nitric oxide in the stratosphere at 44 N in autumn

Precision of the chemiluminescent instrument for balloon-borne NO measurement was improved by precise determinations of the flow rates of the sample air and the calibration NO in N2 gas. Based on the new calibration of these values, NO mixing ratio in the stratosphere was reanalyzed. The revision of the NO data does not at all alter the form of the diurnal variation. The average of the four NO profiles between 15 and 32 km obtained at 44 N in autumn is given.

Kondo, Y.↗

In situ measurements of total reactive nitrogen, total water, and aerosol in a Polar Stratospheric Cloud in the Antarctic

Measurements of total reactive nitrogen, NOy, total water vapor, and aerosols were made as part of the Airborne Antarctic Ozone Experiment. The measurements were made using instruments located onboard the NASA ER-2 aircrafts which conducted twelve flights over the Antarctic continent reaching altitudes of 18 km at 72 S latitude. Each instrument utilized an ambient air sample and provided a measurement up to 1 Hz or every 200 m of flight path. The data presented focus on the flights of Aug. 17th and 18th during which Polar Stratospheric Clouds (PSCs) were encountered containing concentrations of 0.5 to 1.0 micron diameter aerosols greater than 1 cm/cu. The temperature pressure during these events ranged as low as 184 K near 75 mb pressure, with water values near 3.5 ppm by volume (ppmv). With the exception of two short periods, the PSC activity was observed at temperatures above the frost point of water over ice. The data gathered during these flights are analyzed and presented.

Fahey, D. W.↗

Trace gases in the Antarctic Atmosphere

Whole-air samples collected aboard the NASA ER-2 and DC-8 aircraft as part of the Airborne Antarctic Ozone Experiment were analyzed in a field laboratory set up at Punta Arenas, Chile. Mixing ratios obtained from gas chromatographic analyses of these samples are presented for CH4, CO, N2O, CFCl3, CF2Cl2, C2F3Cl3, CH3CCl3, and CCl4. A comparison of CFCl3/N2O mixing ratios from the flights of September 16-29, 1987 provides evidence of sustained subsidence.

Heidt, L. E.↗

NASA/USRA high altitude reconnaissance aircraft

At the equator, the ozone layer ranges from approximately 80,000 to 130,000+ feet which is beyond the capabilities of the ER-2, NASA's current high altitude reconnaissance aircraft. This project is geared to designing an aircraft that can study the ozone layer at the equator. This aircraft must be able to cruise at 130,000 lbs. of payload. In addition, the aircraft must have a minimum of a 6,000 mile range. The low Mach number, payload, and long cruising time are all constraints imposed by the air sampling equipment. A pilot must be able to take control in the event of unforseen difficulties. Three aircraft configurations were determined to be the most suitable for meeting the above requirements, a joined-wing, a bi-plane, and a twin-boom conventional airplane. The techniques used have been deemed reasonable within the limits of 1990 technology. The performance of each configuration is analyzed to investigate the feasibility of the project requirements. In the event that a requirement can not be obtained within the given constraints, recommendations for proposal modifications are given.

Richardson, Michael↗

The Colorado/Missouri 1989 cirrus mini IFO

A series of experiments with aircraft were planned for Nov. and Dec. 1989 to study cirrus ice crystal nucleation mechanisms and to test new aircraft instrumentation. The measurements were conducted using the NCAR Sabreliner and King Air. Sampling was conducted near Boulder, Colorado, in lenticular (mountain wave) clouds, and over Missouri in cirrus generating cells. Field samples of aerosol and ice crystal replicas and melt water from these cirrus clouds were collected and studied. Aircraft instrumentation and sampling techniques are discussed.

Heymsfield, Andrew J.↗

Advanced aircraft for atmospheric research

The development of aircraft for high-altitude research is described in terms of program objectives and environmental, technological limitations, and the work on the Perseus A aircraft. The need for these advanced aircraft is proposed in relation to atmospheric science issues such as greenhouse trapping, the dynamics of tropical cyclones, and stratospheric ozone. The implications of the study on aircraft design requirements is addressed with attention given to the basic categories of high-altitude, long-range, long-duration, and nap-of-the-earth aircraft. A strategy is delineated for a platform that permits unique stratospheric measurements and is a step toward a more advanced aircraft. The goal of Perseus A is to carry scientific air sampling payloads weighing at least 50 kg to altitudes of more than 25 km. The airfoils are designed for low Reynolds numbers, the structural weight is very low, and the closed-cycle power plant runs on liquid oxygen.

Russell, P.↗

Field-Domain Ion Spectrometry

Field-domain ion spectrometry (FDIS) is variant of established technique known as ion-mobility spectrometry. Operates at atmospheric pressure and only requires small pump to draw air sample into instrument. Strength of retarding electric field varied to distinguish among ions of different mobilities. New concept offers potential for development of small, (hand-held), low-power, portable devices detecting airborne chemical substances in real-time at concentrations at parts-per-billion level.

Bowers, W. D.↗

NASA/USRA high altitude research aircraft. Gryphon: Soar like an eagle with the roar of a lion

At the equator, the ozone layer ranges from 65,000 to 130,000+ feet. This is beyond the capabilities of the ER-2, which is NASA's current high altitude reconnaissance aircraft. The Universities Space Research Association, in cooperation with NASA, is sponsoring an undergraduate program which is geared to designing an aircraft that can study the ozoned layer at the equator. This aircraft must be able to satisfy four mission profiles. Mission one is a polar mission which ranges from Chile to the South Pole and back to Chile, a total range of 6000 n. mi. at 100,000 feet with a 2500 lb. payload. The second mission is also a polar mission with a decreased altitude of 70,000 feet and an increased payload of 4000 lb. For the third mission, the aircraft will take-off at NASA Ames, cruise at 100,000 feet carrying a 2500 lb. payload, and land in Puerto Montt, Chile. The final mission requires the aircraft to take-off at NASA Ames, cruise at 100,000 feet with a 1000 lb. payload, make an excursion to 120,000 feet, and land at Howard AFB, Panama. All three missions require that a subsonic Mach number be maintained due to constraints imposed by the air sampling equipment. The aircraft need not be manned for all four missions. Three aircraft configurations were determined to be the most suitable for meeting the above requirements. The performance of each configuration is analyzed to investigate the feasibility of the project requirements. In the event that a requirement can not be obtained within the given constraints, recommendations for proposal modifications are given.

Rivera, Jose↗

The HAMMER: High altitude multiple mission environmental researcher

At the equator, the ozone layer ranges from 65,000 to 130,000+ feet which is beyond the capabilities of the ER-2, NASA's current high altitude reconnaissance aircraft. The Universities Space Research Association, in cooperation with NASA, is sponsoring an undergraduate program which is geared to designing an aircraft that can study the ozone layer at the equator. This aircraft must be able to satisfy four mission profiles. Mission one is a polar mission which ranges from Chile to the South Pole and back to Chile, a total range of 6000 n. mi. at 100,000 feet with a 2500 lb. payload. The second mission is also a polar mission with a decreased altitude of 70,000 feet and an increased payload of 4000 lb. For the third mission, the aircraft will take-off at NASA Ames, cruise at 100,000 feet carrying a 2500 lb. payload, and land in Puerto Montt, Chile. The final mission requires the aircraft to take-off at NASA Ames, cruise at 100,000 feet with a 1000 lb. payload, make an excursion to 120,000 feet, and land at Howard AFB, Panama. All three missions require that a subsonic Mach number is maintained due to constraints imposed by the air sampling equipment. The aircraft need not be manned for all four missions. Three aircraft configurations were determined to be the most suitable for meeting the above requirements. The performance of each configuration is analyzed to investigate the feasibility of the project requirements. In the event that a requirement can not be obtained within the given constraints, recommendations for proposal modifications are given.

Hayashi, Darren↗

SHARP: Subsonic High Altitude Research Platform

The Universities Space Research Association is sponsoring an undergraduate program which is geared to designing an aircraft that can study the ozone layer at the equator. This aircraft must be able to satisfy four mission profiles. Mission one is a polar mission that ranges from Chile to the South Pole and back to Chile, a total range of 6000 n.mi. at 100,000 ft with a 2500 lb payload. The second mission is also a polar mission, with an altitude of 70,000 ft and an increased payload of 4000 lbs. For the third mission, the aircraft will takeoff at NASA Ames, cruise at 100,000 ft carrying a 2500 lb payload, and land at Puerto Montt, Chile. The final mission requires the aircraft to take off at NASA Ames, cruise at 100,000 ft with a 1000 lb payload, make an excursion to 120,000 ft, and land at Howard AFB, Panama. Three missions require that a subsonic Mach number be maintained due to constraints imposed by the air sampling equipment. The aircraft need not be manned for all four missions. Three aircraft configurations have been determined to be the most suitable for meeting the above requirements. In the event that a requirement cannot be obtained within the given constraints, recommendations for proposal modifications are given.

Beals, Todd↗

Global Kinetic Constants for Thermal Oxidative Degradation of a Cellulosic Paper

Values of global kinetic constants for pyrolysis, thermal oxidative degradation, and char oxidation of a cellulosic paper were determined by a derivative thermal gravimetric study. The study was conducted at heating rates of 0.5, 1, 1.5, 3, and 5 C/min in ambient atmospheres of nitrogen, 0.28, 1.08, 5.2 percent oxygen concentrations, and air. Sample weight loss rate, concentrations of CO, CO2, and H2O in the degradation products, and oxygen consumption were continuously measured during the experiment. Values of activation energy, preexponential factor, orders of reaction, and yields of CO, CO2, H2O, total hydrocarbons, and char for each degradation reaction were derived from the results. Heat of reaction for each reaction was determined by differential scanning calorimetry. A comparison of the calculated CO, CO2, H2O, total hydrocarbons, sample weight loss rate, and oxygen consumption was made with the measured results using the derived kinetic constants, and the accuracy of the values of kinetic constants was discussed.

Kashiwagi, Takashi↗